A Mold Simulator for the Continuous Casting of Steel: Part I. The Development of a Simulator A. BADRI, T.T. NATARAJAN, C.C. SNYDER, K.D. POWERS, F.J. MANNION, and A.W. CRAMB Surface defects, such as oscillation marks, ripples, and cracks that can be found on the surface of continuously cast steel, originate in the continuous casting mold. Therefore, a detailed knowledge of initial solidification behavior of steel in a continuous casting mold is necessary because it determines the surface quality of continuously cast slabs. In order to develop an understanding of the initial solidification of continuous cast steels, a “mold simulator” was designed and constructed to investigate heat-transfer phenomena during the initial phase of strand solidification. The mold simulator was used to obtain solidified steel shells of different grades of steel under conditions similar to those found in industrial casting operations. The resulting cast surface morphologies were compared with industrial slabs and were found to be in good agreement, indicating that it is possible to simulate the continuous casting process by a laboratory scale simulator. I. INTRODUCTION ONE of the difficulties in studying the effects of operational parameters on the initial solidification behavior of steel in a continuous casting mold is the interdependence among different variables. It is not always feasible to conduct controlled experiments on an industrial continuous caster that will allow the effects of different operational parameters on the initial solidification of steel to be studied due to practical constraints. Therefore, most of the information developed on the formation of defects during the continuous casting of steels is collected under uncontrolled conditions. In the past, this constraint has led to the development of different types of mold simulators to study various aspects of continuous casting. Mold simulators can generally be divided into four types— dip tests, static molds, dip simulators, and small-scale casters. The major issue in designing mold simulators is to ensure that the apparatus and the experiment are a true simulation of reality. This has led to the development of experimentspecific simulators that simulate the conditions in a casting mold to different degrees. For example, to study the effects of mold fluxes on the heat transfer between steel and a copper mold, Machingawuta et al.[1] developed a dip-type simulator specifically for that purpose. Another dip-type simulator was used by Bouchard et al.[2] to investigate the effects of mold surface conditions on the heat-transfer rate and attendant surface quality of the cast product. These dip simulators involved chilled plates that were immersed into a molten metal bath without any of the sophistication of continuous caster systems, such as oscillation and shell extraction. The dip simulators are very useful for determining fundamental A. BADRI is with Shell Oil, Malaysia. T.T. NATARAJAN, Senior Research Engineer, C.C. SNYDER, Senior Technician, and K.D. POWERS, Project Analyst, are with the U.S. Steel Research and Technology Center, Monroeville, PA 15140. F.J. MANNION, General Manager, is with U.S. Steel, Slovakia. A.W. CRAMB is with the Department of Metallurgical and Materials Engineering, Carnegie Mellon University, Pittsburgh, PA 15213. Contact e-mail: [email protected] Manuscript submitted February 4, 2004. METALLURGICAL AND MATERIALS TRANSACTIONS B interactions in the continuous casting process, but are not true simulators since they do not mimic the dynamic nature of continuous casting. Related to the dip test simulators are the bottom-pouring molds, which are in essence similar to dip-type mold simulators, with the exception that the bottom-pouring simulators have the metal contained in the mold, instead of having the mold dipped into the metal. This configuration has the advantage that it is easier to observe the surface of the casting during solidification. Tomono et al.[3] used a bottom-filling mold to investigate the behavior of the liquid steel meniscus during casting and projected the results to explain the formation of oscillation marks. Wray[4] developed a simulator to determine the mechanisms by which surface features formed on chill cast surfaces and provided a classification of the different types of features that could be formed. Stemple et al.[5] used a bottom-pouring configuration to investigate the formation of ripple marks on the surfaces of continuously cast products. It was emphasized that the bottom-pouring simulator could only be used to investigate phenomena unrelated to mold oscillation, since the experimental apparatus did not have provision for oscillation. Even so, Stemple et al. were able to observe the motion of the meniscus and provided an explanation for the formation of ripple marks. Nishida et al.[6] developed a mold simulator with the novel addition of an in-situ tool to measure the distortion of the shell from the mold wall. This was done to determine the dynamics of air gap formation and the resulting effect on the steel-mold heat transfer. Again, these were incomplete simulators of the continuous casting process. To incorporate further sophistication into the experiment, several researchers have constructed more complex dip-type experiments in which the mold is equipped with oscillation drives and a mechanism for the extraction of the solidified shell to simulate continuous casting. This type of mold simulator is quite versatile and has been used by Saucedo[7] to investigate the initial solidification phenomena. The simulated castings exhibited the typical surface morphologies of industrial cast slabs, and the results were used to propose a mechanism of oscillation mark formation. The work also included a comprehensive survey of the various hypotheses VOLUME 36B, JUNE 2005—355 proposed in the literature for oscillation mark formation. Suzuki et al.[8] designed simulation experiments on shell formation and mold flux consumption and also presented findings on the formation mechanism of oscillation marks. These simulators simulated the dynamic nature of continuous casting but were not true simulators of the heat-transfer conditions that could be found in the steel plant. The next step in complexity of mold simulators was to build a scale model of an actual continuous casting machine, with the liquid contained in the mold. These mold simulators include various levels of the complexity found in industrial machines, and are generally used as pilot casters to investigate particular conditions that cannot be studied with any of the previous simulators or even on an actual caster. One of the earliest reported experiments was that of Savage and Pritchard,[9] who built a mold to investigate billet rupture during continuous casting. Singh and Blazek[10] constructed a similar model to study the effects of heat transfer and shell formation on surface rippling in low-carbon steels. Building further on this idea, and to determine the various factors affecting mold heat transfer, Blazek et al.[11] built a simulator that had mold plates modified to allow for variations in the water cooling flow configuration. To investigate the effects of high oscillation frequencies on oscillation marks and mold flux consumption, Yasunaka et al.[12] constructed a simulator with a modified oscillation drive that allowed the mold to be oscillated at frequencies up to 50 Hz. To illustrate the importance of using a simulator instead of an actual casting machine, the authors found that a danger with high-frequency oscillation is that there exists the possibility that resonance can occur, leading to catastrophic failure of the machine. The state of the liquid steel meniscus is often considered to be important in the formation of oscillation marks, but it is exceedingly difficult and dangerous to attempt to observe the liquid steel meniscus directly in an industrial caster. To attempt visual observation, Matsushita et al.[13] constructed a simulator with a quartz window near the meniscus. The experiments yielded important information on the distortion of the meniscus during the oscillation cycle as affected by the casting speed. In another effort to improve the surface quality of continuously cast slabs, Itoyama et al.[14] built a simulator with horizontal oscillation in addition to the commonly utilized vertical oscillation, and found that the depth of oscillation marks decreased with the use of horizontal oscillation. In order to conduct comprehensive studies on the effects of operational parameters on casting quality, it is often necessary that the casting parameters be varied independently of each other. With this goal in view, a dip-type simulator of a continuous caster was developed in this study, with capabilities for mold oscillation and continuous shell extraction, and with the cooling conditions and capacity that are found in industrial casting machines. The mold simulator developed in this study is unique in the geometric form of the mold and in the sophistication of the sensor instrumentation. Additionally, this study used sensor configurations that were optimized to detect small changes in temperature and displacement in the system. The main objective of this article is to present a description of the system and several examples of useful data that can be obtained during a normal trial, including subsecond temperature variations, heat 356—VOLUME 36B, JUNE 2005 fluxes related to initial solidification, and surface profiles. Using these experimental data, the validity of hypotheses of oscillation mark formation can be tested. The simulation capability of the mold simulator itself was verified by obtaining solidified shells of different grades of steel under conditions that would be commonly seen in industrial operations. The surface quality of the simulated shells was then compared against that of industrial slabs to ensure reproducibility. It is shown that the mold simulator does indeed replicate the surface features seen in a slab cast under industrial conditions. II. EXPERIMENTAL TECHNIQUE Figure 1 is a schematic of the molten steel in a continuous casting mold. The mold is cooled by water flowing through the grooves and acts as a heat sink. The steel solidifies against the copper mold and increases in thickness as it moves down the length of the mold. The steel shell is about 12 mm in thickness when it exits the mold. The mold is oscillated to prevent the sticking of the steel shell to the copper mold, and this oscillation promotes the infiltration of a film of liquid flux between the shell and the mold. Furthermore, the liquid mold flux on top of the liquid steel solidifies where it contacts the copper mold and gradually builds up a flux/slag rim. It has been theorized that the oscillation of the copper mold is responsible for the formation of oscillation marks.[3] A mold simulator provides an ideal laboratory system for the study of initial solidification of steel in a continuous casting mold. The depth and width of the oscillation marks can be easily modified by changing the mold oscillation cycle, oscillation stroke, and casting speed. In addition, the effects of different mold fluxes on the initial heat transfer can be studied easily without interrupting the normal production operations at the plant. Fig. 1—Schematic sketch of liquid steel in a continuous caster mold. METALLURGICAL AND MATERIALS TRANSACTIONS B Mold Simulator The mold simulator developed in this study is an inversetype mold, where the steel solidifies around the mold, instead of the mold surrounding the solidifying steel. Figure 2 is a schematic sketch of the mold simulator stage, which consists of several distinct modules to simulate the casting process. The different physical modules of the simulator include the mold assembly, the extraction mechanism, the stabilization system, and the oscillation mechanism. The mold assembly consists of a pair of grooved copper plates and a stainless steel baffle that separates the inlet and outlet water, as shown in Figure 3. In this work, the mold surface is flat instead of cylindrical, and is constructed from actual mold plates previously used at the U.S. Steel Gary Works. This flat plate configuration has nickel plating on the hot face, and the cold face is grooved with cooling channels. Figure 4 shows the assembly of a typical mold used in the mold simulator and the placement of the stainless steel baffle that allows the circulation of cooling water. The assembled parts are Tungsten inert gas (TIG)-welded to form a unit, after which the unit is pressurized with water and checked for leaks. Figure 5 shows the dimensions of the copper plates and of the cooling grooves. Figure 5 also shows the location of the meniscus with respect to the bottom of the mold and the locations of thermocouples with respect to the meniscus. The cooling water is fed into the mold from the cooling water manifold, as shown in Figure 2. In order to simulate continuous casting, the mold assembly is fitted with an extraction mechanism, which is fabricated from 6.25-mm-thick steel plates. The extractor pulls the solidifying steel shell in the casting direction (downwards). This exposes liquid steel to the water-cooled copper mold at the meniscus and allows the formation of a new steel shell. The extractor is designed so that only one face (a) (b) Fig. 2—Schematic sketch of the mold simulator stage. METALLURGICAL AND MATERIALS TRANSACTIONS B Fig. 3—The copper mold assembly and extractor mechanism. VOLUME 36B, JUNE 2005—357 Fig. 4—Steps in building the mold assembly. of the mold is exposed to the liquid steel, as seen in Figure 3. This allows a controlled exposure of the mold hot face to the liquid steel while protecting the other faces of the mold. The process of solidification and extraction of the steel shell displaces some liquid steel, and so the stabilization system moves the main stage upward with time to maintain the liquid steel meniscus at a constant level (about 150 mm from the bottom) with respect to the copper mold. All of the sensor systems, data and control cables, and drive systems are protected from the steel bath by a heat shield. 358—VOLUME 36B, JUNE 2005 The mold is connected to an oscillating stage so that the mold oscillates sinusoidally in the vertical direction about the meniscus position. A slotted cam is used to convert the rotational motion of the motor into a linear vertical sinusoidal oscillation of the rectangular mold. The extractor is attached to drive shafts powered by stepper motors. During the experiment, the drive shafts push the steel shell down with respect to the meniscus and expose steel to the copper mold to allow the formation of “new” steel shell. The mold motion is independent of the extractor motion. This allows the incorporation of negative strip time, which can be defined METALLURGICAL AND MATERIALS TRANSACTIONS B Fig. 6—Physical description of the problem domain. Fig. 5—Dimensions of mold copper plate with thermocouple locations (dimensions in millimeters). Note: The oval shown at the right is not exactly the same as that shown at the left. as the portion of the mold oscillation cycle during which the mold moves downward faster than the shell. The translating stage is controlled so that the meniscus remains about 150 mm from the bottom of the mold during an experiment. In order to characterize the heat transfer, the mold was instrumented with thermocouples to observe the transient variation of the temperature and heat flux during the casting period. The instrumentation of the mold with thermocouples was preceded by a comprehensive study[15] of temperature measurements in conducting solids. For example, it is known that when a temperature sensor is inserted into a conducting solid, the void created for the sensor and the sensor material itself can introduce errors into the measured temperature signal. These errors were studied to determine how best to install the sensors in the mold. Additionally, the response of the material, as deduced from the temperature sensors, was studied under conditions of transient high thermal fluxes to determine the ability of the sensor to discriminate between different functional forms of surface heat flux variation. A heat-transfer simulator was also used to confirm the ability of subsurface thermocouples to measure small variations in temperature due to oscillations in the surface heat flux. The resulting conceptual models assisted in the development of a greater understanding of meniscus heat transfer, which finally led to the ability to interpret the heattransfer data obtained from the mold simulator experiments. A heat flux simulator was built that allowed heat fluxes of up to 1 MW/m2 to be applied to a copper mold. A variety of thermocouple designs were modeled to determine the optimum method to allow transient heat fluxes to be measured accurately. This study allowed such issues as hole size, positioning, thermocouple attachment, and data acquisition techMETALLURGICAL AND MATERIALS TRANSACTIONS B niques to be fully developed before application on the mold simulator. Based on the preceding heat-transfer studies, the mold was instrumented with 12 grounded T-type thermocouples at various elevations to detect casting events on the hot face of the mold. The thermocouples were arranged in two columns—1.5 and 5.0 mm from the hot face—of six rows. The six rows were in the immediate vicinity of the aim meniscus location of 150 mm. Figure 5 shows the physical locations of the thermocouples with respect to the meniscus. These thermocouples are located 133, 140, 146, 152, 159, and 165 mm from the bottom of the mold. The molds were machined with 1.59-mm-diameter 50-mm-deep thermocouple voids with an orientation parallel to the mold surface to install the thermocouples. The dual-lead T-type thermocouples used in the experiments have magnesium oxide insulation and a stainless steel sheath with an outer diameter of 0.5 mm. The thermocouples were fitted with metal collars to ensure a good fit in the void so that the positions of the tips were well defined, and the tips were covered with a heat sink compound to enhance heat transfer to the thermocouple tip. In addition to the thermocouples, linear velocity displacement transducers (LVDTs) were used to monitor the motions of the mold and the extractor mechanism. By attaching both LVDTs to the same reference point, motions of the extractor and mold were measured relative to the same frame of reference. The instrumentation of the mold resulted in a complete characterization of heat-transfer phenomena with respect to the motion of the mold. The National Instruments Labview software was used to acquire temperature data at 60 Hz for the duration of the experiment to detect phenomena occurring within individual oscillation cycles. The temperature data acquired from the mold thermocouples were used to develop an estimate of the heat flux through the mold during the initial solidification of the steel shell using the one-dimensional inverse heat conduction program developed by Beck.[16] A typical form of the physical problem which Beck’s method is designed to solve is shown in Figure 6. It is sufficient to use only one internal body VOLUME 36B, JUNE 2005—359 temperature and one boundary condition to determine the unknown boundary condition. In the mold simulator experiments, the known boundary condition is the convective cooling of the mold by water flowing through cooling channels. While there are correlations for determining the heat-transfer coefficient for the cooling channels, another thermocouple was introduced into the domain to provide a well-defined boundary condition. The domain of the problem shown in Figure 7 can be decomposed into two domains by creating an interface S at the second thermocouple. The boundary condition at this point S then applies to the two subdomains. This decomposition is shown in Figure 8. In this case, the first thermocouple was 1.5 mm away from the heated surface, while the second Fig. 7—Problem domain including two thermocouples. Fig. 8—Domain decomposition yielding a known value boundary condition. 360—VOLUME 36B, JUNE 2005 thermocouple 5.0 mm away from the heated surface was used to define the subdomain. Before using this program and the domain decomposition approach to calculate heat fluxes from experimental data, the reliability of the program was tested rigorously using data from simulations. This was done to ensure that the program would calculate results that were accurate and precise for the waveforms of interest in this work, and to examine the effects of the known boundary conditions and signal noise. For more details, interested readers can refer to the work of Badri.[15] III. EXPERIMENTAL PROCEDURE A typical experimental run of the mold simulator involves the heating and melting of a charge of ultra-low carbon steel in a 200-kg induction furnace under an argon atmosphere. After the charge is molten, the chemistry and temperature of the melt are adjusted to aim values and enough mold flux powder is added to the surface so that there will be a layer of molten flux approximately 6.5-mm thick on top of the liquid steel after melting. Following the melting of the mold flux powder, the levels of the liquid steel and mold slag are measured to ensure that the meniscus will be located at a particular level on the mold (150 mm from the bottom of the mold). Samples of the steel and slag are taken for analysis, and then the liquid steel is heated to slightly above the desired casting temperature. When the aim temperature is reached, the main stage is lowered into the steel bath (Figures 9(a) through (c)). During the descent of the main stage, the oscillator motor is turned on. After the main stage reaches a preset depth (Figure 9(d)), it is held for 3 seconds to form an initial shell on the mold. This pause allows for the formation of a shell sufficiently strong to prevent tearing of the initial steel shell during extraction. In the casting phase (Figure 9(e)), the extractor is lowered an additional 3 in. at constant velocity while the mold continues to oscillate about the meniscus to simulate the continuous casting of a 3-in. length of steel shell. The main stage moves to compensate for any additional displacement of the liquid level so that the meniscus is maintained at the same level with respect to the mold. At the end of the casting phase (Figure 9(f)), the entire assembly is withdrawn from the furnace and the shell is allowed to cool (Figures 9(g) through (i)). The profile of this motion is shown in Figure 10(a), while the corresponding velocity profile is shown in Figure 10(b). Additional samples of the liquid steel and mold flux are taken to analyze for any change in composition. After the shell has completely cooled, the portion of the shell that solidified adjacent to the copper mold is cut away. Figure 11 shows a schematic sketch of a cutaway shell from a typical mold simulator run. The solidified shell is removed from the mold while an attempt is made to keep the mold flux film intact on the mold surface. As an example, the shell surface from an ultra-low carbon grade casting is shown in Figure 12. The shell is shown just after it was removed from the mold. Good slag infiltration between the copper mold and the steel shell can be seen. Subsequently, the surface profile is measured along the centerline of the steel shell, corresponding to the location of the thermocouples in the mold, using a contact profilometer. METALLURGICAL AND MATERIALS TRANSACTIONS B (a) (b) (c) (d ) (e) (f) Fig. 9—Digital images showing the progress of the experiment. METALLURGICAL AND MATERIALS TRANSACTIONS B VOLUME 36B, JUNE 2005—361 (g) (h) (i) Fig. 9—(Continued). Digital images showing the progress of the experiment. (a) (b) Fig. 10—Mold and steel shell displacement and velocity during an experiment. 362—VOLUME 36B, JUNE 2005 METALLURGICAL AND MATERIALS TRANSACTIONS B IV. RESULTS AND DISCUSSION Using the mold simulator, experimental runs were conducted for several grades of steel with most of the runs focused on ultra-low carbon steel. Table I summarizes the typical chemical composition for the experimental runs, while Table II summarizes the operating parameters. Some of the typical information that can be obtained during the operation of the mold simulator includes temperature history, the associated heat flux at the hot face of the mold, the surface profile of the cast shell measured using a contact profilometer, and flux film characteristics. The surface profiles of ultra-low, peritectic, and medium (hyperperitectic) carbon steels are shown below to enumer- Fig. 11—Schematic sketch of an expected steel shell from a mold simulator run. ate the differences between different grades of steel. Furthermore, the shells obtained from mold simulator runs are compared with industrial samples. This is an important step because it reveals whether the cast shells are in fact representative of industrial cast slabs. The surface profile of the solidified steel shell can be analyzed in conjunction with the measured temperatures to obtain insight into the solidification history of the shell surface. Such an analysis is the main topic of a subsequent article.[17] Typical temperature traces, as recorded by thermocouples just above and below the meniscus, are shown in Figure 13. The thermocouples below the meniscus measure higher temperatures because of the direct contact of the mold surface with the liquid steel, and they also register the variations in temperature due to mold oscillation. The temperature traces measured by all of the thermocouples have roughly the same form. The initial temperature of the mold is ambient temperature. As the mold is immersed into the liquid steel bath, the temperature rises. However, as the mold enters the bath and the liquid steel begins to solidify on the hot face, there is also an increase in the resistance to further heat transfer, which results in a decrease in the temperature measured by the thermocouples. During the extraction phase of the casting process, the temperature rises as the mold is exposed to fresh liquid steel at the meniscus, and the oscillation in temperature reflects the changing position of the mold with respect to the meniscus. At the end of the casting stage, the mold is withdrawn from the liquid steel and the thermocouples show a rapid decrease in mold temperature. Figure 14 shows typical temperature traces measured by all of the thermocouples during the casting stage of an ultralow carbon grade of steel. The labels 5.25F, 5.25B, etc. refer to the locations of thermocouples. The numeric value denotes the distance of the thermocouple from the bottom of the mold Fig. 12—Example of a mold flux film (left) and steel shell (right) from an ultra-low carbon steel trial. METALLURGICAL AND MATERIALS TRANSACTIONS B VOLUME 36B, JUNE 2005—363 Table I. Typical Chemical Compositions Element Pct Pct Pct Pct Pct carbon manganese silicon sulfur nitrogen Ultra-Low Carbon Steel Peritectic Steel Medium Carbon Steel 0.0046 0.46 0.11 0.0089 0.0057 0.065 0.95 0.22 0.0075 0.0047 0.175 1.17 0.31 0.027 0.0069 Table II. Operating Parameters Stroke (mm) Oscillation frequency (Hz) Casting/extraction speed (mm/s) 6.3 1.3 12.7 Fig. 15—Temperatures measured by thermocouples at the meniscus during solidification of an ultra-low carbon steel grade. Fig. 16—The heat flux calculated using the temperature data from the thermocouples at the meniscus during solidification of an ultra-low carbon steel grade. Fig. 13—Thermocouple temperature traces during immersion and casting of steel using the mold simulator. Fig. 14—Mold thermocouple data during the casting stage of an ultra-low carbon steel grade. in inches, while the character (F or B, meaning front or back) refers to the distance of the thermocouple tip from the hot face. The F refers to thermocouple tips located about 1.5 mm from the hot face, while B refers to the thermocouple tips located 5.0 mm from the hot face. It can be seen that the individual oscillations in temperature due to the oscillation of the mold relative to the meniscus have been resolved. The trials indicate that any phenomenon causing a temperature 364—VOLUME 36B, JUNE 2005 change greater than 0.1 °C can be identified with the current thermocouple instrumentation of the mold. Figure 15 shows a close-up view of the temperature data recorded by the thermocouples at the meniscus, from which the associated heat flux at the meniscus shown in Figure 16 is derived using the one-dimensional inverse heat conduction program developed by Beck. The heat flux plotted is the horizontal heat flux in the area of the meniscus and is not the total heat removed from the steel in the meniscus area. In the meniscus area, the heat flux is multidimensional and transient. Calculation of multidimensional heat conduction using inverse techniques is a very complicated issue and its discussion is beyond the scope of this work. Figure 16 and subsequent plots are shown to illustrate that heat fluxes in the meniscus area can be measured and that, even in the one-dimensional solution, one can adequately resolve transient behavior in the heat flux during the oscillation cycle. In this study, unfiltered and unaltered heat flux data calculated directly from thermal measurement are shown. It is felt that other methods of calculation of heat flux would only change the numbers and not the variation of the heat flux values as a function of oscillation cycle. An image of the surface of the ultra-low carbon steel shell and the associated contact profile measurement are shown in Figure 17. From the surface profile measurement, it can be METALLURGICAL AND MATERIALS TRANSACTIONS B Fig. 18—Mold thermocouple data during casting stage of a peritectic steel grade. (a) Fig. 19—Temperatures measured by thermocouples at the meniscus during solidification of a peritectic steel grade. (b) Fig. 17—(a) Photograph and (b) measured profile of shell surface for an ultra-low carbon steel grade. seen that this grade of steel has peaks that are rounded between oscillation marks. Furthermore, the oscillation marks in the ultra-low carbon grade can be described as being composed of peaks and subpeaks. In other words, each oscillation mark is bracketed by these sharp peaks, and within each oscillation mark, there is an irregularity referred to here as a subpeak. Figures 18 through 20 show the temperature and heat flux graphs for the peritectic grade of steel. Figure 21 is a contact profile measurement of the surface of the steel shell cast by the mold simulator. The surface profile measurement indicates that this particular grade of steel has several plateauMETALLURGICAL AND MATERIALS TRANSACTIONS B Fig. 20—The heat flux calculated using the temperature data from the thermocouples at the meniscus during solidification of a peritectic steel grade. shaped features between oscillation marks and that the shape of the oscillation marks is sharply defined. Figures 22 through 24 show the variation of temperature and heat flux values during the course of an experiment for VOLUME 36B, JUNE 2005—365 a medium carbon (hyperperitectic) grade of steel. Finally, Figure 25 shows the measured surface profile of a medium carbon steel shell from the mold simulator experiment. This grade exhibits poorly defined peaks and relatively smooth plateaus. It was found that the geometry of the oscillation marks in medium carbon steel appears to be a function of the mold flux used. The morphologies of the oscillation marks for ultra-low carbon, peritectic, and medium carbon steel grades are summarized in Figure 26. From the heat flux graphs, it can be seen that the total heat flux at the meniscus can be considered as the sum of an average baseline component and a time-varying component. The time-varying component of the heat flux has a magnitude approximately 10 pct of the average baseline Fig. 22—Mold thermocouple data during the casting stage of a medium carbon steel grade. (a) Fig. 23—Temperatures measured by thermocouples at the meniscus during solidification of a medium carbon steel grade. (b) Fig. 21—(a) Photograph and (b) measured profile of shell surface for a peritectic steel grade. 366—VOLUME 36B, JUNE 2005 Fig. 24—Heat flux calculated using the temperature data from the thermocouples at the meniscus during solidification of a medium carbon steel grade. METALLURGICAL AND MATERIALS TRANSACTIONS B Fig. 26—Morphologies of oscillation marks from three types of steel grades. (a) (b) Fig. 25—(a) Photograph and (b) measured profile of shell surface for a medium carbon steel grade. component. The average heat flux for the peritectic grade is less than that for the ultra-low carbon and medium carbon grades. The heat flux data indicate that it is possiMETALLURGICAL AND MATERIALS TRANSACTIONS B ble to resolve the one-dimensional heat flux profiles from temperature measurements for peritectic grades that are traditionally viewed as difficult to interpret due to the nonuniformity of shell thickness caused by volume changes accompanying the peritectic phase transformation. This technique can be used to determine the exact carbon content where this rippling becomes problematic and also to determine the relationship between the mold flux chemistry and surface quality. For the conclusions deduced from the results of the mold simulator experiments to be applicable to industrial operations, the cast shells from the mold simulator must be shown to be similar to those cast industrially. This was accomplished by comparing the surface profiles of narrow faces of industrially cast slabs with those of the mold simulator shells. The comparisons of surface profiles for different grades of steel are shown in Figures 27 through 29. These figures show that there is reasonable similarity between the narrow faces of industrially cast slabs and the shells from the mold simulator for different grades of steel. The oscillation mark morphology changes with the composition of the steel, and these morphologies change in the same way in the mold simulator as they do in the industrially cast slabs. In addition to using profile measurements to show similarity to industrial slabs, the surface profiles of ultra-low carbon steel were also analyzed for two characteristics of the oscillation marks, the pitch and the depth. The pitch of the oscillation mark is the distance between two consecutive oscillation marks. Ideally, if one oscillation mark were formed in each oscillation cycle, the pitch of the oscillation marks would be equal to the theoretical value vc/f, where vc is the casting speed and f is the frequency of oscillation. In the mold simulator trials, there is a distribution of oscillation mark pitch values. The measured values were compared against the published data of Cramb and Mannion,[18] as shown in Figure 30. It was found that the distribution of oscillation mark pitch measurements conforms to a Gaussian distribution and that the peak is located at the theoretical value. The spread in the data about the theoretical calculated value is expected, because the spacing of oscillation marks does not depend uniquely on the casting speed and oscillation frequency, but is actually determined by the relative velocity between the shell and the meniscus. Since the meniscus level is not absolutely constant, but varies slightly with time about the mean position, there is a spread in the measured values. The simulation quality of the mold simulator is again confirmed by the fact VOLUME 36B, JUNE 2005—367 (a) (b) Fig. 27—(a) Comparison of surfaces of ultra-low carbon steel from the narrow face of a slab and the shell from the mold simulator. (b) Comparison of surface profiles. that the distribution of the pitch measurements is similar to that found in the industrial measurements reported by Cramb and Mannion. In addition to the pitch of the oscillation marks, the depths were also measured. The distribution of the measured depths is shown in Figure 31, and also appears to conform to a Gaussian distribution. The average depth of the oscillation marks is about 275 m, but there were a few instances in which the depth was much larger, up to 700 m. The quality of the measured distribution would increase with an increase in sample size. The distribution of the depths is comparable to that measured by Cramb and Mannion, as can be seen in Figure 31. The experimental data show that the measured characteristics of the oscillation marks agree well with industrial slab profiles and the reported measurements of Cramb and Mannion, again showing that the mold simulator does indeed simulate the conditions of industrial continuous casting machines. This is in addition to the comparison between the surface profiles of mold simulator shells and industrial slab surfaces, which confirmed the ability of the mold simulator to reproduce the surface features of industrially cast slabs. This confirmation justifies the use of the mold simulator to 368—VOLUME 36B, JUNE 2005 analyze the solidification and heat-transfer phenomena in the industrial mold. V. SUMMARY An apparatus was successfully designed and constructed to simulate the mold of a continuous casting machine. The main features of the mold simulator the following: (1) a copper mold designed using actual mold plates; (2) an extracting mechanism, which allows continuous casting; (3) a translating stage to maintain the meniscus at a constant level on the mold; (4) a sinusoidal oscillating drive that allows the mold to oscillate independently of the shell; and (5) sensors that measure in-mold temperatures, bath temperature, steel shell displacement, and mold displacement. The temperature data obtained were converted to heat flux values using the one-dimensional heat conduction program developed by Beck. The mold simulator was used to obtain steel shells of varying composition in order to confirm that it could indeed act METALLURGICAL AND MATERIALS TRANSACTIONS B (a) (b) Fig. 28—(a) Comparison of surfaces of peritectic steel from the narrow face of a slab and the shell from the mold simulator. (b) Comparison of surface profiles. as a simulator of the continuous casting mold. The surface profile was measured using a contact profilometer. It was determined that mold simulator shells exhibited surface features similar to those of industrially cast slabs. It was found that the features on the surfaces of the cast slabs varied with steel composition, and that the changes in these features were reflected in the cast shells from the mold simulator. This confirmation was essential in that it shows that the mold simulator is a realistic model of the continuous casting process, and can therefore be used to conduct experiments reflective of conditions in an industrial caster. Furthermore, the distribution of depth and pitch measurements of oscillation marks on mold simulator shells compared favorably with measurements by Cramb and Mannion of the oscillation marks on the narrow faces of slabs. Therefore, the mold simulator can be used to investigate phenomena affecting the surface quality of cast shells and also the castability of various steel grades. The unique feature of this mold simulator is the instrumentation of the apparatus, which permits the resolution of the temperature and heat flux variations within the period of a single oscillation cycle. Furthermore, the shell cast by METALLURGICAL AND MATERIALS TRANSACTIONS B the mold simulator is typical of what is seen on the narrow face of a slab. This allows valid conclusions to be deduced from results of the mold simulator experiments. Last but not least, the mold flux film between the mold and the shell can be retrieved intact after an experiment, something that has not been accomplished in earlier studies. ACKNOWLEDGMENTS The authors thank the United States Steel Corporation and the former Bethlehem Steel Corporation (now part of ISG) for their financial support of this project. Additionally, we thank G. Biddle, J. Sadecky, and R.C. Evans for their assistance with apparatus design and construction. In addition, the authors deeply appreciate the assistance of Falcon Foundries in welding the copper mold plates. The material in this paper is intended for general information only. Any use of this material in relation to any specific application should be based on independent examination and verification of its unrestricted availability for such use, VOLUME 36B, JUNE 2005—369 (a) (b) Fig. 29—(a) Comparison of surfaces of ultra-low carbon steel from the narrow face of a slab and the shell from the mold simulator. (b) Comparison of surface profiles. Fig. 30—Distribution of oscillation mark pitch measurements for an ultralow carbon steel grade. Fig. 31—Distribution of oscillation mark depth measurements for an ultralow carbon steel grade. and a determination of suitability for the application by professionally qualified personnel. No license under any United States Steel Corporation patents or other proprietary interest is implied by the publication of this paper. Those making use of or relying upon the material assume all risks and liability arising from such use or reliance. 370—VOLUME 36B, JUNE 2005 METALLURGICAL AND MATERIALS TRANSACTIONS B REFERENCES 1. N.C. Machingawuta, S. Bagha, and P. Grieveson: Steelmaking Conf. Proc., ISS-AIME, Warrendale, PA, 1991, vol. 74, pp. 163-70. 2. D. Bouchard, F.G. Hamel, J.P. Nadeau, S. Bellemare, F. Dreneau, D.A. Tremblay, and D. Simard: Metall. Mater. Trans. B, 2001, vol. 32B, pp. 111-18. 3. H. Tomono, P. Ackermann, W. Kurz, and W. 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