12/5/2016 Learning Target: Classify elements according to their location on the Periodic Table This is a brief review of that information. Identify the following as being an alkalai metal, alkaline earth metal, transition metal, semi-conductor (aka metalloid), halogen, or noble gas: Germanium Tungsten Potassium Radon Strontium Uranium Silicon Beryllium Palladium Iodine Which of the following are main-group elements? Magnesium Vanadium Antimony Lead Neptunium Cesium Rutherfordium Boron Indium 1 12/5/2016 Section 1: Who’s Who??? Learning Target: Explain the development of Periodic Law 1817 – Dobereiner • Grouped elements in TRIADS… • Three elements with similar properties 1865 – Newlands • Arranged by increasing atomic MASS. • Law of Octaves = Similar properties over EIGHT elements 1870 – Mendeleev • Created an 8 Column table based on ATOMIC MASS • Elements with similar properties were in the same column • Problems w/ Mendeleev’s table: 1. Some elements did not fit the order he described. Ex: Tellurium (Te) and Iodine (I): he put them out of order in terms of atomic mass, but did this so they were in the same column as elements with similar properties (he broke his own rules) 2. There were gaps in the table • BUT he was able to predict the properties and masses of the unknown elements very accurately. 2 12/5/2016 1913 – Moseley 1944 • Studied X-ray spectra of elements and noticed they correlated with atomic number • Arranged elements with increasing ATOMIC NUMBER PERIODIC –Glenn Seaborg Last rearrangement of the periodic table – created the actinide series LAW: • Properties of the elements are a (periodic) function of their atomic number 1817 1865 Dobereiner Newlands Triads Law of Octaves 1870 1913 1944 Mendeleev Mosley Seaborg First 8 column table Periodic Law Actinide Series Section 2 Atomic properties are determined by ELECTRON CONFIGURATION. Ex. 1s2 2s2 2p6 3s2 3p3 Therefore…the table is designed on the basis of electron configuration… 3 12/5/2016 Valence Electrons: Electrons that are found in an atom’s outer most shell Determines chemical properties of an atom These are the electrons that can be gained, lost or shared when forming compounds OCTET RULE… • 8 electrons in the outer energy level renders an atom UNREACTIVE • Unreactive = Very Stable • So…which elements are considered unreactive? A: The Noble Gases Atoms react with other atoms so all atoms end up with FULL OUTER ENERGY LEVELS (i.e. compounds) 1. They may add electrons 2. They may lose electrons 3. They may share electrons 4 12/5/2016 Don’t Section 3 forget your color-coded periodic table… It identifies the… • Groups • Periods • Main Group Elements Learning Target: Identify properties of metals, nonmetals and metalloids It also classifies elements as… • Metals: Alkali metals Alkaline Earth metals Transition metals Metals –On the LEFT of the stairs – On the RIGHT of the stairs Metalloids – Attached to stairs Nonmetals Lanthanide Series Actinide Series Other Metals • Nonmetals: Noble gases Halogens Other nonmetals • Metalloids: semiconductors METALS NONMETALS 1. Typically Solids 1. Gasses or BRITTLE solids 2. Shiny 2. Dull 3. Conduct Heat and Electricity 3. Insulators 4. Tendency when forming 4. Tendency when forming compounds to lose compounds to GAIN or outer electrons SHARE electrons RULE of THUMB Metals: • 3 or fewer outer energy level electrons Nonmetals: • 5 or more outer energy level electrons Metalloids: • Properties of both Metals and Nonmetals • aka Semiconductors 5 12/5/2016 What Section 4 is a trend? A predictable change in a particular direction Learning Target: Describe element trends on the Periodic Table (FOCUS ON MAIN GROUP ELEMENTS) Atomic Radii ½ the distance between the nuclei of identical atoms that are bonded together Atomic Radii increase from top to bottom and from right to left on the periodic table Increases Increases Radius = d/2 Periodic Table Increases as you move down due to electron shielding • electrons in the inner energy levels are between the nucleus and the outer electrons and therefore are shielded from being pulled away • **More energy levels as you go down PT 6 12/5/2016 Decreases as you go right due to increasing charge of the nucleus (**means increases as you go left due to decreasing charge of nucleus) • although more electrons are also present they are at the same distance from the nucleus b/c they are in the same energy level • Stronger force of attraction, pulling electrons closer—making radius smaller Gallium Thallium Yttrium Strontium Helium Neon Hafnium Vanadium Ions Atom or group of atoms that has a positive or negative charge • Positive charge occurs when atom loses electrons This process that results in an ion requires energy—this process is referred to as ionization Ex: Na+: Sodium that has lost an electron, and now has 10 e• Negative charge occurs when atom gains electrons Ex: Cl-: Chlorine that has gained an electron, and now has 18 e- Ionization Energy required to remove one electron from a neutral atom of an element • This happens when compounds form Ionization energy tends to increase from bottom to top and left to right Increases Increases Energy Periodic Table 7 12/5/2016 As you move across, the nucleus gets larger and holds the electrons more tightly THEREFORE harder to remove Requires MORE energy (higher ionization energy) As you move down, the outer most electrons are farther away from the nucleus THEREFORE easier to remove Iron Cobalt Cesium Rhenium Sulfur Tin Iodine Bismuth Requires LESS energy (lower ionization energy) 8
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