MATERIALS HANDBOOK Introduction Rocks are classed into three classes according to their origins: - magmatic rocks sedimentary rocks metamorphic rocks Magmatic rocks: originate from the solidification of the magma beneath the earth’s crust. Magmatic rocks can be divided into: - Intrusive or plutonic rocks formed from the solidification of the magma deep below the surface (eg. granite, diorite ,sienite, gabbro) - Effusive or volcanic rocks formed from the solidification of the magma on the earth’s surface (eg. basalt, porphry, trachyte) - Pyroclastic rocks formed from the subaerial deposit of erupted materials from volcanos like peperino. MAGMATIC ROCKS Basalt (Sicily) Diorite (Piedmont) Peperino (Latium) Granite (Sardinia) 1 Sedimentary rocks: originate from the deposition of preexisting rock debris and/or animal or vegetal remains. Sedimentary rocks are divided into: -clast or mechanical deposited rocks formed from the stratification of existing rock fragments which, by a process of cementing, subsequently moulded together to form new coherent rocks such as breccias, puddinghe and sandstones; -physical-chemical deposited rocks such as travertine which is formed in continental areas at the mouth of sources of limewater; following the reduction in pressure and the dispersion of carbon dioxide precipitation (deposition) of the calcium carbonate occurs; -biochemical rocks formed from the deposit of the remains of animal and vegetal organisms; the rocks of particular interest in this group for ornamental use are limestones. SEDIMENTARY ROCKS Ceppo di Grè (Lombardy) Arabescato Orobico grigio (Lombardy) Pietra di Firenzuola (Tuscany) 2 Metamorphic Rocks: formed from the chemical, physical and/or mechanical transformation of magmatic or sedimentary rocks. Examples of metamorphic rocks of magmatic origin are serizzi, serpentine schists and quartzites while those of sedimentary origin are marbles. METAMORPHIC ROCKS Beola (Piedmont) Bardiglio (Tuscany) Slate (Liguria) Pietra del Cardoso (Tuscany) 3 Magmatic Rocks solidification of melted masses (magma) Sedimentary Rocks deposition of debris on the Earth surface Metamorphic Rocks transformation of pre-existing rocks (metamorphism) The scientific and commercial classification of ornamental building stones Ornamental rocks can either be classified scientifically which essentially involves a definition of their mineral composition or commercially which considers other criteria such as the degree to which they can be worked and polished. Commercial classification divides rocks into four main groups: granites, marbles, stones and travertines. 4 GRANITES: hard silicate rocks which can be polished (granite, diorite, gabbro, sienite; porphyry, andesite, gneiss, granulite) According to EN standard 12670:2001 a granite is a compact rock which can be polished and is used for ornamental and building purposes. It is composed mostly of minerals, such as quartz and feldspar, the hardness of which on the Mohs scale is between 5 and 7. Commercially, other magmatic and volcanic rocks with a porphyric structure and metamorphic rocks with a similar composition to granitoids such as gneiss are defined as granites too. Again, according to EN standard 12670:2001, scienfically-speaking plutonic rocks containing feldspar, quartz, small quanities of plagioclast, mica and other minerals are also classed as granites. MARBLES: compact carbonatic rocks which can be polished (marble, lime schist, compact limestone). These are compact rocks which can be polished and used for ornamental and building purposes.They are composed mostly of minerals such as calcite, dolomite and serpentinite, the hardness of which is between 3 and 4 on the Mohs scale. This category includes rocks scientifically defined as marbles as well as limestones, dolomites, limestone brecce, travertines and serpentinites which can be polished (EN 12670:2001). Scientifically speaking EN 12670:2001 defines marbles as metamorphic rocks with a carbonate content of over 50% (calcite and dolomite) formed from the metamorphic recrystallisation of a carbonatic rock. 5 STONES: compact or porous rocks which cannot be polished (basalt, trachyte, conglomerate, sandstone, clay, tufo, soft limestone, dolomite, phyllite, micaschist, quartzite, serpentinite, amphibolite). Stones can be classified according to the following groups: -soft and/or compact rocks such as sedimentary rocks (calcarenites, lime-cemented sandstones, etc.) various pyroclastic rocks (peperino, tufo, etc.) -hard and/or compact rocks such as natural split rocks (quartzites, micaschists, layered gneiss, slates, etc.), some volcanites (basalts, trachytes, leucites, etc..). TRAVERTINES: are sedimentary rocks formed from physical-chemical deposition on the earth’s surface due to weathering from thermal mineral waters with a strong concentration of calcium carbonate. Calcium carbonate in the form of calcite is the main component. Travertines have a microcrystalline structure with pores; some varieties cannot be polished. 6 The technical characterisation of ornamental and building stones: new standards and CE marking in the stone industry Every rock has its own chemical, physical, mechanical and aesthetic characteristics according to its origin and mineral and petrographic characteristics. Consequently, every stone material has specific technical and ornamental propoerties which condition its performance. It is therefore vital for designers to be aware not only of a material’s aesthetic characteristics but also of its technical characteristics and in particular those which will influence its performance for the specific use in question. In addition, it is important for designers to be aware of current legislation on the subject of stone products. The 89/106/CEE directive on construction products (CPD) deals with stone materials with a view to removing the technical barriers which currently prevent the free circulation of construction products in the EC markets. The CPD applies to building materials and by this term means any product made to be permanently incorporated in buildings and civil engineering works. In Italy, the CPD has been applied with law 246/93 which sets out the criteria for placing building materials on the market, based on the suitability of their use and the consequent CE marking. With regard to CE marking products bearing this mark comply with the criteria set out in the 89/100/CEE directive. Hence CE marking shows that the product complies with all the legal requirements to be marketed in the European Economic Area. However, this does not mean that the product is necessarily suitable for all the end uses in all the Member States. The tables below list the standards for natural stone products and the relevant references to the different tests (geometric, petrographic, physical-mechanical, technological and durability) which may be conducted on these materials. We have also provided some brief indications as to the characteristics to be defined for each type of product. Classification of the standards for natural stone products 1 Standard product 1.1 Semi-finished products 1.1.1 Raw blocks (EN 1467) 1.1.2 Raw slabs (EN 1468) 1.2 Finished products 1.2.1 Slabs for cladding (EN 1469) 1.2.2 Slabs for floors and stairs (EN 12058) 1.2.3 Modular tiles (EN 12057) 1.2.4 Slabs for external paving (EN 1341) 1.2.5 Cubes for external paving (EN 1342) 1.2.6 Kerbs for pavements (EN 1343) 1.2.7 Products for discontinuous roofing (EN 12326-1) 1.2.8 Products for walls (prEN 771-6 rev*) 1.2.9 Solid products (in the process of being drawn up) 2 Terms standards EN 12440 Criteria for definitions EN 12670 Terminology 3 Test methods** 3.1 Geometric tests EN 772-16 Determination of product sizes for walls 7 EN 772-20 Determination of surface smoothness for wall products EN 13373 Determination of geometric characteristics of products 3.2 Petrographic tests EN 12407 Petrographic analysis 3.3 Physical-mechanical tests EN 772-1 Determination of compressive strength for wall products EN 772-11:2000/A1 Determination of water absorption coefficient by capillarity for wall products EN 1925 Determination of water absorption coefficient by capillarity EN 1926 Determination of compressive strength EN 1936 Determination of real density and apparent density and of total and open porosity EN 12372 Determination of flexural strength under concentrated load EN 13161 Determination of flexural strength under constant movement EN 13364 Determination of breaking load at dowel hole EN 13755 Determination of water absorption at atmospheric pressure EN 14146 Determination of dynamic elastic modulus by measuring the fundamental resonance frequency EN 14158 Determination of rupture energy EN 14205 Determination of knoop hardness EN 14579 Determination of sound speed propagation EN 14580 Determination of static elastic modulus EN 14581 Determination of thermal dilation coefficient 3.4 Durability tests EN 12370 Determination of resistance to salt crystallisation EN 12371 Determination of frost resistance EN 13919 Determination of resistance to ageing by SO2 action in presence of humidity EN 14066 Determination of thermal shock resistance EN 14147 Determination of resistance to ageing by salt mist 3.5 Technological tests EN 14157 Determination of the abrasive resistance EN 14231 Determination of the slip resistance by means of the pendulum tester (friction) * The ZA appendix to turn it into harmonised standard has been attached ** For slates for discontinuous roofing there is only one standard with all the test methods EN 12326-2 8 Characteristics to be defined for individual product types CHARACTERISTICS Geometric characteristics Definition of the geometric characteristics of products EN 13373 Petrographic characteristics Petrographic examination EN 12407 Physical-mechanical characteristics Raw blocks Raw slabs Slabs for claddings Slabs for floors and stairs Modular tiles X X X X X EN 1341 APP. A. X X X X X X Raw blocks Raw slabs Slabs for claddings Slabs for floors and stairs Modular tiles X(2) X(2) X(2) Water absorption coefficient by capillarity Slabs for Cubes for external paving external paving Kerbs for pavements Wall blocks EN 1342 APP. A EN 1343 APP. A EN 772-16 EN 772-20 X X X Kerbs for pavements Wall blocks Slabs for Cubes for external paving external paving EN 772 -11 EN 1925 Compressive strength EN X 1926 Real density and apparent density and of total and open porosity EN 1936 Flexural strength under concentrated load EN X X X X X X X X X X X X X X X X X EN 772 - 1 X X X 12372(1) Flexural strength under constant movement EN 13161 (1) Breaking load at dowel hole EN 13364 Water absorption at atmospheric pressure EN X X(2) X(2) X(2) X(2) 13755 Dynamic elastic modulus by measuring the fundamental resonance frequency EN 14146 9 Mechanical-physical characteristics Rupture energy EN 14158 Knoop hardness EN 14205 Raw blocks Raw slabs Slabs for claddings Slabs for floors and stairs Modular tiles Slabs for Cubes for external paving external paving Kerbs for pavements Wall blocks Raw blocks Raw slabs Slabs for claddings Slabs for floors and stairs Modular tiles Slabs for Cubes for external paving external paving Kerbs for pavements Wall blocks X X Sound speed propagation EN 14579 Static elastic modulus EN 14580 Thermal dilation coefficient EN 14581 Durability Resistance to salt crystallisation EN 12370 Frost resistance EN 12371 Resistance to ageing by SO2 action in presence of humidity EN 13919 Thermal shock resistance EN 14066 Resistance to ageing by salt mist EN 14147 Abrasive resistance EN 14157 Slip resistance by means of the pendulum tester (friction) EN 14231 (2) (2) (2) X X X X X X(2) X(2) X(2) X(2) X(2) X(2) X X(3) EN 1341 APP C EN 1342 APP B X X(3) EN 1341 APP D EN 1342 APP C (1) The two methods are alternatives (2) Only upon request (3) Only for use for floors and stairs General notes 1) The test method to be applied for the various products is the one given in the first column, if not otherwise specified 2) For the test methods for discontinuous roofing EN 12326 – 2 applies. 10 For further information regarding CE marking in the stone industry and the requirements for the current standards we advise you to consult the “Guida alla marcatura CE nel settore lapideo” (Guide to EC marking in the stone industry) by the Internazionale Marmi e Macchine Carrara Spa. 11
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