2/17/2015 Chemistry of Aqueous Lead(II) Ions - Chemwiki Ashley Robison My Preferences Site Tools Popular pages MindTouch User Guide FAQ Sign Out If you like us, please share us on social media. The latest UCD Hyperlibrary newsletter is now complete, check it out. ChemWiki BioWiki Periodic Table of the Elements GeoWiki Reference Tables StatWiki Physical Constants PhysWiki MathWiki SolarWiki Units & Conversions Lab Techniques ChemWiki: The Dynamic Chemistry E-textbook > Inorganic Chemistry > Descriptive Chemistry > p-Block Elements > Group 14: The Carbon Family > Chemistry of Group 14 Elements > Chemistry of Aqueous Lead(II) Ions Chemistry of Aqueous Lead(II) Ions This page discusses the precipitation of insoluble lead(II) compounds from aqueous lead(II) ions in solution. It describes the formation of lead(II) hydroxide, lead(II) chloride, lead(II) iodide and lead(II) sulfate. Because many lead(II) compounds are insoluble, a common source of aqueous lead(II) ions is lead(II) nitrate; this source is assumed in all following examples. Making lead(II) hydroxide If a small amount of sodium hydroxide solution is added to colorless lead(II) nitrate solution, a white precipitate of lead(II) hydroxide is produced: If more sodium hydroxide solution is added, the precipitate redissolves, forming colorless sodium plumbate(II) solution: Making lead(II) chloride Lead(II) chloride, a white precipitate, is formed by adding a chloride ions (in dilute hydrochloric acid) to lead(II) nitrate solution. The chemical equation is shown below: Adding excess concentrated hydrochloric acid dissolves lead(II) chloride by forming soluble, complex ions such as PbCl42-. Making lead(II) iodide If you add colorless potassium iodide solution (or any other source of iodide ions in solution) to a solution of lead(II) nitrate, a bright yellow precipitate of lead(II) iodide is produced. Making lead(II) sulfate Adding aqueous sulfate ions to a solution of lead(II) nitrate results in a white precipitate of lead(II) sulfate. The most convenient source of sulfate ions is dilute sulfuric acid. The equation is given below: Contributors Jim Clark (Chemguide.co.uk) © Copyright 2015 Chemwiki Powered by MindTouch ® Unless otherwise noted, content in the UC Davis ChemWiki is licensed under a Creative Commons Attribution-Noncommercial-Share Alike 3.0 United States License. Permissions beyond the scope of this license may be available at [email protected]. Questions and concerns can be directed toward Prof. Delmar Larsen ([email protected]), Founder and Director. Terms of Use http://chemwiki.ucdavis.edu/Inorganic_Chemistry/Descriptive_Chemistry/p-Block_Elements/Group_14%3A_The_Carbon_Family/Chemistry_of_Group_14_Elemen… 1/1
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