5th International & 26th All India Manufacturing Technology, Design and Research Conference (AIMTDR 2014) December 12th–14th, 2014, IIT Guwahati, Assam, India MATHEMATICAL MODELLING OF SOLIDIFICATION IN A CURVED STRAND DURING CONTINUOUS CASTING OF STEEL Ambrish Maurya1*, Pradeep Kumar Jha2 1 *MIED, Indian Institute of Technology, Roorkee, 247667, [email protected] 2 MIED, Indian Institute of Technology, Roorkee, 247667, [email protected] Abstract A two dimensional fluid flow, heat transfer and solidification model has been developed for a curved shape continuous steel slab caster. The strand has been divided in various sections depending upon cooling conditions in the mold and secondary cooling zone. Themodel was validated against the experimental results for solid shell thickness in the moldas reported by Hakaru et al.(1984)CFD software Ansys Fluenthas been used for solving the differential equations to predict the temperature distribution,solid shell thickness by finding the liquid fraction of steelwithin the domain. Process parameters, casting speed and cooling rate has been varied to analyse their effects on metallurgical length and solid shell thickness at the mold exit. Keywords: Solidification, CFD, Mathematical Modelling, Metallurgical Length. 1 Introduction Continuous casting is a process whereby molten metal get solidified into semi-finished products. During continuous casting of steel, solidification starts as molten metal comes from tundish to mold (water cooled copper mold) and forms a solid shell at the inner surface of the mold. This solid shell should have adequate thickness(Li & Thomas 2004)at the exit of mold to withstand the ferrostatic pressure(Brimacombe et al. 1977)of liquid metal present inside it. Due to insufficient shell thickness at the mold exit causes breakout that will not only decrease the productivity and quality but also cause fatal accident. About two-thirdto half of the superheat given to the liquid steel is removed in the mold(Huang et al. 1992, Zhao et al. 2005). Solidification in the moldmay promote the defects and cracks formation. Further, solidification and transformation of strand from vertical to horizontal(W. I. Irving 1993) takes place in secondary cooling zone (SCZ. Water sprays are used for cooling and rollers are used for pulling the solid shell from mold and guiding it to move in a predefined curvature.Quality of the cast slab is directly linked with the cooling intensity and thermal gradient of the slab during solidification in SCZ, as most of the surface and internal defects are found due to improper spray cooling of strand in SCZ. It was found that, in continuous casting productivity and quality are coupled with each other, as high casting speed is required to increase productivity,while cooling conditionshas to be alteredaccordingly to have continuous defect free casting.However, chemical compositions of the steel and other casting parameters also havemuch significance in defining the cooling rate of the strand. 1.1 Casting Speed High productivity is foremost requirement from a continuous casting machine, which means high casting speed of the caster. As casting speed increases the solid shell thickness gets reduced if the cooling rate is not increased accordingly(Liu et al. 2012). However, casting speed can’t be beyond a certain value, because cooling capacities are limited in practice. Breakout and bulging (causing centreline segregation) phenomenon are most commonly observed at high speed casting(Binder 1992, Ha et al. 2001)because of ferrostatic pressure of the liquid metal inside solid shell and the pressure due to rolls. High casting speed may leads to increase the metallurgical length beyond the cut-off point. It is to be noticed that liquid core should exist at the straightening(W. I. Irving 1993) of the strand to reduce the strain and stress development. 1.2 Cooling Rate Surface temperature of the strand is most significant parameter during continuous casting which directly affect the surface quality of cast. So, secondary cooling rate is required to be reviewed carefully in order to achieve the desired surface temperatures at different sections of the strand. At the same time metallurgical length of the strand should also be controlled not to exceed the cut-off point(Sadat et al. 2011) and required cut-off temperature(Binder 1992). In a real caster machine, the secondary cooling zone is subdivided into many sections which are engaged by various water nozzles to provide desire cooling and surface temperature. The surface temperature of strand during secondary cooling should be controlled between 825oC and 1225oC (depending on steel composition) in order to avoid the surface cracks caused by fluctuation of temperature. In order to avoid transverse surface cracking the strand surface temperature should be 451-1 MATHEMATICAL MODELLING OF SOLIDIFICATION IN A CURVED STRAND DURING CONTINUOUS CASTING OF STEEL either more than the high-temperature limit or lesser than the lower-temperature limit of the ductility trough. Longitudinal cracks at the bending and unbending regions are more usual in steels with carbon contents of about 0.08– 0.14%. To avoid that, strand surface temperature should in between the upper and lower limit temperature of elasticity at bending and unbending zone(Kandeil 1991). In the present work strand surface temperature is kept between the limiting temperatures ranges discussed above by controlling the cooling rate. solid shell formation to estimate the optimal condition for continuous casting process.Various process parameters have been varied by taking into account of metallurgical requirements to have defect free casting. There is no universal method to optimize the process however; many researchers have tried to give optimum modelwithin the constraints and variables selected. The objective of the study is to find the relation between casting speed and cooling rate by fixing the metallurgical length and solid shell thickness at mold exit. 1.3 Superheat Superheat has an adverse effect on the surface quality. Increase in superheat temperature slows down solid shell growth.The hotter and thinner shell is more susceptible to deformation, bulging and crack formation(Zhao et al. 2005). On the other hand, by lowering the superheat, the temperature of the liquid steel during the first stage of solidification may be too low, which may cause freezing of the meniscus and excessive solidification of a thick slag rim. This could lead to transverse cracks in the cast. Hence, superheat has an important influence on the microstructure and internal quality.In continuous casting process, casting speed is restricted according to superheat of the liquid metal to minimize the chance of breakout. The measurement of the temperature variations during continuous casting process is very difficult, as it is operated above the melting pointtemperature of steel. So, mathematical modelling of continuous castingbecomes a successful way to analyse and optimize the process. Over the years many mathematical models have been developed to find the solidification behaviour in mold and secondary cooling zone. Most of the models developed are limited to mold region or for vertical stranddue togeometrical and computational simplicity.Louhenkilpi et al. (1993) have predicted the temperature distribution and solidifying shell thickness in a vertical slab caster.However, it’s very difficult to developmodel for surface and internal cracks prediction, because the temperature, strain and stress fields have to be calculated over the process by considering the industrial cooling conditions. Huang et al. (1992) investigated the solidification process by varying superheat and casting speed (Kandeil et al. 1991) within and below the mold and reported that casting speed and superheat temperature directly raises the rate of superheat extraction. Hong et al. (2002) have reported that due to bend type mold, recirculating flow appears in the upper-outer region, resulting in less solid shell thickness at the inner region and at the lower part of the mold.Ideal taper of the mold has been reported by Meng and Thomas (2003)by predicting the interfacial gap between mold wall and solidified shell. In the present work two dimensional heat transfer solidification model has been developed for a curved slab caster. The model predicts the surface temperature, temperature profile in the strand and 2 Governing Equations 2.1 Heat transfer Energy conservation equation for solidification is given as: ߩ ߲ܪ + ߩ∇. ሺݑത ܪሻ = ∇൫݇ ∇ܶ൯ + ܳ ߲ݐ Where, H is the enthalpy of the material and can be computed as the sum of sensible heat (h) and latent heat content (∆H), = ܪℎ + ∆ܪ Sensible enthalpy and latent heat content are defined as, ℎ = ℎ + න ் ்ೝ ∆ߚܮ = ܪ ܿ ݀ܶ Where, L = latent heat of material,β = liquid fraction, href= reference enthalpy, Tref = reference temperature, keff = effective conductivity, cp = specific heat, ρ = density, ݑത = velocity, QL = source term. The source term QL, has two terms in it; explicit latent heat term and convective term. In a single phase solidification model,QLcan be expressed as ߲݂௦ ܳ = ߩܮ + ߩݑܮത௨ . ∇݂௦ ߲ݐ Latent heat of material is released from the mushy zone. The solidified shell formed is pulled out at a constant casting velocity “ݑത௨ ”. That means the region having solid fraction “fs” equals to one, will move along the casting direction with the casting speed. It is to be noted that sum of liquid fraction “β” and solid fraction “fs” is always 1(Hong et al. 2002). The liquid fraction can be calculated by determining the temperature as 0 ۓ ۖ ܶ − ܶ௦ௗ௨௦ ߚ= ܶ۔௨ௗ௨௦ − ܶ௦ௗ௨௦ ۖ 1 ە ݂݅ ܶ < ܶ௦ௗ௨௦ ݂݅ ܶ௦ௗ௨௦ < ܶ < ܶௗ௨௦ ݂݅ ܶ > ܶௗ௨௦ 2.2 Fluid flow The continuity equation can be expressed as ߲ ሺߩݑ ሻ = 0 ߲ݔ While, transient Navier-Stokes equation momentum conservation can be expressed as for ߲ ሺߩݑሻ + ߩ∇ሺݑݑሻ = −∇ܲ + ∇൛ߤ ሺ∇. ݑሻൟ + ߩ݃ + ܵ ߲ݐ 451-2 5th International & 26th All India Manufacturing Technology, Design and Research Conference (AIMTDR 2014) December 12th–14th, 2014, IIT Guwahati, Assam, India Where, µeff = µl + µt is the effective viscosity due to turbulence realizablek-ε model is used for present study, µl is the dynamic viscosity and µt is the turbulent viscosity. In the enthalpy-porosity technique mushy zone is treated as porous medium and the porosity of every cell is set equal to the liquid fraction in that cell. The porosity equals to zero if the zone is fully solidified, which extinguishes the velocity in that zone. Thus the momentum sink term “S” was added to the right hand side of the Navier-Stokes equation. The presence of this term allows the newly solidified material to move downward at constant pull velocity. The momentum sink can be expressed as ܵ= ሺ1 − ߚሻଶ ܣ ൫ݑത − ݑത௨ ൯ ሺߚ ଷ − ߦሻ ௨௦ Where, ξ is a small number (0.001) just to prevent zero in denominator, Amush is mushy zone constant. The mushy zone constant measures the amplitude of the damping; the higher this value, the steeper the transition of the velocity of the material to zero as it solidifies. Very large value may cause the solution to oscillate. In the momentum sink term, the relative velocity between the molten liquid and the solid is used rather than the absolute velocity of the liquid. For simulating turbulence, the realizable k-ε turbulence model was used, which is found to be mostsuitable(Shih et al. 1995). The turbulence viscosity is given by ߤ௧ = ߩܥఓ ݇ଶ ߝ The two partial differential equations for turbulent kinetic energy (k) and dissipation rate (ε) (9) are given by ߲݇ + ߩሺ∇݇ݑሻ = ∇൫ߙ ߤ ∇݇൯ + ܩ + ߩߝ + ܵ ߲ݐ ߲ߝ ߝ ߝଶ ∗ ߩ + ߩሺ∇ߝݑሻ = ∇൫ߙఌ ߤ ∇ߝ൯ + ܥଵఌ ܩ − ܥଶఌ ߩ + ܵ ߲ݐ ݇ ݇ ߩ Sinks are added to all of the turbulence equations in the mushy and solidified zones to account for the presence of solid matter. The sink term(Ansys®, academic research)is very similar to the momentum sink term. ܵ = ሺ1 − ߚ ଶ ሻ ܣ ߮ ሺߚ ଷ − ߝሻ ௨௦ Where φ represents the turbulence quantity being solved (k, ε, ω, etc.), and the mushy zone constant, Amush, is the same as the one used in equation above. αk and αε are the inverse effective Prantdl ∗ numbers, C1ε and ܥଶఌ are the model parameters, Gk is the generation of the turbulence kinetic energy due to mean velocity gradients. C1 = 1.44, C2 = 1.92, Cµ = 0.09, σk = 1.0, σε = 1.3(Versteegand Malalasekra 2012) 3 Assumptions and Boundary Conditions The following assumptions were made during formulation of the solidification model to simplify the governing equations: • Liquid steel as Newtonian incompressible fluid. • Only two dimensional heat transfers (lateral direction) is considered. • Convective boundary condition has been taken for extraction of heat from mold and strand. • Density and specific heat of steel are invariant. • Moldoscillation, effect of segregation, etc. has been ignored. • Perfect contact between the shell and mold is considered as shrinkage due to solidification is ignored. • No slip boundary condition prevails at the walls. Based on the above assumptions, the material properties of steel anddimensions of the model are listed in Table 1(Huang et al. 1992) and Table 2 respectively. Table1Material properties of steel being used Material Properties Density (Kg.m-3) Solidus temperature (K) Liquidus temperature (K) Degree of superheat (K) Specific heat (J.Kg-1K-1) Thermal conductivity (W.m-1K-1) Viscosity (Kg.m-1s-1) Latent heat of solidification (J.Kg-1) Steel emissivity Value 7020 1783 1795 15 750 41 0.0067 272000 0.8 Table2 Dimensions of the model Dimensions(m) Mold length SCZ-1 SCZ-2 SCZ-3 SCZ-4 SCZ-5 SCZ-6 SCZ-7 SCZ-8 Radius of curve Cut-off length Value 1.0 1.2 0.5 2.4 3.0 4.5 5.4 6.5 9.5 9.74 34 3.1 Inlet The mold is fed from inlet port with velocity inlet of the molten steel. The velocity component at the inlet is only in z-direction (casting direction) while, inlet velocity was obtained by balancing the inlet flow rate with the casting speed. However, inlet temperature (Tinlet) of the molten steel was fixed according to the superheat (∆T) supplied to the steel above the liquidus temperature (TL). The inlet temperature can be expressed as: Tinlet=TL+∆T 3.2 Wall To avoid the computational difficulties associated with the heat extraction from steel through cooling water flowing within mold, heat transfer by convection(Li &Thomas 2004, Meng & Thomas 2003) has been considered for the mold walls. The solidified shell was set to move with casting velocity in the casting direction. In secondary cooling zone, 451-3 MATHEMATICAL MODELLING OF SOLIDIFICATION IN A CURVED STRAND DURING CONTINUOUS CASTING OF STEEL different heat transfer rates werequantifiedfor eightsub-sections sections modelled with consideration of different cooling rateswhile moving down the strand. 3.3 Outlet To maintain the constant casting speed, speed velocity outlet boundary condition has been applied at the exit (cut-off point).. The velocity at the outlet is equal to the casting speed in casting direction. Computational domain has been broadly divided in into two parts: mold and secondary cooling zone (SCZ). Further, SCZ is subdivided into eight sections, as cooling rate varies while moving down the strand. strand The geometry of the model is shown in Fig.1. The geometrical length is measured from the inlet and outlet along the axis of the strand. Ansys 14.0.Second Second order implicit scheme and realizable k – ε turbulence model were used to solve the fluid flow equations by finite volume method. For solidification, instead of tracking liquid liquid-solid front explicitly, enthalpy-porosity porosity technique has been used as explained in previous section.. The solution was executed in transient state with time step of 0.01 second. The solution convergence has been achieved with momentum residuals ˂ 10-4 and energy residuals ˂ 10-7. Liquid iquid fraction of the steel and temperature distribution in the strand has been calculated. The liquid fraction in the complete domain and velocity vector of the steel flow in the mold at casting speed of 1.6 m/min is shown in Fig.3. A discontinuity in the solid shell formation can be found at the top portion of the mold due to circulation of the liquid steel;however a continuous solid shell formed later. model Figure 1 Schematic diagram of the model. Figure 3 Liquid fraction and velocity vector (mold) 4 Validation In order to validate the computational model, model a three dimensional model of mold has been prepared and validated against the experimental resultsfor solid shell thickness at the narrow wall as reported byHakaru et al.(1984).. The comparison of both the results is shown in Fig.2. Form the figure, figure a good agreement between the two can be observed. observed Figure 2 Validation of the model 5 Results and Discussion The two dimensional model has been prepared and discretised equations were solved in CFD tool 5.1 Effect of casting speed The variation of surface temperature at the inner wall of the strand with different casting speed is shown in Fig. 4. The rise and fall in the curve is due to the change in cooling rate in different cooling zone. The cooling rate for all cooling zone were kept constant. It is found ound that with the increase in casting speed, surface temperature of the strand increases significantly. Onn the other hand, due to fluctuation in temperature, high surface temperature may le lead to surface cracks. In Fig. 5temperature temperature distribution at cut-off point (outlet) is shown.It .It was found that temperature curve at the outlet become steeper with the increase in casting speed and maximum centre temperature was predicted forcasting casting speed 2.0 m/min, as solidification was not completed till cut-off point. Solid shell thickness at the mold exit for slab caster is to be 10-14 14 mm to avoid breakout and bulging defect. For finding the shell thickness, Liquid Fraction has been calculated and liquid fraction of 0.7 is considered as a solid zone (mushy zone having 30% solid is assumed to have strength ngth and can withstand the load). From Fig. 6, it is clear that to avoid these defects, casting speed should be below 1.8 m/min. On the other hand, casting speed below 1.4m/min will solidify more than the minimum requirement, as slag 451-4 5th International & 26th All India Manufacturing Technology, Design and Research Conference (AIMTDR 2014) December 12th–14th, 2014, IIT Guwahati, Assam, India solidification may occur in mold and also the process may be too slow. Figure 7 shows the difference between the cut-off length and the metallurgical length. It was found that at casting speed of 1.2 m/min slab get completely solidified before the straightening zone, due to which large stress will develop during straightening and surface defects likely to be generated. At the speed of 2.0 m/min metallurgical length is more than the cutoff length, while very little difference as for 1.8 m/min is also not preferable because any fluctuation in the process parameter may stop the process. Figure 6 Shell thicknesses at mold exit Figure 4 Surface temperatures at inner wall Figure 7Difference between cut-off length and metallurgical length 5.2 Effect of cooling rate The cooling rate of previous section has been considered as a standard cooling rate and casting speed was fixed at 1.6 m/min. The standard cooling rate has been reduced to 75 and 85 percent and increased to 115 and 125 percent in secondary cooling zone, while heat loss from mold was kept constant to maintain the shell thickness at the mold exit. Figure 5 Temperature distributions at cut-off point Figure 8 Surface temperatures at inner wall 451-5 MATHEMATICAL MODELLING OF SOLIDIFICATION IN A CURVED STRAND DURING CONTINUOUS CASTING OF STEEL It was found that with the increase in cooling rate, surface temperature decreases, shown in Fig. 8. The surface temperature for 75 percent is high enoughand may cause surface defects in present model. Centre temperature at the cut-off point is maximum when cooling rate is lowered to 75 percent also lowering to 85 percent is very close to it. Conversely surface temperature for both cases has significant difference, shown in Fig. 9. By finding the metallurgical length, it was found that solidification completed before cut-off point for all the cases. It can be seen from Fig. 10 that difference between metallurgical length and cut-off length is low for 75 and 85 percent case which may cause critical problem during any fluctuation in cooling rate as well as casting speed. At the same time metallurgical length for 125 percent is much more than requiredfor the process. Figure 9 Temperature distributions at cut-off point Figure 10 Difference between cut-off length and metallurgical length 6 Conclusions A two dimensional numerical model has been developed to study the solidification of continuous casting of steel slab. The temperature distribution and solid shell thickness has been calculated to study the effect of casting speed and cooling rate. It was observed that casting speed can be increased up to a certain limit to increase the productivity, after which incomplete solidification can be found at the cut-off point or insufficient shell thickness at the mold exit. 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