Activity 151-2 Dimensional Analysis

Activity 151-2
Dimensional Analysis
Directions: This Guided Learning Activity (GLA) focuses on using dimensional analysis to solve chemical
problems. Part A describes the dimensional analysis approach, Part B discusses how to identify
conversion factors for dimensional analysis, and Part C gives examples of using dimensional analysis to
solve chemical problems. The worksheet is accompanied by instructional videos. Please visit
http://www.canyons.edu/Departments/CHEM/GLA for additional materials.
Part A – Dimensional Analysis Strategy
In chemistry, many calculations rely on the units used to express the quantities. Many of the problems
you see will utilize a process termed dimensional analysis, or the factor-based method. Dimensional
analysis involves adding, subtracting, dividing, and multiplying units just as you would real numbers.
When using dimensional analysis, we β€˜cancel’ units to guide the problem solving strategy.
Dimensional Analysis Strategy
1. Write known measurements with their units as fractions. If the measurement has multiple units,
write the units separately.
9.35 π‘šπ‘šπ‘šπ‘š
7.87 𝑔𝑔
9.35 mL becomes οΏ½
οΏ½
7.87 g/cm3 becomes οΏ½
3οΏ½
1
1 π‘π‘π‘šπ‘š
2. Identify equalities that relate the given units to the desired units, and write these equalities as
conversion factors by dividing one side by the other.
1 π‘π‘π‘šπ‘š3
οΏ½
1 π‘šπ‘šπ‘šπ‘š
1 mL = 1 cm3 becomes οΏ½
1 π‘šπ‘šπ‘šπ‘š
οΏ½
1 π‘π‘π‘šπ‘š3
or οΏ½
453.6 𝑔𝑔
οΏ½
1 𝑙𝑙𝑙𝑙.
1 lb. = 453.6 g becomes οΏ½
1 𝑙𝑙𝑙𝑙.
οΏ½
453.6 𝑔𝑔
or οΏ½
3. Multiply given quantities by conversion factors that allow you to β€˜cancel’ unwanted units (divide
like units), and acquire desired units.
9.35 π‘šπ‘šπ‘šπ‘š 1 π‘π‘π‘šπ‘š3
οΏ½
οΏ½οΏ½
οΏ½ = 9.35 π‘π‘π‘šπ‘š3
1 π‘šπ‘šπ‘šπ‘š
1
οΏ½
1 𝑙𝑙𝑙𝑙.
𝑙𝑙𝑙𝑙.
7.87 𝑔𝑔
οΏ½οΏ½
οΏ½ = 0.174 3
3
453.6 𝑔𝑔
π‘π‘π‘šπ‘š
1 π‘π‘π‘šπ‘š
Chemistry Guided Learning Activities
Activity 151 – 2
College of the Canyons
Page 1 of 4
Example #1. How many jelly beans will fit in a 32.0 oz. mason jar?
To solve this problem, we must know how much space is occupied by a single jelly bean. If we know that
one jelly bean occupies 3.5 cm3, then we can write:
We must also know the unit conversion between ounces and cubic centimeters:
The goal of dimensional analysis is to arrange the conversion factors in a way that will allow unwanted
units to divide out, or β€˜cancel.’
Part B – Identifying Conversion Factors for Dimensional Analysis
One of the challenging parts of dimensional analysis is learning how to identify and write conversion
factors. Here are a few common types of dimensional analysis conversion factors:
1. Unit Conversion Factors
Example: An inch is equivalent to 2.54 cm, 0.254 m, and 1/12 ft.
Conversion Factors:
οΏ½
𝟏𝟏 π’Šπ’Šπ’Šπ’Š.
𝟐𝟐.πŸ“πŸ“πŸ“πŸ“ 𝒄𝒄𝒄𝒄
οΏ½
οΏ½
𝟏𝟏 π’Žπ’Ž
𝟏𝟏𝟏𝟏𝟏𝟏 𝒄𝒄𝒄𝒄
οΏ½
οΏ½
𝟏𝟏𝟏𝟏 π’Šπ’Šπ’Šπ’Š.
𝟏𝟏 𝒇𝒇𝒇𝒇
οΏ½
2. Physical Properties or Quantities like density, percent composition, concentration, or speed
Example: A 68% nitric acid solution has a concentration of 15.8 M and a density of 1.42 g/cm3
Conversion Factors: οΏ½
πŸ”πŸ”πŸ”πŸ” π’ˆπ’ˆ 𝒏𝒏𝒏𝒏𝒏𝒏𝒏𝒏𝒏𝒏𝒏𝒏 𝒂𝒂𝒂𝒂𝒂𝒂𝒂𝒂
𝟏𝟏𝟏𝟏𝟏𝟏 π’ˆπ’ˆ 𝒔𝒔𝒔𝒔𝒔𝒔𝒔𝒔𝒔𝒔𝒔𝒔𝒔𝒔𝒔𝒔
οΏ½
οΏ½
𝟏𝟏𝟏𝟏.πŸ–πŸ– π’Žπ’Žπ’Žπ’Žπ’Žπ’Žπ’Žπ’Ž 𝒏𝒏𝒏𝒏𝒏𝒏𝒏𝒏𝒏𝒏𝒏𝒏 𝒂𝒂𝒂𝒂𝒂𝒂𝒂𝒂
𝟏𝟏 𝑳𝑳 𝒔𝒔𝒔𝒔𝒔𝒔𝒔𝒔𝒔𝒔𝒔𝒔𝒔𝒔𝒔𝒔
3. Stoichiometric Coefficients
Example: 𝐢𝐢3 𝐻𝐻8 (𝑔𝑔) + 5𝑂𝑂2 (𝑔𝑔) β†’ 3𝐢𝐢𝑂𝑂2 (𝑔𝑔) + 4𝐻𝐻2 𝑂𝑂(𝑔𝑔)
Conversion Factors:
οΏ½
πŸ“πŸ“ π’Žπ’Žπ’Žπ’Žπ’Žπ’Žπ’Žπ’Ž π‘Άπ‘ΆπŸπŸ
𝟏𝟏 π’Žπ’Žπ’Žπ’Žπ’Žπ’Žπ’Žπ’Ž π‘ͺπ‘ͺπŸ‘πŸ‘ π‘―π‘―πŸ–πŸ–
οΏ½ οΏ½
πŸ‘πŸ‘ π’Žπ’Žπ’Žπ’Žπ’Žπ’Žπ’Žπ’Ž π‘ͺπ‘ͺπ‘Άπ‘ΆπŸπŸ
πŸ“πŸ“ π’Žπ’Žπ’Žπ’Žπ’Žπ’Žπ’Žπ’Ž π‘Άπ‘ΆπŸπŸ
οΏ½
οΏ½
𝟏𝟏.πŸ’πŸ’πŸ’πŸ’ π’ˆπ’ˆ 𝒏𝒏𝒏𝒏𝒏𝒏𝒏𝒏𝒏𝒏𝒏𝒏 𝒂𝒂𝒂𝒂𝒂𝒂𝒂𝒂
𝟏𝟏 π’„π’„π’Žπ’ŽπŸ‘πŸ‘ 𝒔𝒔𝒔𝒔𝒔𝒔𝒔𝒔𝒔𝒔𝒔𝒔𝒔𝒔𝒔𝒔
οΏ½
βˆ†π»π»π‘Ÿπ‘Ÿπ‘Ÿπ‘Ÿπ‘Ÿπ‘Ÿ = βˆ’2220 π‘˜π‘˜π‘˜π‘˜
οΏ½ οΏ½
βˆ’πŸπŸπŸπŸπŸπŸπŸŽπŸŽ π’Œπ’Œπ’Œπ’Œ
𝟏𝟏 π’Žπ’Žπ’Žπ’Žπ’Žπ’Žπ’Žπ’Ž π‘ͺπ‘ͺπŸ‘πŸ‘ π‘―π‘―πŸ–πŸ–
οΏ½
*Mole conversions and stoichiometry are discussed in more detail in GLA 151-8 and GLA 1519. Please refer to these for further guidance. *
Chemistry Guided Learning Activities
Activity 151 – 2
College of the Canyons
Page 2 of 4
Keep in mind that the conversion factor that is used is chosen based on the given units and the desired
units, so these must be identified at the beginning of each problem.
Example #2. Perform the following calculations by identifying and employing appropriate conversion
factors.
a. A pharmaceutical company produced 7885 g of a drug in one reactor. If one tablet of the drug
will contain 425 mg, how many tablets can be prepared from that reactor?
Given unit: grams
Desired unit: tablets
πŸ•πŸ•πŸ•πŸ•πŸ•πŸ•πŸ•πŸ• π’ˆπ’ˆ 𝟏𝟏𝟏𝟏𝟏𝟏𝟏𝟏 π’Žπ’Žπ’Žπ’Ž 𝟏𝟏 𝒕𝒕𝒕𝒕𝒕𝒕𝒕𝒕𝒕𝒕𝒕𝒕
οΏ½
οΏ½οΏ½
οΏ½οΏ½
οΏ½ = 𝟏𝟏𝟏𝟏, πŸ”πŸ”πŸ”πŸ”πŸ”πŸ” 𝒕𝒕𝒕𝒕𝒕𝒕𝒕𝒕𝒕𝒕𝒕𝒕𝒕𝒕
𝟏𝟏
𝟏𝟏 π’ˆπ’ˆ
πŸ’πŸ’πŸ’πŸ’πŸ’πŸ’ π’Žπ’Žπ’Žπ’Ž
b. Mia’s car has an average mileage of 26 miles per gallon, and has a 16.0 gallon gas tank. How
many times can Mia go to work (8.4 mile round trip) before needing to refill the tank?
Part C – Performing Multiple Unit Conversions
Often, conversion factors need to be combined to find the final solution to a problem. Using dimensional
analysis, you can use the units to guide the problem solving strategy.
Example #3. Perform the following calculations.
a. The speed of light is 2.998 x 108 m/s. How far does light travel in 60.0 seconds? Report the
answer in miles. (1 mi = 1.61 km).
Given unit: seconds
Desired unit: miles
πŸ”πŸ”πŸ”πŸ”. 𝟎𝟎 𝒔𝒔 𝟐𝟐. πŸ—πŸ—πŸ—πŸ—πŸ—πŸ— 𝒙𝒙 πŸπŸπŸπŸπŸ–πŸ– π’Žπ’Ž
𝟏𝟏 π’Œπ’Œπ’Œπ’Œ
𝟏𝟏 π’Žπ’Žπ’Žπ’Ž
οΏ½
οΏ½οΏ½
οΏ½οΏ½
οΏ½ = 𝟏𝟏. 𝟏𝟏𝟏𝟏 𝒙𝒙 πŸπŸπŸπŸπŸ•πŸ• π’Žπ’Žπ’Žπ’Ž
οΏ½οΏ½
𝟏𝟏
𝟏𝟏𝟏𝟏𝟏𝟏𝟏𝟏 π’Žπ’Ž 𝟏𝟏. πŸ”πŸ”πŸ”πŸ” π’Œπ’Œπ’Œπ’Œ
𝟏𝟏 𝒔𝒔
b. A sample of ore contains 34.0% malachite, a copper mineral. Malachite is 57.5% copper. What
is the maximum amount of pure copper that could be extracted from 250 kg of the ore?
Chemistry Guided Learning Activities
Activity 151 – 2
College of the Canyons
Page 3 of 4
Part D – Extra Practice
1. A light-year is the distance that light will travel in a year. Express this distance in kilometers. (The
speed of light is 2.998 x 108 m/s).
2. 18.0 mL of water contains 6.022 x 1023 water molecules. How many hydrogen atoms are in 1.00 L of
water? (Each water molecule, H2O, contains two hydrogen atoms.)
3. What is the volume occupied by one water molecule? (See #2).
4. A certain ore contains 34% hematite, Fe2O3. Hematite is 69.9% iron. How much iron can be isolated
from 250 tons of this ore? (1 ton = 2000 lb.)
5. An ounce of coffee contains 12 mg of caffeine, while a dark chocolate Hershey’s kiss contains 2.2 mg
of caffeine. How many Hershey’s kisses contain as much caffeine as a cup (8.0 oz) of coffee?
6. The lava from a volcano can travel up to 100 km/hr. If a village is located 3.6 mi from the volcano,
how many minutes will it take the lava to reach the village?
Chemistry Guided Learning Activities
Activity 151 – 2
College of the Canyons
Page 4 of 4