Radiation Thermometry (輻射測温學) Presented by : Standards and Calibration Laboratory (SCL) Innovation and Technology Commission The Government of the HKSAR 標準及校正實驗所 創新科技署 香港特別行政區政府 Contents (I) Blackbody Radiation (II) Emissivity (III) Radiation Thermometers (IV) Infrared Ear Thermometers (V) Errors in Radiation Thermometry (VI) Calibration of Radiation Thermometers (VII) Temperature Calibration Services offered by SCL for Radiation Thermometers and Infrared Ear Thermometers Radiation Thermometry in a Nutshell All materials emit thermal radiation (熱輻射) when their temperature is above absolute zero. Amount of temperature. thermal radiation depends Therefore, we can measure temperature determining the amount of thermal radiation. on by Characteristics of Radiation Thermometry Non contact Radiation thermometers do not need to be in contact with the target. Use the surface of the target as sensor The amount of infrared emitted by the target depends on the characteristic of the target surface Measure thermodynamic temperature (熱力學温度) Based on a universal physical law (I) Blackbody Radiation (黑体輻射) Electromagnetic Radiation (電磁輻射) Radio waves, microwaves, infrared radiation, visible light, ultraviolet radiation, X-rays and gamma rays are all electromagnetic radiation. They are self-propagating wave with electric and magnetic components. They differ in wavelength 波長 (frequency頻率). Wavelength of visible light (可見光): 0.4 µm to 0.7 µm Wavelength of infrared (紅外線): 0.7 µm to 1 mm Wavelength of ultraviolet (紫外線): 0.4 µm to 0.01 µm Thermal Radiation (熱輻射) All materials at temperature above absolute zero (0 K) emit electromagnetic radiation. Amount of radiation increases with temperature. Wavelength of radiation decreases with temperature. e.g. cosmic microwave background radiation (temperature ~2.725 K, peak wavelength ~1.9 mm) Surface of the sun (temperature ~5500 °C, peak wavelength ~500 µm ) Visible light Ultraviolet Infrared 6000 K 3000 K 1000 K 500 K 0.01 0.1 1 10 Wavelength (um) Thermal Radiation at 500 K, 1000 K, 3000 K, 6000 K 100 Blackbody Radiation (黑体輻射) Besides temperature, amount of thermal radiation also depends on the characteristics of the emitting surface. As rough examples, a white surface emits less thermal radiation whilst a black surface emits more. Blackbody radiates the maximum thermal radiation for a given temperature when compared to other surfaces. Spectral Radiance (光譜輻射亮度) Spectral radiance is the rate of energy emitted by a surface per unit area per unit wavelength per unit solid angle. The unit for spectral radiance is W m-2 µm-1 sr-1 Planck’s Radiation Law (普朗克輻射定律) Planck’s radiation law gives the spectral radiance L(λ,T) emitted by a blackbody for a given temperature T (in kelvin). C1 L(λ , T) = λ (e 5 C1 = 1.191044x 10 –16 C2 λT −1) W m-2 C2 = 0.014388 m K C1 and C2 are the first and second radiation constants Stefan-Boltzmann’s Law (斯特藩-玻耳茲曼定律) Stefan-Boltzmann’s law gives the total rate of emission of thermal energy from a unit area of a blackbody for a given temperature T (in kelvin). P = σT σ = 5.67 x 10 –8 W m-2 K-4 4 Stefan-Boltzmann’s Law Using the Stefan-Boltzmann’s law, some examples of blackbody radiation is calculated as follows : Temperature Rate of Emission 23 °C 436 W m-2 500 °C 20 000 W m-2 1000 °C 150 000 W m-2 2500 °C 3 400 000 W m-2 5500 °C 77 000 000 W m-2 Wein’s Displacement Law (維恩位移定律) Wein’s law gives the wavelength where the spectral radiance is a maximum. λ max T ≈ 2898µmK 6000 K 3000 K 1000 K 500 K 0.01 0.1 1 10 Wavelength (um) Thermal Radiation at 500 K, 1000 K, 3000 K, 6000 K 100 Example 1 The surface temperature of sun is about 5800 K. Estimate the peak of the solar radiation. Solution : λ max 2898 ≈ K = 0.5µm 5800 Practical Blackbodies Practical Blackbodies are cavities, not surfaces. Light entering a cavity will be reflected and absorbed many times before it exits the aperture of the cavity. Hence a cavity can achieve a much higher emissivity than a surface. aperture of blackbody (II) Emissivity (發射率) Emissivity (發射率) A real surface will emit less thermal radiation than a blackbody at the same temperature. The emissivity ε is the ratio of the amount of radiation actually emitted from a surface to that emitted by a blackbody For blackbodies, the emissivity is very close to 1. For real surface, it is less than 1. Emissivity Emissivity for a material is a parameter. It is NOT a constant. Emissivity is a function of the following : temperature of surface wavelength angle of emission Emissivities of Common Materials For some common materials, the emissivities at wavelength of 0.65 µm and over the band 8 to 13 µm are as follows : Material ε0.65µm ε8-13µm Aluminium 0.11- 0.19 < 0.1 Carpets - 0.85 – 0.95 Fire brick 0.75 - Paper - 0.85 – 1.00 Plastics - 0.95 Stainless steel 0.40 – 0.60 0.10 - 0.25 Tungsten 0.35 - 0.50 - Wood - 0.85 - 0.95 Thermal Radiation from Real Surfaces For real surfaces, Planck’s radiation law becomes the following L(λ , T) = ε(λ, T)C1 λ (e 5 C1 = 1.191044x 10 –16 C2 λT −1) W m-2 C2 = 0.014388 m K ε(λ,T) = emissivity of surface Stefan-Boltzmann’s Law for Real Surfaces Stefan-Boltzmann’s law for real surfaces is as follows P = ε total σT σ = 5.67 x 10 –8 4 W m-2 K-4 εtotal = total hemispherical emissivity of surface (III) Radiation Thermometers (輻射温度計) Types of radiation thermometer Total radiation thermometers (全輻射温度計) Measure the total radiance of a surface. Sensitive to variation in sensor temperature and emissivity of target Spectral band radiation thermometers (帶域輻射温度計) Use a filter to measure only thermal radiation in a narrow wavelength band (e.g. 0.65 μm, 0.85 μm) The most common type of radiation thermometers The choice of wavelength depends on the temperature range, the environment and the target surface The emissivity of the target must be either measured or estimated. A Radiation Thermometer (-50 °C to 1000 °C) Operating Wavelength : 8 to 13 µm A Radiation Thermometer (600 °C to 3000 °C) Operating Wavelength : 0.96 to 1.05 µm (IV) Infrared Ear Thermometer (紅外線耳温計) Detection of Human Body Temperature by Infrared Ear Thermometers The human body temperature is controlled by the hypothalamus in the brain. The eardrum, also called the tympanic membrane, is close to and shares blood with the hypothalamus. The temperature of the eardrum reflects the core body temperature. Infrared Ear Thermometer measures the thermal energy radiated from the surface of the eardrum. It includes a detector that measures infrared radiation at wavelengths around 10 μm. Infrared Ear Thermometer is actually a special type of radiation thermometer designed to measure the temperature of the eardrum. The auditory canal is close to a blackbody with emissivity approaching 1. Infrared Radiation Emitted by Human Body -2 -1 Thermal Radiation (Wm um ) Thermal Radiation at 35 °C, 37 °C and 39 °C 40 35 30 25 20 15 35 °C 10 37 °C 5 39 °C 0 0 2 4 6 8 10 Wavelength (um) 12 14 16 Standards for Infrared Ear Thermometers ASTM E1965-98, "Standard Specification for Infrared Thermometers for Intermittent Determination of Patient Temperature" EN 12470-5:2003, "Clinical Thermometers - Part 5 : Performance of Infra-red Ear Thermometers (with Maximum Device)" Requirements of Infrared Ear Thermometers (1) Measurement Range ASTM E1965-98 at least 34.4 °C to 42.2 °C EN 12470-5:2003 35.5 °C to 42.0 °C Accuracy ASTM E1965-98 Maximum Permissible Laboratory Error < ± 0.2 °C (for 36 °C to 39 °C) < ± 0.3 °C (<36 °C or >39 °C) EN 12470-5:2003 Maximum Permissible Error < ± 0.2 °C (for 35.5 °C to 42.0 °C) < ± 0.3 °C (<35.5 °C or >42.0 °C) Requirements of Infrared Ear Thermometers (2) Display Resolution ASTM E1965-98 0.1 °C EN 12470-5:2003 0.1 °C Operating Range ASTM E1965-98 16 °C to 40 °C EN 12470-5:2003 16 °C to 35 °C (V) Errors in using Radiation Thermometers Errors in using radiation thermometers 3 main categories of errors : Errors arising from target area : e.g. emissivity, reflection Errors arising from tranmission path : e.g. absorption, scattering, size of source effect. Errors arising from signal processing : e.g. variation in ambient temperature, linearisation Estimation of Temperature Error The major errors in using a spectral band radiation thermometer arise from either the measured radiance or the estimation of target emissivity. The following equation estimates the uncertainty of the measured temperature σT measured = λT 2 c2 σL σ ε (λ ) 2 ( ) +( ) Lmeasured ε (λ ) measured 2 Estimation of Temperature Error From the equation, we can see that The errors and uncertainties increase with operation wavelength. Hence, generally a thermometer with a short operating wavelength is more accurate. The errors and uncertainties increase with the square of temperature. The errors and uncertainties increase with 1/ε(λ). Therefore, the error is larger when measuring low emissivity substances, such as metals. Errors Arising from Emissivity (發射率引起的誤差) The difficulty in estimating the emissivity of the target surface is the largest source of errors in radiation thermometry. For example, the emissivity of a nickel alloy varies between 0.1 and 0.95 depends on the state of oxidation, roughness and wavelength. To make a good estimate, it is important to know the operating wavelength of the thermometer, the material and surface properties (e.g. roughness, oxidation) of the target. In general, manufacturers of radiation thermometers will provide a list of emissivities. If followed properly, it is possible to make estimate to about ± 0.05. Example 2 A radiation thermometer with operating wavelength of 0.65 µm is used to measure the temperature of a piece of highly oxidised steel at around 1200 °C. The emissivity is about 0.80 ± 0.10. Calculate the uncertainty of the measured temperature due to the uncertainty of emissivity. Solution : U Tmeasured 0.65×10 −6 × (1200 + 273.15) 2 = 0.014388 = 12.3°C 0.1 2 ( ) 0.8 Errors Arising from Emissivity It is difficult to estimate the emissivity based on visual assessment. Surface that are black in the visible spectrum may NOT be black in the infrared. On the other hand, white paint can be very black in the infrared. For most surfaces the emissivity also depend on the viewing angle. Normally the published values for emissivity are for normal incidence. Hence radiation should be used at normal incidence to the target surface. Errors Arising from Reflection (反射引起的誤差) A radiation thermometer assumes all radiation is emitted from the target surface. Anything added to the emitted radiation, such as reflection, will become error in measured temperature. Reflection problem is more serious when measuring low temperatures since the whole environment is emitting radiation at ambient temperature of about 300K. The best way to reduce reflection error is to eliminate the unwanted radiation sources. Some examples are the sun, the lamps, etc. The target surface should be shaded from unwanted radiation sources. Absorption Errors (吸收引起的誤差) Anything in the path between the target and the radiation thermometer can absorb thermal radiation. Common absorption sources are : atmospheric gases (e.g. carbon dioxide, water vapour), windows and suspended material The absorption error increases with distance. The magnitude of the error can be estimated by varying the distance between the radiation thermometer and the target. Scattering Errors (散射引起的誤差) Caused by dust in the transmission path between the target and the radiation thermometer Dust has 3 effects : It scatters away radiation from target It scatters radiation from other source to the thermometer It may emit blackbody radiation. Size-of-source Effects (輻射源尺寸效應) A radiation thermometer collects radiation from a zone on the target. The size of the zone varies with the distance between the target and the thermometer and is called field of view. The target must fill the field of view completely. Otherwise error will occur. The variation of thermometer readings with the size of the target zone is called the size-of-source effects. To reduce this effect, always overfill the field of view as much as possible. Some radiation thermometers use laser to mark the field of view Ambient Temperature Effects (室温效應) As sensitivity of the detector and the wavelength response of the filter are temperature dependent, radiation thermometers are susceptible to change in ambient temperature. The ambient temperature effect is more serious for low temperature radiation thermometer. Avoid rapid change in ambient temperature. When bringing a radiation thermometer to a new environment, allow sufficient time, say 1 hours, for it to stabilise before taking readings. (VI) Calibration of Radiation Thermometers and Infrared Ear Thermometers Calibration Methods Transfer from a calibrated blackbody Transfer from a calibrated radiation thermometer Transfer from a calibrated contact type thermometer such as thermocouple or platinum resistance thermometer (PRT) Use fixed-point blackbody Transfer from a calibrated radiation thermometer Step 1 : Establish the radiance temperature of a blackbody using a calibrated reference radiation thermometer. reference radiation thermometer Transfer from a calibrated radiation thermometer Step 2 : Calibrate the radiation thermometer under test with the blackbody. radiation thermometer under test Transfer from a calibrated contact type thermometer The temperature of the blackbody is measured by a contact type thermometer such as thermocouple or PRT. PRT or thermocouple radiation thermometer under test A Blackbody Calibration Source Calibration of Infrared Ear Thermometers Infrared Ear Thermometer under Test Aperture of blackbody Detector Blackbody radiator maintained at a constant temperature between 34 °C and 43 °C in a constant temperature bath Blackbody Radiator for Calibration of Infrared Ear Thermometers (Based on EN 12470-5:2003 ) Infrared Ear Thermometer Calibration System (VII) Temperature Calibration Services offered by SCL for Radiation Thermometers Radiation Thermometers Specific tests or properties measured Best measurement capability Calibration over the following ranges : -40 °C to 0 °C 0.5 K 0 °C to 200 °C (0.33 + 0.003 t) K 200 °C to 1000 °C (1.5 + 0.002 t) K where t is the test temperature Blackbody Radiators Specific tests or properties measured Best measurement capability Calibration over the following ranges : 0 °C to 200 °C (0.31 + 0.0025 t) K where t is the test temperature Infrared Ear Thermometers Specific Tests or Properties Measured Best Measurement Capability Calibration over the following ranges : 34 °C to 42 °C 0.2 °C Infrared Ear Thermometer Calibrators Specific Tests or Properties Measured Best Measurement Capability Calibration over the following ranges : 34 °C to 42 °C 0.15 °C
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