Gases Kinetic-molecular Theory Objects in motion have energy called kinetic energy. The kinetic-molecular theory describes the behavior of matter in terms of particle motion. Gas particle size Small particles that are separated from one another by empty space. The particles are small compared to the volume of the space. Gas particle motion ★ Gas particles are in constant random motion. ★ They move in a straight line until they collide with other particles or with the walls of their container. ★ Collisions between gas particles are considered elastic. ★ An elastic collision is one in which no kinetic energy is lost. Particle Energy Two factors determine the kinetic energy of a particle: 1. Mass 2. Velocity The kinetic energy of a particle can be represented by the following equation: Where: KE-Kinetic energy m- mass of the particle v- velocity TEMPERATURE IS THE MEASURE OF THE AVERAGE KINETIC ENERGY OF THE PARTICLES IN A SAMPLE OF MATTER!!! Behavior of gases Low density: There is a great deal of space between gas particles, so there are fewer particles in a given area. Compression and expansiongas can be compressed into smaller volumes. It can also spread out to fill larger volumes. Diffusion The random motion of gas particles cause gases to mix. Diffusion is the term used to describe the movement of one material through another. Example: When you’re cooking in the kitchen, you can smell it through the house because the gases diffuse. Effusion Effusion is when gas escapes through a tiny opening. ★ This is what happens when you puncture a tire. Graham’s law- states that the rate of effusion is inversely proportional to the square root of its molar mass. Lighter particles diffuse more rapidly than heavier particles. Gas pressure Pressure is defined as the force per unit area. A Barometer measures atmospheric pressure. ➔ The height of Mercury in a Barometer at sea level is 760 mm. This measurement is also called a Torr (for Torricellithe scientist who measured it.) Manometer Measures the pressure in a closed container. Units of pressure ● Pascals ● Atmospheres- One atmosphere = 760 mm Hg or 760 Torr Dalton’s law of partial pressures States that the total pressure of a mixture of gases is equal to the sum of the pressures of all the gases in the mixture.
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