Vidic 2:00 R01 Disclaimer—This paper partially fulfills a writing requirement for first year (freshman) engineering students at the University of Pittsburgh Swanson School of Engineering. This paper is a student, not a professional, paper. This paper is based on publicly available information and may not provide complete analyses of all relevant data. If this paper is used for any purpose other than these authors’ partial fulfillment of a writing requirement for first year (freshman) engineering students at the University of Pittsburgh Swanson School of Engineering, the user does so at his or her own risk. THE CIRCLE OF LIFE Tristan Witek ([email protected]) OUR MESS OF A WORLD In today’s world, we have innumerable problems, ranging from the political to the ethical to the technical. With so many problems to solve, how has humanity not already collapsed from lacking the intellectual infrastructure to support itself? The answer: engineers. To solve any problem, or complex of problems, one must analyze the parts of the problem, and only then can it be solved. So, this paper will fill that duty, analyzing a current problem in the world, and analyzing problems with potential solutions to that problem. THE NITROGEN CYCLE One of the most eminent problems of this century, global warming has roots like a weed; tons of sources spreading out, and all of them contributing to its exponential growth. However, the nitrogen cycle could be the most dangerous root. The Natural Nitrogen Cycle The nitrogen cycle is not inherently bad; it is, in fact, a natural occurrence through which plants and animals receive necessary nutrients, and microbes then release nitrogen back into the air. Indeed, the Ecological Society of America (ESA) board members note in a journal on issues in ecology that “Nitrogen is an essential component of proteins, genetic material, chlorophyll, and other key organic molecules. All organisms require nitrogen in order to live” [1]. Being so important, how does this essential cycle work? It starts with the atmosphere; nitrogen molecules compose 78% it. But, as Scott Fields points out, “most atoms of nitrogen… are bound tightly in pairs as N2. Most organisms can’t break the powerful triple bond of the N2 molecule’s two atoms” [2]. For the organisms to get the nitrogen they need, there must be some organic way to get nitrogen out of its unreactive state. These more reactive states of nitrogen exist as the ammonium (NH4) and nitrate (NO3) ions, and only lightning and certain University of Pittsburgh, Swanson School of Engineering 1 11.1.2016 bacteria can cause this transformation. The ESA board says that “these bacteria manufacture an enzyme that enables them to convert gaseous nitrogen directly into plant-usable forms. Lightning may also indirectly transform atmospheric nitrogen into nitrates, which rain onto soil” [1]. However, lightning does not contribute a very significant amount of reactive nitrogen to the cycle; the majority comes from the microbes in soil. Once ammonium and nitrate are in the soil, plants can access these reactive nitrogen compounds, and perform biological processes to extract the necessary nitrogen atoms. Microbes complete the cycle when any living thing dies and they decompose it, converting the nitrogen in the dead organism back into gaseous, unreactive nitrogen, or the reactive nitrogen compounds stay in the soil. Naturally, the nitrogen cycle is perfectly fine; the problem arises when it becomes altered. The Altered Nitrogen Cycle As humans discover new ways to exploit nature, nature often pays a grave price; the exact occurrence with the nitrogen cycle. Humans started altering the nitrogen cycle when two scientists, Fritz Haber and Carl Bosch, developed a chemical process that converted atmospheric nitrogen into ammonia, which allowed humans to artificially increase the reactive nitrogen concentration in soil, a process more commonly known as fertilizing [2]. At the time, the breakthrough was considered miraculous; Fields cites Smil as saying that “for at least a third of humanity in the world’s most populous countries, the use of nitrogen fertilizers makes the difference between malnutrition and adequate diet” [2]. However, despite the good nitrogen fertilizers do in supporting humanity’s population, it causes some serious detriments to the environment. Because of the exponential growth in human population, the demand for food has risen proportionately, requiring the over-use of these nitrogen fertilizers. But can we have too much of a good thing? As it turns out, this process does not solely produce “good things;” the ESA points out that “intensive fertilization of agricultural soils can increase the rates at which at which ammonia is Tristan Witek to a landfill” [5], which does ring true. Immediately, it is more expensive to send not only recyclables, but also organic waste to recycling and composting centers than it is to send them to landfills. Since Tierny also asserts that “all trash generated by Americans for the next 1000 years would fit on .1% of the land available for grazing” [5], a fear of running out of landfill space is also impractical. Another potential problem lies within the net environmental impact of the composting process. Depending on the location of a composting center, transporting the materials could use up so much fuel that it offsets the benefit of using the material as compost. Howard records DatzRomero as saying “What I’m concerned about is our capacity to handle the material locally, because that’s a big part of making composting sustainable; otherwise you are spending a lot of fuel transporting it, and that doesn’t make sense” [3]. What point is there in composting if it’s simply a tradeoff from one environmental poison to another? Again regarding negative impacts on the environment, the process of composting can release the very potent greenhouse gases methane and nitrous oxide [6], again contributing to global warming. Tierny argues that landfills handle this biogas release better than composting, because “landfill operators have started capturing it and using it to generate electricity” [5]. Aside from the greenhouse effect, methane smells exactly like what one would expect from decomposing organic matter. Nearly every source that one can find on composting makes some mention of the rancid smell as a byproduct of composting. By this argument, composting is an economically, environmentally, and olfactory failure of a solution. volatized and lost to the air. It can also speed the microbial breakdowns of ammonium and nitrates in the soil, enhancing the release of nitrous oxide [(NO)]” [1]. All this fertilizer causes a large release of ammonia and nitrous oxide into the air, both of which carry deadly impacts for the environment. Starting with ammonia, it can react with acidic compounds in the atmosphere, forming particulate matter which then becomes a basis for smog and potential lung infections if too much is breathed in [2]. Nitrous oxide, a far deadlier beast, has a wide array of problems it can cause, as Fields mentions that “a single atom [of reactive nitrogen] can make mischief repeatedly” [2]. A few of these effects include the formation of smog in the lower atmosphere, contributions to global warming and acid rain in the middle atmosphere, and the destruction of protective ozone in the stratosphere. These effects from one atom, which can stay around in the atmosphere for over a century, makes it imperative to all citizens of the planet to contribute some help in fixing this massive problem. If nobody attempts to stop the destruction of the Earth’s atmosphere, then the planet will die. REDUCING USE OF NITROGEN FERTILIZERS One major source of all this extra nitrogen does come from the artificial fertilizers we use on our farms. Logically, if there were a way to reduce the use of those fertilizers, it should help reduce the amount of new nitrogen added to the nitrogen cycle. As it turns out, there is a way. Composting already happens naturally in the nitrogen cycle, which releases nonreactive nitrogen, but also releases reactive nitrogen compounds back into the soil. But left on its own, this process can take at least a year. However, techniques exist to speed up the natural process to 1-3 months. This sped up process involves putting organic material in a giant grinder to grind it to a desired texture, then placing it in a device that manages oxygen levels and heat to stimulate microbial breakdown of the organic material. This mixture then sits outside, receives water, and is turned occasionally to keep the conditions ideal for microbial digestion [3]. The resulting mixture resembles soil, but has a lot of reactive nitrogen compounds. Pros of Composting On the other hand, since compost is so rich in reactive nitrogen compounds, it makes sense that farmers can use it as an alternative to the artificial fertilizers. In fact, Brian Howard for the National Geographic cites Robert Weed as saying that “such compost helps farmers rely less on chemical fertilizers” [3]. Both compost and nitrogen fertilizers do the same job; they add more reactive nitrogen to the soil, which helps the plant grow. However, since compost comes from organic material, it does not add any new nitrogen to the cycle, whereas artificial fertilizers continue to add new nitrogen, which causes problems in the atmosphere. Composting also reduces the amount of organic material sent to landfills. This impacts the world positively, as Howard writes that “she [Christine Datz-Romero] notes that when placed in landfills, organic waste releases methane, a potent greenhouse gas” [3]. To counter Tierny’s argument on Cons of Composting First off, composting does have its flaws. John Tierny in the New York Times expresses that “Despite decades of exhortations and mandates, it’s still typically more expensive for municipalities to recycle household waste than to send it 2 Tristan Witek landfills handling methane better, one could simply repurpose the same technology used at landfills to composting centers. Thus, composting can easily perform better than simply sending waste to landfills. One last fantastic aspect about composting centers on money. When cities compost organic material, they can sell the product to farmers, companies, or regular citizens and turn a profit. Once again, to counter Tierny, Stephanie Strom reports in the New York Times that “The city [New York] brought in $267,00 from the sale of 21,000 cubic yards of Dillo Dirt [compost] in the fiscal year that ended September 30th [of 2013]” [4]. With that figure only on the rise, cities stand to make a lot of money from compost as the years progress. This source of revenue more than pays for the extra cost of sending waste to composting centers, leading to a profit. Overall, composting is a good thing for society because it provides our government with more money and it protects the planet on which we live. thrown in a dumpster. It always hurt my conscience that I was contributing to a massive food waste problem. Thus, using food waste, quantitatively and ethically, is a totally viable option. With so much food wasted, all resources that went into making that food can be considered wasted as well. With nitrogen fertilizers considered as a resource, logically one could say that we used the nitrogen only to waste it. If we must accept the amount of food American society wastes, then we can at least try to use that food to lessen the use of nitrogen fertilizers. With all the wasted food available, we can add it to compost, and use it to aid in the reduction of the usage of nitrogen fertilizers. This reduction returns to the idea of reducing nitrogen pollution, part of the engineer’s job to save the world. On top of saving the world, this repurposing can help society feel a little less guilty about their enormous waste; as Al Baker of the New York Times observes, “Depending on the viewpoint, the sheer amount of food now being composted is either impressive or depressing” [8]. It is indeed depressing that we waste so much food, in light of all the hunger that exists in the nation. However, we can take pride as a nation that the food wasted is not totally lost. UNTAPPED CONTRIBUTIONS TO COMPOST Public Compliance Since microbes can decompose anything organic, they can also decompose just about any food that we humans eat. If the microbes can digest it, then humans can compost it. Cities around the country have been collecting yard trimmings for years, but, as Strom quotes Bob Gedert, “we have been collecting yard trimmings from residents, but not food waste” [4]. Since food counts as organic material, why can’t we use it for compost? It appears as if the green light shines bright for using food in compost; compost effectively combats the use of nitrogen fertilizer, food counts as a candidate for organic material in compost, and there’s plenty of excess food lying around. Yet, one last burden stands in the way. Since most food waste occurs in households, governments require the participation of the public if they have any hopes of effectively collecting food waste for composting purposes. In cities where the local government already collects some food waste, officials say that education is key for encouraging citizens to participate. Guillermo Rodriguez, an official from San Francisco (which was the first city in the United States to make composting food waste mandatory) commented to Howard that “we do a lot to educate our residents about it… there was some resistance to the mandatory program, but a lot of that comes down to education” [3]. So for citizens to comply with recycling food waste, it is necessary to educate them on why they should partake in it. If citizens can realistically be expected to contribute to the compost of food waste, then the only remaining component to worry about is if such a goal is fiscally possible. Elizabeth Daigneau reports in Governing that “Portland, [Oregon] estimates that its composting program cost about $1 million to set up – most of which was spent on education efforts” [9]. To set up similar programs across the country would roughly Food Waste The answer is we can, but the real question is, should we? Is there enough wasted food in this country to make recycling it a viable option for addition to compost? For perspective, Strom records that “Americans threw away more than 36 million tons of food in 2012” [4], which, as Kevin Hall and his colleagues calculate, is about 40% of all food produced in America [7]. To truly get a sense of how wasteful that is, imagine going to the grocery store, buying five bags worth of food, and then instantly throwing away two of those five bags. That figure does not even consider unavoidable food waste, such as egg shells, coffee grinds, and bones, which can also become compost. I have seen this waste firsthand after working in a kitchen for over a year. I saw countless amounts of food go to waste from customers, entire trash bags full of what could be repurposed into fertilizer for other crops be 3 Tristan Witek be the $1 million across about 300 cities, or $300 million; a small figure compared to the $601 billion the US spends on military. If we can afford to spend more than every American collectively earns on only military, surely we can spend $300 million to try and help the environment. As a society, it is imperative that we try to atone for our sins; recycling food waste for compost knocks out two birds with one stone. It repurposes all the wasted food we throw away, and helps repair the destruction we’ve wrought upon the atmosphere. Engineers also score a two-for-one here, as food waste forces many critical discussions in the engineering community, and now there’s a comprehensible solution. “the unhappy neighbors of the composting plant successfully campaigned to shut it down” because of complaints of “nauseating odors” [5]. Aside from the fact that it was shut down, the use of a composting plant in Delaware makes little to no sense for New York City; this ties back into the potential issue with transporting the organic materials causing too many environmental problems of its own. So, to be expected, the city’s efforts had a somewhat mixed resolution; there were key successes, yet also fundamental flaws. IMPLEMENTATIONS OF FOOD WASTE IN COMPOST Finally, it appears there are three main challenges that composting must overcome before it can truly begin to save the nitrogen cycle. One main point of debate is its true cost effectiveness; sources on either side of the argument exclaim that composting is either more or less expensive than landfills. Since it obviously can’t be both, professionals need to examine the costs and benefits, and determine a sound financial result on composting before everyone is convinced of its use. Another challenge comes from ensuring that composting is more environmentally friendly than alternatives. To ensure that composting remains eco-friendly, governments must use local plants so materials need not travel too far. The last, and as far as I can find, the apparent toughest challenge to overcome, is the smell. We’re shooting down this potential solution to one of the environment’s largest problems because delicate human noses can’t take the smell. The real challenge here is, as Rodriguez said, to educate people, and make composting be seen as a necessity, not an alternative, or a way to make a quick buck. Tierny captures David P. Steiner epitomizing this problematic way of thinking, recording “Trying to turn garbage into gold costs a lot more than expected. We need to ask ourselves. What are we trying to accomplish here?” [5]. However, when we capture biogas from sewage treatment plants, nobody criticizes that as trying to turn fecal matter into gold, even though sewage is just as smelly as compost. Why? Because cleaning our sewage defines a healthy, civilized society, and so should composting. If we can tolerate sewage, surely we can tolerate compost as well. It’s about time that in addition to our carbon footprint, we begin worrying about our nitrogen noseprint as well. FINAL THOUGHTS A few years ago, New York City tried to follow in San Franciso’s footsteps and impose a so-called “zero waste” policy. This translates to the introduction of food waste recycling, and New York City itself set an amazing example. Successes New York’s plan essentially accomplished all it set out to do. The city reduced its landfill food waste by about 10%, sending 100,000 tons of food scraps for compost in the first year, a number which only rose and continues to rise. Obviously due to the success the city has had, the public obliged, and went along with the plan. In fact, many citizens had been composting on their own before the local government announced its plan. The city also acquired revenue from the process, which, as mentioned before, offsets the net cost to a net profit instead. The mayor’s plan worked perfectly. What’s more, public schools in the surrounding area caught on, and added their food waste to the compost pile. Baker notes that “children are still as picky and wasteful as ever, but at least now there’s a happier ending – that bananafilled bin is a composting container, part of growing effort to shrink the amount of perfectly good food being hauled to landfills every year” [8]. With so many schools adding to the compost heap, which has already been shown to be a good, effective solution, New York has been basking in the glory of many jobs well done. Failures However, after a few years of the program, New York ran into one major obstacle. One of the main composting plants the city used was based in Delaware, and, according to Tierny, 4 Tristan Witek http://www.governing.com/topics/energy-env/gov-curbsidecomposting-added-to-major-city.html SOURCES ADDITIONAL SOURCES [1] S. Carpenter et al. “Human Alterations of the Global Nitrogen Cycle: Causes and Consequences.” Issues in Ecology. 11.1.1997. Accessed 10.28.2016. http://www.esa.org/esa/documents/2013/03/issues-inecology-issue-1.pdf [2] S. Fields. “Global Nitrogen: Cycling Out of Control.” Environmental Health Perspectives. 7.2004. Accessed 10.28.2016. https://www.ncbi.nlm.nih.gov/pmc/articles/PMC1247398/ [3] B. Howard. “How Cities Compost Mountains of Food Waste.” National Geographic. 7.18.2013. Accessed 10.28.2016. http://news.nationalgeographic.com/news/2013/06/130618food-waste-composting-nyc-san-francisco/ [4] S. Strom. “Recycling the Leftovers.” New York Times. 5.16.2014. Accessed 10.28.2016. http://www.nytimes.com/2014/05/17/business/cities-andcompanies-tackle-the-food-waste-problem.html?_r=0 [5] J. Tierny. “The Reign of Recycling.” New York Times. 10.3.2015. Accessed 10.28.2016. http://www.nytimes.com/2015/10/04/opinion/sunday/thereign-ofrecycling.html?rref=collection%2Ftimestopic%2FCompost &action=click&contentCollection=timestopics®ion=stre am&module=stream_unit&version=latest&contentPlacemen t=2&pgtype=collection&_r=0 [6] National Academy of Engineering. “Manage the Nitrogen Cycle.” Grand Challenges for Engineers. Accessed 10.28.2016. http://www.engineeringchallenges.org/9132.aspx [7] K. Hall et al. “The Progressive Increase of Food Waste in America and its Environmental Impact.” PLoS One. 11.25.2009. Accessed 10.28.2016. https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2775916/ [8] A. Baker. “At School, Turning Perfectly Good Food into Perfectly Good Compost.” New York Times. 6.22.2014. Accessed 10.28.2016. http://www.nytimes.com/2014/06/23/nyregion/at-new-yorkcity-schools-turning-good-food-into-perfectly-goodcompost.html?rref=collection%2Ftimestopic%2FCompost& action=click&contentCollection=timestopics®ion=strea m&module=stream_unit&version=latest&contentPlacement =10&pgtype=collection [9] E. Daigneau. “Curbside Composting Added to a Major City: Is it Yours?” Governing. 2.2012. Accessed 10.28.2016. “Compost.” Accessed 10.28.2016. http://www.madehow.com/Volume-5/Compost.html “List of United States cities by population.” Wikipedia. Accessed 10.28.2016 https://simple.wikipedia.org/wiki/List_of_United_States_citi es_by_population B. Thomas. “The Nitrogen Cycle.” 2.25.2000. Accessed 10.28.2016. https://www.cas.miamioh.edu/mbiws/biogeochemicalcycles/nitrogen/nitrogen.htm ACKNOWLEDGEMENTS I would like to thank Trevor Lingle for imparting his formatting knowledge once again, and for his supplemental information on the subject matter. I would also like to thank Shohini Banerjee for assisting me in cultivating the idea for this paper before the research even started. As always, I must thank Claude Debussy for the music which keeps me busy at work. Finally, I would like to thank Tim Miller, the man who hired me in his kitchen and sparked my interest in food waste in the first place, sending my brain on a scavenger hunt to look for solutions. 5
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