3 Handworking Handworking of Platinum Specific Handworking Processes Platinum Working Equipment Manual Index 3.1 Handworking Handworking of Platinum Hot-Working At its simplest, an alloy is hot-worked above the annealing temperature so that any work- Mechanical working of platinum jewellery alloys, whether by hand for individually crafted pieces or small batches by specialist manufacturers to catalogue designs, is similar to the working of most white golds. For economic reasons, most workers prefer as smooth a surface as possible rather than remove metal. It is very important to maintain cleanliness to avoid contamination that leads to embrittlement, particularly when hot-working. Otherwise hot and cold working are standard. Platinum alloys are oxidation resistant, formable and easily annealed, but die and tool wear can be a problem for the large scale producer if suitable precautions are not taken. effect. In most cases, though not all, this is undesirable because it complicates the finishing and polishing of the piece. hardening is relieved as quickly as it is generated. Hot-working is best if economic batches have to be subjected to considerable reductions or repeated shaping blows. There are no significant problems in hot-working normal platinum jewellery alloys. Even casting alloys can be hotworked. A typical example of hot-working platinum is the open die forging of 5kg cast ingots of chain-making alloys at 1100 to 1200ºC. Reductions of up to 70% may be made between reheats to form slabs for thin strip rolling or bars for wire drawing prior to automatic chain making. Figure 3A. Rate of work hardening of several (initially annealed) platinum alloys. Cold-Working When cold working platinum: The general annealing temperature for platinum • Keep all tooling clean alloys is about 1000ºC and the jobbing jeweller • Do not use excess lubrication rarely needs to work them so extensively that prolonged or repeated heating above 1000ºC is justified. Cold-working and annealing is normally • Keep roll surface and dies highly polished • Clean drawplates of beeswax, other preferred because it more accurately controls the lubricants, and metal particles that could properties of the piece prior to joining and damage a high finish polishing. Such cold-working operations include rolling, section-drawing, hammering and pressing. • There is a tendency to smear or drag wear on working tools A few platinum alloys work harden fairly rapidly and the work necessary to continue deforming • Keeping a high tool polish minimises wear. those that start off relatively hard is significant; cracking is less of a problem. Figure 3A shows examples of some 5% and 10% alloys of platinum compared with a typical 18 carat gold alloy. Alloys like platinum-palladium have a lower rate of work-hardening. With most platinum jewellery alloys it is possible to make reductions in cross-section of up to 70% between anneals if there is adequate power. For good repeated practice it is better to choose reduction/annealing sequences to suit each alloy and so control grain size and mechanical properties. Normally, reductions of less than 30% between anneals should be avoided because a combination of light cold work and frequent anneals can cause coarse grain Annealing Almost all platinum jewellery alloys resist oxidation during annealing and either conventional torch flames (air- or oxy-fuel gas) or electric furnace annealing may be used. Furnace annealing allows better control of the level and evenness of temperature and, in turn, the mechanical properties of the component. Most cold worked alloys begin to stress-relieve at 600ºC (dull-red) and they soften rapidly at 1000ºC (bright orange) which may be regarded as the general annealing temperature. Because of the speed and ease of annealing and oxidation resistance, many workers use a gas torch for inter-stage anneals. growth and corresponding orange peel surface Index 3.2 Handworking Annealing Temperature Guide For most metals and alloys, the annealing temperature in °C is a little over half the melting point in ¡Kelvin. (Add 273 to the normal melting point in ºC., to get ºK.) Standard Silver 9ct Gold 14ct Gold 18ct Gold Pt 1000 fine Pt 585 fine Pt-5%Cu Pt-5%Ir Pt-5%W Pt-10%Pd mptºC 890* 800-960* 850-920* 900-990* 1773 1580 1725 1780 1830 1740 mptºK 1163 1153 1158 1218 2046 1853 1998 2053 2103 2013 AnnealºC 581 577 579 609 1023 927 999 1027 1052 1007 } about 600ºC *mpt varies with ratio of the other metals alloyed with gold. Annealing temperatures are not exact; they vary in practice with annealing time and with the amount of prior cold work. Heavy work at low temperatures lowers the normal annealing temperature. Except for the extremes of carat platinum alloys at the low end & Pt-Ir or Pt-W alloys at the high end, an annealing temperature of 1000ºC is adequate for most purposes. Where very thin, heavily cold-worked or highly to be caused by arsenic, boron, magnesium, or stressed sections are to be annealed it is silicon. While it is not common, it is possible, in a advisable to stress-relieve by heating for period reducing flame during melting, joining or of a few minutes at 500 to 600ºC before full annealing, to liberate aluminium or silicon from annealing or strongly heating for soldering or refractory materials such as crucibles or support welding. Time at the full annealing temperature bricks, or carborundum (silicon carbide) will depend on the thickness of the section, but abrasives. This can only occur under reducing 1 minute per mm of section thickness should conditions, when the platinum alloy is in close be sufficient for thicknesses up to about 5mm. contact with the support, well above red heat. Too frequent annealing or annealing for too Hydrocarbons such as oils or grease are typical long can cause grain growth which may make contaminants that can give rise to unexpected subsequent working or polishing to a smooth reducing conditions. It is important to avoid surface more difficult. Except for platinum- trapping potential contaminants in the metal ruthenium, platinum alloys do not generally age during working processes such as rolling, drawing, harden and so can be either cooled in air or hammering, cutting or abrading. Good water quenched from the annealing temperature housekeeping prevents these potential without harm. problems by avoiding contamination. Contamination Most metal contaminants of platinum surfaces may be removed by pickling in hot, but not Platinum combines with most molten metals. While this is useful for making alloys with controlled characteristics, it can also cause boiling, 10% nitric acid, prior to annealing. Iron contamination is best removed with hot hydrochloric acid. trouble. For instance, small amounts of aluminium, lead or tin can cause low melting If contamination has occurred after heating, it is point compounds with platinum and this can lead very difficult to correct other than by cutting it out to intergranular cracking called hot-shortness and repairing by joining in a new piece of clean (silver, indiscriminately alloyed with platinum alloy. Attempts to solder intercrystalline cracking can cause intergranular cracking, but this is or to dilute the effect by annealing usually results very unlikely under ordinary annealing in spreading the problem. conditions). Intergranular cracking is more likely Index 3.3 Handworking Contamination Some Possible Causes: Some Preventatives: • Lead-Tin solders on the same work bench • Avoid reducing flames and furnace • Charcoal soldering blocks • Abrasives rolled into the surface atmospheres • Use oxidising conditions; platinum itself will not oxidise • Filings from other precious or non-precious metals • Avoid trapping contaminants in platinum during working • Filings or drillings from gemstones or mineral crystals • Degrease and positively clean surfaces before heating • Oils, grease or soaps used for drawing, rolling, etc. • Avoid contaminated supports during heating and joining • Machining suds (lubricants) • Prefer refractory supports to charcoal when joining Specific Handworking Processes Forging The term "forging", while metallurgically correct, sounds heavy for jewellery processes. It covers squaring or rounding by planishing, spreading widthwise, (Figure 3B) tapering/pointing (Figure 3C), or upsetting the cross-section of the jewellery component, usually between a smooth faced hammer and an anvil or stake or swaging between open or closed dies. Much the same principle applies in ring forming, forming tube sections, and on a small scale, hammer Figure 3B. Spreading platinum strip widthwise using a thinned and polished cross-peen or small raising hammer to move metal outwards at right angles to the long axis of the piece. The back of the hammer head needs to be weighty to provide force. texturing, embossing and chasing. Platinum is very malleable and forges well, but it does require deliberate and forceful blows especially when dealing with large cross-sections. A good indication of its malleability in the annealed state is that strip sections up to 3 or 4mm thick can be folded double and compressed by hammering without cracking. In fact, this is a good way of combining the excellent strength of cold-worked platinum in thin sections, with bulkier sections achieved by folding and hammering without soldering or welding (Figure 3D). Figure 3C. Tapering/pointing a section. Hammer moves in a constant short arc, finishing normal to the taper angle (otherwise, a square section will offset to one side to form a rough rhomboid shape). Work may be rotated radially beneath the hammer blows to achieve pointing (all round tapering) for start end of section drawing. Index 3.4 Handworking To maintain good shape control, use square or corners and re-entrant sections. While hand- radial blows as appropriate; otherwise the made draw plates may be satisfactory (with acid section tends to offset to one side or the other. cleaning) for an occasional piece of craft jewellery Once the near final dimensions are achieved, the in platinum, economic batches demand best section can be trued by planishing, die drawing or quality tungsten carbide drawing dies kept in a even rolling. It can of course be finished by filing high state of polish, particularly in the work zone; but it is always preferable to use compression otherwise platinum will further roughen the processes to conserve metal weight and minimise surface and lead to platinum build up and loss of the need for extensive surface finishing. cross-sectional accuracy. Anneal after about each 30-35% reduction in cross-sectional area even though platinum will usually withstand greater reductions without cracking; its workhardening ability is such that it requires considerable increases in force to continue working. Heavily work-hardened platinum alloys can dent stake, anvil and hammer surfaces, making it progressively more difficult to maintain a good surface finish on the work. Figure 3E. Starting a thin walled tube from strip with a taper cut smoothly at the lead end, hammered into a channel to start curving the tube wall and completed by die drawing (with seam welding if necessary). Reducing tubular cross-sections with the wall finding its own thickness is known as sinking (Figure 3F). This is a simple variant on wire drawing and wire drawing dies may be used. Where the wall has to be controlled for short platinum hollow sections for jewellery it is convenient to use a mandrel. This is a polished steel rod or hard-drawn wire (piano wire as slender as 0.5 mm diameter may be used) Figure 3D. Platinum strip/tape can be repeatedly doubled back on itself and, in effect, cold forged to produce a thick section (which may then be locally annealed, if required) attached to a filigree section (which may be left cold-worked). whose external shape matches that of the required internal cross-section of the platinum component. The mandrel is placed inside the Section and tubular section drawing starter tube and the two are co-drawn through the die sequence. In the first few passes the mandrel is loose inside the platinum, but after With draw plates, channelled and taper-ended being drawn down onto the mandrel the platinum platinum strip can be formed into more precise wall is controlled between the mandrel and the channel sections, hollow ring stock and seamed die. The total reduction in the wall cross-sectional tube (Figure 3E). Thin rod and wire can be area between anneals should be limited to about modified to many different cross-sections. 35%, particularly after the platinum is in full Prepolished dies are available commercially, but contact with the mandrel, so an inter-stage some craft jewellers prefer to draw simple anneal before the platinum grips the mandrel is sections through a hand-made draw plate. This is advisable. The mandrel must start with a length still possible with platinum, but time consuming if greater than the finishing length of the platinum complex sections are attempted. The limiting tube or it will be enclosed. The mandrel also factor is the smearing ability of platinum on introduces another dragging friction interface insufficiently polished die surfaces or where the that, with platinum, requires careful lubrication interface pressure is very high such as at tight and techniques to remove the mandrel. Index 3.5 Handworking than the outer diameter of the platinum tube to be removed. These are “played like castanets” along and around the mandrel/tube combination to achieve many small pinching blows to loosen the tube (Figure 3G). The loose tube, now off the mandrel, may be given a finishing pass through the last die hole again to clean up the surface and shape. Figure 3F. Tube sinking with relative wall thickening compared to mandrel drawing for short lengths. the mandrel controls the wall thickness and also takes part of the load at the short end. Spinning and Doming The ductility of platinum makes it quite amenable to spinning. The jobbing jeweller is unlikely to Lubrication and mandrel separation need to spin large pieces into deep shapes but, if A hard soap such as “Pale curd industrial” in bar the need for too many annealing stages. Virtually or powder form is used on the die and the all alloys can be spun to produce shallow dished mandrel for lubrication and to ease the removal shapes for jewellery pieces in a single stage. The of the platinum tube after drawing is completed. metal is worked against a former at a shallow Bar soap can be applied to a stout mandrel by angle and the strain is not severe. Relatively deep rubbing; soap powder can be tapped into the pieces may need two stages with an interstage tube bore prior to mounting on the mandrel. To anneal, mainly to reduce the off-centre pressure get a better finish, particularly on the outside of to be exerted by the burnisher (Figure 3H). the finished section, it helps to use a soft soap Making small round shapes up to hemispherical lubricant for the last two or three passes. depth is best accomplished by doming. Platinum so, the most ductile alloy is preferable to avoid jewellery alloys respond well to this technique. Indeed, doming of a blank, and perhaps annealing, may be useful as a start to spinning. Some of the larger scale (deep drawing and deep spinning) or more continuous working processes (stamping), and processes like ring sizing more akin to finishing operations, will be dealt with later in the Manual. Figure 3G. Loosening the mandrel by tapping with parallel bars or “castanets”. Attempting to drag the mandrel out of the tube is likely to tear or buckle the platinum. To free the tube from the mandrel after completing the final pass, it must be burnished off with one or two passes through rolls that just pinch across a series of outer diameters and impart a slight degree of twist. In effect, the tube wall is slightly expanded away from the mandrel. For occasional short lengths, it is possible to achieve the roller/twist effect with a pair of parallel tool steel Figure 3H. Outline sketch of small scale spinning arrangement for making a collet for a stone setting from a sheet-circle using a burnisher. The bottom section may be parted off and may be useful as a bezel ring. rods (or tungsten carbide for very long life) gripped in a handle with a gap just a little larger Index 3.6 Handworking Cutting One of the most frequently used processes in handworking a piece of jewellery is cutting to shape or length, by piercing and sawing, slitting, drilling, filing or grinding. On a small scale, there is little need to differentiate between tools, grades and techniques for white gold and for angle (about 15 degrees or less) to the cut surface to avoid excessive snagging at the leading edge. Filing should also be done at a similarly flat angle with frequent changes of the file surface and cleaning. The lubricant "oil of wintergreen" has been proven to be effective in relieving wear on files. platinum. It is always worthwhile minimising the “Sanding” papers should be chosen for their free- amount of metal removed or scrapped, by cutting ability, in which case the abrasive particles carefully sizing the piece to minimise or eliminate will remain upright on a stiff bonded backing the need for cutting. Often, platinum wires, tubes paper. 240 and 400 grades are usually adequate or strips will be thin, taking advantage of high in two stages. It is often better to part off strength. As with any hard jewellery alloy, it is platinum sections with thin alumina or silicon unwise to cut thin sections with coarse settings. carbide disks running at 1300 to 3800 M/min. Jewellers' (tool steel) saw blades are rated from peripheral speed rather than use a lathe tool 8/0 for the very finest pierced work, through 0,1 which tends to leave a coarse burr and and 2 which are better for silver but too coarse undergoes rapid tool wear. for most platinum jewellery work, and on up to size 8. Platinum alloys appear to wear out saw blades and similar hand tools more quickly than do gold or silver. This is because the alloys cold weld very well. Metal builds up on cutting edges, followed by stick/slip binding/removal of the debris, and this causes extra wear. Figure 3I sketches the different effects between aluminium, gold/silver, and platinum alloys on a coarse saw blade. Compromise between too smooth and too coarse. Use around 3/0 grade which is a good general purpose blade for white gold and Figure 3I. Sketch of different modes of debris build up/clearance on a jewellers’ sawblade. platinum. The blade should travel at a fairly flat Platinum Working Equipment Ideally, rolls, dieplates, dies, saw blades, chasing If this is not economical, then the best tools, files, grinding wheels, and similar tools alternative is to apply good housekeeping and where there is a degree of sliding movement segregate tooling used for platinum; clean it during working, should be kept specifically for and the working areas before and after platinum alloys only. This is because platinum is platinum working. This ensures maximum more vulnerable to contamination from other recovery of platinum scrap and sweepings and metals picked up under working conditions. minimises cross contamination of platinum. For Polished hammer and stake faces cause fewer instance, when the same rolls are used for problems because the impact is normally square platinum and other metals, platinum should be rather than sliding. Large platinum jewellery placed in 10% nitric acid at 70ºC to remove any producers, in Japan for instance, dedicate separate residues of other metals before any annealing or parts of the same factory, let alone separate joining process. tooling, to platinum or gold jewellery production. Index
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