Activity 151-2 Dimensional Analysis Directions: This Guided Learning Activity (GLA) focuses on using dimensional analysis to solve chemical problems. Part A describes the dimensional analysis approach, Part B discusses how to identify conversion factors for dimensional analysis, and Part C gives examples of using dimensional analysis to solve chemical problems. The worksheet is accompanied by instructional videos. Please visit http://www.canyons.edu/Departments/CHEM/GLA for additional materials. Part A β Dimensional Analysis Strategy In chemistry, many calculations rely on the units used to express the quantities. Many of the problems you see will utilize a process termed dimensional analysis, or the factor-based method. Dimensional analysis involves adding, subtracting, dividing, and multiplying units just as you would real numbers. When using dimensional analysis, we βcancelβ units to guide the problem solving strategy. Dimensional Analysis Strategy 1. Write known measurements with their units as fractions. If the measurement has multiple units, write the units separately. 9.35 ππππ 7.87 ππ 9.35 mL becomes οΏ½ οΏ½ 7.87 g/cm3 becomes οΏ½ 3οΏ½ 1 1 ππππ 2. Identify equalities that relate the given units to the desired units, and write these equalities as conversion factors by dividing one side by the other. 1 ππππ3 οΏ½ 1 ππππ 1 mL = 1 cm3 becomes οΏ½ 1 ππππ οΏ½ 1 ππππ3 or οΏ½ 453.6 ππ οΏ½ 1 ππππ. 1 lb. = 453.6 g becomes οΏ½ 1 ππππ. οΏ½ 453.6 ππ or οΏ½ 3. Multiply given quantities by conversion factors that allow you to βcancelβ unwanted units (divide like units), and acquire desired units. 9.35 ππππ 1 ππππ3 οΏ½ οΏ½οΏ½ οΏ½ = 9.35 ππππ3 1 ππππ 1 οΏ½ 1 ππππ. ππππ. 7.87 ππ οΏ½οΏ½ οΏ½ = 0.174 3 3 453.6 ππ ππππ 1 ππππ Chemistry Guided Learning Activities Activity 151 β 2 College of the Canyons Page 1 of 4 Example #1. How many jelly beans will fit in a 32.0 oz. mason jar? To solve this problem, we must know how much space is occupied by a single jelly bean. If we know that one jelly bean occupies 3.5 cm3, then we can write: We must also know the unit conversion between ounces and cubic centimeters: The goal of dimensional analysis is to arrange the conversion factors in a way that will allow unwanted units to divide out, or βcancel.β Part B β Identifying Conversion Factors for Dimensional Analysis One of the challenging parts of dimensional analysis is learning how to identify and write conversion factors. Here are a few common types of dimensional analysis conversion factors: 1. Unit Conversion Factors Example: An inch is equivalent to 2.54 cm, 0.254 m, and 1/12 ft. Conversion Factors: οΏ½ ππ ππππ. ππ.ππππ ππππ οΏ½ οΏ½ ππ ππ ππππππ ππππ οΏ½ οΏ½ ππππ ππππ. ππ ππππ οΏ½ 2. Physical Properties or Quantities like density, percent composition, concentration, or speed Example: A 68% nitric acid solution has a concentration of 15.8 M and a density of 1.42 g/cm3 Conversion Factors: οΏ½ ππππ ππ ππππππππππππ ππππππππ ππππππ ππ ππππππππππππππππ οΏ½ οΏ½ ππππ.ππ ππππππππ ππππππππππππ ππππππππ ππ π³π³ ππππππππππππππππ 3. Stoichiometric Coefficients Example: πΆπΆ3 π»π»8 (ππ) + 5ππ2 (ππ) β 3πΆπΆππ2 (ππ) + 4π»π»2 ππ(ππ) Conversion Factors: οΏ½ ππ ππππππππ πΆπΆππ ππ ππππππππ πͺπͺππ π―π―ππ οΏ½ οΏ½ ππ ππππππππ πͺπͺπΆπΆππ ππ ππππππππ πΆπΆππ οΏ½ οΏ½ ππ.ππππ ππ ππππππππππππ ππππππππ ππ ππππππ ππππππππππππππππ οΏ½ βπ»π»ππππππ = β2220 ππππ οΏ½ οΏ½ βππππππππ ππππ ππ ππππππππ πͺπͺππ π―π―ππ οΏ½ *Mole conversions and stoichiometry are discussed in more detail in GLA 151-8 and GLA 1519. Please refer to these for further guidance. * Chemistry Guided Learning Activities Activity 151 β 2 College of the Canyons Page 2 of 4 Keep in mind that the conversion factor that is used is chosen based on the given units and the desired units, so these must be identified at the beginning of each problem. Example #2. Perform the following calculations by identifying and employing appropriate conversion factors. a. A pharmaceutical company produced 7885 g of a drug in one reactor. If one tablet of the drug will contain 425 mg, how many tablets can be prepared from that reactor? Given unit: grams Desired unit: tablets ππππππππ ππ ππππππππ ππππ ππ ππππππππππππ οΏ½ οΏ½οΏ½ οΏ½οΏ½ οΏ½ = ππππ, ππππππ ππππππππππππππ ππ ππ ππ ππππππ ππππ b. Miaβs car has an average mileage of 26 miles per gallon, and has a 16.0 gallon gas tank. How many times can Mia go to work (8.4 mile round trip) before needing to refill the tank? Part C β Performing Multiple Unit Conversions Often, conversion factors need to be combined to find the final solution to a problem. Using dimensional analysis, you can use the units to guide the problem solving strategy. Example #3. Perform the following calculations. a. The speed of light is 2.998 x 108 m/s. How far does light travel in 60.0 seconds? Report the answer in miles. (1 mi = 1.61 km). Given unit: seconds Desired unit: miles ππππ. ππ ππ ππ. ππππππ ππ ππππππ ππ ππ ππππ ππ ππππ οΏ½ οΏ½οΏ½ οΏ½οΏ½ οΏ½ = ππ. ππππ ππ ππππππ ππππ οΏ½οΏ½ ππ ππππππππ ππ ππ. ππππ ππππ ππ ππ b. A sample of ore contains 34.0% malachite, a copper mineral. Malachite is 57.5% copper. What is the maximum amount of pure copper that could be extracted from 250 kg of the ore? Chemistry Guided Learning Activities Activity 151 β 2 College of the Canyons Page 3 of 4 Part D β Extra Practice 1. A light-year is the distance that light will travel in a year. Express this distance in kilometers. (The speed of light is 2.998 x 108 m/s). 2. 18.0 mL of water contains 6.022 x 1023 water molecules. How many hydrogen atoms are in 1.00 L of water? (Each water molecule, H2O, contains two hydrogen atoms.) 3. What is the volume occupied by one water molecule? (See #2). 4. A certain ore contains 34% hematite, Fe2O3. Hematite is 69.9% iron. How much iron can be isolated from 250 tons of this ore? (1 ton = 2000 lb.) 5. An ounce of coffee contains 12 mg of caffeine, while a dark chocolate Hersheyβs kiss contains 2.2 mg of caffeine. How many Hersheyβs kisses contain as much caffeine as a cup (8.0 oz) of coffee? 6. The lava from a volcano can travel up to 100 km/hr. If a village is located 3.6 mi from the volcano, how many minutes will it take the lava to reach the village? Chemistry Guided Learning Activities Activity 151 β 2 College of the Canyons Page 4 of 4
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