Phosphorus Transport in Agricultural Drain Tiles in the Saginaw Bay Watershed David S. Karpovich H. H. Dow Endowed Chair of Chemistry Director, Saginaw Bay ESI Saginaw Valley State University Summer 2015 Research team Justin Martin - Bullock Creek High School, graduated Alicia Ball - Garber High School, senior Evan Craig – Cass City High School, senior Craig Coopersmith II - White Pine Middle School, teacher Kathlyn Underwood - SVSU, Biology sophomore Sampling locations • • • • • • Arenac County Pine and Rifle River Watersheds Flat farmland, row crops Tiled fields, vegetative buffers Organic & conventional fertilizer Landowner permission Measurements & Data • Soil (>5 samples/field) • • • • Porosity Soil type Sand, silt, clay Phosphorus • Tile and ditch water • SRP and TP • Rain events Rifle River Sample sites Pine River Standish Saginaw Bay Soil erosion • • • Vegetative buffer strips • • Considered effective in reducing suspended solid and phosphorus run-off Long-time assumption that phosphorus only moves with surface erosion (~0.0005 lbs P/ton soil) Run-off puts suspended solids in stream water Insoluble phosphorus accompanies suspended solids Considered a major source of P to Saginaw Bay Our sampling targets Field tiles at a glance 2 to 4 ft deep Field Soil Characteristics Soil type Filter strip Tillage method Fertilizer method P %Porosity % sand % silt % clay (mg/kg) 1 Allen Dale Loamy Sand No No-till conventional 48 33 27 40 75 2 Selkirk Silty Clay Loam No conventional organic 50 33 20 47 46 3 Sims Loam No conventional organic 23 20 10 70 75 4 Sims Loam No conventional organic 52 50 13 37 5 Selkirk Loam Yes conventional organic 6 Allen Dale Loamy Sand Yes conventional organic 7 Sims Loam No conventional conventional 8 Selkirk Fine Sandy Loam Yes conventional conventional 75 38 83 10 7 44 33 20 47 Samples taken • Field tile effluent and receiving ditch water • Four dates (two rain events, two dry) • Measured for SRP and TP 37 75 Phosphorus (mg/L) Phosphorus in ditch water 0.25 0.20 0.15 0.10 TP 0.05 SRP 0.00 1 2 3 4 5 6 7 8 Site Phosphorus in Tile water Phosphorus (mg/L) 0.25 0.20 0.15 0.10 TP 0.05 SRP 0.00 1 2 3 4 5 Site 6 7 8 Summary of Results • SRP Tile/Ditch = 1.79 + 1.11 • Subsurface water does transport SRP • TP Tile/Ditch = 0.63 + 0.24 • Subsurface water also transports TP • Tile SRP/TP = 0.90 + 0.16 • Higher than “typical” for watershed streams • Greater mobility of SRP in water compared to TP on particles • Ditch SRP/TP = 0.39 + 0.21 • Lower than typical for streams, grassy ditches may be a sink for SRP • Possible correlations to note (preliminary) • Tile phosphorus and porosity (weak, positive, 0.4) • Tile/ditch phosphorus and soil P (strong, negative, -0.8) • Phosphorus is transported in subsurface water, not just by surface soil erosion. • Need to determine volume and loading Acknowledgements • Dow Chemical Company Foundation for the funding of the Dow Science and Sustainability Education Center – For funding of Alicia Ball, Evan Craig, Kathlyn Underwood, Jeremy Schultz, and Craig Coopersmith) • American Chemical Society Project SEED – For funding Justin Martin • Saginaw Bay Environmental Science Institute at SVSU – Hosted Dow SSEC internship program – Facilitated and directed research • Professor Martin Arford (Geography) and Jeremy Schultz (biology senior) for soil data
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