Last Name _________________________ First Name __________________ Period ____ Date_______ 4.2 Atomic Calculations- Notation and Average Atomic Mass Nuclear Symbols and Hyphen Notation tell us the Symbol of the Element, the number of protons and the Mass Number ( Protons + Neutrons). You will need your Periodic Table to complete this worksheet. PART A - Convert the following between Nuclear Symbols and Hyphen Notation. Nuclear Symbol Hyphen Notation 17 8π 15 7π 41 19πΎ 22 10π π 36 17πΆπ O- 17 N- 15 K - 41 Ne-22 Cl - 36 PART B - Find or calculate the number of protons, electrons and neutrons in each of the following neutral atoms: Symbol 17 22 35 8π Protons 8 Neutrons 17 β 8 = 9 17πΆπ K - 41 17 19 35 β 17 = 18 41 β 19 = 22 10π π Cl - 36 10 17 22 β 10 = 12 36 β 17 = 19 Calculating Average Atomic Mass from Abundance of Isotopes and their Mass Please See Examples on the Website Calculate the Average Atomic Masses as stated below. 1. K has 2 abundant isotopes. They are K β 39 (abundance is 93.12%) and the remainder is K β 41 . a. Calculate the % that is K -41. (You should know how to do this) 100% - 93.12 % = 6.88% a. Calculate the Average Atomic Mass using the table given (39.14 amu) % 0.9312 0.0688 Mass Subtotal K-39 39 36.3168 K-41 41 2.8208 Total -> 39.1376 2. The natural abundance of Boron isotopes is : 19.9 % B-10 and 80.1% B β 11 Calculate the atomic mass of boron. Create a table as shown in the example above. Include units with your numbers. (10.81 amu) B-10 B-11 % 0.199 0.801 Mass 10 11 Total -> Subtotal 1.99 8.811 10.801 3. The natural abundance of Gallium isotopes is : 60.11 % Ga-69 and 39.89% Ga β 71. Calculate the atomic mass of Gallium. . Include units with your numbers. (69.8 amu) Ga - 69 Ga - 71 % 0.6011 0.3989 Mass 69 71 Total -> Subtotal 41.4759 28.3219 69.7978 HERE ARE SOME MORE COMPLEX 4. Mass # 24 25 26 % 0.7899 0.1 0.1101 Total -> 18.9576 2.5 2.8626 24.3202 5. Mass 27.97693 28.9765 29.97377 % 0.9223 0.0467 0.031 Total -> 25.80312 1.353202 0.929187 28.08551 OPTIONAL QUESTION EXTRA CREDIT = 2 POINTS ON YOUR UNIT TEST. Complete the calculation of the Average Atomic Mass for Molybdenum (data shown to the right) in and Excel Spread sheet. To receive the credit you must: ο· Include your name ο· Hand in on time (late submissions will not be accepted for any credit) ο· Print out the calculation ο· Print out the equations/formulas used in excel (To view eq/form CTRL ~) ο· Submit a copy by email Mass 92 94 95 96 97 98 100 % 0.1484 0.0925 0.1592 0.1668 0.0955 0.2413 0.0963 Total -> 13.6528 8.695 15.124 16.0128 9.2635 23.6474 9.63 96.0255 EQUATIONS Mass 92 94 95 96 97 98 100 % 0.1484 0.0925 0.1592 0.1668 0.0955 0.2413 0.0963 Total -> =D3*E3 =D4*E4 =D5*E5 =D6*E6 =D7*E7 =D8*E8 =D9*E9 =SUM(F3:F9) 6. CONCEPTUAL QUESTION - Silver has an atomic mass of 107.868 amu. Does any atom of any isotope of silver have a mass of 107.868 amu? Explain why. The atomic mass represents the average of all abundant masses present. It is possible but unlikely that it will be equal to the mass of any isotope, just like it is unlikely that a class average will be the grade for any one student. 7. HERE IS A MORE CHALLENGING QUESTION REQUIRING SOME ALGEBRA The atomic mass of Cu is 63.540 amu. It is composed of two isotopes, Cu-63 and Cu-65, with atomic masses of 62.930 and 64.928. What is the % abundance of these isotopes? HINT 1 : IF you calculate one, you will know the other. HINT 2: What is the relation between the two % abundances? HINT 3: Use the following Equation: Atomic Mass = (% Cu-63 x mass Cu-63) + (% Cu-65 x mass Cu-65) Since the total % Abundance = 100% an equation between the two can be written as X + Y = 100 , assign X = % Abundance of Cu-63 and Y = % Abundance of Cu-65 So Y = 100 β X 63.540 = (63 X) + (65 Y) but this has two unknowns so it cant be solved. Yes, it can if Y = 100 β X is used as follows: 63.540 = (63 X) + (65(1.00-X)) now solve for X 63.540 = 63X + 65-65X Now collect the X terms and constants: Now collect the constants: -1.46 = -2X 63.540 = 65-2X Divide both sides by -2 which gives the value of X πΏ= The other percent 100 β 73 = 27% Solution: Cu β 65 is 27% & Cu β 63 is 73% βπ. ππ =. ππ βπ
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