NUMERICAL MODELING OF PARTIAL SATURATION IN SANDS INDUCED THROUGH TRANSPORT AND REACTIVITY SUTRA-BUBBLE Professor M. K. Yegian Seda Gokyer, Ph.D. Candidate NEESR Project: Induced Partial Saturation (IPS) Through Transport and Reactivity for Liquefaction Mitigation (Grant Number: CMMI-1134940) SUTRA – BUBBLE - COMPUTER PROGRAM TO MODEL PARTIAL SATURATION IN SANDS INDUCED THROUGH TRANSPORT AND REACTIVITY Injection of sodium percarbonate solution Inj. Pres. =? Inj. Conc. =? Inj. Duration =? Sand S=100% S = f (C) S Computer simulation kr = f (S) kr time S Injection nodes S < 100% X Sand Y Z Governing Equation Fluid mass balance Ideal gas law Darcy’s law S = f (x,y,z,t) Degree of saturation Moles of gas bubbles Concentration of solute Governing Flow Equation time time S = f (C) time k k r ρ (1 Sbw ) P (Sb )2 δρ ρ C εSw RTερ w . p-ρg Qp r C Pb MWsolute C t Pb t μ Sw ρSop ερSbw CONSTITUTIVE MODELS IN SUTRA-BUBBLE - CONT’D LABORATORY EXPERIMENTS FOR CONSITUTIVE MODELS Rate of reaction for gas generation Relative permeability of soil k PS k FS k FS - permeability for fully saturated specimen kr kr S δ time S υ b (t) 1 υ b0 exp( rt) C(t) C0 exp( rt) Moles of gas bubbles k PS - permeability for partially saturated specimen Concentration of solute kr time CONSTITUTIVE MODELS IN SUTRA-BUBBLE - CONT’D LABORATORY EXPERIMENTS FOR CONSITUTIVE MODELS Relative permeability of soil kr kr k PS kr S δ k FS k PS - permeability for partially saturated specimen k FS - permeability for fully saturated specimen Relative permeability, kr ( kPS / kFS) 1.0 0.8 Fitted line -S 2 0.6 0.4 0.2 Lower bound S for IPS – 40% Fredlund relation 3 for clean sands - S 0.0 0.0 k PS S2 - used in SUTRA-Bubble model k FS 0.2 0.4 0.6 0.8 Degree of Saturation, S 1.0 FS5-1 FS5-2 FS5-3 FS5-4 PS3-1 PS3-2 PS3-3 PS3-4 PS2-1 PS2-2 PS2-3 PS2-4 PS4-1 PS4-2 PS4-3 PS4-4 Specimen 1 Fully Saturated (FS) Specimen 2 Partially Saturated (PS) Specimen 3 Partially Saturated (PS) Specimen 4 Partially Saturated (PS) Degree of Saturation Gradient, i Permeability, cm/s Void Ratio 1.00 1.00 1.00 1.00 0.90 0.90 0.90 0.90 0.64 0.65 0.66 0.66 0.49 0.49 0.49 0.49 0.83 0.63 0.40 0.22 0.89 0.66 0.43 0.23 0.64 0.44 0.22 0.89 1.17 0.90 0.66 0.43 0.056 0.053 0.050 0.044 0.048 0.050 0.049 0.048 0.028 0.029 0.024 0.027 0.016 0.020 0.019 0.023 0.71 0.71 0.71 0.71 0.77 0.77 0.77 0.77 0.80 0.80 0.80 0.80 0.75 0.75 0.75 0.75 kR (kPS/kFS) 1.00 1.00 1.00 1.00 0.77 0.80 0.79 0.76 0.41 0.42 0.35 0.40 0.28 0.35 0.33 0.39 CONSTITUTIVE MODELS IN SUTRA-BUBBLE - CONT’D LABORATORY EXPERIMENTS FOR CONSITUTIVE MODELS Moles of gas bubbles Electrical Conductivity (microsiemens/cm) time Exp Data Set 1 2500 Fitted Line - Data Set 1 2000 Exp Data Set 2 Fitted Line - Data Set 2 1500 Fitted gas bubble generation relation in SUTRA-Bubble 1000 500 r0.76% = 0.000133 (1/sec) 1.2 0 0 250 500 750 1000 Time, min 1250 0.8 r = 0.000083 (1/sec) - Ceqv=0.38% 0.6 r = 0.000133 (1/sec) - Ceqv=0.76% 0.4 Exp Data Set 1 Fitted Line - Data Set 1 Exp Data Set 2 Fitted Line - Data Set 2 1200 1 1500 Generation of Oxygen Bubbles in Sand Ceqv =0.38% 1600 Electrical Conductivity (microsiemens/cm) time 3000 Generation of Oxygen Bubbles in Sand Ceqv =0.76% (t) / b0 Concentration of solute Rate of gas generation 0.2 0 0 800 400 r0.5% = 0.0000833 (1/sec) 0 0 250 500 750 1000 Time, min 1250 1500 500 Time, min 1000 1500 VALIDATION OF SUTRA-BUBBLE WITH LABORATORY EXPERIMENTS LARGE SAND SPECIMEN IN A GLASS TANK EXPERIMENTS FOR VALIDATION OF SUTRA-BUBBLE Test 1 and Test 2 Measurements made to validate SUTRA-Bubble: • Inflow/Outflow rates and pore water pressures • Rate of transport of chemical solution during injection – using Electrical Conductivity Probes • Degree of saturation in soil – using Electrical Conductivity Probes EXPERIMENTAL TEST SET UP Mariotte’s Bottle (MB) 12 EC Probes and 5 PPT’s Injection tube with relief valve Glass Tank Electrical conductivity meters Data acquisition system to read PPT’s Picture shows the experimental set up with measurement instruments including electrical conductivity meters and data acquisition system EXPERIMENTAL TEST SET UP - CONT’D 2.3 cm in diameter Pore pressure transducers – PPT Injection Tube Electrical Conductivity – EC Probe Kulite XCL– 11-250 Druck PDCR 81 EC Probe Two electrodes measuring electrical resistance Meters to read the EC probes Final locations of instruments for both Test 1 and Test 2 PPT - Pore pressure transducer EC - Electrical Conductivity Probe Each square side is 5 cm Injection tip Table of parameters of injection Test 1 e = 0.70 Test 2 e = 0.72 Depth of Inj. pressure – Inj. Inj. inj. tube H (TIP) duration concentration Water inj. 25.5 cm 26 cm 5 min 0% IPS inj. 25.5 cm 26 cm 13 min 1% (by weight) Water inj. 25.5 cm 26 cm 5 min 0% IPS inj. 25.5 cm 26 cm 13 min 0.5% (by weight) RESULTS AND DISCUSSIONS Results from TEST 1 Inflow and pressure measurements Cumulative flow of sodium percarbonate solution Test 1 Cumulative flow of water Test 1 16000 qave = 1944 gr/min end of injection 8000 qave = 1892 gr/min 4000 Inflow, gr Outflow, gr 0 0 1 2 3 4 5 6 7 Time, min 8 9 12000 8000 4000 H = 20.5 cm 30 Hydrostatic pressure 20 PPT 1 PPT 2 10 0 1 2 3 4 5 6 Time, min 7 8 9 30 Hydrostatic pressure 0 1 2 9 12 15 H (TIP) = 26 cm 40 10 10 6 Injection of sodium percarbonate solution PPT 3 PPT 4 PPT 5 20 3 Time, min 3 4 5 6 Time, min 7 8 9 10 PPT 1 & PPT 2 50 PPT Pressure, cm 40 Outflow, gr 0 10 PPT 3, 4 & 5 50 PPT Pressure, cm PPT Pressure, cm 50 Inflow, gr 0 Injection of water - Test 1 H (TIP) = 26 cm PPT 1 & PPT 2 end of injection 13 min 40 H = 20 cm 30 Hydrostatic pressure 20 PPT 1 PPT 2 10 0 3 6 9 Time, min PPT 3, 4 & 5 50 12 15 PPT Pressure, cm 12000 Cumulative flow, gr Cumulative flow, gr 16000 PPT 3 PPT 4 PPT 5 40 30 20 Hydrostatic pressure 10 0 3 6 9 Time, min 12 15 RESULTS AND DISCUSSIONS Results from TEST 1 Outflow measurements 24000 Cumulative flow, gr 20000 Volume of gas 16000 12000 8000 4000 Inflow 0 – 10 hours Outflow 0 0 1 2 3 4 5 6 Time, hrs 7 8 9 10 TEST 1 SAVE in the zone of partial saturation using outflow measurements: (Outflow - Inflow) @ 360 minutes = (Vwater ) (Vbubble ) = 4292 cm3 (Vv ) 27310 cm3 for total specimen Partial saturated zone 55% of the total volume (Vv ) for partially saturated zone = 27310 * 0.55 = 15021 cm3 (SAVE ) = (Vv Vbubble ) / Vv (15021-4292)/15021 = 0.71 RESULTS AND DISCUSSIONS Results from TEST 1 Transport of chemical solution – Electrical Conductivity measurements • Solution arrives at the locations of probes EC1 to EC9. • Solution transports ~ 25 cm away from injection. TEST 1 EC11 Each square side is 5 cm EC9 EC7 EC6 EC1 EC3 EC4 EC2 EC5 EC8 EC10 EC12 Electrical Conductivity, mS/cm 4.0 EC - Electrical Conductivity Probe End of Injection 3.5 EC1 EC2 3.0 EC3 EC4 2.5 EC5 2.0 EC6 1.5 EC8 EC7 EC9 1.0 EC10 During injection 0.5 0.0 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Time, min EC11 EC12 RESULTS AND DISCUSSIONS Results from TEST 1 Degree of Saturation – Electrical Conductivity measurements TEST 1 4.0 1/ S= Degree of Saturation n=Saturation exponent close to 2 =Porosity a= Tortuosity factor Electrical conductivity of brine m=Cementation exponent P Electric Conductivity Assumption: From P to R only change in the Archie’s Law if due to change in S R Electrical Conductivity, mS/cm Archie’s law : 3.5 EC1 EC2 3.0 EC3 EC4 2.5 EC5 EC6 2.0 EC7 EC8 1.5 EC9 EC10 1.0 EC11 EC12 0.5 0.0 0 1 13 min. injection Time 2 3 4 5 Time, hrs 6 7 8 9 10 RESULTS AND DISCUSSIONS Results from TEST 1 Degree of Saturation – Electrical Conductivity measurements ~ 60% - 70% degree of saturation achieved in the zone of partial saturation TEST 1 Degree of saturation results EC probes in the zone of influence (EC 1-9) 100 1.0 Degree of Saturation, % EC1 0.62 0.63 0.66 0.65 0.67 0.59 0.73 0.60 0.68 1.0 0 – 10 hours 90 EC2 EC3 80 EC4 EC5 EC6 70 EC7 EC8 60 EC9 50 0 1 2 3 4 5 6 Time, hrs 7 8 9 10 RESULTS AND DISCUSSIONS Results from TEST 2 Inflow and pressure measurements TEST 2 Cumulative flow of sodium percarbonate solution TEST 2 Cumulative flow of water 16000 Cumulative flow, gr qave = 2400 gr/min 8000 end of injection 4000 qave = 2420 gr/min Inflow, gr 3 8000 6 9 12 Time, min 9 12 15 H (TIP) = 26 cm PPT Pressure, cm 20 Hydrostatic pressure 3 PPT 3, 4 & 5 PPT 1 & PPT 2 50 50 30 2 6 Injection of sodium percarbonate solution 40 1 3 Time, min PPT 3 PPT 4 PPT 5 0 Outflow, gr 0 15 PPT 3, 4 & 5 10 Inflow, gr 0 Injection of water - Test 2 H (TIP) = 26 cm 50 end of injection 13 min 4000 Outflow, gr 0 0 12000 PPT Pressure, cm 12000 PPT Pressure, cm Cumulative flow, gr 16000 40 30 20 Hydrostatic pressure PPT 1 4 5 6 7 8 9 10 40 30 20 Hydrostatic pressure PPT 2 10 Time, min PPT 3 PPT 4 PPT 5 10 0 3 6 9 Time, min 12 15 0 3 6 9 Time, min 12 15 RESULTS AND DISCUSSIONS Results from TEST 2 Outflow measurements Cumulative flow, gr 20000 16000 Volume of gas 12000 8000 4000 0 – 16 hours Inflow Outflow 0 0 2 4 6 8 10 Time, hrs 12 14 16 TEST 2 SAVE in the zone of partial saturation using outflow measurements: (Outflow - Inflow) @ 600 minutes = (Vwater ) (Vbubble ) = 1483 cm3 (Vv ) 28311 cm3 for total specimen Partial saturated zone 40% of the total volume (Vv ) for partially saturated zone = 28311 * 0.40 = 11324 cm3 (SAVE ) = (Vv Vbubble ) / Vv (11324-1483)/11324 = 0.87 RESULTS AND DISCUSSIONS Results from TEST 2 Transport of chemical solution – Electrical Conductivity measurements • Solution arrives at the locations of probes EC1 to EC9 except EC8 • Solution transports ~ 20 cm away from injection. TEST 2 EC - Electrical Conductivity Probe EC11 Each square side is 5 cm EC9 EC7 EC6 EC1 EC3 EC4 EC2 EC5 EC8 EC10 Electrical Conductivity, mS/cm 4.0 End of Injection 3.5 EC2 3.0 EC3 EC4 2.5 EC5 2.0 EC6 1.5 EC8 EC7 EC9 EC10 1.0 During injection 0.5 0.0 EC12 EC1 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Time, min EC11 EC12 RESULTS AND DISCUSSIONS Results from TEST 2 Degree of Saturation – Electrical Conductivity measurements TEST 2 Archie’s law : P Electric Conductivity Assumption: From P to R only change in the Archie’s Law if due to change in S R Electrical Conductivity, mS/cm 1/ S= Degree of Saturation n=Saturation exponent close to 2 =Porosity a= Tortuosity factor Electrical conductivity of brine m=Cementation exponent 4.0 3.5 3.0 EC2 EC3 2.5 EC4 2.0 EC6 1.5 EC8 EC5 EC7 EC9 1.0 EC10 EC11 0.5 EC12 0.0 0 Time EC1 0 – 18 hours 2 13 min. injection 4 6 8 10 Time, hrs 12 14 16 18 RESULTS AND DISCUSSIONS Results from TEST 2 Degree of Saturation – Electrical Conductivity measurements ~ 60% - 75% degree of saturation achieved in the zone of partial saturation TEST 2 Degree of saturation results EC probes in the zone of influence (EC 1-9) 100 0 – 18 hours 0.65 0.71 0.77 0.77 0.69 Degree of Saturation, % 1.0 0.54 0.71 0.75 0.65 EC1 90 EC2 EC3 80 EC4 EC5 EC6 70 EC7 EC8 60 EC9 1.0 50 0 2 4 6 8 Time, hrs 10 12 14 16 SUTRA-BUBBLE PREDICTIONS FOR GLASS TANK TEST Modeling of injection tube Mesh for test specimen Free surface boundary 55 cm 25.5 cm Injection tube 13.5 cm Source of flow boundary Injection nodes Sand 91 cm Injection tube Permeability (m2) 25.5 cm SUTRA-BUBBLE PREDICTIONS FOR GLASS TANK TEST Parameters used in SUTRA-Bubble runs TEST 1 and TEST 2 Size of model Specimen height Depth of Injection tip Porosity Mean Average Permeability Dispersivity (Long. & Trans.) Diffusion coefficient Coefficient of density change ρ ) C Initial pressure Initial concentration Actual concentration of H2O2 solution (CH 2 O 2 )actual ( Injection pressure Duration of injection Total duration of the model Time increment Mesh size Number of nodes Number of elements Solver for pressure Solver for pressure TEST 1 91 cm (L) x 13.5 cm (W) 55 cm 25.5 cm 0.41 1.5 E-10 m2 * 1E-4 m 1E-9 m2/s TEST 2 91 cm (L) x 13.5 cm (W) 55 cm 25.5 cm 0.42 1.75 E-10 m2 * 1E-4 m 1E-9 m2/s 4052 (kg/m3) 4052 (kg/m3) Hydrostatic pressure 0 (kg/kg) Hydrostatic pressure 0 (kg/kg) 0.002468 (kg/kg) 0.001234 (kg/kg) H (TIP) = 26 cm 13 minutes 360 minutes 10 seconds (for 15 minutes) 60 seconds (15 to 105 minutes) 360 seconds (105 to 360 minutes) 0.5 cm (hexahedral) 571872 543510 Iterative – GMRES Tolerance – 1E-13 # of iterations - 1600 Iterative – GMRES Tolerance – 1E-13 # of iterations - 1600 H (TIP) = 26 cm 13 minutes 600 minutes 10 seconds (for 15 minutes) 60 seconds (15 to 105 minutes) 360 seconds (105 to 600 minutes) 0.5 cm (hexahedral) 571872 543510 Iterative – GMRES Tolerance – 1E-13 # of iterations - 1600 Iterative – GMRES Tolerance – 1E-13 # of iterations - 1600 VALIDATION OF SUTRA-BUBBLE PREDICTIONS TEST 1 Inflow/Outflow and pressure measurements TEST 1 Inflow of solution -SUTRA-Bubble Input TEST 1 24000 Cumulative flow, gr Cumulative flow, gr 16000 12000 8000 Measured q assigned every 2.5 minutes 4000 0 3 6 9 12 15 PPT 1 & PPT 2 PPT Pressure, cm PPT Pressure, cm 30 PPT 1 PPT 2 PPT 1&PPT 2-Model 10 0 3 6 9 Time, min 16000 Inflow 12000 8000 Inflow-Exp Inflow-Model Outflow-Exp Outflow-Model 0 12 15 1 2 3 Time, hrs PPT 3, 4 & 5 50 40 Hydrostatic pressure Outflow Exp 0 Time, min 20 20000 4000 0 50 SUTRA-Bubble PPT 3 PPT 4 PPT 5 PPT 3-Model PPT 4-Model PPT 5-Model 40 30 20 Hydrostatic pressure 10 0 3 6 9 Time, min 12 15 4 5 6 VALIDATION OF SUTRA-BUBBLE PREDICTIONS TEST 1 Transport of chemical solution SUTRA-Bubble output of concentration TEST 1- 15 minutes Ceqv (H EC11 EC9 EC6 EC7 EC1 EC2 EC5 EC3 EC8 EC4 EC10 EC12 2O 2 ) (kg/kg) VALIDATION OF SUTRA-BUBBLE PREDICTIONS TEST 1 Transport of chemical solution SUTRA-Bubble output of concentration & electrical conductivity measurements Arrival of Solution - EC 1 & EC2 Arrival of Solution - EC3, EC5 & EC6 1.2 0.8 Exp SUTRA-Bubble 0.4 Concentration-EC1&EC2-Model Conductivity-EC1-Exp Conductivity-EC2-Exp 0.2 0.0 0 2 4 6 8 10 Time, min 12 14 16 1.0 0.8 0.6 Exp SUTRA-Bubble 0.4 Concentration-EC3,EC5&EC6-Model Conductivity-EC3-Exp Conductivity-EC5-Exp Conductivity-EC6-Exp 0.2 0.0 18 0 2 4 6 8 10 12 14 16 15 cm away from injection 1.0 0.8 Exp 0.6 SUTRA-Bubble 0.4 0.2 Concentration-EC7-Model Conductivity-EC7-Exp 0.0 0 18 2 4 6 Time, min Arrival of Solution - EC4 & EC9 1.2 ~ 20 cm away from injection 1.0 0.8 0.6 SUTRA-Bubble Exp 0.4 Concentration-EC4&EC9-Model Conductivity-EC4-Exp Conductivity-EC9-Exp 0.2 0.0 0 2 4 6 8 10 Time, min 12 14 16 18 8 10 12 Time, min Arrival of Solution - EC8 1.2 Normalized to peak value 0.6 Arrival of Solution - EC7 1.2 10 cm away from injection Normalized to peak value Normalized to peak value 1.0 Normalized to peak value Normalized to peak value 1.2 25 cm away from injection 1.0 0.8 0.6 Exp SUTRA-Bubble 0.4 ConcentrationEC8-Model ConductivityEC8-Exp 0.2 0.0 0 2 4 6 8 10 Time, min 12 14 16 18 14 16 18 VALIDATION OF SUTRA-BUBBLE PREDICTIONS TEST 1 Degree of Saturation SUTRA-Bubble output of degree of saturation TEST 1 – 360 minutes S EC11 1.0 EC9 EC6 EC7 EC1 0.62 EC2 0.66 EC5 EC3 0.65 0.67 EC8 0.59 EC4 EC10 0.68 EC12 0.63 0.73 0.60 1.0 VALIDATION OF SUTRA-BUBBLE PREDICTIONS TEST 1 Degree of Saturation SUTRA-Bubble output of degree of saturation & Experiment (EC measurements) EC1 & EC2 70 Exp 60 EC1-Exp EC2-Exp EC1&EC2-Model 50 40 0 1 2 3 Time, hrs 5 Exp 80 SUTRA-Bubble 70 60 EC3-Exp EC5-Exp EC6-Exp EC3,EC5&EC6 - Model 50 40 6 0 1 2 3 Time, hrs EC4 100 Degree of Saturation,% 4 90 Exp 80 SUTRA-Bubble 70 60 EC4-Exp EC4-Model 50 40 0 1 2 3 Time, hrs 4 5 6 4 5 6 Exp SUTRA-Bubble 80 70 60 50 EC9-Exp EC9-Model 40 0 1 2 3 Time, hrs Exp 80 SUTRA-Bubble 70 60 50 EC7-Exp EC7-Model 40 0 1 2 5 6 4 5 6 25 cm away from injection 90 Exp SUTRA-Bubble 80 70 60 50 EC8-Exp EC8-Model 40 4 3 Time, hrs EC8 100 21 cm away from injection 90 15 cm away from injection 90 EC9 100 18 cm away from injection Degree of Saturation,% SUTRA-Bubble 10 cm away from injection 90 EC7 100 Degree of Saturation,% 80 Degree of Saturation,% @ Injection 90 EC3, EC5, & EC6 100 Degree of Saturation,% Degree of Saturation,% 100 0 1 2 3 Time, hrs 4 5 6 VALIDATION OF SUTRA-BUBBLE PREDICTIONS TEST 2 Inflow/Outflow and pressure measurements TEST 2 Inflow of solution -SUTRA-Bubble Input TEST 2 20000 SUTRA-Bubble Cumulative flow, gr Cumulative flow, gr 16000 12000 8000 Measured q assigned every 1 minute 4000 0 0 3 6 9 12 15 Exp 16000 Outflow 12000 Inflow 8000 Inflow-Exp Inflow-Model Outflow-Exp Outflow-Model 4000 0 Time, min 0 1 2 3 4 5 6 Time, min 50 Exp PPT Pressure, cm PPT Pressure, cm PPT 3, 4 PPT 1 & PPT 2 50 40 30 SUTRA-Bubble 20 Hydrostatic pressure PPT 1 PPT 2 PPT 1&PPT 2 - Model 10 0 3 6 9 Time, min 12 15 PPT 3 PPT3-Model 40 30 PPT 4 PPT4-Model Exp 20 Hydrostatic pressure 10 0 3 SUTRA-Bubble 6 9 Time, min 12 15 7 8 9 10 VALIDATION OF SUTRA-BUBBLE PREDICTIONS TEST 2 Transport of chemical solution SUTRA-Bubble output of concentration TEST 2- 15 minutes Ceqv (H EC11 EC9 EC6 EC7 EC1 EC2 EC5 EC3 EC8 EC4 EC10 EC12 2 O2 ) (kg/kg) VALIDATION OF SUTRA-BUBBLE PREDICTIONS TEST 2 Transport of chemical solution SUTRA-Bubble output of concentration & Electrical conductivity measurements Normalized to peak value Exp SUTRA-Bubble 0.6 0.4 Concentration-EC1&EC2-Model 0.2 Conductivity-EC1-Exp Conductivity-EC2-Exp 0.0 0 2 4 6 Time, min 8 10 cm away from injection 1.0 Exp 0.8 0.6 SUTRA-Bubble 0.4 Concentration-EC3,EC5&EC6-Model Conductivity-EC3-Exp Conductivity-EC5-Exp Conductivity-EC6-Exp 0.2 0.0 10 1.2 0 12 2 4 6 8 10 15 cm away from injection 1.0 0.8 Exp 0.6 SUTRA-Bubble 0.4 Concentration-EC7-Model 0.2 Conductivity-EC7-Exp 0.0 0 12 2 Time, min ~ 20 cm away from injection 0.8 Exp SUTRA-Bubble 0.4 Concentration-EC4&EC9-Model Conductivity-EC4-Exp Conductivity-EC9-Exp 0.2 0.0 0 2 4 6 Time, min 8 6 Time, min 8 10 1.2 1.0 0.6 4 Arrival of Solution - EC8 Arrival of Solution - EC9 1.2 10 12 Normalized to peak value 0.8 Normalized to peak value Normalized to peak value @ Injection 1.0 Arrival of Solution - EC7 Arrival of Solution - EC3, EC5 & EC6 1.2 Normalized to peak value Arrival of Solution - EC 1 & EC2 1.2 25 cm away from injection 1.0 0.8 SUTRA-Bubble 0.6 0.4 Exp ConcentrationEC8-Model 0.2 Conductivity-EC8Exp 0.0 0 30 60 90 Time, min 120 150 12 VALIDATION OF SUTRA-BUBBLE PREDICTIONS TEST 2 Degree of Saturation SUTRA-Bubble output of degree of saturation TEST 2 – 600 minutes S EC11 1.0 EC9 EC6 EC7 EC1 0.65 EC2 0.71 0.77 0.77 0.54 EC5 EC3 0.69 0.71 EC8 EC4 0.75 EC10 EC12 0.65 1.0 VALIDATION OF SUTRA-BUBBLE PREDICTIONS TEST 2 Degree of Saturation SUTRA-Bubble output of degree of saturation & Experiment (EC measurements) Exp 60 EC1-Exp EC2-Exp EC1&EC2-Model 50 0 1 2 3 4 5 6 Time, hrs 7 8 9 80 SUTRA-Bubble 60 EC4-Exp 50 EC4-Model 1 2 3 4 5 6 Time, min 60 EC3-Exp EC5-Exp EC6-Exp EC3, EC5 & EC6-Model 50 0 1 2 3 4 5 6 Time, hrs 7 8 9 7 8 9 10 70 Exp 60 EC7-Exp 50 EC7-Model 0 10 21 cm away from injection SUTRA-Bubble 80 1 2 3 4 5 6 Time, hrs Exp 60 EC9-EXp EC9-Model 7 8 9 10 EC8 100 90 50 SUTRA-Bubble 80 EC9 70 15 cm away from injection 90 40 40 40 0 SUTRA-Bubble 100 Exp 70 70 10 18 cm away from injection 90 Exp 80 40 EC4 100 10 cm away from injection 90 EC7 100 Degree of Saturation, % SUTRA-Bubble 40 Degree of Saturation,% Degree of Saturation, % 80 Degree of Saturation,% Degree of Saturation, % @ Injection 90 70 EC3, EC5, & EC6 100 Degree of Saturation,% EC1 & EC2 100 25 cm away from injection 90 Exp 80 SUTRA-Bubble 70 60 EC8-EXp 50 EC8-Model 40 0 1 2 3 4 5 6 Time, min 7 8 9 10 0 1 2 3 4 5 6 Time, min 7 8 9 10 Findings: • • • • Computer program SUTRA-Bubble was developed to model partial saturation induced through transport and reactivity. Parameters for constitutive models were determined experimentally. • Relative permeability - kr = S2 • Rate for gas generation – r = 0.0001333 (1/sec) for C = 0.76% r = 0.0000833 (1/sec) for C = 0.38% Measurements from two glass tank tests (Test 1 and Test 2) were compared with SUTRA-Bubble outputs of: • Flow and pore water pressure measurements • Concentration of solution – Transport of solution • Degree of saturation Observations and Conclusions from the comparisons of glass tank experimental and SUTRA-BUBBLE results: • Outflow matches well - representing average degree of saturation in zone of flow • Pressure outputs do not match as well as the other parameters – pressures are very sensitive to soil permeability, assumption of uniform permeability may be rigorous • Transport of solution matches very well – arrival time of the solution matches very well at each electric conductivity probe location • Degree of saturation matches quite well • The shape of the zone of partial saturation achieved matches quite well • At each probe location the final degree of saturation matches well • In general, the match is better for TEST 1 results compared to TEST 2 results. • The two experimental tests helped validate SUTRA-BUBBLE
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