Years IIT-JEE
CHAPTERWISE SOLVED PAPERS
CHEMISTRY
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Preface
Whenever a student decides to prepare for any examination, her/his first and foremost curiosity
about the type of questions that he/she has to face. This becomes more important in the context of
competitive examinations where there is neck-to-neck race.
We feel great pleasure to present before you this book. We have made an attempt to provide
chapter wise questions asked in IIT-JEE / JEE Advanced from 1978 to 2016 along with solutions.
Solutions to the questions are not just sketch rather have been written in such a manner that the
students will be able to under the application of concept and can answer some other related
questions too.
We firmly believe that the book in this form will definitely help a genuine, hardworking student.
We have tried our best to keep errors out of this book. Comment and criticism from readers will be
highly appreciated and incorporated in the subsequent edition.
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Career Point Ltd.
CONTENTS
Chapter
Page No.
1.
Mole‐Concept & Stoichiometry
♦ Answers
♦ Solutions
1‐30
10
11
2.
Atomic Structure
♦ Answers
♦ Solutions
31‐46
38
39
3.
Chemical Bonding
♦ Answers
♦ Solutions
47‐66
54
55
4.
Gaseous & Liquid States
♦ Answers
♦ Solutions
67‐90
77
78
5
Chemical & Ionic Equilibrium
♦ Answers
♦ Solutions
6.
Chemical Energetics
♦ Answers
♦ Solutions
121‐140
130
131
7.
Periodic Table
♦ Answers
♦ Solutions
141‐148
144
145
8.
Extraction of Metals & the s‐block elements
♦ Answers
♦ Solutions
149‐160
154
155
9.
General organic Chemistry
♦ Answers
♦ Solutions
161‐186
10.
Hydrocarbons & Halogen Derivatives
♦ Answers
♦ Solutions
187‐218
200
202
11.
Colligative Properties of solutions
♦ Answers
♦ Solutions
219‐232
224
225
91‐120
101
102
173
174
Cont....
12.
Chemical Kinetic & Nuclear Chemistry
♦ Answers
♦ Solutions
233‐254
242
243
13
Solid State, Surface Chemistry & Colloids
♦ Answers
♦ Solutions
255‐266
261
262
14.
Electrochemistry
♦ Answers
♦ Solutions
267‐292
277
278
15.
The p‐block elements
♦ Answers
♦ Solutions
293‐322
306
308
16.
The transition & Co‐ordination compounds
♦ Answers
♦ Solutions
323‐350
335
337
17.
Analytical chemistry
♦ Answers
♦ Solutions
351‐364
357
358
18.
Compounds containing oxygen
♦ Answers
♦ Solutions
365‐434
19.
20.
21.
Compounds containing nitrogen & Practical
organic chemistry
♦ Answers
♦ Solutions
Carbohydrates Aminoacids & Misc Match the
following
♦ Answers
♦ Solutions
Model Test Papers
♦ Practice Test‐1 [Paper‐1]
♦ Practice Test‐1 [Paper‐2]
♦ Practice Test‐2 [Paper‐1]
♦ Practice Test‐2 [Paper‐2]
391
393
435‐466
446
447
467‐476
473
474
477‐500
477
483
489
495
Chapter
1
Mole Concept & Stoichiometry
ONLY ONE CORRECT ANSWER
1.
27 g of Al will react completely with how many
grams of oxygen ?
[1978]
(A) 8 g
(B) 16 g
(C) 32 g
(D) 24 g
2.
A compound was found to contain nitrogen and
oxygen in the ratio 28 gm and 80 gm respectively.
The formula of compound is
[1978]
(A) NO
(B) N2O3
(D) N2O4
(C) N2O5
3.
The largest number of molecules is in
(A) 36 g of water
(B) 28 g of carbon monoxide
(C) 46 g of ethyl alcohol
(D) 54 g of nitrogen pentaoxide
4.
5.
6.
7.
8.
If 0.50 mole of BaCl2 is mixed with 0.20 mol
of Na3PO4, the maximum number of moles of
Ba3(PO4)2 that can be formed is [1981, 1M]
(A) 0.70
(B) 0.50
(C) 0.20
(D) 0.10
9.
One mole of N2H4 loses ten moles of electrons
to form a new compound Y. Assuming that all
the nitrogen appears in the new compound, what
is the oxidation state of nitrogen in Y ? (There is
no change in the oxidation state of hydrogen).
[1981, 1M]
(A) –1
(B) –3
(C) +3
(D) +5
10.
The oxidation number of carbon in CH2O is
[1982, 1M]
(A) –2
(B) +2
(C) 0
(D) +4
11.
A molal solution is one that contains one mole
of a solute in
[1986, 1M]
(A) 1000 g of the solvent
(B) one litre of the solvent
(C) one litre of the solution
(D) 22.4 litres of the solution
12.
The brown ring complex compound is formulated as
[Fe(H2O)5(NO)+]SO4. The oxidation state of iron is :
[1987, 1M]
(A) 1
(B) 2
(C) 3
(D) 0
13.
The equivalent weight of MnSO4 is half its
molecular weight when it is converted to :
[1988, 1M]
(A) Mn2O3
(B) MnO2
[1979]
The total number of electrons in one molecule of
carbon dioxide is
[1979]
(A) 22
(B) 44
(C) 66
(D) 88
A gaseous mixture contains oxygen and nitrogen in
the ratio of 1 : 4 by weight. Therefore the ratio of
their number of molecules is
[1979]
(A) 1 : 4
(B) 1 : 8
(C) 7 : 32
(D) 3 : 16
2.76 g of silver carbonate on being strongly
heated yields a residue weighing
[1979]
(A) 2.16 g
(B) 2.48 g
(C) 2.32 g
(D) 2.64 g
M is molecular weight of KMnO4. The equivalent
weight of KMnO4 when it is converted into
K2MnO4 is
[1980]
(A) M
(B) M/3
(C) M/5
(D) M/7
(C) MnO −4
(D) MnO 24−
2
39 YEARS TOPIC- WISE JEE Advanced Questions with Solutions
14.
In which mode of expression, the concentration of
a solution remains independent of temperature ?
[1988, 1M]
(A) Molarity
(B) Normality
(C) Formality
(D) Molality
15.
The oxidation number of phosphorus in
Ba(H2PO2)2 is :
[1990, 1M]
(A) +3
(B) +2
(C) +1
(D) –1
16.
17.
18.
The oxidation states of the most electronegative
element in the products of the reaction, BaO2 will
dil. H2SO4 is
[1991, 1M]
(A) 0 and –1
(B) –1 and –2
(C) –2 and 0
(D) –2 and –1
Read the following statement and explanation
and answer as per the options given below :
STATEMENT(S) : In the titration of Na2CO3
with HCl using methyl orange indicator, the
volume required at the equivalence point is twice
that of the acid required using phenolphthalein
indicator.
EXPLANATION (E) : Two moles of HCl are
required for the complete neutralization of one
mole of Na2CO3.
[1991, 2M]
(A) Both S and E are true, and E is the correct
explanation of S.
(B) Both S and E are true, and E is not the
correct explanation of S.
(C) S is true but E is false.
(D) S is false but E is true.
19.
The number of moles of KMnO4 that will be
needed to react completely with one mole of
ferrous oxalate in acidic solution is [1997C, 1M]
3
2
(A)
(B)
5
5
4
(D) 1
(C)
5
20.
The normality of 0.3 M phosphorous acid
[1999, 2M]
(H3PO3) is,
(A) 0.1
(B) 0.9
(C) 0.3
(D) 0.6
21.
The oxidation number of sulphur in S8, S2F2, H2S
[1999, 2M]
respectively, are
(A) 0, +1 and –2
(B) +2, +1 and –2
(C) 0, +1 and +2
(D) –2, +1 and –2
22.
Amongst the following identify the species with
[2000S]
an atom in +6 oxidation state
23.
(A)
(B)
(C)
(D)
C 2O 24−
H+
2
16
5
2
5
5
16
16
16
2
2
5
(C) NiF62−
(D) CrO2Cl2
The reaction,
example of
(A) oxidation reaction
(B) reduction reaction
(C) disproportionation reaction
(D) decomposition reaction
[2001 S]
24.
An aqueous solution of 6.3 g oxalic acid
dihydrate is made up to 250 ml. The volume of
0.1 N NaOH required to completely neutralize
[2001 S]
10 ml of this solution is
(A) 40 ml
(B) 20 ml
(C) 10 ml
(D) 4 ml
25.
In the standardization of Na2S2O3 using K2Cr2O7
by iodometry, the equivalent weight of K2Cr2O7 is:
[2001 S]
(A) (molecular weight)/2
(B) (molecular weight)/6
(C) (molecular weight)/3
(D) same as molecular weight
MnO −4 + C 2O 24− + H + → Mn 2+ + CO 2 + H 2O
MnO −4
(B) Cr (CN)36−
3ClO–(aq) → ClO3− (aq) + 2Cl − (aq), is an
For the redox reaction :
the correct coefficients of the reactants for they
balanced reaction are
[1992, 1M]
(A) MnO −4
3
MOLE CONCEPT & STOICHIOMETRY
26.
How many moles of electron weigh one
[2002S]
kilogram ?
1
(A) 6.023 × 1023
(B)
× 1031
9.108
6.023
1
× 1054
(D)
× 108
(C)
9.108
9.108 × 6.023
27.
Which has maximum number of atoms ?
[2003S]
(A) 24g of C (12)
(B) 56g of Fe (56)
(C) 27g of Al (27)
(D) 108g of Ag (108)
28.
Mixture X = 0.02 mol of [Co(NH3)5 SO4]Br and
0.02 mol of [Co(NH3)5 Br]SO4 was prepared in
[2003S]
2 litre of solution.
1 litre of mixture X + excess AgNO3 → Y
1 litre of mixture X + excess BaCl2 → Z
No. of moles of Y and Z are
(A) 0.01, 0.01
(B) 0.02, 0.01
(C) 0.01, 0.02
(D) 0.02, 0.02
32.
The reaction of white phosphorus with aqueous
NaOH gives phosphine along with another
phosphorus containing compound. The reaction
type ; the oxidation states of phosphorus
phosphine and the other product are
[2012]
respectively
(A) redox reaction ; –3 and –5
(B) redox reaction ; +3 and +5
(C) disproportionation reaction ; –3 and +5
(D) disproportionation reaction ; –3 and +3
33.
Hydrogen peroxide in its reaction with KIO4
and NH2OH respectively, is acting as a
[2014]
(A) reducing agent, oxidising agent
(B) reducing agent, reducing agent
(C) oxidising agent, oxidising agent
(D) oxidising agent, reducing agent
ASSERTION‐REASON TYPE
1.
29.
The pair of the compounds in which both the
metals are in the highest possible oxidation
[2004S]
state is
(A) [Fe(CN)6]3–, [Co(CN)6]3–
(B) CrO2Cl2, MnO −4
(C) TiO3, MnO2
(D) [Co(CN)6]3–, MnO3
30.
Consider a titration of potassium dichromate
solution with acidified Mohr’s salt solution
using diphenylamine as indicator. The number
of moles of Mohr’s salt required per mole of
[2007]
dichromate is
(A) 3
(B) 4
(C) 5
(D) 6
31.
Which ordering of compounds is according to
the decreasing order of the oxidation state of
[2012]
nitrogen ?
(A) HNO3, NO, NH4Cl, N2
(B) HNO3, NO, N2, NH4Cl
(C) HNO3, NH4Cl, NO, N2
(D) NO, HNO3, NH4Cl, N2
STATEMENT-1 : Pb4+ compounds are
stronger oxidizing agents than Sn+ compounds.
and
STATEMENT-2 : The higher oxidation states
for the group 14 elements are more stable for
the heavier members of the group due to inert
[2008]
pair effect.
(A) STATEMENT-1 is True, STATEMENT-2
is True; STATEMENT-2 is a correct
explanation for STATEMENT-1.
(B) STATEMENT-1 is True, STATEMENT-2
is True; STATEMENT-2 is NOT a correct
explanation for STATEMENT-1.
(C) STATEMENT-1 is True, STATEMENT-2
is False.
(D) STATEMENT-1 is False, STATEMENT-2
is True.
ONE OR MORE THAN ONE CORRECT ANSWERS
1.
Reduction of the metal centre in aqueous
[2011]
permanganate ion involves
(A) 3 electrons in neutral medium
(B) 5 electrons in neutral medium
(C) 3 electrons in alkaline medium
(D) 5 electrons in acidic medium
4
2.
39 YEARS TOPIC- WISE JEE Advanced Questions with Solutions
For the reaction
–
I +
ClO 3−
5.
−
+ H 2 SO 4 → Cl +
HSO 4−
+ I2
The correct statement(s) in the balanced
[2014]
equation is/are :(A) Stoichiometric coefficient of HSO −4 is 6
ANALYTICAL & DESCRIPTIVE QUESTIONS
(B) Iodide is oxidized
(C) Sulphur is reduced
(D) H2O is one of the products
1.
What weight of AgCl will be precipitated when a
solution containing 4.77 g of NaCl is added to a
[1978]
solution of 5.77 g of AgNO3 ?
2.
One gram of an alloy of aluminium and
magnesium when treated with excess of dil. HCl
forms magnesium chloride, aluminium chloride
and hydrogen. The evolved hydrogen, collected
over mercury at 0°C has a volume of 1.20 litres at
0.92 atm. pressure. Calculate the composition of
the alloy.
[H = 1, Mg = 24, Al = 27]
[1978]
3.
Igniting MnO2 converts it quantitatively to
Mn3O4. A sample of pyrolusite is of the
following composition : MnO2 80%, SiO2 and
other inert constituents 15%, rest being water.
The sample is ignited in air to constant weight.
What is the percentage of Mn in the ignited
sample ?
[O = 16, Mn = 54.9]
[1978]
4.
4.215 g of a metallic carbonate was heated in a
hard glass tube and the CO2 evolved was found
to measure 1336 ml at 27°C and 700 mm
pressure. What is the equivalent weight of the
[1979]
metal ?
5.
(a) 5.5 g of a mixture of FeSO4 . 7H2O and
Fe2(SO4)3. 9H2O requires 5.4 ml of 0.1 N
KMnO4 solution for complete oxidation.
Calculate the number of gram mole of
hydrate ferric sulphate in the mixture.
(b) The vapour density (hydrogen = 1) of a
mixture consisting of NO2 and N2O4 is 38.3
at 26.7°C. Calculate the number of moles of
[1979]
NO2 in 100 g of the mixture.
MATRIX MATCH TYPE
1.
The unbalanced chemical reactions given in
List I show missing reagent or condition (?)
which are provided in List II. Match List I with
List II and select the correct answer using the
[2013]
code given below lists :
List-II
List-I
?
1. NO
P. PbO2 + H2SO4 
→
PbSO4 + O2 + other product
?
Q. Na2S2O3 + H2O 
→
NaHSO4 + other product
2. I2
?
R. N2H4 
→
N2 + other product
3.Warm
?
→
Xe + other product
S. XeF2 
Codes :
P
Q
R
(A) 4
2
3
(B) 3
2
1
(C) 1
4
2
(D) 3
4
2
4. Cl2
S
1
4
3
1
FILL IN THE BLANKS
1.
The compound YBa2Cu3O7, which shows
super-conductivity, has copper in oxidation
state …………, assume that the rare earth
element yttrium is in its usual +3 oxidation
[1994, 1M]
state.
The modern atomic mass unit is based
[1980]
on …………
2.
The total number of electrons present in 18 ml
[1980]
of water is …………
3.
3g of a salt of molecular weight 30 is dissolved
in 250 g of water. The molality of the solution
[1983, 1M]
is …………
4.
The weight of 1 × 1022 molecules of
[1991, 1M]
CuSO4.5H2O is …………
5
MOLE CONCEPT & STOICHIOMETRY
6.
7.
5 ml of a gas containing only carbon and
hydrogen were mixed with an excess of oxygen
(30 ml) and the mixture exploded by means of
an electric spark. After the explosion, the
volume of the mixed gases remaining was 25 ml.
on adding a concentrated solution of potassium
hydroxide, the volume further diminished to
15 ml of the residual gas being pure oxygen. All
volumes have been reduced to N.T.P. Calculate
the molecular formula of the hydrocarbon gas.
[1979]
In the analysis of 0.005 g sample of feldspar. a
mixture of chloride of sodium and potassium is
obtained which weighs 0.1180 g. Subsequent
treatment of mixed chlorides with silver nitrate
gives 0.2451 g of silver chloride. What is the
percentage of sodium oxide and potassium oxide
[1979]
in feldspar.
8.
A compound contains 28 percentage of
nitrogen and 72 percent of metal by weight. 3
atoms of metal combine with 2 atoms of N.
[1980]
Find the atomic weight of metal.
9.
Find the equivalent weight of H3PO4 in the
[1980]
reaction :
Ca(OH)2 + H3PO4 = CaHPO4 + 2H2O
10.
(i) A sample of MnSO4 . 4H2O is strongly
heated in air. The residue is Mn3O4.
(ii) The residue is dissolved in 100 ml of 0.1 N
FeSO4 containing dilute H2SO4.
(iii) The solution reacts completely with 50 ml
of KMnO4 solution.
(iv) 25 ml of the KMnO4 solution used in step
(iii) requires 30 ml of 0.1 N FeSO4 solution
for complete reaction.
Find the amount of MnSO4 . 4H2O present in the
[1980]
sample.
11.
(a) One litre of a sample of hard water contains 1
mg of CaCl2 and 1 mg of MgCl2. Find the
total hardness in terms of parts of CaCO3 per
106 parts of water by weight.
(b) A sample of hard water contains 20 mg of
Ca++ ions per litre. How many
milli-equivalent of Na2CO3 would be
required to soften 1 litre of the sample ?
(c) 1 gm of Mg is burnt in a closed vessel which
contains 0.5 gm of O2.
(i) Which reactant is left in excess ?
(ii) Find the weight of the excess reactants ?
(iii) How many milliliters of 0.5 N H2SO4
will dissolve the residue in the vessel.
[1980]
12.
A hydrocarbon contains 10.5 g of carbon per
gram of hydrogen. 1 litre of the vapour of the
hydrocarbon at 127°C and 1 atmosphere
pressure weighs 2.8 g. Find the molecular
[1980]
formula.
13.
Find
(i) The total number of neutrons and
(ii) The total mass of neutron in 7 mg of 14C.
(Assume that mass of neutron = mass of
[1980]
hydrogen atom)
14.
A mixture contains NaCl and unknown chloride
MCl.
(i) 1g of this is dissolved in water. Excess of
acidified.AgNO3 solution is added to it.
2.567 g of white ppt. is formed.
(ii) 1g of original mixture is heated to 300°C.
Some vapours come out which are absorbed in
acidified AgNO3 solution. 1.341 g of white
precipitate was obtained.
Find the molecular weight of unknown
[1980]
chloride.
15.
A 1.00 gm sample of H2O2 solution containing X
per cent H2O2 by weight requires X ml of a
KMnO4 solution for complete oxidation under
acidic conditions. Calculate the normality of the
[1981, 3M]
KMnO4 solution.
16.
Balance the following equations.
(i) Cu2O + H+ + NO3− = Cu2+ + NO + H2O
[1981, 1M]
(ii)K4[Fe(CN)6] + H2SO4 + H2O
= K2SO4 + FeSO4 + (NH4)2 SO4 + CO
[1981, 1M]
(iii)C2H5OH + I2 + OH–
= CHI3 + HCO3− + I– + H2O
[1981, 1M]
6
17.
18.
39 YEARS TOPIC- WISE JEE Advanced Questions with Solutions
21.
MnO −4 + 5Fe2+ + 8H+ → Mn2+ + 5Fe3+ + 4H2O
A 10 ml. sample of hydroxylamine solution was
diluted to 1 litre. 50 ml. of this diluted solution
was boiled with an excess of iron (III) solution.
The resulting solution required 12 ml. of 0.02M
KMnO4 solution for complete oxidation of iron
(II). Calculate the weight of hydroxylamine in
one litre of the original solution.
(H = 1, N = 14, O = 16, K = 39, Mn = 55, Fe = 56
[1982, 4M]
22.
Five ml of 8N nitric acid, 4.8 ml of 5N
hydrochloric acid are mixed together and made
upto 2 litre. Thirty ml. of this acid mixture
exactly neutralize 42.9 ml of sodium carbonate
solution
containing
one
gram
of
Na2CO3.10H2O in 100 ml. of water. Calculate
the amount in gram of the sulphate ions in
[1985, 4M]
solution.
23.
Arrange the following in increasing oxidation
[1986, 1M]
number of iodine.
I2, HI, HIO4, ICl
24.
(i) What is the weight of sodium bromate and
molarity of solution when the half-cell
reaction is
The density of a 3M sodium thiosulphate
solution (Na2S2O3) is 1.25 g per ml. Calculate
(i) the percentage by weight of sodium
thiosulphate, (ii) the mode fraction of sodium
thiosulphate and (iii) the molalities of Na+ and
S2O32− ions.
19.
20.
2.68 × 10–3 moles of a solution containing an ion
Hydroxylamine reduces iron (III) according to
the equation :
2NH2OH + 4Fe3+ → N2O(g) ↑ + H2O + 4Fe2 + 4H+
Iron (II) thus produced is estimated by titration
with a standard permanganate solutions.
The reaction is :
An+ acquire 1.61 × 10–3 moles of MnO −4 for the
oxidation of An+ to AO3− in acid medium. What
is the value of n ?
[1983, 5M]
4.08 g of a mixture of BaO and an unknown
carbonate MCO3 was heated strongly. The
residue weighed 3.64 g. This was dissolved in
100 ml of 1N HCl. The excess acid required
16 ml of 2.5 N NaOH solution for complete
neutralization. Identify the metal M.
(At. Wt. H = 1, C = 12, O = 16, Cl = 35.5,
[1983, 4M]
Ba = 138)
BrO 3− + 6H + + 6e − → Br − + 3H 2 O
(ii) What would be the weight as well as
molarity if the half-cell reaction is :
2 BrO3− + 12H + + 10e − → Br2 + 6H 2O
[1987, 5M]
25.
A sugar syrup of weight 214.2 g contains 34.2 g
of sugar (C12H22O11).
Calculate : (i) mole concentration and (ii) mole
[1988, 5M]
fraction of sugar in the syrup.
26.
A sample of hydrazine sulphate (N2H6SO4) was
dissolved in 100 ml. of water, 10 ml of this
solution was reacted with excess of ferric
chloride solution and warmed to complete the
reaction. Ferrous ion formed was estimated and
it required 20 ml. of M/50 potassium
permanganate solution. Estimate the amount of
hydrazine sulphate in one litre of the solution.
Reaction :
4Fe3+ + N2H4 → N2 + 4Fe2+ + 4H+
Complete and balance the following reactions :
(i) Zn + NO3− = Zn 2+ + NH +4
[1983, 1M]
(ii) Cr2O 72− + C 2 H 4O = C 2 H 4O 2 + Cr 3+
[1983, 1M]
(iii) HNO3 + HCl = NO + Cl2
[1983, 1M]
(iv) Ce3+ + S2O82− = SO 24− + Ce 4+
(v) Cl2 + OH– = Cl– + ClO–
[1983, 1M]
[1983, 1M]
(vi) Mn2+ + PbO2 → MnO −4 + H2O [1986, 1M]
(vii) S + OH– → S2– + S2O32−
[1986, 1M]
(viii) ClO3− + I − + H 2SO 4 → Cl − + HSO −4
[1983, 1M]
(ix) Ag+ + AsH3 → H3AsO3 + H+
[1986, 1M]
[1984, 2M]
MnO 4− + 5Fe2+ + 8H + → Mn 2+ + 5Fe3+ + 4H 2O
[1988, 3M]
7
MOLE CONCEPT & STOICHIOMETRY
27.
28.
An equal volume of a reducing agent is titrated
separately with 1M KMnO4 in acid neutral and
alkaline media. The volumes of KMnO4 required
are 20 ml. in acid, 33.4 ml. neutral and 100 ml. in
alkaline media. Find out the oxidation state of
manganese in each reduction product. Give the
balanced equations for all the three half reactions.
Find out the volume of 1M K2Cr2O7 consumed; if
the same volume of the reducing agent is titrated in
[1989, 5M]
acid medium.
A mixture of H2C2O4 (oxalic acid) and NaHC2O4
weighing 2.02 g was dissolved in water and
solution made upto one litre. Ten milliliters of the
solution required 3.0 ml. of 0.1 N sodium
hydroxide solution for complete neutralization. In
another experiment, 10.0 ml. of the same solution,
in hot dilute sulphuric acid medium. require
4.0 ml. of 0.1 N potassium permanganate solution
for complete reaction. Calculate the amount of
H2C2O4 and NaHC2O4 in the mixture. [1990, 5M]
29.
A solid mixture (5.0 g) consisting of lead
nitrate and sodium nitrate was heated below
600°C until the weight of the residue was
constant. If the loss in weight is 28.0 per cent,
find the amount of lead nitrate and sodium
[1990, 4M]
nitrate in the mixture.
30.
Calculate the molality of 1 litre solution of
93% H2SO4 (weight/volume). The density of the
[1990, 1M]
solution is 1.84 g/ml.
31.
A solution of 0.2g of a compound containing
Cu2+ and C 2O 24− ions on titration with 0.02 M
32.
A 1.0 g sample of Fe2O3 solid of 55.2% purity is
dissolved in acid and reduced by heating the
solution with zinc dust. The resultant solution is
cooled and made upto 100.0 ml. An aliquot of
25.0 ml of this solution requires 17.0 ml of
0.0167 M solution of an oxidant for titration.
Calculate the number of electrons taken up
by the oxidant in the reaction of the above
[1991, 4M]
titration.
33.
A 2.0 g sample of a mixture containing sodium
carbonate, sodium bicarbonate and sodium
sulphate is gently heated till the evolution of
CO2 ceases. The volume of CO2 at 750 mm Hg
pressure and at 298 K is measured to be
123.9 ml. A 1.5g of the same sample requires
150 ml. of (M/10) HCl for complete
neutralization. Calculate the % composition of
[1992, 5M]
the components of the mixture.
34.
One gram of commercial AgNO3 is dissolved in
50 ml. of water. It is treated with 50 ml. of a KI
solution. The silver iodide thus precipitated is
filtered off. Excess of KI in the filtrate is titrated
with (M/10) KIO3 solution in presence of 6M
HCl till all I– ions are converted into ICl. It
requires 50 ml. of (M/10) KIO3 solution. 20 ml.
of the same stock solution of KI requires 30 ml.
of (M/10)KIO3 under similar conditions.
Calculate the percentage of AgNO3 in the
sample.
(Reaction : KIO3 + 2KI + 6HCl → 3ICl + 3KCl +
[1992, 4M]
3H2O)
35.
Upon mixing 45.0 ml. of 0.25 M lead nitrate
solution with 25.0 ml of 0.10 M chromic
sulphate solution, precipitation of lead sulphate
takes place ? How many moles of lead sulphate
are formed. Also, calculate the molar
concentration of the species left behind in the
final solution. Assume that lead sulphate is
[1994, 2M]
completely insoluble.
36.
The composition of a sample of Wustite is
Fe0.39 O1.00. What percentage of the iron is
[1994, 2M]
present in the form of Fe (III) ?
KMnO4 in presence of H2SO4 consumers
22.6 ml. of the oxidant. The resultant solution
is neutralized with Na2CO3, acidified with dil.
acetic acid and treated with excess KI. The
liberated iodine requires 11.3 ml of 0.05 M
Na2S3O3 solution for complete reduction.
Find out the molar ratio of Cu2+ to C 2O 24− in
the compound. Write down the balanced redox
reactions involved in the above titrations.
[1991, 5M]
8
37.
38.
39.
39 YEARS TOPIC- WISE JEE Advanced Questions with Solutions
–2
8.0575 × 10 kg of Glauber’s salt is dissolved in
water to obtain 1 dm3 of a solution of density
1077.2 kg m–3. Calculate the molarity, molality
and mole fraction of Na2SO4 in the solution.
[1994, 3M]
A 3.00 g sample containing Fe3O4, Fe2O3 and an
inert impure substance, is treated with excess of
KI solution in presence of dilute H2SO4.
The entire iron is converted into Fe2+ along with
the liberation of iodine. The resulting solution is
diluted to 100 ml. A 20 ml of the diluted solution
requires 11.0 ml of 0.5 M Na2S2O3 solution to
reduce the iodine present. A 50 ml of the diluted
H2SO4 medium for the oxidation of Fe2+.
Calculate the percentages of Fe2O3 and Fe3O4 in
[1996, 5M]
the original sample.
An aqueous solution containing 0.10 g KIO3
(formula weight = 214.0) was treated with the an
excess of KI solution. The solution was acidified
with HCl. The liberated I2 consumed 45.0 mL of
thiosulphate solution to decolourise the blue starchiodine complex. Calculate the molarity of the
[1998, 5M]
sodium thiosulphate solution.
40.
How many millilitres of 0.5 M H2SO4 are
needed to dissolve 0.5 g of copper(II)
[1999, 3M]
carbonate?
41.
A plant virus is found to consist of uniform
cylindrical particles of 150 Å in diameter and
5000 Å long. The specific volume of the virus is
0.75 cm3/g. If the virus is considered to be a
single particle, find its molar mass. [1999, 3M]
42.
Hydrogen peroxide solution (20 ml) reacts
quantitatively with a solution of KMnO4(20 ml)
acidified with dilute H2SO4. The same volume
of the KMnO4 solution is just decolourised
by 10 ml of MnSO4 in neutral medium
simultaneously forming a dark brown
precipitate of hydrated MnO2. The brown
precipitate is dissolved in 10 ml of 0.2 M sodium
oxalate under boiling condition in the presence
of dilute H2SO4. Write the balanced equations
involved in the reactions and calculate the
[2001, 5M]
morality of H2O2.
43.
Calculate the molarity of water if its density is
[2003, 2M]
1000 kg/m3.
44.
The oxidation number of Mn in the product of
alkaline oxidative fusion of MnO2 is [2009]
45.
A student performs a titration with different
burettes and finds titre values of 25.2 mL,
25.25 mL and 25.0 mL. The number of
significant figures in the average titre value is
[2010]
46.
Silver (atomic weight = 108 g mol–1) has a
density of 10.5 g cm–3. The number of silver
atoms on a surface of area 10–12 m2 can be
expressed in scientific notation as y × 10x. The
[2010]
value of x is
47.
Among the following, the number of elements
showing only one non-zero oxidation state is
O,
Cl,
F,
N.
P,
Sn,
Tl,
Na,
TI
[2010]
48.
Reaction of Br2 with Na2CO3 in aq. solution
gives sodium bromide and sodium bromate
with evolution of CO2 gas. The number of
sodium bromide molecules involved in the
[2011]
balanced chemical equation is.
49.
The difference in the oxidation numbers of the
two types of sulphur atoms in Na2S4O6 is.
[2011]
50.
A decapeptide (mol. wt. 796) on complete
hydrolysis gives glycine (mol. wt. 75), alanine
and phenylalanine. Glycine contributes 47.0%
to the total weight of the hydrolysed products.
The number of glycine units present in the
[2011]
decapeptide is.
51.
The volume (in mL) of 0.1 M AgNO3 required
for complete precipitation of chloride ions
present in 30 mL of 0.01 M solution of
[Cr(H2O)5Cl]Cl2, as silver chloride is close to
[2011]
9
MOLE CONCEPT & STOICHIOMETRY
52.
29.2% (w/w) HCl stock solution has a density
of 1.25 g mL–1. The molecular weight of HCl is
36.5 g mol–1. The volume (mL) of stock
solution required to prepare a 200 mL solution
[2012]
of 0.4 M HCl is.
54.
If the value of Avogadro number is
6.023 × 1023 mol–1 and the value of Boltzmann
constant is 1.380 × 10–23 J K–1, then the
number of significant digits in the calculated
[2014]
value of the universal gas constant is
53.
Consider the following list of reagents :
Acidified K2Cr2O7, alkaline KMnO4, CuSO4,
H2O2, Cl2, O3, FeCl3, HNO3 and Na2S2O3.
The total number of reagents that can oxidise
[2014]
aqueous iodide to iodine is
55.
In neutral or faintly alkaline solution, 8 moles
of permanganate anion quantitatively oxidize
thiosulphate anions to produce X moles of a
sulphur containing product. The magnitude of
[2016]
X is
10
39 YEARS TOPIC- WISE JEE Advanced Questions with Solutions
ANSWERS
¾ Only One Correct Answer
1.(D)
2.(C)
3.(A)
4.(A)
5.(C)
6.(A)
7.(A)
8.(D)
9.(C)
10.(C)
11.(A)
12.(B)
13.(B)
14.(D)
15.(C)
16.(B)
17.(B)
18.(A)
19.(A)
20.(D)
21.(A)
22.(D)
23.(C)
24.(A)
25.(B)
26.(D)
27.(A)
28.(A)
29.(B)
30.(D)
31. (B)
32. (C)
33. (A)
4. 4.14g
5. +
3. 59.36 %
4. 8.38
6. CH4
7. Na2O = 3.58 %, K2O = 10.62 %
¾ Assertion‐Reason Type
1. (C)
¾ One or More than One Correct Answers
1. (A,C,D)
2. (A,B,D)
¾ Matrix Match Type
1. (D)
¾ Fill in the Blanks
2. 6.02 × 1023
1. Carbon
3. 0.4
7
3
¾ Analytical & Descriptive Question
1. 4.87 g
2. Al 54.87 %, Mg 45.13 %
–3
5. (a) 9.5 × 10 gram mole, (b) 0.437
8. 24
9. 49
10. 1.338 gm
11. (a) 1.95 parts ; (b) 1 milli equivalents ; (c) (i) Mg, (ii) 0.25, (iii) 62.5 ml
13. 3.5 × 10–3 g 14. 53.53
12. C7H8
18. (i) 37.92 ; (ii) 0.065 ; (iii) 7.74, 3.87
23. HI < I2 < ICI < HIO4
15. 0.588 N
17. 39.6 g l–1
19. Ca
21. 2
22. 6.3648 g
24. (i) 1.446 gm, 0.112 M ; (ii) 1.7532 g, 0.1334 M
25. (i) 0.56 ; (ii) 0.0999
26. 6.5 g
27. +2, +4, +6, 16.66 ml
28. 1.12 g, 0.90 g
30. 10.43
31. 1:2
33. Na2CO-26.5%, Na2SO4-31.5%
32. 6
29. 3.324 g, 1.676 g
34. 85%
35. 0.0075, Pb2+ = 0.05357 M, NO3− = 0.3214 M, Cr3+ = 0.0714 M
36. 15.05%
37. 0.25 M, 0.24 mg, 4.3 × 10–3
38. 49.33%, 34.8%
39. 0.062
40. 8.097 l ml
7
41. 7.09 × 10
42. 0.1
43. 55.55 M
44. 6
45. 3
46. 7
47. 2
48. 5
49. 5
50. 6
51. 6
52. 8
53. 7
54. 4
55. 6
11
MOLE CONCEPT & STOICHIOMETRY
SOLUTIONS
Ratio of molecules of oxygen : nitrogen
Only One Correct Answer
1.
4Al + 3O2 → 2Al2O3
At. wt. of Al = 27 g
=
Q 4 × 27 g of Al reacts with = 3 × 32 g of oxygen
3 × 32
∴ 27 g of Al reacts with =
× 27 g of
4 × 27
oxygen = 24 g of oxygen
2.
No. of Nitrogen atoms =
No. of oxygen atoms =
6.
1
2Ag + O 2
2
(residue)
Mol. wt. of Ag2CO3 = 107 × 2 + 12 + 16 × 3
= 274 g
∴ 274 g of Ag2CO3 on heating gives = 2 × 107
= 214 g of Ag
∴ 2.76 g of Ag2CO3 on heating gives
214
=
× 2.76
274
= 2.16 g of Ag
Mass 28
=
=2
M. wt. 14
Mass 80
=
=5
M. wt. 16
(a) 18 g of H2O = 6.02 × 1023 molecules of H2O
∴36 g of H2O = 2 × 6.02 × 1023 molecules of H2O
(b) 28 g of CO = 6.02 × 1023 molecules of CO2
(c) 46 g of C2H5OH = 6.02 × 1023 molecules
of C2H5OH
(d) 108 g of N2O5 = 6.02 × 1023 molecules of
N2O5
1
∴ 54 g of N2O5 = × 6.02 × 10 23 molecules of
2
N2O5
∴ 36 g water has highest number of
molecules.
4.
No. of e– in C = 6 and in O = 8
∴ Total no. of e– in CO2 = 6 + 8 × 2 = 22
5.
Let mass of oxygen = 1g
Let mass of Nitrogen = 4g
Mol. wt. of N2 = 28g,
Mol. wt. of O2 = 32g
Q 28 g of N2 has = 6.02 × 1023 molecules
Q 4g of N2 has =
6.02 × 10 23
× 4 molecules
28
6.02 × 1023
molecules
7
∴ 32 g of O2 has = 6.02 × 1023 molecules
=
∴ 1g of O2 has =
6.02 × 10 23
6.02 × 10 23
×1 =
32
32
∆
Ag2CO3 
Ag2O + CO2
→
∆
↓
∴ Formula of compound is N2O5.
3.
6.02 × 10 23 / 32
= 7 : 32
6.02 × 10 23 / 7
7.
M : e − + MnO 4− → MnO 24−
E.wt =
Mol. wt
M
=
=M
No. of e − 1
8.
Tips/Formula
(i) Write balance chemical equation for chemical
change.
(ii) Find limiting agent.
(iii) Amount of product formed will be
determined by amount of product formed.
Method :
3BaCl2 + 2Na3PO4 → Ba3(PO4)2 + 6NaCl
0.5
0.2
Limiting reagent is Na3PO4(0.2 mol), which
gives 0.1 mol of Ba2(PO4)2.
9.
Tips/Formula
(i) Find oxidation state of N in N2H4.
(ii) Find change in oxidation number with the help
of number of electrons given out during
formation of compound Y.
Method :
N2H4 → Y + 10 e–.
O.S. of N in N2H4 : 2x + 4 = 0 ⇒ x = –2
12
39 YEARS TOPIC- WISE JEE Advanced Questions with Solutions
The 2, nitrogen atoms will balance the charge of
10 e–.
Hence oxidation state of N will increase by +5,
i.e. from –2 to +3.
10.
Tips/Formula :
The sum of oxidation states of all atoms in
compound is zero.
Method :
O.S. of H = +1, O.S of O = –2 ;
∴ for CH2O.
x + 2 + (–2) = 0 ⇒ x = 0
11.
Tips/Formula :
Define molality
Method : A molal solution is one which contains
one mole of solute per 1000 g of solvent.
12.
Tips/Formula :
Sum of oxidation state of all atoms in compound is
zero.
Method :
Method :
(A) Molarity – Moles of solute/volume of
solution in L.
(B) Normality
–
gm
equivalents
of
solute/volume of solution in L.
(C) Formality – formula wt./volume of solution
in L.
(D) Molality – Moles involve volume term.
Q Molality does not involve volume term.
∴ It is independent of temperature.
15.
2 + 2 (2 + x – 4) = 0
or x = 2 – 1 ⇒ x = + 1
16.
Tips/Formula :
(i) Write balance chemical equation for given
changes.
(ii) Identify most electronegative element and
find its oxidation state.
Method :
BaO2 + H2SO4 → BaSO4 + H2O2
Oxygen being the most electronegative element
in the reaction has the oxidation states of –1 (in
H2O2) and –2 (in BaSO4)
17.
Tips/Formula :
Write reaction for titration between Na2CO3
and HCl.
Method :
Na 2CO3(aq ) + HCl(aq ) → NaHCO3 + NaCl( aq )
[Fe(H2O)5(NO)+]2+ SO 24− ; x + 5 × 0 + 0 = +2
13.
Tips/Formula :
(i) Equivalent weight
Molecular Weight
=
Change in oxidation state
(ii) Find oxidation state of Mn in MnSO4 and in
the choice in which the choice in which the
oxidation state is 2, will have equivalent
weight equal to molecular weight.
Method :
For equivalent weight of MnSO4 to be half of its
molecular weight, change in oxidation state must
be equal to 2. It is possible only when oxidation
state of Mn is +4 because oxidation state of Mn
in MnSO4 is +2. So, MnO2 is correct answer.
14.
Tips/Formula :
(i) Volume is substance changes with
temperature and mass is not effected by
change in temperature.
(ii) Find expression which does not have volume
term in it.
( no colour
with HPh )
( yellow colour
with HPh )
NaHCO3 +
( yellow colour
second half
with methyl
orange)
HCl →
( Half
neutralisation )
NaCl + H 2O + CO 2
( red colour
with methyl
neutralization
orange)
From these reaction it is clear that
(i) 2 moles of HCl are requires for complete
neutralization of Na2CO3.
(ii) Titre
value
using
phenolphthalein
corresponds only to neutralization of
Na2CO3 to NaHCO3, i.e. half of value
required by Na2CO3 solution.
(iii) Titre value using methyl orange corresponds
to complete neutralization of Na2CO3.
∴ Both S and E are correct but S is not correct
explanation of E.