Toshiba Client Solutions CO., Ltd. Guidelines for Green Procurement Ver.10 1 Toshiba Group’s Basic Policy for the Environment Based on the recognition that it is our responsibility to maintain the health of the global environment as an irreplaceable asset for future generations, Toshiba contributes to the development of a sustainable society by promoting environmental activities designed to realize a world that is low carbon, recycling based and environmentally harmonious. Promoting environmental management - Toshiba considers environmental stewardship to be one of management's primary responsibilities and promotes environmental activities in harmony with economic activities. - Toshiba assesses the impacts of its business activities, products and services on the environment, including with regard to biodiversity, and specifies objectives and targets with respect to the reduction of environmental impacts and prevention of pollution. - Toshiba strives to continuously improve environmental management through internal audits and reviews of activities. - Toshiba complies with all laws and regulations, industry guidelines it has endorsed, and its own standards concerning the environment. - Toshiba strives to enhance the awareness of all its employees with respect to the environment and requires that they make a practical contribution to the environment through their work. Toshiba operates globally, and accordingly, promotes environmental activities throughout Toshiba Group. Providing environmentally conscious products and services, and reducing their environmental impact through business activities - Toshiba recognizes that natural resources are finite and implements vigorous environmental measures to promote their effective and practical use in terms of both products and business processes. - Toshiba develops and provides environmentally conscious products and services which contribute to the reduction of environmental impacts throughout their life cycles. - Toshiba strives to reduce the environmental impacts of all business processes, encompassing design, manufacturing, logistics, sale, and disposal, with a particular focus on the mitigation of climate change, efficient use of resources and management of chemicals. As a corporate citizen of planet Earth - Toshiba contributes to society through its environmental activities, which include the development and provision of excellent, environmentally conscious technologies and products in cooperation with society at large and with local communities. - Toshiba is committed to maximizing disclosure and transparency in communication with stakeholders and society at large in order to facilitate mutual understanding. Guidelines for Green Procurement Toshiba Client Solutions CO., Ltd 2 2 Contents I. Green procurement 1. Objective ----------------------------------------------------------------------------------------------------------------4 2. Requirements to suppliers-----------------------------------------------------------------------------------------4 2.1 Suppliers’ activities for environmental conservation -------------------------------------------------4 2.2 Control of environment-related substances for articles to be supplied--------------------------4 II. Environment-related substances control criteria 1. Scope----------------------------------------------------------------------------------------------------------------------5 2. Definitions --------------------------------------------------------------------------------------------------------------5 3. Requirements for environment-related substances control for articles to be supplied----------6 3.1 Substances whose inclusion in articles to be supplied is prohibited -----------------------------6 3.2 Substances whose inclusion in articles to be supplied is subject to reduction and substitution--------------------------------------------------------------------------------------------------------9 4. Requirements for packaging materials------------------------------------------------------------------------10 5. Requirements for batteries----------------------------------------------------------------------------------------10 6. Requirement for US-EPEAT restriction-----------------------------------------------------------------------10 Attached Table: Details of substances (typical examples) referred in these Guidelines --------------------------------------13 Guidelines for Green Procurement Toshiba Client Solutions CO., Ltd 3 3 I. Green procurement 1. Objective Toshiba Client Solutions CO., Ltd. Group (hereafter, we) promote procurement from suppliers that aggressively promote activities for environmental conservation. The objective of these Guidelines are to procure articles with a lower environmental impact, in respect of procurement of parts, materials, units, products and sub-materials (hereafter, articles to be supplied) for products. 2. Requirements to suppliers 2.1 Suppliers’ activities for environmental conservation We request every supplier to undertake proactive activities for environmental conservation. We prioritize suppliers who perform such proactive activities in our procurement. Suppliers are expected to perform such environmental activities as 1) Formulating environmental policy 2) Establishing and maintaining a system for environmental conservation 3) Training and monitoring of system performance Suppliers are also expected to promote activities for energy saving, 3R (reduce, reuse and recycle), and preservation of biodiversity such as tree planting. In order to understand suppliers’ activities for environmental conservation, we want to investigate the points below, and ask for your understanding and support. 1) Document-based inquiry into supplier’s environmental activities 2) On-site investigation of supplier’s environmental activities 2.2 Control of environment-related substances for articles to be supplied Suppliers are required to comply with Chapter II. “Environment-related substances control criteria” of these Guidelines and supply articles with a lower environmental impact. In order to ensure this, suppliers should carry out the following items. 1) Make every supporting organization and your suppliers understand the requirements stated in these Guidelines. 2) Realize the requirements described in our purchase specifications and drawings. 3) Reply to our inquiries about control of environment-related substances. Although inquiries depend on types of articles to be supplied and necessity, the major ones are: i) Confirmation of no inclusion of prohibited substances, using “Use/Non-use Declaration of Environment-related Substances” ii) Inquiries about content values of EU REACH SVHC, using JAMP (Joint Article Management Promotion-consortium) AIS form, etc. iii) Requests to provide sample test result iv) Other necessary inquiries to confirm supplier’s performance 4) Obtain necessary information from your suppliers as base data for your reply. 5) Perform sample tests or obtain sample test result from your suppliers if these are an effective means to realize our requirements. 6) Investigate your suppliers’ control systems (including supplier audit). Guidelines for Green Procurement Toshiba Client Solutions CO., Ltd 4 4 II. Environment-related substances control criteria 1. Scope The scope is environment-related substances in the articles to be supplied to us for production of our products. “Our products” include products supplied by ODM or OEM vendors, resale products of other company’s brand, spare parts and repaired articles. “Our products” also include products made by or sold by Group Companies of Toshiba Client Solutions CO., Ltd. that have a capital relationship with us and to which you directly supply articles. 2. Definitions (1) Environment-related substances Substances considered to have an environmental impact and specified in these Guidelines. (2) Substances whose use is prohibited Environment-related substances whose use in articles to be supplied is prohibited by law, regulation or these Guidelines. (3) Substances whose use is to be reduced or substituted Environment-related substances specified in these Guidelines whose use in the articles to be supplied should be reduced or substituted. (4) Intentional inclusion Inclusion that cannot appropriately be regarded as impurities, as defined in (5). For example, use of a substance as a necessary ingredient in order to obtain functionality or performance. (5) Not intended inclusion (impurities) Inclusion which can be regarded as resulting from the natural environment or that is the result of a chemical reaction and that cannot be removed by a refining process with existing technology. (6) Homogeneous material The term "homogeneous material" means a material that cannot be mechanically disjointed into different materials. The term "homogeneous" means "of uniform composition throughout", so examples of "homogeneous materials" are plastics, ceramics, glass, metals, alloys, paper, board, resins and coatings. The term "mechanically disjointed" means that the materials can be, in principle, separated by mechanical actions such as unscrewing, cutting, crushing, grinding and abrasive processes. Example: - A plastic cover is homogeneous material if it consisted exclusively of one type of plastic that was not coated with or had attached to it (or inside it) any other kinds of materials. - An electric cable that consisted of material wires surrounded by non-metallic insulation materials is not homogeneous material because mechanical processes could separate the different materials. - A semi-conductor package contains many homogeneous materials, which include the plastic molding material, the tin-electroplating coatings on the lead frame, the lead frame alloy and the gold-bonding wires. Note: In case of chromate treatment, homogeneous material of the coating is defined as only chromate conversion coating, not including any base metal. Guidelines for Green Procurement Toshiba Client Solutions CO., Ltd 5 5 3. Requirements for environment-related substances control for articles to be supplied 3.1 Substances whose inclusion in articles to be supplied is prohibited For substances listed in Table 1 following inclusion is prohibited. 1) Intentional inclusion 2) Inclusion exceeding the maximum tolerance concentration The maximum tolerance concentration for each substance is defined on Table 3. Regarding substances for which maximum tolerance concentrations are not defined, impurities must be well controlled. At least concentration of each substance in components of the article must not exceed 0.1wt% (1000ppm). However, for uses listed in Table 2, neither inclusion 1) nor inclusion 2) is prohibited (exempted uses). Moreover, in some cases such as use for spare parts, we might procure parts, unit or materials which include the prohibited substances. In these cases, please follow the instructions of the person in charge. Please be aware that some uses of the substances whose use is to be reduced or substituted, as described in section 3.2, are prohibited. Please refer notes of Table 7. Table 1 Ref. No. 1 2 3 4 5 6 7 8 9 10 11 Substances whose inclusion in articles to be supplied is prohibited Substance 24 Cadmium and its compounds Hexavalent chromium compounds Lead and its compounds Mercury and its compounds Polybrominated biphenyls (PBBs) Polybrominated diphenyl ethers (PBDEs) Bis(tributyltin)=oxide (TBTO) Polychlorinatedbiphenyls (PCBs) / Polychlorinated terphenyls (PCTs) Polychloronaphtalenes (with 3 or more chlorine atoms) Short Chain Chlorinated Paraffins (with carbon length 10 through 13) Asbestos Azo pigments and dyes (only those able to form certain amines and are directly and continuously applied to the human body) Ozone depleting substances (ODS) Tri-substituted organostannic compounds (Tributyltins (TBTs) , Tripheniltins (TPTs) , etc. ,except TBTO(Ref. No.7)) Radioactive Substances Aldrin Endrin Yellow Phosphorus Chlordanes N,N'-ditolyl-p-phenylenediamin, N-tolyl-N'-xyly l-p-phenylenediamine or N,N'-dixylyl-p-phenylene diamine Dioxins DDT Dieldrin Toxaphene 25 26 27 28 29 30 31 32 2,4,6-Tri-t-Butylphenol 4-Nitrobiphenyl and its salt Bis(chloromethyl)ether Hexachlorobenzene Benzene Mirex 2,2,2-trichloro-1,1-bis(4-chlorophenyl)ethanol (synonyms: Kelthane, Dicofol) Hexachlorobutadiene (synonyms: Hexachloro-1,3-butadiene, Hexachlorobuta-1,3-diene) 12 13 14 15 16 17 18 19 20 21 22 23 Guidelines for Green Procurement Toshiba Client Solutions CO., Ltd Timing of prohibition for articles Previously prohibited Previously prohibited Previously prohibited Previously prohibited Previously prohibited Previously prohibited Previously prohibited Previously prohibited Previously prohibited Previously prohibited Previously prohibited Previously prohibited Previously prohibited Previously prohibited Previously prohibited Previously prohibited Previously prohibited Previously prohibited Previously prohibited Previously prohibited Previously prohibited Previously prohibited Previously prohibited Previously prohibited Previously prohibited Previously prohibited Previously prohibited Previously prohibited Previously prohibited Previously prohibited Previously prohibited Previously prohibited 6 6 33 46 2-benzotriazol-2-yl-4,6-ditert-butyl-phenol Perfluorooctane Sulfonate(PFOS) and its Salts (chemical formula: C8F17SO2X, X is OH group, metal salts, halide, amide and other derivatives including polymers) Dimethylfumarate(DMF) Dibutyltin (DBT) compounds Perfluorooctane sulfonyl fluoride (PFOSF) Pentachlorobenzene (PeCB) Alpha-Hexachlorocyclohexane Beta-Hexachlorocyclohexane Gamma-Hexachlorocyclohexane Clordecone Carcinogenic substances (Group1 and Group2A: evaluated by IARC) for personal computers and tablet Inclusion in the plastic parts not less than 25g of case and housing Beryllium and its compounds for personal computers and tablet Inclusion in any article to be supplied except followings 1) Additives in the gold bonding wire of semi-conductors 2) Inclusion not more than 2.0wt% in copper-beryllium alloys used as spring parts. Certain flame retardants for personal computers and tablet Inclusion of more than 0.1wt% of following flame retardants in the plastic parts more than 25g: Flame retardants that are classified under EU 67/548/EEC and 2009/2/EC as R40, R45, R46, R48, R50, R51, R52, R53, R60, R61 and any combination of these. R40 flame retardants in the external cable (both AC and DC) are exempted from this requirement. 6,9-Methano-2,4,3-benzodioxathiepin,6,7,8,9,10,10-hexachloro-1,5,5a,6,9,9a-hexahydro-, 3-oxide (also known as Benzoepin or Endosulfan) 47 Hexabromocyclododecane (also known as HBCD) 48 Certain polycyclic aromatic hydrocarbons (PAHs) Articles shall not be placed on the market for supply to the general public, if any of their rubber or plastic components that come into direct as well as prolonged or short-term repetitive contact with the human skin or the oral cavity, under normal or reasonably foreseeable conditions of use, contain more than 1 mg/kg (0,0001 % by weight of this component) of any of the listed PAHs. (refer to Table 6, Annex XVII, EU REACH) 34 35 36 37 38 39 40 41 42 43 44 45 Previously prohibited Previously prohibited Previously prohibited Previously prohibited Previously prohibited Previously prohibited Previously prohibited Previously prohibited Previously prohibited Previously prohibited Previously prohibited Previously prohibited Previously prohibited Immediately prohibited Immediately prohibited To be prohibited from July 1, 2015 onward To be prohibited from January 1, 2017 onward To be prohibited from Dibutyl phthalate (DBP) January 1, 2017 50 onward To be prohibited from Butyl benzyl phthalate (BBP) January 1, 2017 51 onward To be prohibited from Diisobutyl phthalate (DIBP) January 1, 2017 52 onward To be prohibited from Red phosphorus (as flame retardant in resin) (*1) 53 July 1, 2015 onward (*) Ref. No.: Reference number to the attached table “Details of substances (Typical examples)”.Please refer the attached table for details. (*1) Restriction of red phosphorus is not based on environmental viewpoint. 49 Bis (2-ethylhexyl)phthalate (DEHP) Table 2 Exempted uses (Allowable uses) Substance Cadmium and its compounds Lead and its compounds Exempted uses (Allowable uses) Expiration date RoHS exemption No. 8(b) 13(b) Cadmium and its compounds in electrical contacts Cadmium in filter glasses and glasses used for reflectance standards Cadmium in printing inks for the application of enamels on glasses, such as borosilicate and soda lime glasses Lead in glass of cathode ray tubes Lead in glass of fluorescent tubes not exceeding 0.2 % by weight Lead as an alloying element in steel for machining purposes and in galvanized steel containing up to 0.35 % lead by weight Lead as an alloying element in aluminum containing up to 0.4 % lead by weight Copper alloy containing up to 4 % lead by weight Guidelines for Green Procurement Toshiba Client Solutions CO., Ltd 21 5(a) 5(b) 6(a) 6(b) 6(c) 7 7 Lead in high melting temperature type solders (i.e. lead- based alloys containing 85 % by weight or more lead) Lead in solders for servers, storage and storage array systems, network infrastructure equipment for switching, signaling, transmission, and network management for telecommunications Electrical and electronic components containing lead in a glass or ceramic other than dielectric ceramic in capacitors, e.g. piezoelectronic devices, or in a glass or ceramic matrix compound Lead in dielectric ceramic in capacitors for a rated voltage of 125 V AC or 250 V DC or higher Lead in PZT based dielectric ceramic materials for capacitors being part of integrated circuits or discrete semiconductors Lead in white glasses used for optical applications Lead in filter glasses and glasses used for reflectance standards Lead in solders to complete a viable electrical connection between semiconductor die and carrier within integrated circuit flip chip packages Lead halide as radiant agent in high intensity discharge (HID) lamps used for professional reprography applications Lead in printing inks for the application of enamels on glasses, such as borosilicate and soda lime glasses Mercury and its compounds PFOS and its salts PFOS and its salts Lead in solders for the soldering to machined through hole discoidal and planar array ceramic multilayer capacitors Lead bound in crystal glass as defined in Annex I (Categories 1, 2, 3 and 4) of Council Directive 69/493/EEC Lead in soldering materials in mercury free flat fluorescent lamps (which e.g. are used for liquid crystal displays, design or industrial lighting) Mercury in single capped (compact) fluorescent lamps not exceeding (per burner): a) For general lighting purposes < 30 W: 2.5 mg b) For general lighting purposes ≥ 30 W and < 50 W: 3.5mg c) For general lighting purposes ≥ 50 W and < 150 W: 5 mg d) For general lighting purposes ≥ 150 W: 15 mg e) For general lighting purposes with circular or square structural shape and tube diameter ≤ 17 mm: 7mg f) For special purposes: 5 mg Mercury in double-capped linear fluorescent lamps for general lighting purposes not exceeding (per lamp): a) Tri-band phosphor with normal lifetime and a tube diameter < 9 mm (e.g. T2): 4mg b) Tri-band phosphor with normal lifetime and a tube diameter ≥ 9 mm and ≤ 17 mm (e.g. T5): 3mg c) Tri-band phosphor with normal lifetime and a tube diameter > 17 mm and ≤ 28 mm (e.g. T8): 3.5mg d) Tri-band phosphor with normal lifetime and a tube diameter > 28 mm (e.g. T12): 3.5mg e) Tri-band phosphor with long lifetime (≥ 25 000 h): 5mg Mercury in fluorescent lamps other than listed in (H1), (H2) or (H4) not exceeding 15mg (per lamp) excluding linear halophosphate lamps with tube > 28 mm (e.g. T10 and T12). Mercury in cold cathode fluorescent lamps and external electrode fluorescent lamps (CCFL and EEFL) for special purposes not exceeding (per lamp): a) Short length (≤ 500 mm) 3.5mg b) Medium length (> 500 mm and ≤ 1 500 mm) 5mg c) Long length (> 1 500 mm) 13mg In other low pressure discharge lamps not exceeding 15 mg (per lamp) Mercury in other discharge lamps for special purposes not specifically mentioned in the Annex of COMMISSION DECISION 2010/571/EU Photoresists or anti reflective coatings for photolithography processes, Photographic coatings applied to films, papers, or printing plates, Mist suppressants for non-decorative hard chromium (VI) plating and wetting agents for use in controlled electroplating systems where the amount of PFOS released into the environment is minimized, by fully applying relevant best available techniques. Guidelines for Green Procurement Toshiba Client Solutions CO., Ltd 7(a) 7(b) 7(c)-I 7(c)-II 7(c)-Ⅳ, 13(a) 13(b) 15 17 21 24 29 31 1(a)-(f) 2(a)(1)-(5) 2(b)(2)-(4) 3(a)-(c) 4(a) 4(f) - 8 8 Table 3 Maximum tolerance concentration as impurities Substance Uses and regal requirements Use other than described bellow. Under the EU RoHS Directive. Use restricted by EU chemical substances restriction (REACH ANNEX XVII (former: EU Directive 76/769/EEC and its amendments.) - Resin, paint, ink, etc Cadmium and its compounds (*4) Hexavalent chromium compounds (*4) Lead and its compounds (*4) Mercury and its compounds (*4) PBB PBDE PFOS and its salts Maximum tolerance concentration (*1)(*2) 0.01wt% (100ppm) 0.0075wt% (75ppm) All uses. Under the RoHS Directive. 0.1wt% (1000ppm) All uses. Under the RoHS Directive. 0.1wt% (1000ppm) All uses. Under the RoHS Directive. 0.1wt% (1000ppm) All uses. Under the RoHS Directive. All uses. Under the RoHS Directive. Coated materials (use restricted by EU chemical substances restriction (EU Directive 76/769/EEC and its amendments.)) 0.1wt% (1000ppm) 0.1wt% (1000ppm) (*3) less than 1 ug/m2 less than 0.1wt% (1000ppm) Others (same as above) Certain polycyclic aromatic hydrocarbons (PAHs) (*5) Rubber or plastic components that come into direct as well as prolonged or short-term repetitive contact with the human skin or the oral cavity 0.0001wt% (1ppm) Bis (2-ethylhexyl)phthalate (DEHP) Dibutyl phthalate (DBP) Butyl benzyl phthalate (BBP) Diisobutyl phthalate (DIBP) Red Phosphorus All uses. Under the RoHS Directive. 0.1wt% (1000ppm) All uses. Under the RoHS Directive. 0.1wt% (1000ppm) All uses. Under the RoHS Directive. 0.1wt% (1000ppm) All uses. Under the RoHS Directive. 0.1wt% (1000ppm) Inclusion to all the supplies except metal 0.1wt% (1000ppm) (*6) (*1) Maximum tolerance concentration as impurities of each substance is defined as the weight percentage in homogeneous materials. (*2) Maximum tolerance concentration of heavy metal compounds is defined as the weight percentage of metal element in homogeneous materials. e.g.) In the case of cadmium and its compound the concentration relates to the cadmium element. (*3) Maximum tolerance concentration of PBDE is defined as the accumulated concentration of all PBDEs, including Deca-BDE, in the homogenous materials. (*4) Refer to Table 9, regarding maximum tolerance concentration in packaging materials. (*5) Substances described in the Annex XVII of the EU REACH (refer to Table 6) (*6) Maximum tolerance concentration of red phosphorous included intentionally is defined as a concentration of total phosphorous element. Table 4 List of specific amines (generated by the decomposition of one or more azo group) Substance 4-amino azobenzene o-anisidine 2-naphthylamine (β-Naphthylamine) 3, 3’-dichlorobensidine Biphenyl-4-ylamine Benzidine o-toluidine 4-chloro- o-toluidine 2, 4-toluenediamine o-aminoazotoluene 5- nitro-o-toluidine 3, 3’-dichloro-4, 4’-diaminodiphenylmethane 4, 4’-methylenedianiline Guidelines for Green Procurement Toshiba Client Solutions CO., Ltd Chemical formula C12H11N3 C7H9NO C10H9N C12H10Cl2N2 C12H11N C12H12N2 C7H9N C7H8ClN C7H10N2 C14H15N3 C7H8N2O2 C13H12Cl2N2 C13H14N2 CAS No. 60-09-3 90-04-0 91-59-8 91-94-1 92-67-1 92-87-5 95-53-4 95-69-2 95-80-7 97-56-3 99-55-8 101-14-4 101-77-9 9 9 4, 4’-diaminodiphenylether p-chloroaniline 3, 3’-dimethoxybenzidine 3, 3’-dimethylbenzidine 2-methoxy-5-methylaniline 2, 4, 5-trimethylaniline 4, 4’-Thiodianiline 2, 4’-methoxy-m-Phenylenediamine 4, 4’-methylenedi- o -toluidine Table 5 C12H12N2O C6H6ClN C14H16N2O2 C14H16N2 C8H11NO C9H13N C12H12N2S C7H10N2O C15H18N2 101-80-4 106-47-8 119-90-4 119-93-7 120-71-8 137-17-7 139-65-1 615-05-4 838-88-0 Ozone depleting substances (ODS) CFC Halon CFC other than above Carbon tetrachloride 1, 1, 1-Trichroloethane HCFC HBFC Bromochloromethane Methylbromide (Defined in Appendix A group I of Montreal Protocol) (Defined in Appendix A group II of Montreal Protocol) (Defined in Appendix B group I of Montreal Protocol) (Defined in Appendix B group II of Montreal Protocol) (Defined in Appendix B group III of Montreal Protocol) (Defined in Appendix C group I of Montreal Protocol)) (Defined in Appendix C group II of Montreal Protocol)) (Defined in Appendix C group III of Montreal Protocol) (Defined in Appendix E of Montreal Protocol) Table6 Certain polycyclic aromatic hydrocarbons (PAHs) Uses and groups of substances in the Annex XVII of the EU REACH are in scope. Substance Benzo[a]pyrene (BaP) Benzo[e]pyrene (BeP) Benzo[a]anthracene (BaA) Chrysen (CHR) Benzo[b]fluoranthene (BbFA) Benzo[j]fluoranthene (BjFA) Benzo[k]fluoranthene (BkFA) Dibenzo[a,h]anthracene (DBAhA) Chemical formula C20H12 C20H12 C18H12 C18H12 C20H12 C20H12 C20H12 C22H14 CAS No. 50-32-8 192-97-2 56-55-3 218-01-9 205-99-2 205-82-3 207-08-9 53-70-3 3.2 Substances whose inclusion in articles to be supplied is subject to reduction and substitution The volume of substances listed in Table 7 should be reduced in articles to be supplied, or should be replaced with other substances. We give priority to articles that do not include these substances, if commercially available. Please be aware that some of these substances used for specified application are prohibited. Refer to the notes of Table 7. Table 7 Substances whose inclusion in articles to be supplied is subject to reduction and substitution Ref. No. 54 55 56 57 58 59 60 61 62 63 64 65 66 Substance Polyvinyl chloride (PVC) Tetrabromo-bisphenol A (TBBPA) Brominated flame retardant (except PBBs(Ref. No.5), PBDEs(Ref. No.6) and TBBPA(Ref. No.44)) Antimony and its compounds Arsenic and its compounds Beryllium and its compounds (Except Ref. No.44) Bismuth and its compounds Nickel and its compounds (*1) Some Phthalic Esters (Except DEHP(Ref. No.49), DBP(Ref. No.50), BBP(Ref. No.51), DIBP(Ref. No.52)) Selenium and its compounds Zinc and its compounds Chlorinated paraffin (except some short chain chlorinated paraffins (Ref. No.10)) Chromium compounds (III) Guidelines for Green Procurement Toshiba Client Solutions CO., Ltd 10 10 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 Cyanogen compounds Perfluorocarbon (PFC) Hydrogenerated fluorocarbon (HFC) Hydrogenerated organic compounds (except those listed in Table1 (Ref. No.5, No.6, etc.) Manganese and its compounds Organic Tin Compounds (except TBTO (Ref. No.7), Tri-substituted organostatic compounds (Ref. No.14) and DBT (Ref. No.36)) Sulfur hexafluoride (SF6) Anthracene 4,4'- Diaminodiphenylmethane Cobalt dichloride Cobalt(II) sulphate Cobalt(II) dinitrate Cobalt(II) carbonate Cobalt(II) diacetate 5-tert-butyl-2,4,6-trinitro-m-xylene(synonym: musk xylene) 2,4-Dinitrotoluene Coal tar pitch, high temperature Aluminosilicate, Refractory Ceramic Fibres Zirconia Aluminosilicate, Refractory Ceramic Fibres Acrylamide Tris(2-chloroethyl)phosphate Trichloroethylene Boric acid Disodium tetraborate, anhydrous Tetraboron disodium heptaoxide, hydrate 2-Methoxyethanol 2-Ethoxyethanol (*1) The use of nickel and its compounds for the area expected for direct and prolonged skin contact is prohibited. (*2) Ref. No.: Reference number to the attached table “Details of substances (typical examples) referred in these Guidelines”. Please refer the attached table for details. 4. Requirements for packaging materials All packaging materials to be supplied, not limited to individual packaging, must fulfill the requirements of section 3. “Requirements for environment-related substances control for articles to be supplied”, and also must not include substances listed in Table 8. For substance where a maximum tolerance concentration is defined, any inclusion exceeding that concentration is prohibited. For substances that do not define a maximum tolerance concentration, intentional inclusion is prohibited. Table 8 Ref. No. 1-4 54 Substances whose inclusion in the packaging to be supplied is prohibited Substance Restriction Lead, cadmium, mercury, hexavalent chromium and their compounds Polyvinyl chloride (PVC) Inclusion of cadmium, hexavalent chromium, lead, mercury and their compounds in the packaging when the accumulated concentration of these substances at any portion of the packaging exceeds the maximum tolerance concentration. Intentional inclusion of PVC in the packaging Maximum tolerance concentration (*1)(*2) 0.01wt% (100ppm) (Intentional inclusion) Halogen compounds use in the plastic of packaging for personal computers : fluorine (F), chlorine (Cl), bromine (Br), iodine (I) and astatine (Intentional inclusion) (At) (*1) Maximum tolerance concentration is defined as the weight percentage in homogeneous materials. (*2) Maximum tolerance concentration of metal compounds is defined as the weight percentage of metal element in homogeneous materials. Halogen compounds Guidelines for Green Procurement Toshiba Client Solutions CO., Ltd 11 11 5. Requirements for batteries Any type of batteries or accumulators, whether stand-alone or installed in units or products, must comply with the EU Battery Directives (2006/66/EC and 2013/56/EU). The requirements include prohibition of inclusion exceeding the maximum tolerance concentration described on Table 9. The area other than cells of the battery device, such as battery pack, must fulfill not only requirements described in this section but also those described in section 3. “Requirements for environment-related substances control for articles to be supplied”. Table 9 Substances whose inclusion in the battery is prohibited Ref. No. Substance 1 Cadmium and its compounds 4 Mercury and its compounds Restriction Portable batteries or accumulators that contain cadmium and its compounds exceeding the maximum tolerance concentration. All batteries or accumulators, except button batteries, that contain mercury and its compounds exceeding the maximum tolerance concentration. Button batteries that contain mercury and its compounds exceeding the maximum tolerance concentration. Maximum tolerance concentration (*1) Timing of application 0.002wt% (20ppm) Previously applied 0.0005wt% (5ppm) Previously applied 2wt% (20000ppm) Prohibition of intentional addition By September 30, 2015 from October 1, 2015 onward (*1) Maximum tolerance concentration is defined as the weight percentage of metal element in the battery. 6. Requirements for US-EPEAT restriction Addition to the requirements that are described before, requirements for US-EPEAT restriction that is described on Table10 must be fulfilled.. Table10 Restriction by US-EPEAT Substance Cadmium Hexavalent chromium Lead Polyvinyl chloride (PVC) Contents of restriction Inclusion ratio in homogeneous material is less than or equal to 0.005wt% (50ppm) (excluding recycled content) Inclusion ratio in homogeneous material is less than or equal to 0.05wt% (500ppm) (Exempted use in (excluding recycled content) Inclusion ratio in total weight of object item is less than or equal to 0.005wt% (50ppm) (*1) (Exempted use in EU-RoHS directives is applicable,) PVC is not included in plastic parts that weigh 25g or more (excluding cable or internal wiring) (*1) Object items for Lead are Liquid crystal in LCD unit, Housing of LCD unit, Printed circuit board in LCD unit, AC adapter and AC cable. Guidelines for Green Procurement Toshiba Client Solutions CO., Ltd 12 12 Attached Table: Details of substances (typical examples) referred in these Guidelines Guidelines for Green Procurement Toshiba Client Solutions CO., Ltd 13 13 Attached Table: Details of substances (typical examples) referred in these guidelines No. 1 2 3 CAS 7440-43-9 1306-19-0 1306-23-6 10108-64-2 10124-36-4 7789-12-0 10588-01-9 1333-82-0 13765-19-0 7758-97-6 7778-50-9 7789-00-6 7439-92-1 598-63-0 1309-60-0 1314-41-6 1314-87-0 1317-36-8 1319-46-6 1344-36-1 7446-14-2 7446-27-7 7758-97-6 12060-00-3 15739-80-7 12202-17-4 1072-35-1 56189-09-4 12656-85-8 1344-37-2 - 4 5 6 7 8 9 7439-97-6 7487-94-7 21908-53-2 59536-65-1 1163-19-5 56-35-9 1336-36-3 61788-33-8 70776-03-3 Chemical substance name Cadmium and its compounds Cadmium Cadmium oxide Cadmium sulfide Cadmium chloride Cadmium sulfate Other cadmium compounds Hexavalent chromium compounds Chemical formula Cd CdO CdS CdCl2 CdSO4 - Sodium dichromate Na2Cr2O7 Chromium(VI) oxide Calcium chromate Lead (II) chromate Potassium dichromate Potassium chromate Other hexavalent chromium compounds Lead and its compounds Lead Lead(II) carbonate Lead(IV) oxide Lead(II,IV) oxide Lead(II) sulfide Lead(II) oxide Lead(II) carbonate basic Lead Hydroxidcarbonate Lead(II) sulfate Lead(II) phosphate Lead(II) chromate Lead(II) titanate Lead sulfate,sulphuric acid,lead salt Lead sulfate,tribasic Lead stearate Lead stearate,dibasic Lead chromate molybdate sulfate red (C.I. Pigment Red 104) Lead sulfochromate yellow (C.I. Pigment Yellow 34) Other lead compounds Mercury and its compounds. Mercury Mercury(II) chloride Mercury(II) oxide Other mercury compounds Polybrominated biphenyls (PBBs) Polybrominated biphenyls Other polybrominated biphenyls Polybrominated diphenyl ethers (PBDEs) Polybrominated diphenyl ethers Other Polybrominated diphenyl ethers Bis(tributyltin)oxide Bis(Tri-n-butyltin)oxide Polychlorinatedbiphenyls (PCBs)/ Polychlorinated terphenyls (PCTs) PCB(Polychlorinated biphenyls) PCT(Polychlorinated terphenyls) Other PCBs Polychlorinated naphthalene(Cl3) Polychlorinated naphthalene(Cl3) CrO3 Guidelines for Green Procurement Toshiba Client Solutions CO., Ltd CaCrO4 PbCrO4 K2Cr2O7 K2CrO4 Pb PbCO3 PbO2 Pb3O4 PbS PbO 2PbCO3.Pb(OH)2 2PbCO3.Pb(OH)2 PbSO4 Pb3(PO4)2 PbCrO4 PbTiO3 PbSO4 PbSO4H2O Pb(C17H35COO)2 2PbOPb(C17H35COO)2 PbCrO4, PbMoO4, PbSO 4 Pb(Cr,S)O4 Hg HgCl2 HgO C12HxBr(10-x) C12HxBr(10-x)O O(Sn(C4H9)3)2 C12HnCl(10-n) (n: 0-9) C18HnCl(14-n) (n: 0-13)- 14 14 - Other Polychlorinated naphthalene(Cl3) Short chain chlorinated paraffins 10 85535-84-8 Short chain chlorinated paraffins(C10-13) Asbestos 77536-66-4 Actinolite 12172-73-5 Amosite 77536-67-5 Anthophylite 11 12001-29-5 Chrysotile 12001-28-4 Crocidolite 77536-68-6 Tremolite Other asbestos Azo pigments and dyes.(those able to form certain amines) 60-09-3 4-Aminoazobenzene 90-04-0 -Anisidine 91-59-8 2-Naphthylamine (β-Naphthylamine) 91-94-1 3,3'-Dichlorobenzidine 92-67-1 4-Biphenylamine 92-87-5 Benzidine 95-53-4 -Toluidine 95-69-2 4-Chloro--toluidine 95-80-7 2,4-Toluendiamine 97-56-3 -Aminoazotoluene 12 99-55-8 5-Nitro--toluidine 101-14-4 3,3'-Dichloro-4,4'-diaminodiphenylmethan 101-77-9 4,4'-Methylenedianiline 101-80-4 4,4'-Diaminodiphenylether 106-47-8 p-Chloroaniline 119-90-4 3.3’-Dimethoxybenzidine 119-93-7 3,3'-Dimethylbenzidine 120-71-8 2-Methoxy-5-methylaniline 137-17-7 2,4,5-Trimethylaniline 139-65-1 4,4'-Thiodianiline 615-05-4 4-Methoxy-m-phenylenediamine 838-88-0 4,4'-Diamino-3,3'-dimethyldiphenylmethane Ozone Depleting Substances 75-69-4 CFC-11 75-71-8 CFC-12 76-13-1 CFC-113 76-14-2 CFC-114 76-15-3 CFC-115 353-59-3 Halon1211 75-63-8 Halon1301 124-73-2 Halon2402 75-72-9 CFC-13 354-56-3 CFC-111 28605-74-5 CFC-112 422-78-6 CFC-211 CFC-212 13 3182-26-1 2354-06-5 CFC-213 2268-46-4 CFC-214 76-17-5 CFC-215 661-97-2 CFC-216 422-86-6 CFC-217 56-23-5 Carbon tetrachloride 71-55-6 1,1,1-Trichloroethane 1868-53-7 Dibromofluoromethane 1511-62-2 Bromodifluoromethane 373-52-4 Bromofluoromethane 306-80-9 Tetrabromofluoroethane Tribromodifluoroethane 354-04-1 Dibromotrifluoroethane Guidelines for Green Procurement Toshiba Client Solutions CO., Ltd CnH2 n+2-xClx (n:10-13) Ca2(Mg,Fe)5(Si8O22)(OH)2 Fe5Mg2(Si8O22)(OH)2 (Mg, Fe)7Si8O22(OH)2 Mg3(Si2O5)(OH)4 Na2Fe2+3Fe3+2Si8O22(OH)2 Ca2Mg5Si8O22(OH)2 - C12H11N3 C7H9NO C10H9N C12H10Cl2N2 C12H11N C12H12N2 C7H9N C7H8ClN C7H10N2 C14H15N3 C7H8N2O2 C13H12Cl2N2 C13H14N2 C12H12N2O C6H6ClN C14H16N2O2 C14H16N2 C8H11NO C9H13N C12H12N2S C7H10N2O C15H18N2 CFCl3 CF2Cl2 C2F3Cl3 C2F4Cl2 C2F5Cl CF2BrCl CF3Br C2F4Br2 CF3Cl C2FCl5 C2F2Cl4 C3FCl7 C3F2Cl6 C3F3Cl5 C3F4Cl4 C3F5Cl3 C3F6Cl2 C3F7Cl CCl4 C2H3Cl3 CHFBr2 CHF2Br CH2FBr C2HFBr4 C2HF2Br3 C2HF3Br2 15 15 124-72-1 75-62-1 421-06-7 358-97-4 359-07-9 762-49-2 431-78-7 2252-79-1 480-88-8 70192-80-2 70192-83-5 679-84-5 75372-14-4 460-25-3 421-46-5 51584-26-0 352-91-0 74-97-5 74-83-9 75-43-4 75-45-6 593-70-4 134237-32-4 41834-16-6 34077-87-7 306-83-2 63938-10-3 2837-89-0 134237-34-6 25915-78-0 75-88-7 25167-88-8 1717-00-6 25497-29-4 75-68-3 1615-75-4 134237-35-7 134237-36-8 134237-37-9 134237-38-0 127564-92-5 422-56-0 507-55-1 134308-72-8 134190-48-0 134237-39-1 134237-40-4 127564-83-4 134237-41-5 134190-49-1 134237-42-6 Bromotetrafluoroethane Tribromofluoroethane Dibromodifluoroethane Bromotrifluoroethane Dibromofluoroethane Bromodifluoroethane Bromofluoroethane Hexabromofluoropropane Pentabromodifluoropropane Tetrabromotrifluoropropane Tribromotetrafluoropropane Dibromopentafluoropropane Bromohexafluoropropane Pentabromofluoropropane Tetrabromodifluoropropane Tribromotrifluoropropane Dibromotetrafluoropropane Bromopentafluoropropane Tetrabromofluoropropane Tribromodifluoropropane Dibromotrifluoropropane Bromotetrafluoropropane Tribromofluoropropane Dibromodifluoropropane Bromotrifluoropropane Dibromofluoropropane Bromodifluoropropane Bromofluoropropane Chlorobromomethane Methylbromide HCFC-21 HCFC-22 HCFC-31 HCFC121 HCFC-122 HCFC-123 HCFC-123 HCFC-124 HCFC-124 HCFC-131 HCFC-132 HCFC-133 HCFC-141 HCFC-141(b) HCFC-142 HCFC-142(b) HCFC-151 HCFC-221 HCFC-222 HCFC-223 HCFC-224 HCFC-225 HCFC-225 ca HCFC-225 cb HCFC-226 HCFC-231 HCFC-232 HCFC-233 HCFC-234 HCFC-235 HCFC-241 HCFC-242 Guidelines for Green Procurement Toshiba Client Solutions CO., Ltd C2HF4Br C2H2FBr3 C2H2F2Br2 C2H2F3Br3 C2H3FBr2 C2H3F2Br C2H4FBr C3HFBr6 C3HF2Br5 C3HF3Br4 C3HF4Br3 C3HF5Br2 C3HF8Br C3H2FBr5 C3H2F2Br4 C3H2F3Br3 C3H2F4Br2 C3H2F5Br C3H3FBr4 C3H3F2Br3 C3H3F3Br2 C3H3F4Br C3H4FBr3 C3H4F2Br2 C3H4F3Br C3H5FBr2 C3H5F2Br C3H6FBr CH2BrCl CH3Br CHFCl2 CHF2Cl CH2FCl C2HFCl4 C2HF2Cl3 C2HF3Cl2 CHCl2CF3 C2HF4Cl CHFClCF3 C2H2FCl3 C2H2F2Cl2 C2H2F3Cl C2H3FCl2 C2H3FCl2 C2H3F2Cl CH3CF2Cl C2H4FCl C3HFCl6 C3HF2Cl5 C3HF3Cl4 C2HF4Cl3 C3HF5Cl2 CF3CF2CHCl2 CF2ClCF2CHClF C3HF6Cl C3H2FCl5 C3H2F2Cl4 C3H2F3Cl3 C3H2F4Cl2 C3H2F5Cl C3H3FCl4 C3H3F2Cl3 16 16 134237-43-7 134190-50-4 134190-51-5 134190-52-6 134237-44-8 134237-45-9 134190-53-7 134190-54-8 1803-12-9 379-52-2 900-95-8 639-58-7 76-87-9 47672-31-1 7094-94-2 2155-70-6 6454-35-9 1983-10-4 31732-71-5 14 56-36-0 3090-36-6 4782-29-0 6517-25-5 14275-57-1 1461-22-9 - 7440-61-1 7440-07-5 10043-92-2 15 7440-35-9 7440-29-1 7440-46-2 7440-24-6 16 17 18 309-00-2 72-20-8 12185-10-3 5566-34-7 5103-74-2 5103-71-9 19 76-44-8 27304-13-8 39765-80-5 5103-73-1 20 HCFC-243 HCFC-244 HCFC-251 HCFC-252 HCFC-253 HCFC-261 HCFC-262 HCFC-271 Tri-substituted organostannic compounds (Tributyltin, Triphenyltin, etc. except TBTO(No.7)) Triphenyltin N,N’-dimethyldithiocarbamate Triphenyltin fuloride Triphenyltin acetate Triphenyltin chloride Triphenyltin hydroxide Triphenyltin fatty acid salts(C=9-11) Triphenyltin chloroacetate Triphenyltin methacrylate Bis(tributyltin)2,3-dibromosuccinate Tributyltin fluoride Bis(tributyltin) 2,3-dibromosuccinate Tributyltin acetate Tributyltin laurate Bis(tributyltin)phthalate Copolymer of alkyl acrylate,methyl methacrylate and tributyltin methacrylate (alkyl;C=8) Tributyltin sulfamate Bis(tributyltin)maleate tributyltin chloride Mixture of tributyltin cyclopentane carboxylate and its analogs Mixture of tributyltin-1,2,3,4,4,a,5,6,10,10a-decahydro-7-isopro pyl-1,4a-dimethyl-1-phenanthren carboxylate and its analogs Other tri-substituted organostannic compounds Radioactive substances Uranium Plutonium Radon Americium Thorium Cesium Strontium Other radioactive substances Aldrin Aldrin Endrin Endrin Yellow Phosphorus Yellow Phosphorus Chlordanes Gamma-chlordane Trans- chlordane Cis- chlordane Heptachlor Oxychlordane Trans-nonachlor Cis-nonachlor N,N'-ditolyl-p-phenylenediamin, N-tolyl-N'-xyly l-p-phenylenediamine and Guidelines for Green Procurement Toshiba Client Solutions CO., Ltd C3H3F3Cl2 C3H3F4Cl C3H4FCl3 C3H4F2Cl2 C3H4F3Cl C3H5FCl2 C3H5F2Cl C3H6FCl (C6H5)3Sn(CH3)2NCS2 (C6H5)3SnF (C6H5)3SnOCOCH3 (C6H5)3SnCl (C6H5)3SnOH (C6H5)3SnOCOCH2Cl (C4H9)3SnC4H5O2 C2H2(COO)2((C4H9)3Sn)2 (C4H9)3SnF ((C4H9)3Sn)2 C2H2(Br)2(COO)2 (C4H9)3SnOCOCH3 (C4H9)3SnC12H23 O2 (C6H4)(COO)2((C 4H9)3Sn)2 (C4H9)3SnSO3NH2 C2H2(COO)2((C4H9)3Sn)2 (C4H9)3SnCl - - U Pu Rn Am Th Cs Sr C12H8Cl6 C12H8Cl6O P4 C10H6Cl8 C10H6Cl8 C10H6Cl8 C10H5Cl7 C10H4C l8O C10H5Cl9 C10H5Cl9 17 17 37 307-35-7 38 608-93-5 N,N'-dixylyl-p-phenylenediamine N,N’-ditolyl-p-phenylenediamin N-Tolyl-N'-Xylyl-p-phenylenediamine N,N'-dixylyl-p- phenylenediamine Dioxins Polychlorinated dibenzo-p-dioxin Polychlorinated dibenzofuran Co- PCBs DDT Dieldrin Toxaphene 2,4,6-Tri-t-butylphenol 4-Nitrodiphenyl and its salt 4-Nitrodiphenyl Bis(chloromethyl)ether Hexachlorobenzene Benzene Mirex 2,2,2-trichloro-1,1-bis(4-chlorophenyl)ethanol Hexachlorobutadiene (Hexachloro-1,3-butadiene, Hexachlorobuta-1,3-diene) 2-benzotriazol-2-yl-4,6-di-tert-butyl-phenol Perfluorooctane Sulfonate(PFOS) and its salts Perfluorooctanesulfonic acid Perfluorooctanesulfonate amine Bis(2-hydroxyethyl) ammonium perfluorooctanesulfonate Potassium perfluorooctanesulfonate Lithium perfluorooctanesulfonate Other perfluorooctane Sulfonate and its Salts Dimethylfumarate(DMF) Dibutyltin (DBT) compounds Dibutyltin oxide Dibutyltin diacetate Dibutyltin dilaurate Dibutyltin maleate Other dibutyltin compounds Perfluorooctane sulfonyl fluoride (PFOSF) Pentachlorobenzene (PeCB) 39 319-84-6 Alpha-Hexachlorocyclohexane 40 319-85-7 41 58-89-9 42 143-50-0 Beta-Hexachlorocyclohexane Gamma-Hexachlorocyclohexane Clordecone Carcinogenic substances (Group1 and Group2A:evaluated by IARC) Beryllium and its compounds Beryllium Beryllium oxide Other Beryllium compounds 6,9-Hethano-2,4,3-benzodioxathiepin, 6,7,8,9,10,10-hexachloro-1,5,5a,6,8,9a-hexahydro-,3 -oxide (also known as Benzoepin or Endosulfan) Hexabromocyclododecane (also known as HBCD) Certain Polycyclic aromatic hydrocarbon (PAHs) Benzo[a]pyrene (BaP) Benzo[e]pyrene (BeP) Benzo[a]anthracene (BaA) Chrysen (CHR) Benzo[b]fluoranthene (BbFA) Benzo[j]fluoranthene (BjFA) Benzo[k]fluoranthene (BkFA) 27417-40-9 28726-30-9 70290-05-0 21 22 23 24 25 26 27 28 29 30 31 50-29-3 60-57-1 8001-35-2 732-26-3 92-93-3 542-88-1 118-74-1 71-43-2 2385-85-5 115-32-2 32 87-68-3 33 3846-71-7 1763-23-1 29081-56-9 34 70225-14-8 2795-39-3 29457-72-5 35 624-49-7 818-08-6 1067-33-0 36 77-58-7 78-04-6 43 44 7440-41-7 59 1304-56-9 46 115-29-7 47 25637-99-4 50-32-8 192-97-2 56-55-3 48 218-01-9 205-99-2 205-82-3 207-08-9 Guidelines for Green Procurement Toshiba Client Solutions CO., Ltd C14H9Cl5 C12H8Cl6O C10H10Cl8 C18H30O C12H9NO2 C2H4Cl2O C6Cl6 C6H6 C10Cl12 C14H9C l5O C4Cl6 C20H25N3O C8F17SO2X C8HF17O3S C8F17S O3 NH4 C12H12F17NO5S C8F17KO3S C8F17LIO3S C6H8O4 C8H18OSn C12H24O4Sn C32H64O4Sn C12H20O4Sn C8F17SO2F C6HCl5 C6H6Cl6 C6H6Cl6 C6H6Cl6 C10Cl10O - Be BeO C9H6Cl6 O3S C12H18Br6 C20H12 C20H12 C18H12 C18H12 C20H12 C20H12 C20H12 18 18 49 50 51 52 53 54 55 56 53-70-3 117-81-7 84-74-2 85-68-7 84-69-5 Dibenzo[a,h]anthracene (DBAhA) Bis(2-ethylhexyl)phthalate (DEHP) Dibutyl Phthalate (DBP) Butyl benzyl phthalate (BBP) Diisobutyl phthalate (DIBP) Red phosphorus (flame retardant application in the 7723-14-0 resin) 9002-86-2 Polyvinylchloride(PVC) Tetrabromo-bisphenol A(TBBPA,TBBA) 79-94-7 Tetrabromo-bisphenol A 30496-13-0 TBBA, unspecified 40039-93-8 TBBA-epichlorhydrin oligomer 70682-74-5 TBBA-diglycidyl-ether oligomer 28906-13-0 TBBA carbonate oligomer 94334-64-2 TBBA carbonate oligomer,phenoxy end capped TBBA carbonate 71342-77-3 oligomer,2,4,6-tribromo-phenolterminated 32844-27-2 TBBA-bisphenol A-phosgene polymer 21850-44-2 TBBA-(2,3-dibromo-propyl-ether) 4162-45-2 TBBA bis-(2-hydroxy-ethyl-ether) 25327-89-3 TBBA-bis-(allyl-ether) 37853-61-5 TBBA-dimethyl-ether Brominated flame retardant (except: PBB,PBDE,TBBPA) Brominated flame retardant which comes under notation of ISO 1043-4 code number FR(14) [ Aliphatic/alicyclic brominated compounds] Brominated flame retardant which comes under notation of ISO 1043-4 code number FR(15) [ Aliphatic/alicyclic brominated compounds in combination with antimony compounds] Brominated flame retardant which comes under notation of ISO 1043-4 code number FR(16) [ Aromatic brominated compounds(excluding brominated diphenyl ether and biphenyls)] Brominated flame retardant which comes under notation of ISO 1043-4 code number FR(17) [ Aromatic brominated compounds(excluding brominated diphenyl ether and biphenyls )in combination with antimony compounds] Brominated flame retardant which comes under notation of ISO 1043-4 code number FR(22) [ Aliphatic/alicyclic chlorinated and brominated compounds ] Brominated flame retardant which comes under notation of ISO 1043-4 code number FR(42) [Brominated organic phosphorus compounds] 69882-11-7 Poly(2,6-dibromo-phenylene oxide) 58965-66-5 Tetra-decabromo-diphenoxy-benzene 37853-59-1 1,2-Bis(2,4,6-tribromo-phenoxy)ethane Brominated epoxy resin end-capped with 139638-58-7 tribromophenol Brominated epoxy resin end-capped with 135229-48-0 tribromophenol 39635-79-5 Tetrabromo-bisphenol S 42757-55-1 TBBS-bis-(2,3-dibromo-propyl-ether) 615-58-7 2,4-Dibromo-phenol 118-79-6 2,4,6-tribromo-phenol 608-71-9 Pentabromo-phenol 3278-89-5 2,4,6-Tribromo-phenyl-allyl-ether 26762-91-4 Tribromo-phenyl-allyl-ether, unspecified 25637-99-4 , Hexabromocyclododecane (HBCDD) and all major Guidelines for Green Procurement Toshiba Client Solutions CO., Ltd C22H14 C24H38 O4 C16H22 O4 C19H20 O4 C16H22 O4 P (CH2CHCl)n C15H12Br4O2 (C15H12Br4O2.C3H5ClO)x (C15H12Br4O2.CCl2O)x (C7H5O2)(C 16H10Br4O3)x(C 6H5O) (C7H2Br3O3)(C16H10Br4O3)n(C6H2Br3) (C15H16O2.C15H12Br4O2.CCl2O)x C21H20Br8O2 C19H20Br4O4 C21H20Br4O2 C17H16Br4O2 ISO code 1043-4 ISO code 1043-4 ISO code 1043-4 ISO code 1043-4 ISO code 1043-4 ISO code 1043-4 (C6H2Br2O)x C18Br14O2 C14H8Br6O2 C12H6Br4O4S C18H14Br8O4S C6H4Br2O C6H3Br3O C6HBr5O C9H7Br3O C9H7Br3O C12H18Br6 19 19 3194-55-6 diastereoisomers identified (α – HBCDD, (134237-51-7, β-HBCDD, γ-HBCDD) 134237-50-6, 134237-52-8) 31454-48-5 3322-93-8 25357-79-3 632-79-1 55481-60-2 Tetrabromo-chyclo-octane 1,2-Dibromo-4-(1,2dibromo-methyl)-cyclo-hexane TBPA Na salt Tetrabromo phthalic anhydride Bis(methyl)tetrabromo-phtalate Phthalic acid, 3,4,5,6-tetrabromo-, dialkyl ester (C=6~23) 20566-35-2 2-Hydroxy-propyl-2-(2-hydroxy-ethoxy)-ethyl-TBP 75790-69-1 TBPA, glycol-and propylene-oxide esters 32588-76-4 N,N’-Ethylene–bis (tetrabromo-phthalimide) Ethylene-bis(5,6-dibromo-norbornane-2,3-dicarboxi 52907-07-0 mide) 3234-02-4 2,3-Dibromo-2-butene-1,4-diol 3296-90-0 Dibromo-neopentyl-glycol 96-13-9 2,3-Dibromo-propanol 36483-57-5 Tribromo-neopentyl-alcohol 57137-10-7 Poly tribromo-styrene 61368-34-1 Tribromo-styrene 171091-06-8 Dibromo-styrene grafted PP 31780-26-4 Poly-dibromo-styrene 68955-41-9 Bromo-/Chloro-paraffins 82600-56-4 Bromo-/Chloro-alpha-olefin 593-60-2 Vinylbromide 52434-90-9 Tris-(2,3-dibromo-propyl)-isocyanurate 49690-63-3 Tris(2,4-Dibromo-phenyl) phosphate 19186-97-1 Tris(tribromo-neopentyl) phosphate 125997-20-8 Chlorinated and brominated phosphate esther 87-83-2 Pentabromo-toluene 38521-51-6 Pentabromo-benzyl bromide 68441-46-3 1,3-Butadiene homopolymer,brominated 59447-55-1 Pentabromo-benzyl-acrylate, monomer 59447-57-3 Pentabromo-benzyl-acrylate, polymer 61262-53-1 Decabromo-diphenyl-ethane 59789-51-4 Tribromo-bisphenyl-maleinimide 59789-51-4 Brominated trimethylphenyl-lindane Other Brominated flame retardants Antimony and its compounds 7440-36-0 Antimony 10025-91-9 Antimony trichloride 57 1309-64-4 Antimony trioxide 1314-60-9 Antimony pentoxide 15432-85-6 Sodium antimony Other antimony compounds Arsenic and its compounds 7440-38-2 Arsenic 1303-00-0 Gallium arsenide 1303-28-2 Diaresenic pentoxide 58 1327-53-3 Diaresenic trioxide 7784-40-9 Lead hydrogen arsenate 15606-95-8 Triethyl aresenate Other arsenic compounds Bismuth and its compounds. 60 7440-69-9 Bismuth Nickel and its compounds. 1313-99-1 Nickel(II) oxide 61 3333-67-3 Nickel(II) carbonate 7786-81-4 Nickel(II) sulfate 7440-02-0 Nickel Guidelines for Green Procurement Toshiba Client Solutions CO., Ltd C8H12Br4 C8H12Br4 C8Br4O4Na2 C8Br4O3 C10H6Br4O4 - C15H16Br4O7 C18H4Br8N2O4 C20H20Br4N2O4 C4H6Br2O2 C5H10Br2O2 C3H6Br2O C5H9Br3O C8H5Br3 C8H6Br2 C2H3Br C12H15Br6N3O3 C18H9Br6O4P C15H24Br9O4P C7H3Br5 C7H2Br6 C10H5Br5O2 (C10H5Br5O2)x C14H4Br10O2 C10H4Br3NO2 C18H13Brn (n=7,8) Sb SbCl3 Sb2O3 Sb2O5 Na3O4Sb As GaAs As2O5 As2O3 AsHO4Pb C6H15AsO4 Bi NiO NiCO3 NiSO4 Ni 20 20 117-81-7 84-74-2 85-68-7 62 26761-40-0 28553-12-0 117-84-0 84-69-5 63 7782-49-2 7783-00-8 - 10025-64-6 10139-47-6 10196-18-6 10361-95-2 1313-49-1 1314-13-2 1314-84-7 1314-98-3 1315-11-3 13530-65-9 13637-61-1 13814-87-4 13932-17-7 14485-28-0 14639-97-5 64 15060-64-7 16871-71-9 544-97-8 557-20-0 557-21-1 557-34-6 557-42-6 5970-45-6 73640-07-0 7446-20-0 7646-85-7 7699-45-8 7733-02-0 7779-86-4 7779-88-6 7783-49-5 77998-33-5 65 10022-47-6 10025-73-7 10031-25-1 10060-12-5 10101-53-8 66 10141-00-1 1066-30-4 12018-22-3 1308-38-9 13475-98-4 13478-06-3 Other nickel compounds Some Phthalic Esters Bis(2-ethyl(hexyl)phthalate) (DEHP) Dibutyl phthalate (DBP) Benzyl butyl phthatate(BBP) Diisodecyl phthalate(DIDP) Diisononyl phthalate(DINP) Di-n-octyl phthalate(DnOP) Diisobutyl phthalate(DIBP) Selenium and its compounds Selenium Selenous acid Other selenium compounds Zinc and its compounds Zinc perchlorate hexahydrate Zinc Iodide Zinc nitrate hexahydrate Zinc chlorate Zinc nitride Zinc oxide Zinc phosphide Zinc sulfide Zinc telluride Zinc chromate Zinc perchlorate Ammonium zinc sulfate Potassium zinc sulfate Zinc phosphate,monobasic Zinc ammonium chloride Zinc hypophoshite Zinc fluorosilicate Dimethyl zinc Diethyl zinc Zinc cyanide Zinc acetate Zinc thiocyanate Zinc acetate dihydrate Zinc fluoride tetrahydrate Sulfuric acid, zinc salt(1:1), Heptahydrate Zinc chloride Zinc bromide Zinc sulfate Zinc hydrosulfite Zinc nitrate Zinc fluoride Ammonium zinc sulfate hydrateE Chlorinated paraffine (except short chain chlorinated paraffins (No.10) ) Medium chain chlorinated paraffins (C14-17) Long chain chlorinated paraffins (C18-30) Chromium(III) compounds Ammonium chromium(III) sulfate dodecahydrate Chromic chloride Chromium(III) bromide Chromium Trichloride Hexahydrate Chromic Sulfate Chromium Potassium Sulfate Chromic Acetate Chromium(III) sulfide Chromium oxide Chromium(III) phosphate hexahydrate Chromium(III) bromide hexahydrate Guidelines for Green Procurement Toshiba Client Solutions CO., Ltd C6H4(CO2C8H17)2 C6H4(COO(CH2)3CH3)2 C19H20O4 C6H4(COOC10H21)2 C6H4(COOC9H19)2 (C6H4)(COO(CH2)7CH3)2 C6H4(COOCH2CH(CH3)2)2 Se H2SeO3 Zn(ClO4)26H2O ZnI2 Zn(NO3)26H2O Zn(ClO3)2 Zn3N2 ZnO Zn3P2 ZnS ZnTe CrO4Zn Zn(ClO4)2 (NH4)2Zn(SO4)2 K2Zn(SO4)2 Zn(H2PO4)2 (NH4)2[ZnCl4] Zn(PH2O2)2 Zn[SiF6] Zn(CH3)2 Zn(C2H5)2 Zn(CN) 2 Zn(CH3COO)2 Zn(SCN)2 Zn(CH3COO)22H2O ZnF24H2O ZnSO47H2O ZnCl2 ZnBr2 ZnSO4 ZnS2O4 Zn(NO3)2 ZnF2 (NH4)2Zn(SO4)26H2O CnH2 n+2-xClx (n:14-17) CnH2 n+2-xClx (n:18-30) Cr(NH4)(SO4)22H2O CrCl3 CrBr3 CrCl36H2O Cr2(SO4)3 CrK(SO4)2 Cr(CH3COO)3 Cr2S3 Cr2O3 CrPO46H2O CrBr36H2O 21 21 13537-21-8 13548-38-4 13548-43-1 13569-75-0 13573-16-5 13573-17-6 13601-11-1 15244-38-9 16165-32-5 21679-31-2 24094-93-7 25013-82-5 26342-61-0 30737-19-0 55147-94-9 64093-79-4 7440-47-3 7788-97-8 7788-99-0 7789-02-8 7789-04-0 100-47-0 107-13-1 109-78-4 1194-65-6 13453-34-4 140-29-4 143-33-9 14763-77-0 151-50-8 156-62-7 2035-66-7 21159-32-0 21725-46-2 420-04-2 460-19-5 506-64-9 506-65-0 67 506-68-3 506-77-4 506-78-5 535-37-5 535-37-5 542-62-1 542-83-6 542-84-7 544-92-3 557-19-7 557-21-1 592-01-8 592-04-1 592-05-2 592-06-3 74-90-8 7677-24-9 917-61-3 68 115-25-3 Chromic perchlorate Chromium nitrate Ammonium chromic sulfate Chromium(III) iodide Chromate(1-),Diamine tetrakis(Thiocyanate-N)-, Ammonium,(OC-6-11) Reinecke salt monohydrate;Ammonium Tetra thiocyanate diammine chromate Potassium hexacyano chromate(III) Chromium(III) sulfate N-hydrate Tris(ethylene diamine)chromium(III) Chloride hydrate Chromiumu(III) acetyl acetonate Chromium(III) nitride Chromium(III) acetate monohydrate Chromium phosphide Chromium(III) oxalate Chromium(III) perchlorate hexahydrate Neochromium Chromium Chromium(III) fluoride Chromium potassium sulfate dodeca hydrate Chromium nitrate, Nona hydrate Chromium(III) phosphate Cyanogen compounds. Benzonitrile Acrylonitrile Ethylene cyanohydrin 2,6-Dichloro benzonitrile Thallium(I) cyanide Phenyl acetonitrile Sodiumu cyanide Copper cyanide Potassium cyanide Calcium cyanamide Palladium(II) cyanide Cesium cyanide Cyanazine Cyanamide Cyanogen Silvber cyanide Gold(I) cyanide Cyanogen bromide Cyanogen chloride Cyanogen iodide Gold(I)cyanide trihydrate Gold(I) cyanide Barium cyanide Cadmium cyanide Cobalt(II) cyanide Cuprous cyanide Nickel cyanide Zinc cyanide Calcium cyanide Mercuric cyanide Lead cyanide Platinam(II) cyanide Hydrogen cyanide Trimethylsilyl cyanide Sodium cyanide Perfluorocarbon (PFC) Octafluorocyclobutane Guidelines for Green Procurement Toshiba Client Solutions CO., Ltd Cr(ClO4)3 Cr(NO3)3 Cr(NH4)(SO4)2 CrI3 trans-NH4[Cr(NCS)4(NH3)2] trans-NH4[Cr(NCS)4(NH3)2] H2O K3[Cr(CN)6] Cr2(SO4)318H2O [Cr(C2H8N2)3]Cl33H2O Cr(C5H7O2)3 CrN Cr(CH3COO)3H2O CrP Cr2(C2O4)3 Cr(ClO4)36H2O Cr(OH)SO4·Na2SO4·H2O Cr CrF3 CrK(SO4)212H2O Cr(NO3)39H2O CrPO4 C7H5N C3H3N C3H5NO C7H3Cl2N TlCN C8H7N NaCN Cu(CN)2 KCN CCaN2 Pd(CN) 2 CsCN C9H13ClN6 NCNH2 (CN)2 AgCN AuCN CNBr CNCl CNI Au(CN)33H2O Au(CN) 3 Ba(CN)2 Cd(CN) 2 Co(CN)2 CuCN Ni(CN) 2 Zn(CN) 2 Ca(CN) 2 Hg(CN) 2 Pb(CN) 2 Pt(CN) 2 HCN Si(CN)(CH3)3 CNNaO C4F8 22 22 307-34-6 335-57-9 355-25-9 355-42-0 678-26-2 75-73-0 76-16-4 76-19-7 Octadecafluorooctane, Perfluorooctane PFC72,PFC-51-14 PFC218 Tetradecafluorohexane, Perfluorohexane PFC410 Tetrafluoromethane PFC14 PFC116 Hydrogenerated fluorocarbon (HFC) 811-97-2 HFC-134a 138495-42-8 HFC-43-10mee 354-33-6 HFC-125 407-59-0 HFC-356mff,HFC-356ffa 420-46-2 HFC-143a 430-66-0 HFC-143 431-89-0 HFC-227ea 679-86-7 HFC-245ca 690-39-1 HFC-236fa 75-10-5 HFC-32 75-37-6 HFC-152a 69 75-46-7 HFC-23 593-53-3 HFC-41 359-35-3 HFC-134 HFC-245fa HFC-125/143a/134a=44/52/4 HFC-32/125/134a=20/40/40 HFC-32/125/134a=23/25/52 HFC-32/125=50/50 HFC-32/125=45/55 HFC-32/143a=50/50 HFC-23/FC-116=39/61 HFC-23/FC-116=46/54 Halogenated additives 115-96-8 Tris (2-chloroethyl)phosphate 21850-44-2 TBBA-(2,3-dibromo-propyl-ether) 3194-55-6 1,2,5,6,9,10-Hexabromocyclodecane 79-27-6 1,1,2,2-Tetrabromoethane 70 79-94-7 Tetrabromo-bisphenol A(TBBA) 87-82-1 Hexabromobenzene 9002-84-0 Polytetrafuluoroethylene 75-25-2 Tribromomethane 118-79-6 2,4,6-Tribromo-Phenol 4162-45-2 TBBA-bis(2-Hydroxy-ethyl-ether) Maganese and its compounds 7439-96-5 Manganese 10031-20-6 Manganese(II) bromide tetrahydrate 10034-96-5 Manganese(II) sulfate heptahydrate 10043-84-2 Manganese hypophosphite 10101-50-5 Sodium permanganate 10124-54-6 Manganese(III) phosphate hydrate 10170-69-1 Dimanganese decacarbonyl 10377-66-9 Manganese(II) nitrate 71 12005-95-7 Manganese arsenide 12032-78-9 Manganese phosphide 12032-86-9 Manganese silicide 12032-88-1 Manganese telluride 12427-38-2 Maneb 12777-96-7 Manganese carbide 1313-13-9 Manganese(IV) oxide 1313-22-0 Manganese monoselenide Manganese(III) oxide, 98%(assay); manganese 1317-34-6 trioxide Guidelines for Green Procurement Toshiba Client Solutions CO., Ltd C8F18 C7F16 C4F10 C6F14 C5F12 CF4 C2F6 C3F8 CH2FCF3 C5H2F10 CHF2CF3,C2HF5 C4H4F6 CH3CF3 CHF2CH2F CF3CHFCF3,C3HF7 C3H3F5 C3H2F6 CH2F2 CH3CHF2 CHF3 CH3F CHF2CHF2 C6H12Cl3PO4 C21H20Br8O2 C12H18Br6 C2H2Br4 C15H12Br4O2 C6Br6 (C2F4)n CHBr3 C6H3Br3O C19H20Br4O4 Mn Mn Br24H2O Mn(C2O4) 2H2O Mn(PH2O2)2 NaMnO4 MnPO4H2O Mn2(CO)10 Mn(NO3)2 MnAs MnP MnSi MnTe C4H6MnN2S4 Mn3C MnO2 MnSe Mn2O3 23 23 1317-35-7 13224-08-3 1344-43-0 13446-03-2 13446-34-9 13566-22-8 13568-71-3 14154-9-7 14284-89-0 15364-94-0 17141-63-8 18820-29-6 598-62-9 6156-78-1 638-38-0 640-67-5 6556-16-7 7722-64-7 7773-01-5 7782-64-1 7782-76-5 7783-16-6 7783-53-1 7790-33-2 993-2-2 72 73 2551-62-4 74 120-12-7 90640-80-5 91995-17-4 91995-15-2 75 76 77 78 79 80 81 82 83 84 90640-82-7 90640-81-6 101-77-9 7646-79-9 10124-43-3 10141-05-6 513-79-1 71-48-7 81-15-2 121-14-2 65996-93-2 - 85 - Manganomanganic oxide; manganese tetra oxide; trimanganese tetraoxide; manganese(II,III) oxide; manganese oxide(II,III) Manganese(II) sulfate Manganese(II) oxide Manganese(II) bromide Manganese(II) chloride tetrahydrate Ammonium manganese sulfate Manganese(II) sulfite Manganese(II) phosphate Acetylacetone manganese(III) salt; Tris(2,4-pentanedionate)manganese; Manganese(II) perchlorate Manganese(II) nitrate hexahydrate Manganese sulfide Manganese(II) carbonate Manganese(II) acetate tetrahydrate Manganese(II) acetate Manganese oxalate Manganese(II) oxalate dihydrate Potassium permanganate Manganese(II) chloride; Manganesedichloride Manganese difluoride Manganese phosphate, dibasic Manganese(II) hypophosphite monohydrate Manganese(III) fluoride Manganese(II) iodide Manganese(III) acetate Other manganese compounds Organic Tin Compounds (except TBTO (No.7) and TBT/TPT (No.14)) Sulfur hexafluoride(SF6) Anthracene Anthracene Anthracene oil Anthracene oil, anthracene paste, distn. Lights Anthracene oil, anthracene paste, anthracene fraction Anthracene oil, anthracene-low Anthracene oil, anthracene paste 4,4'- Diaminodiphenylmethane Cobalt dichloride Cobalt(II) sulphate Cobalt(II) dinitrate Cobalt(II) carbonate Cobalt(II) diacetate 5-tert-butyl-2,4,6-trinitro-m-xylene(musk xylene) 2,4-Dinitrotoluene Coal tar pitch, high temperature Aluminosilicate, Refractory Ceramic Fibres Zirconia Aluminosilicate, Refractory Ceramic Fibres Acrylamide Tris(2-chloroethyl)phosphate Trichloroethylene 86 79-06-1 87 115-96-8 88 79-01-6 10043-35-3, 89 Boric acid 11113-50-1 1303-96-4 90 1330-43-4 Disodium tetraborate, anhydrous 12179-04-3 91 12267-73-1 Tetraboron disodium heptaoxide, hydrate Guidelines for Green Procurement Toshiba Client Solutions CO., Ltd Mn3O4 MnSO4 MnO MnBr2 MnCl24H2O Mn(NH4)2(SO4) MnSO3 Mn3(PO4)2 Mn(C5H7O2)3 Mn(ClO4) 2 Mn(NO3) 26H2O MnS MnCO3 Mn(CH3COO) 24H2O Mn(CH3COO) 2 Mn(C2O4) Mn(C2O4)・2H2O KMnO4 MnCl2 MnF2 MnHPO4 Mn(PH2O2) 2H2O MnF3 MnI2 Mn(CH3COO) 3 Mn(CH3COO) 3 F6S C14H10 C13H14N2 CoCl2 CoO4S Co(NO3)2 CCoO3 C4H6CoO4 C12H15N3O6 C7H6N2O4 C3H5NO C2HCl3 B(OH)3 B4H20Na2O17, B4Na2O7、 B4H10Na2O12 Na2B4O7 * nH2O (n=1,5-2) 24 24 92 109-86-4 93 110-80-5 2-Methoxyethanol 2-Ethoxyethanol C3H8O2 C4H10O2 Guidelines for Green Procurement Toshiba Client Solutions CO., Ltd. Issue Date: January 2011 (First edition) April 2015 (Tenth edition) Document No.: 360045308 Ver.10 Guidelines for Green Procurement Toshiba Client Solutions CO., Ltd 25 25
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