LECTURE 7 HEAT Lecture Instructor: Kazumi Tolich Lecture 7 2 ¨ Reading chapter 14-1 to 14-2. ¤ Heat and mechanical work ¤ Specific heats ¤ Calorimetry Heat 3 ¨ ¨ ¨ ¨ Heat (Q) is the energy transferred from one object to another due to temperature difference. Objects do not contain heat. Temperature and heat are not the same quantities. The word “hot” does not mean “high heat” but rather “high temperature.” Heat, like work, is a kind of energy transfer, so it needs to be taken into account when applying conservation of energy. Heat and mechanical work 4 ¨ ¨ ¨ As the weights fall, they turn a paddle wheel, which does work on the water. Joule found that it takes about 4186 J of work to increase the temperature of 1kg of water by 1°C. Heat was measured in calories before his work, and this experiment showed the mechanical equivalent of heat. 1 cal = 4.186 J Insulating walls Units for heat 5 ¨ In nutrition, the Calorie (C) is used instead of calorie. 1 kcal = 1 C ¨ Another common unit for measuring heat is the British thermal unit (Btu). A Btu is the energy required to heat 1 lb of water from 63 °F to 64 °F. 1 Btu = 0.252 kcal = 1055 J Demo: 1 6 ¨ Drill and Dowel ¤ Demonstration ¨ of frictional work producing heat Cork popper ¤ Demonstration of friction producing heat Example: 1 7 ¨ During a workout, a person repeatedly lifts a barbell with a weight w = 53 N through a height of h = 0.46 m. How many “reps” of this lift are required to burn off 120 C? Don’t get burnt! 8 ¨ Have you ever noticed that some foods remain hotter much longer than others? ¤ ¤ ¤ The filling of hot apple pie can burn your tongue while crust will not. You can touch with your bare hand the aluminum foil covering a hot dinner out of the oven, but not the dinner. You can touch a toast straight out of a toaster, but not soup from a stove as hot as the toaster. Heat capacity 9 ¨ The heat required (Q) for a given increase in temperature (ΔT) of an object is given by the heat capacity (C) of the object. The heat capacity is a positive constant for a given object. Q C= ΔT Q = CΔT ¨ Q > 0 if ΔT > 0. Heat is added to a system. ¨ Q < 0 if ΔT < 0. Heat is removed from a system. ¨ We can think of heat capacity as thermal inertia. Specific heat 10 ¨ ¨ ¨ Different substances have different capacities for storing thermal energy. The specific heat (c) of a substance is defined as Q c= mΔT m is the mass of an object. at Pat Heat capacity vs. specific heat 11 Heat capacity depends on both what kind of substance an object is made of and the mass of the object. ¨ Analogy: ¨ ¤ Heat capacity of an object is like mass of an object. ¤ Specific heat of a substance is like density of a substance Example: 2 12 ¨ Suppose Q = 63.0 J of heat is added to a piece of aluminum with a mass of m = 128 g at a temperature of T0 = 25.0 °C. What is the final temperature of the aluminum? Specific heat capacity of water 13 ¨ Water has a much higher specific heat capacity than most common materials. ¤ The climate in many places are influenced by ocean currents. ¤ Islands and peninsulas do not have extreme temperatures (hot and cold) that are observed in the interior of a continent. Hot coal walking 14 ¨ People have walked barefoot on hot coals. ¨ Coals have low specific heat. ¨ Sweat on their feet and blood in their feet have high specific heat. ¨ As heat transfers from the coals to the feet, coals’ temperature decreases a lot, but feet’s temperature increases only by a little amount. Demo: 2 15 ¨ Balloon heat capacity ¤ Demonstration of heat capacity Clicker question: 1 16 Calorimetry 17 ¨ With a calorimeter (a lightweight thermally insulated container), we can determine the specific heat of a substance with known mass. 1. 2. 3. 4. Heat the sample to a known temperature. Placing it in a known mass of a substance with a known specific heat (often water). Measure the change in temperature of that substance. Apply conservation of energy: the heat flow from the sample is equal to the heat flow to the water. Demo: 3 18 ¨ Calorimetry and specific heat ¤ Measuring specific heat for aluminum (900 J/kg°C), steel (450 J/kg°C), and lead (128 J/kg°C) Qm + Qw = 0 mm cm (T − Tm ) + mwcw (T − Tw ) = 0 " " J % J % 0.080 kg) $ 4186 ' (T − Tw ) $ 2791 ' (T − Tw ) ( m c (T − Tw ) kgK & kgK & # # cm = w w = = mm (Tm − T ) (0.120 kg) (Tm − T ) (Tm − T ) Example: 3 19 ¨ A blacksmith drops an iron horseshoe with a mass of mh = 0.50 kg into a bucket of water with a mass of mw = 25 kg. If the initial temperature of the horse shoe is Thi = 450 °C, and the initial temperature of the water is Twi = 23 °C, what is the equilibrium temperature of the system, T? Assume no heat is exchanged with the surroundings.
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