CP Chapter 11 Notes Reactions and Equations Evidence of Chemical Reactions How can you tell a _________________ reaction has taken place? – Temperature change – Color change – _________________ – Gas/bubbles – Appearance of a _________________ (precipitate) Chemical Reaction A chemical reaction is the process by which atoms of one or more substances are _________________ to form _________________ substances. Question Time What are the signs that a chemical reaction has taken place? What is a chemical reaction? Reactant(s) and Product(s) Reactant(s) are the _________________ substance(s) of a reaction Product(s) are the substance(s) formed _________________ the reaction means “react to produce” or “yield” Reactant(s) are on the left Product(s) are on the _________________ Representing Chemical Reactions reactant A+ reactant B product C + product D The plus sign _________________ each reactant or product (s) Identifies solid state (l) Identifies _________________ state (g) Identifies gaseous state (aq) Identifies _________________ solution - ________________is applied to the reaction Example NH4NO3(s) N2O(g) + 2H2O(g) Question Time What are reactants? What are products? What does “” mean in a chemical reaction? Where are the reactants located in a written chemical reaction? Where are the products located in a written chemical reaction? Word Equation Uses _________________ not chemical symbols to indicate the _________________ (s) and product(s) of a chemical reaction. – Example iron(s) + chlorine(g) iron(III) _________________ (s) Skeleton Equation Skeleton equation uses _________________rather than words to identify the reactant(s) and product(s) – Example _________________ (s) + Cl2(g) FeCl3(s) 1 Balanced Chemical Equation The equation that shows the _________________ of atoms of each reactant and each product is _________________ on both sides of the arrow is a _________________ chemical equation – Example 2Fe(s) + 3Cl2(g) 2FeCl3(s) Question Time What is a word equation? What is a skeleton equation? What is a balanced chemical equation? Balancing Equations Step 1 Step 2 Step 3 Step 4 Step 5 Write the _________________ equation. Balance each element by placing _________________in front of the chemical formulas. Balance in this order: – metals – non-metals – hydrogen – oxygen _________________ Select coefficients that will give the _________________number of atoms on each side of the equation. If you have an _________________number of oxygen atoms, multiply the coefficient by ______ first to make it an even number. Then try to balance the equation. Check all other elements to see whether the equation is _________________. Other elements may have become unbalanced. Make _________________to balance all the elements. If it becomes difficult to balance an equation, use a _________________ as a coefficient then _________________to get rid of the fraction. Balance these equations. 1. HgO Hg + O2 2. Mg + O2 MgO 3. KClO3 KCl + O2 4. AgNO3 + H2S Ag2S 5. Al(OH)3 + H2SO4 Al2(SO4)3 + H2O 6. Zn(OH)2 + H3PO4 Zn3(PO4)2 + H2O 7. FeCl3 + NaOH Fe(OH)3 + NaCl 2 + HNO3 Types of Reactions Five Types of Reactions There are _________________different types of reactions – Synthesis/Combination Reaction – _________________Reaction – Decomposition Reaction – Single-replacement Reaction – Double-_________________Reaction Synthesis/Combination Reaction A+B __________ 2Fe(s) + 3Cl2(g) 2FeCl3(s) CaO(s) + H2O(l) Ca(OH)2(s) Two or more substances react to produce a _________________product To tell if it is a synthesis/combination reaction, one product is formed from two or more ____________ Combustion Reaction In a combustion reaction _________________combines with a substance and _________________ energy. Oxygen (O2) is a _________________in a combustion reaction Example: 2H2(g) + O2(g) 2H2O(g) In the combustion of a hydrocarbon (molecule with just hydrogen and carbon) _________________and carbon dioxide are produced Ex: CH4(g) + O2(g) CO2(g) + H2O(g) Question Time How can you tell if there is a synthesis/combination reaction? How can you tell if there is a combustion reaction? Determine if the reaction is synthesis/combination or combustion – 2Na + Cl2 2NaCl – C(s) + O2(g) CO2(g) Decomposition Reaction In a decomposition reaction a _________________compound breaks down into two or more ________ elements or compounds AB A + B 2NaN3(s) 2Na(s) + 3N2(g) One reactant breaks up into two or more _________________. To tell if it is a decomposition reaction, there is only one reactant forming two or more products Single Replacement Reactions Single replacement reactions are when atoms of one element _________________the atoms of another element in a compound. A + BX AX + B 2Li(s) + 2H2O(l) 2LiOH(aq) + H2(g) To tell if it is a single replacement reaction, a _________________, H2 or a halogen is by itself. Like a “boyfriend thief” 3 Double Replacement Reactions A double replacement reaction is when there is an _________________of ions between ________ compounds. AX + BY AY + BX Ca(OH)2(aq) +2HCl(aq) CaCl2(aq) + 2H2O(l) To tell if it is a double replacement reaction, there are two compounds reacting with each other forming two _________________compounds Question Time How can you tell if there is a decomposition reaction? What is a single replacement reaction and how can you tell if there is one? What is a double replacement reaction and how can you tell if there is one? Single Replacement Reactions Single Replacement Reaction: A + BX Metals will replace _______________ or ________________ Halogens will replace ______________ If an ion can take on two different charges, we will use the _____ charge for this worksheet. Metals + H2O H2 + __________OH You must use the Activity Series Chart to find out if the reaction takes place. For each reaction use the activity series to complete the reaction. If no reaction will occur, write “no reaction. Make sure to balance your final answer. Most reactive AgNO3 ___________________________________ 1. Zn + 2. Cl2 + KI ___________________________________ 3. Ag + KNO3 ___________________________________ 4. Mg + HCl ___________________________________ 5. Fe + CuSO4 ___________________________________ 6. Al + CuSO4 ___________________________________ 7. Br2 + CaI2 ___________________________________ 8. Mg + H2SO4 ___________________________________ 9. Cu + H2O ___________________________________ Least reactive 10. Fe + AgC2H3O2 ___________________________________ 4 Activity Series Metals Non-metals Li F2 Rb Cl2 K Br2 Cs I2 Ba Sr Ca Na Mg Al Ti Mn Zn Cr Fe Cd Co Ni Sn Pb H Sb Bi Cu Hg Ag Pt Au Double Replacement Reactions AY + BX AX + BY DR Reactions Equation: _____________________________________ One of Three things happens in a DR Reaction: 1. ___________________ (s) 2. ___________________(l) Or __________________(aq) 3. ___________________(g) ________ ________ ________ If both products are ___________________ then there will be no __________________. Use the Solubility Chart to predict if a substance is soluble or insoluble. 1. Na3PO4____________________ 4. Fe(OH)3__________________ 2. PbBr2______________________ 5. AlCl3_____________________ 3. CaCl2______________________ 6. NaCl______________________ Complete and balance the equations for the following double-replacement reactions. Write “(s)” next to the product that is insoluble, “(aq)” next to the product that is soluble, or “(l)” next to water. If no reaction takes place write “NR.” 1. AgNO3(aq) + NaCl(aq) _______________________________________ 2. Mg(NO3)2(aq) + KOH(aq) _______________________________________ 3. NaNO3(aq) + K3PO4(aq) _______________________________________ 4. HI(aq) + Li2S(aq) _______________________________________ 5. AgNO3(aq) + KCl(aq) _______________________________________ 6. HCl(aq) + Na2CO3(aq) _______________________________________ 7. H2SO4 (aq) + Mg(OH)2(aq) _______________________________________ 8. KCN(aq) + HBr(aq) _______________________________________ 5 Activity Series Metals Li Rb K Cs Ba Sr Ca Na Mg Al Ti Zn Cr Fe Ni Sn Pb *H Cu Ag Pd Hg Pt Au Nonmetals F2 Cl2 Br2 I2 Most Reactive Least Reactive SOLUBILITY CHART NEGATIVE ION (ANION) PLUS POSITIVE ION (CATION) any negative ion any negative ion nitrate (NO3-) acetate (C2H3O2-) + + + + chloride (Cl-), bromide (Br-), or iodide (I-) sulfate (SO4-2) + alkali metal ions ammonium (NH4+) any positive ion any positive ion except Ag+ or Hg+ Ag+, Pb+2, Hg+, or Cu+ + + any other positive ion Ca+2, Sr+2, Ba+2, Ra+2, Ag+, or Pb+2 soluble not soluble sulfide (S-2) + + any other positive ion alkali metal ions, NH4+, Be+2, Mg+2, Ca+2, Sr+2, Ba+2, or Ra+2 soluble soluble hydroxide (OH-) + + any other positive ion alkali metal ions or NH4+ not soluble soluble + + any other positive ion alkali metal ions or NH4+ not soluble soluble + any other positive ion not soluble phosphate (PO4-3), carbonate (CO3-2), or sulfite (SO3-2) 6 FORMS A COMPOUND WHICH IS: soluble soluble soluble soluble not soluble
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