ENT147/3 Engineering Materials QUIZ 1 17 October 2016 : 1 hour 1. Element C, Al and Fe have an atomic number (Z) of 6, 13, and 26, respectively. Show the electron configuration of the elements by utilizing orbital box diagram. (3 marks) 2. What are primary and secondary bond? Give an example for each. (4 marks) 3. Rhodium has an atomic radius of 0.1345 nm and a density of 12.41 g/cm3. Determine whether it has an FCC or BCC crystal structure. Given ARh = 102.91 g/mol and NA is Avogadro’s number. Use density (3 marks) ANSWERS 1. Element C, Al and Fe have an atomic number (Z), 6, 13, and 26, respectively. Show the electron configuration of the elements by utilizing orbital box diagram. Element C : 1s2 2s2 2p2 Element Al : 1s2 2s2 2p6 3s2 3p1 Element Fe: 1s2 2s2 2p6 3s2 3p6 4s2 3d5 3 Marks 2. Type + Example • Ionic • Covalent • Metallic • Permanent or Fluctuating Dipoles Chapter 3 - Chapter 3 - 4 Atomic Packing Factor: FCC • APF for a face-centered cubic structure = 0.74 maximum achievable APF Close-packed directions: length = 4R = 2 a 2a a Adapted from Fig. 3.1(a), Callister & Rethwisch 8e. Unit cell contains: 6 x 1/2 + 8 x 1/8 = 4 atoms/unit cell atoms volume 4 3 p ( 2a/4 ) 4 unit cell atom 3 APF = volume 3 a unit cell Chapter 3 - 5
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