Propane
Propane 95
Safety data sheet
1 Identification of the substance and of the company
Propane
Product name:
Propane 95
Brand name:
Use of the substance:
Supplier:
Issuer:
Industrial gas, process gas, fuel
E.ON Gas Sverige AB, SE-205 09 Malmö, Sweden
Karin Zetterström ([email protected])
In emergency situations Call for further information regarding the product:
• Our on-duty engineer +46 (0)20-25 20 00 or 112 (poison information)
2 Hazards identification
Extremely flammable
Extremely flammable. Spilled liquid has a very low temperature; risk of frostbite upon rapidly
leaking liquid propane. Condensed gas, which is heavier than air and may spread across the
ground. Leaking propane creates severe risk of fire. Propane is odorless, but may become foggy
on contact with humid air.
3 Composition/information on ingredients
Subject
Propane Butane Ethane Ethanethiol
Methanol CAS no.
74-98-6
106-97-8
74-84-0
75-08-1
67-56-1
EG no.
200-827-9
203-448-7
200-814-8
200-837-3
200-659-6
Concentration/weight%
> 95%
< 5%
< 2%
< 0,1%
< 1%
Composition comments: A mixture of hydrocarbons, primarily propane.
Classification
F+; R12
F+; R12
F+; R12
F; R11 Xn; R20 N; R50-5
F; R11 T; R23/24/25-39/23/24/25
2(4)
4 First aid measures
Inhalation
Skin contact
Eye contact
Ingestion
Inhalation of propane in small amounts causes dizziness, headaches, nausea, apathy. Inhalation of propane in large amounts causes risk of respiratory difficulty, unconsciousness,
paralysis, suffocation without warning. Ensure inhalation of fresh air. Keep the injured party
warm and immobile. If respiratory or/and cardiac arrest occurs, give first aid. Call a physician.
Skin contact may cause frostbite. Remove contaminated clothing and visit physician in case
of frostbite. In case of spill, wash with lukewarm water (20-30 °C) for not less than 15 minutes.
Eye contact may cause frostbite. Visit a physician. In case of liquid spill, wash with water for
not less than 15 minutes. In case of burn, wash with large quantities of water for not less
than 15 minutes.
Unlikely.
5 Fire-fighting measures
Method
Extinguishing media
Alert fire department. Stop gas flow if possible. Evacuate risk area. Keep tank cool with a broad water spray from a
protected area. Do not extinguish leaking gas that is on fire unless necessary, meaning unless
there is a risk of the fire spreading. After extinguishing, the propane must be aired out.
Water mist, powder, foam or carbon dioxide (CO2). Consult experts. Use fire suit, protective
gloves and protective glasses. In enclosed areas, use respiratory apparatus with independent
tank.
6 Accidental release measures
Stop leaks if it is possible to do so without risk.
Remove incendiary sources. Drainage holes must be covered, and basement levels and work
pits evacuated.
Post warning signs and alert people in the vicinity of the fire hazard, evacuate in case of large
spills. (Refer to point 3.)
Contact (alert) fire department.
Ensure sufficient air circulation. Use respiratory apparatus with independent tank.
Never enter gas cloud.
7 Handling and storage
Special characteristics
and risks Handling
Storage
Extremely flammable liquid gas. Vapors may gather on the ground and in low-lying areas. Use
explosion-protected electrical equipment. Ensure proper ventilation.
Under pressure in enclosed system.
Use only approved equipment and material. Store liquid gas in pressure tanks outside or
in well-ventilated areas. Use bonded equipment. Well separated from incendiary sources,
oxidizing gases and elements. Store at temperatures below 50°C.
8 Exposure controls/personal protection
Exposure controls
Tightly fitting protective goggles. Gloves made from leather or heavy-duty textile material. Jumpsuit clothing. Sufficient ventilation.
3(4)
9 Physical and chemical properties
-42,1 °C
-187 °C
Flash point
-108 °C
Flammability (solid, gas)
2.1-9.5 vol% gas
Explosion limitations
2.1-9.5 vol% gas mixed with air
Vapour pressure
730 kPa (20 °C)
Density
507 kg/m3
Relative density (air=1.00)
1.55
Solubility in water
0.039 l/kg (20 °C)
Autoignition in air
450-500 °C
Appearance
Odorless liquid/gas
Odor
Odor agent ethanethiol (smells of rotten egg)
Perceptibility limit
4000 ppm
Occupational exposure limit value 1000 ppm (MAK)
Other data
Propane gas is heavier than air
Boiling point
Melting point
10 Stability and reactivity
Stable at normal temperatures. May form combustible combinations with air. Polymers
should be avoided in contact with the liquid.
11 Toxilogical information
Propane is poison free, although inhalation of concentrated propane gas may cause some
narcotic effect, respiratory difficulties and suffocation symptoms when the oxygen level in
the breathing air becomes too low.
12 Ecological information
The compound’s high volatility causes minor immediate environmental effect. In the
atmosphere, propane is estimated to decay at a half life of one to two weeks.
13 Disposal considerations
Any remaining gas in the tank or pipes is disposed of by flaring.
14 Transport information
RID/RID-S, ADR/ADR-S (road, railway):
Class: 2
Classification code:
2F
Danger code: 23
UN no: 1965
Label: 2.1
IMDG (maritime)
Class: EmS no: 2.1
2-07
15 Regulatory information
Danger code: R phrases: S phrases:
F+ (Flame, Extremely flammable)
12 (Extremely flammable)
9 (Tanks stored in a well-ventilated area)
16 (Stored separately from incendiary sources, smoking prohibited)
33 (Take measures to prevent static electricity)
16 Other information
Applicable system design, government requirements, control, operations, maintenance,
handling, etc. of propane systems are referred to SGA 01 (Large Propane facilities) and EGN 01
(Energigasnorm) published by the Swedish Gas Association, The Flammables and Explosives
Ordinance SFS (2010:1011), Swedish Civil Contingencies Agency’s Provisions regarding cisterns,
gasometers, rock shelters and pipes for flammable gas (SÄIFS 2000:4) and the Ordinance
of the Work Environment Authority on Pressure-retaining devices (AFS 1999:4), Gases (AFS
1997:7) and the Inspection of Pressure-retaining Devices (AFS 2005:3).
Product name: Brand name: Date of issue: Revision: Propane Propane 95
2000-01-01
2011-04-12
E.ON Gas Sverige AB 205 09 Malmö Sweden
T +46 40 25 50 00
eon.se
Print Holmbergs i Malmö AB 2011.04
4(4)