Name ________________________________ Period ____ Regents Review 4: Stoichiometry Review Book Topic 2,3 23 multiply by 6.02 x 10 divide by GFM grams atoms/ molecules moles 23 multiply by GFM divide by 6.02 x 10 multiply by 22.4 L divide by 22.4 L liters (gases only) A. The Mole a. Mole is defined as the number of atoms of carbon present in 12.000 grams of C-12. o The number of particles in a mole of a substance is 6.022 x 1023, which is called Avogadro’s number (Think 1 dozen means 12, 1 mole is 6.022 x 1023 particles) o The gram formula mass of any substance is the mass of one mole of the substance. b. Converting grams to moles or moles to grams use formula on the reference table c. Converting moles to atoms (particles) for elements or atoms to moles (see above) d. Converting moles to liters or liters to moles (see above) B. Determining Missing Mass in Equations (conservation of mass) mass of reactants=mass of products example: If 103.0 g of potassium chlorate are decomposed to form 62.7 grams of potassium chloride and oxygen gas according to the equation 2KClO3 → 2KCl + 3O2, how many grams of oxygen are formed? 2KClO3 → 2KCl + 3O2 ? 103.0 g = 62.7 g + ?(mass of oxygen) -62.7 g -62.7 g 40.3 g = ? (grams of oxygen) C. Molarity- use formulas on the reference table D. Molecular vs. Empirical Formula C3H6 is the molecular formula, CH2 is the empirical formula (simplest integer ratio) E. Mole relations in balanced equations Given quantity = Given quantity Moles in equation Moles in equation How many moles of water will be produced from the complete combustion of 3.0 mol of ethane according to the following equation? 2C2H6 (g) + 7 O2 (g) 4CO2 + 6H2O (g) 3 mol C2H6 = ? mol H2O 2 mole C2H6 6H2O Solve for ? mol water = 9 _____1. What is the empirical formula of the compound whose molecular formula is P4O10? (1) PO (2)PO2 (3) P2O5 (4) P8O20 _____2. Which gas sample at STP has the same total number of molecules as 2.0 liters of CO2(g) at STP? (1) 5.0 L of CO2(g) (3) 3.0 L of H2S(g) (2) 2.0 L of Cl2(g) (4) 6.0 L of He(g) Given the formula representing a hydrocarbon: ____3. The molecular formula and the empirical formula for this hydrocarbon are (1) C5H10 and CH2 (3) C4H8 and CH2 (2) C5H10 and CH3 (4) C4H8 and CH3 _____4. Which formula is both a molecular and an empirical formula? (1) C6H12O6 (3) C3H8O (2) C2H4O2 (4) C4H8 _____5. The molarity of an aqueous solution of NaCl is defined as the (1) grams of NaCl per liter of water (2) grams of NaCl per liter of solution (3) moles of NaCl per liter of water (4) moles of NaCl per liter of solution _____6. The gram-formula mass of NO2 is defined as the mass of (1) one mole of NO2 (2) one molecule of NO2 (3) two moles of NO (4) two molecules of NO _____7. What is the molarity of 1.5 liters of an aqueous solution that contains 52 grams of lithium fluoride, LiF, (gram-formula mass 26 grams/mole)? (1) 1.3 M (3) 3.0 M (2) 2.0 M (4) 0.75 M _____8. A compound has the empirical formula CH2O and a gram-formula mass of 60. grams per mole. What is the molecular formula of this compound? (1) CH2O (3) C3H8O (2) C2H4O2 (4) C4H8O4 _____9. A 1.0-mole sample of krypton gas has a mass of (1) 19 g (3) 39 g (2) 36 g (4) 84 g _____10.What is the empirical formula for a compound with the molecular formula C6H12Cl2O2? (1) CHClO (3) C3H6ClO (2) CH2ClO (4) C6H12Cl2O2 _____11.The compounds C2H4 and C4H8 have the same (1) freezing point at standard pressure (2) boiling point at standard pressure (3) molecular formula (4) empirical formula ____12. Which sample of HCl(aq) contains the greatest number of moles of solute particles? (1) 1.0 L of 2.0 M HCl(aq) (2) 2.0 L of 2.0 M HCl(aq) (3) 3.0 L of 0.50 M HCl(aq) (4) 4.0 L of 0.50 M HCl(aq) _____13. Given the balanced equation representing a reaction: 2Fe(s)+ 3Cu2+(aq)→2Fe3+(aq)+3Cu(s) When the iron atoms lose six moles of electrons, how many moles of electrons are gained by the copper ions? (1) 12 moles (3) 3 moles (2) 2 moles (4) 6 moles _____14.Given the balanced equation representing a reaction: Mg(s) + Ni 2+ (aq) →Mg 2+ (aq) + Ni(s) _____13. What is the total number of moles of electrons lost by Mg(s) when 2.0 moles of electrons are gained by Ni 2+(aq)? (1) 1.0 mol (3) 3.0 mol (2) 2.0 mol (4) 4.0 mol _____15. Which sample at STP has the same number of molecules as 5 liters of NO2(g) at STP? (1) 5 grams of H2(g) (2) 5 liters of CH4(g) (3) 5 moles of O2(g) (4) 5 ∙1023 molecules of CO2(g) _____16.The number of moles of ions in 1 mol of copper(II)phosphate is 1) 1 2) 4 3)2 4) 5 _____17. What is the gram formula mass of K2CO3? (1) 138 g (2) 106 g (3)99 g (4) 67 g _____18. What is the total number of atoms contained in 2.00 moles of nickel? (1) 58.9 (2)118 (3) 6.02 x 1023 (4)1.2 x 1024 _____19. Which solution is the most concentrated? (1) 1 mole of solute dissolved in 1 liter of solution? (2) 2 moles of solute dissolved in 3 liters of solution? (3) 6 moles of solute dissolved in 4 liters of solution? (4) 4 moles of solute dissolved in 8 liters of solution? _____20. What is the total number of moles of H2SO4 needed to prepare 5.0 liters of a 2.0 M solution of H2SO4? (1) 2.5 (2)5.0 (3)10 (4) 20 21. During a test, a propane lantern is operated for three hours and consumes 5.0 moles of propane from the lantern’s tank. The balanced equation below represents the combustion of propane. C3H8 + 5O2 →3CO2 + 4H2O + energy Determine the total number of moles of CO2 produced in the combustion of propane.[1] 19. Given the balanced equation representing a reaction: C3H8(g) + 5O2(g) →3CO2(g) + 4H2O(g) What is the total number of moles of O2(g) required for the complete combustion of 1.5 moles of C3H8(g)? 20. In an experiment, 40.0 milliliters of HCl(aq) is completely neutralized by 20.0 milliliters of 0.10 M NaOH(aq). Calculate the molarity of the titrated acid in this trial. Your response must include both a numerical setup and the calculated result. [2] 21. Determine the mass of 5.20 moles of C6H12 (gram-formula mass = 84.2 grams/mole).[1] 22. An unsaturated solution is made by completely dissolving 20.0 grams of NaNO3 in 100.0 grams of water at 20.0°C. Show a correct numerical setup for calculating the number of moles of NaNO3 (gram-formula mass = 85.0 grams per mole) used to make this unsaturated solution and solve. [1]
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