ACTIVITY NAME THAT COMPOUND 1 Minute to Name It! A list of chemical formula and names would be shown on the screen. Each student would need to identify the corresponding name (if a formula is given) or formula (if a name is given). 2 Li2Se AlCl3 Sr3P2 BaI2 Mg2N2 KF CaC2 MgH2 BeCl2 Cd3P2 CsCl NaBr BeCl2 Al2O3 BaS Ferric oxide Ferrous oxide Chromium(II) sulfide Chromium(III) oxide Lead(IV) oxide Copper(II) telluride Mercury(II) oxide Stannic fluoride Plumbous bromide Copper(I) chloride Cobalt(II) fluoride Lead(IV) oxide Nickel(II) phosphide Lead(IV) sulfide Nickel(II) iodide Li2Se Lithium selenide Fe2O3 Ferric oxide AlCl3 Sr3P2 BaI2 Mg3N2 KF CaC2 MgH2 BeCl2 Cd3P2 CsCl NaBr BeCl2 Al2O3 BaS Aluminum chloride Strontium phosphide Barium iodide Magnesium nitride Potassium fluoride Calcium carbide Magnesium hydride Beryllium chloride Cadmium phosphide Cesium chloride Sodium bromide Beryllium chloride Aluminum oxide Barium sulfide FeO CrS Cr2O3 PbO2 CuTe HgO SnF4 PbBr2 CuCl CoF2 PbO2 Ni3P2 PbS2 NiI2 Ferrous oxide Chromium(II) sulfide Chromium(III) oxide Lead(IV) oxide Copper(II) telluride Mercury(II) oxide Stannic fluoride Plumbous bromide Copper(I) chloride Cobalt(II) fluoride Lead(IV) oxide Nickel(II) phosphide Lead(IV) sulfide Nickel(II) iodide Stoichiometry of Formulas and Equations CHAPTER 3 Burning Magnesium Chemical reaction: 2 Mg(s) + O2(g) 2 MgO(s) 48 amu 32 amu 80 amu How do we look at this in terms of mass? ? grams 7 ? grams ? grams Mole (abbreviated mol) SI unit for amount of substance Number of entities as there are atoms in exactly 12 g of 12C Equal to 6.022 x 1023 entities 8 Called the Avogadro’s number How big is Avogadro’s Number? Volume of world’s oceans (L) Age of the earth (s) World population Avogadro’s Number: 602,200,000,000,000,000,000,000 Distance from earth to sun (cm) 9 College tuition Spreading 1 mole of marbles over the entire surface of the earth would produce a blanket of marbles almost 5 km high. A mole of water 10 A mole of other substances O2 (g) 32.00 g H2O (l) 18.02 g CaCO3 100.09 g Cu (s) 63.55 g 11 1 mole of Fe vs 1 mole of S 1 mole Fe 6.022 x 1023 Fe atoms 55.85 g Fe 12 1 mole S 6.022 x 1023 S atoms 32.07 g S The mole allows us to count out exactly the same number of things but use mass to do it! Molecular Mass and Molar Mass The molecular mass (or molecular weight) is the sum of the atomic masses (in amu) in a single molecule. The molar mass of a covalent compound is numerically equal to the molecular mass, but in grams per mole. 13 Formula Mass and Molar Mass The formula mass (or formula weight) is the sum of the atomic masses (in amu) in a formula unit. The molar mass of an ionic compound is numerically equal to the formula mass, but in grams per mole. 14 Summary of Different Mass Terms Term Definition Unit Isotopic Mass Mass of an isotope of an element amu Atomic Mass (aka Atomic Weight) Weighted average mass of an element’s naturally occurring isotopes amu Molecular or Formula Mass (aka Molecular or Formula Weight) Sum of the atomic masses of the atoms (or ions) in a molecule (or formula unit) amu Molar Mass Mass of 1 mole of a chemical grams per entity (e.g. atoms, ions, mole (g/mol) molecules, or formula units) 15 Practice Problem What is the molecular mass of glucose (C6H12O6)? Molecular Mass: 16 6 x 12.011 + 12 x 1.007 + 6 x 15.99 = 180.16 amu Practice Problem Complete the table below for glucose (C6H12O6, MW = 180.16 g/mol) Carbon Hydrogen Oxygen Atoms in 1 glucose molecule 6 12 6 Mass C/H/O in 1 glucose molecule 6 x 12.01 = 72.06 amu 12 x 1.008 = 12.10 amu 6 x 15.99 = 96.00 amu Atoms per mole of compound Moles of atoms in 1 mole cmpd Mass per 1 mole of compound 17 6 (6.022x1023) 12 (6.022x1023) atoms atoms 6 moles of 12 moles of atoms atoms 72.06 g 12.10 g 6 (6.022x1023) atoms 6 moles of atoms 96.00 g What’s in a Chemical Formula? Al2(SO4)3 (s) 18 2 atoms of Al and 3 molecules of (SO4)21 formula unit of Al2(SO4)3 = 342.17 amu 1 mole Al2(SO4)3 = 342.17 g Al2(SO4)3 1 mole Al2(SO4)3 = 6.022 x 1023 formula units Al2(SO4)3 1 mole Al2(SO4)3 = 2 moles Al3+ ions 1 mole Al2(SO4)3 = 3 moles (SO4)2- ions 1 mole Al2(SO4)3 = 12 moles O atoms = 12 x A.N. O atoms 1 mole Al2(SO4)3 = 3 moles S atoms = 3 x A.N. S atoms 1 mole Al2(SO4)3 = 2 moles Al atoms = 2 x A.N. Al atoms Conversion Factors in a Molecular Formula H2O (l) 1 molecule of H2O = 2 H atoms and 1 O atom Molecular mass = (2 x 1.008) + 15.99 = 18.00 amu Molar mass = 18.00 g/mol H2O 1 mole of H2O = 6.022 x 1023 molecules of H2O 1 mole of H2O = 2 mol H atoms = 2 (6.022x1023) H atoms 1 mole of H2O = 1 mol O atoms = 1 (6.022x1023) O atoms 19 Conversion Among Different Quantities 20 Practice Problem 1. 2. 3. 4. 21 Silver is often used in jewellery and tableware. How many grams of Ag are in 0.0342 mol Ag? Iron, the main component of steel, is the most important metal in industrial society. How many Fe atoms are in 95.8 g of Fe? Urea, (NH2)2CO, is a nitrogen-containing compound used as a fertilizer. How many molecules of urea are in a 25.6 g sample? How many hydrogen atoms are present in a 25.6 g sample of urea, (NH2)2CO? Practice Problem The plant photosynthetic pigment chlorophyll contains 2.68% magnesium by weight. How many atoms of Mg will there be in 1.00 g of chlorophyll? 22
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