Oil, Gas & Mining Gas Treating Solutions Removal and Recovery of Natural Gas Liquids Using UCARSORB™ NGL Adsorbents UCARSORB™ NGL Adsorbents | February 2015 Recover More from Your Natural Gas Operations Natural gas streams often contain varying levels of natural gas liquids (NGLs), which can hold significant value for operators – sometimes outweighing the value of methane to be recovered. Previously, if the goal was to generate a separate NGL stream or simply exclude NGLs from contaminating a process, a large scale, high-cost cryogenic, refrigeration or other low-temperature unit was required to separate out NGLs. Dow offers operators a lower-cost, value-added option, particularly for small-scale gas treatment: UCARSORB™ NGL Adsorbents. This highly selective system is designed to allow water, CO2 and NGLs of lesser value to slip through the bed, removing and capturing only targeted NGLs. Advantages of UCARSORB™ NGL Adsorbents -- Tunable for targeted NGLs, allowing other components to slip through -- Ease of use, with minimal operator intervention required -- Low pressure drop across the system -- Small footprint, often less than 6' x 6' -- Low capital and operating expense --Ability to handle varying gas inlet conditions -- Minimal electrical demand -- No waste stream to manage Common Natural Gas Liquids Component Chemical Formula Shorthand Classification Methane CH4 C1 Natural Gas Ethane C2H6 C2 NGL Propane C3H8 C3 NGL Butane C4H10 C4 NGL Pentane C5H12 C5 NGL Natural gas contains many hydrocarbon components, some in trace quantities. pg 2 UCARSORB™ NGL Adsorbents | February 2015 Example 1: Recovery of NGLs from Flared Gas For some remote oil wells there is little to no infrastructure to recover the natural gas produced with the oil from these wells. In such situations, the natural gas with large amounts of NGLs is flared. UCARSORB™ NGL Adsorbents can capture the valuable NGL products from these gas streams, thus allowing mainly low-value methane and ethane to be flared. Inlet Gas to Pipeline Conditions 50 psi, 1 MMSCFD 54% C1, 20% C2, 13% C3, 6.7% C4+, balance N2, CO2 Outlet Natural Gas to Flare or Pipeline 58% C1, 23% C2, 11% C3, <1% C4+, balance CO2, N2 Can remove more or less C2 depending on combustion systems NGLs Produced <4% C1&C2, >30% C3, >50% C4+, some CO2, trace other components Hydrocarbons to trucking at 200 psi C1, C2, C3 Gas to Flare or Pipeline 45 psi 0.9 MMSCFD 58% C1 23% C2 11% C3 <1% C4+ Gas from Pipeline UCARSORB™ Treatment Unit* 50 psi 1 MMSCFD 54% C1 20% C2 13% C3 6.7% C4+ Gas or Liquid Product C3, C4+ 200 psi 2 gpm <4% C1&C2 >30% C3 >50% C4+ *Typical performance - design dependent pg 3 UCARSORB™ NGL Adsorbents | February 2015 Example 2: Protecting Compressors or Engines from NGLs The challenge for combustion operators is that rich inlet gas (NGL-containing gas) modifies their combustion zone sufficiently to negatively impact emissions from the plant, often exhibited as NOx, CO and volatile organic compound (VOC) emissions. Plants may change operating conditions to reduce the total emissions, but the net power output or efficiency of the combustion engine is reduced. UCARSORB™ NGL Adsorbents remove NGLs from the inlet gas stream instead of installing post-combustion solutions such as catalysts. The UCARSORB system is a selective and effective means to remove and recover NGLs, reducing emissions without sacrificing combustion engine power and efficiency. Inlet Gas to Pipeline Conditions 500 psi, 0.6 MMSCFD 91% C1, 6% C2, 0.85% C3+, balance N2, CO2 Gas to Engine Outlet Natural Gas to Engine Conditions 92% C1, 5% C2, trace C3+, balance CO2, N2 Gas Returned to Pipeline Conditions <40% C1, >50% C2, >10% C3+, balance N2, CO2, trace other components Can remove more or less C2 depending on combustion systems Rejected hydrocarbons returned to pipeline at 500 psi C1, C2 C2, C3+ 450 psi 0.57 MMSCFD 92% C1 5% C2 Trace C3+ Gas from Pipeline Gas to Pipeline 500 psi 0.03 MMSCFD <40% C1 >50% C2 >10% C3+ UCARSORB™ Treatment Unit 500 psi 0.6 MMSCFD 91% C1 6% C2 0.85% C3+ *Typical performance - design dependent pg 4 UCARSORB™ NGL Adsorbents | February 2015 Example 3: Concentrating NGLs in Pipelines Some natural gas pipelines are running over capacity. These pipeline operators must flare the natural gas that cannot be put through the pipelines. UCARSORB™ NGL Adsorbents can be used to recover the valuable NGLs from the gas that is being flared, and return the valuable hydrocarbons to the pipeline, thus allowing volume shrinkage with little value loss. Inlet Gas to Pipeline Conditions 500 psi, 10 MMSCFD 65% C1, 19% C2, 8% C3, 2% C4+, balance N2, CO2 Outlet Dry Gas >70% C1, >15% C2, <5% C3+, balance N2, CO2, trace other components Rich gas returned to pipeline for maximum value Gas Returned to Pipeline Conditions <10% C1&C2, >90% C3+, some N2, CO2 Can remove more or less C2 or C3 depending on customer requests C1, C2 Dry Gas to Flare 490 psi 9 MMSCFD >70% C1 >15% C2 <5% C3+ Gas from Pipeline UCARSORB™ Treatment Unit 500 psi 10 MMSCFD 65% C1 19% C2 8% C3 2% C4+ Rich Gas to Pipeline C3, C4+ 500 psi 20 gpm <10% C1&C2 >90% C3+ *Typical performance - design dependent pg 5 UCARSORB™ NGL Adsorbents | February 2015 Experience You Can Trust Dow has been at the forefront of gas treating technology for more than 65 years. From computer simulations to hands-on operations support and analytical evaluations, our team is with you every step of the way to meet your everyday gas treating challenges. Backed by more than 1,000 global references in gas treating, the Dow technical service team can help to customize a solution based on individual needs, and our advanced simulator is continually and consistently refined through the incorporation of real customer plant data. Providing Comprehensive Solutions for Market Needs Dow is committed to the success of our customers through chemistry and continuous innovation. To learn more about our products, innovations, technologies or other Dow services, please speak with your local Dow representative or visit www.dowoilandgas.com. A Note About Product Safety When considering the use of any Dow products in a particular application, you should review the latest Material Safety Data Sheets from Dow and ensure that they are intended for safe use. 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