CHEM-UP! DAY 1 - 2013 The Academic Support Center @ Daytona State College (Chem-Up 1, Page 1 of 128) Chem Up! An Introduction to Basic Chemistry Concepts As you come in: 1. Please create a name plate to take to your seat. 2. Write your name on a “raffle ticket” to leave at the front desk. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 2 of 128) Welcome! Please introduce yourself to your neighbors. Some activities will require working in groups of two to three. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 3 of 128) Course Overview Day 1 • Measurements Day 2 • Atoms and Elements Day 3 • Bonds and Intermolecular Forces Day 4 • Reactions and Organic Molecules The Academic Support Center @ Daytona State College (Chem-Up 1, Page 4 of 128) SKILLS TO HELP YOU SUCCEED Before Class During Class After Class • Course Expectations • Using your Textbook Wisely • Note taking Skills for Science Courses • Active Class Participation • Study Techniques • Creating Study Aids • Resources We will cover these topics in addition to reviewing Chemistry! The Academic Support Center @ Daytona State College (Chem-Up 1, Page 5 of 128) AGENDA FOR DAY 1 Measurements •Scientific Notation •Measured vs. Exact Numbers •Significant Figures •Calculations & Rounding •Units of Measurement •Prefixes •Conversion Factors and Problem Solving The Academic Support Center @ Daytona State College (Chem-Up 1, Page 6 of 128) Measurements 1) Scientific Notation Learning Goal Write a number in scientific notation. © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 7 of 128) Scientific Notation Scientific notation is used to write very large or very small numbers such as • the width of a human hair, 0.000 008 m, which is also written as 8 × 10−6 m • the number of hairs on a human scalp,100 000, which is also written as 1 × 105 hairs © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 8 of 128) Writing Numbers in Scientific Notation • A number written in scientific notation contains a coefficient and a power of ten. coefficient power unit of ten 1.5 × 102 m • The coefficient is at least 1 but less than 10. © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 9 of 128) Writing Numbers in Scientific Notation • The number of spaces moved to obtain a coefficient between 1 and 10 is shown as a power of ten. 52 000. = 5.2 × 104 move decimal 4 spaces left 0.003 78 = 3.78 × 10−3 move decimal 3 spaces right © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 10 of 128) Some Powers of Ten © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 11 of 128) Comparing Numbers in Standard and Scientific Notation Standard Format Scientific Notation Diameter of the Earth 12 800 000 m 1.28 × 107 m Mass of a human 68 kg 6.8 × 101 kg Diameter of a virus 0.000 000 3 cm 3 × 10−7 cm © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 12 of 128) Scientific Notation and Calculators You can enter a number written in scientific notation on many calculators using the EE or EXP key. © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 13 of 128) Scientific Notation and Calculators When a calculator display appears in scientific notation, it is shown as a number between 1 and 10, followed by a space and the power (exponent). © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 14 of 128) Scientific Notation and Calculators On many scientific calculators, a number is converted to scientific notation, using the appropriate keys. 0.000 52 2nd or 3rd function key SCI Key Key = 5.2 −04 or 5.2−04 = 5.2 × 10−4 Calculator display © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 15 of 128) Guide to Writing a Number in Scientific Notation © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 16 of 128) Learning Check Write the following number in the correct scientific notation, 0.000 058 g. © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 17 of 128) Solution Write the following number in the correct scientific notation, 0.000 058 g. Step 1 Move the decimal point to obtain a coefficient that is at least 1 but less than 10. 0.000 058 5.8 (The decimal moves 5 places to the right, giving a coefficient of 5.8) © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 18 of 128) Solution Write the following number in the correct scientific notation, 0.000 058 g. Step 2 Express the number of places moved as a power of 10. Moving the decimal 5 places to the right gives a power of −5. © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 19 of 128) Solution Write the following number in the correct scientific notation, 0.000 058 g. Step 3 Write the product of the coefficient multiplied by the power of 10 with the unit. 5.8 × 10−5 g © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 20 of 128) Learning Check Select the correct scientific notation for each. 1. 0.000 008 (a) 8 × 106 (b) 8 × 10−6 (c) 0.8 × 10−5 2. 72 000 (a) 7.2 × 104 (b) 72 × 103 (c) 7.2 × 10−4 © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 21 of 128) Solution Select the correct scientific notation for each. 1. 0.000 008 (Move the decimal 6 places to right.) (b) 8 × 10−6 2. 72 000 (Move the decimal 4 places to the left.) (a) 7.2 × 104 © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 22 of 128) Learning Check Write each as a standard number. 1. 2.0 × 10−2 (a) 200 (b) 0.0020 2. 1.8 × 105 (a) 180 000 (c) 0.020 (b) 0.000 018 (c) 18 000 © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 23 of 128) Solution Write each as a standard number. 1. 2.0 × 10−2 (c) 0.020 2. 1.8 × 105 (a) 180 000 © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 24 of 128) Time For Lesson 1 Scientific Notation The Academic Support Center @ Daytona State College (Chem-Up 1, Page 25 of 128) Measurements 2) Measured Numbers and Significant Figures Learning Goal Identify a number as measured or exact; determine the number of significant figures in a measured number. © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 26 of 128) Measured Numbers A measuring tool • is used to determine a quantity such as the length or the mass of an object • provides numbers for a measurement called measured numbers © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 27 of 128) Reporting Length To report the length of an object • observe the numerical values of the marked lines at the end of the object • estimate the last digit by visually dividing the space between the smallest marked lines This estimated number is the final digit that is reported for a measured number. © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 28 of 128) Reporting Length – 4.5 cm • The end of the object is between the 4-cm and 5-cm marks. • Estimate that the end is halfway between the 4-cm and 5-cm marks and report the value as 4.5 cm. © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 29 of 128) Reporting Length – 4.55 cm • The metric ruler is marked at every 0.1 cm. • You can now estimate that the length is halfway between the 4.5-cm and 4.6-cm marks and report the value as 4.55 cm. © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 30 of 128) Learning Check . 8. . . . . . . . 9. . . . . . . . 10. . cm What is the length of the red line? (A) 9.0 cm (B) 9.03 cm (C) 9.04 cm © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 31 of 128) Solution . 8. . . . . . . . 9. . . . . . . . 10. . cm The length of the line could be reported as (B) 9.03 cm (C) 9.04 cm The estimated digit may be slightly different. Both readings are acceptable. © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 32 of 128) Exact Numbers Exact numbers are • those numbers obtained by counting items • definitions that compare two units in the same measuring system © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 33 of 128) Exact Numbers Exact numbers are not measured, do not have a limited number of significant figures, and do not affect the number of significant figures in a calculation. © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 34 of 128) Significant Figures In a measured number, the significant figures, (SFs) are all the digits, including the estimated digit. • All nonzero numbers are counted as significant figures. • Zeros may or may or may not be significant, depending on the position in the number. © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 35 of 128) Counting Significant Figures All nonzero numbers in a measured number are significant. Measurement 38.15 cm 5.6 ft 65.6 lb 122.55 m Number of Significant Figures 4 2 3 5 © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 36 of 128) Zeros Between Digits Zeros between nonzero digits are significant. Measurement 50.8 mm 2001 min 0.0702 lb 0.40505 m Number of Significant Figures 3 4 3 5 © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 37 of 128) Zeros, Decimal Numbers Zeros at the end of decimal numbers are significant. Measurement 50.80 km 200. min 40.00 g Number of Significant Figures 4 3 4 © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 38 of 128) Zeros, Nondecimal Numbers Zeros at the end of nondecimal numbers are not significant. Measurement 44 000 km 810 cm 6 150 000 g Number of Significant Figures 2 2 3 © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 39 of 128) Zeros, Scientific Notation Zeros in the coefficient of numbers written in scientific notation are significant. Measurement 4.90 × 103 m 8.0 × 10–3 kg 6.0330 × 10–5 L Number of Significant Figures 3 2 5 © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 40 of 128) Zeros, Scientific Notation Keep only the significant zeros when writing numbers in scientific notation. Measurement 500. g 400 000 m 0.300 cm Scientific Notation Number of Significant Figures 5.00 × 102 g 3 4 × 105 m 1 3.00 × 10−1 cm 3 © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 41 of 128) Rules for Significant Figures © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 42 of 128) Learning Check State the number of significant figures in each of the following measurements: A. 0.030 m B. 4.050 L C. 0.0008 g D. 2.80 m © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 43 of 128) Solution State the number of significant figures in each of the following measurements: A. 0.030 m 2 SF B. 4.050 L 4 SF C. 0.0008 g 1 SF D. 2.80 m 3 SF © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 44 of 128) Learning Check 1. Which answer contains three significant figures? (a) 0.4760 (b) 0.00476 (c) 4.076 × 103 2. All the zeros are significant in (a) 0.00307 (b) 25.300 (c) 2.050 × 103 3. The number of significant figures in 5.80 × 102 is (a) one (b) two (c) three © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 45 of 128) Solution 1. Which answer contains three significant figures? (b) 0.00476 2. All the zeros are significant in (b) 25.300 (c) 2.050 ×103 3. The number of significant figures in 5.80 × 102 is (c) three © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 46 of 128) Time For Lesson 2 (Part A) Significant Figures The Academic Support Center @ Daytona State College (Chem-Up 1, Page 47 of 128) Measurements 3) Significant Figures in Calculations Learning Goal Adjust calculated answers to give the correct number of significant figures. © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 48 of 128) Significant Figures Calculations Video http://www.youtube.com/watch?v=kB2szfcwu1A The Academic Support Center @ Daytona State College (Chem-Up 1, Page 49 of 128) Rounding Off In calculations • calculated answers are usually rounded off • rounding rules are used to obtain the correct number of significant figures 1. If the first digit to be dropped is 4 or less, then it and all following digits are simply dropped from the number. 2. If the first digit to be dropped is 5 or greater, then the last retained digit is increased by 1. © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 50 of 128) Learning Check Adjust the following calculated answers to give answers with three significant figures: A. 824.75 cm B. 0.112486 g C. 8.2 L © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 51 of 128) Solution Adjust the following calculated answers to give answers with three significant figures: A. 824.75 cm 825 cm B. 0.112486 g C. 8.2 L 0.112 g 8.20 L © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 52 of 128) Addition and Subtraction with Measured Numbers In addition or subtraction, the final answer is written so that it has the same number of decimal places as the measurement having the fewest decimal places. For example, 2.367 + 34.1 36.467 36.5 Thousandths place Tenths place Calculator display Answer, rounded off to tenths place © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 53 of 128) Learning Check For each calculation, round the answer to give the correct number of digits. 1. 235.05 + 19.6 + 2 = (a) 257 (b) 256.7 2. 58.925 – 18.2 = (a) 40.725 (b) 40.73 (c) 256.65 (c) 40.7 © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 54 of 128) Solution 1. 235.05 Hundredths place +19.6 Tenths place + 2 Ones place 256.65 rounds to 257 answer (a) 2. 58.925 –18.2 40.725 Thousandths place Tenths place rounds to 40.7 answer (c) © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 55 of 128) Multiplication and Division with Measured Numbers In multiplication and division, the final answer is written to have the same number of significant figures (SFs) as the measurement with the fewest SFs. For example, 24.65 × 0.67 4 SF 2 SF = 16.5155 Calculator 17 Final answer (2 SF) © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 56 of 128) Adding Significant Zeros When the calculator answer is a small whole number and more significant figures are needed, we can add one or more zeros. For example, = 4 4.00 3 SF Calculator Final answer (3 SF) © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 57 of 128) Learning Check Give an answer for each with the correct number of significant figures. 1. 2.19 × 4.2 = (a) 9 (b) 9.2 (c) 9.198 2. 2.54 × 0.0028 = 0.0105 × 0.060 (a) 11.3 (b) 11 (c) 0.041 © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 58 of 128) Solution Give an answer for each with the correct number of significant figures. 1. 2.19 × 4.2 = (b) 9.2 2. 2.54 × 0.0028 = 0.0105 × 0.060 (b) 11 © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 59 of 128) Time For Lesson 2 (Part B) Significant Figures The Academic Support Center @ Daytona State College (Chem-Up 1, Page 60 of 128) Measurements 4) Units of Measurement Learning Goal Write the names and abbreviations for the metric or SI units used in measurements of length, volume, mass, temperature, and time. © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 61 of 128) Units of Measurement Video http://youtu.be/ddtEz4DRojo The Academic Support Center @ Daytona State College (Chem-Up 1, Page 62 of 128) The International System of Units (SI) Chemists use the metric system and the International System of Units (SI) for measurement when they • measure quantities • do experiments • solve problems © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 63 of 128) Units of Measurement and Their Abbreviations © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 64 of 128) Length Length is measured in • units of meters (m) in both the metric and SI systems • units of centimeters (cm) by chemists © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 65 of 128) Length Useful relationships between units of length include: 1 m = 1.094 yd 1 m = 39.37 in. 1 m = 100 cm 2.54 cm = 1 in. © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 66 of 128) Volume Volume, the space occupied by a substance, • is measured using units of m3 in the SI system • is commonly measured in liters (L) and milliliters (mL) by chemists © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 67 of 128) Volume Useful relationships between units of volume include: 1 m3 = 1000 L 1 L = 1000 mL 1 mL = 1 cm3 1 L = 1.057 qt 946.3 mL = 1 qt © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 68 of 128) Mass The mass of an object, a measure of the quantity of material it contains, • is measured on an electronic balance • has the SI unit of kilogram (kg) • is often measured by chemists in grams (g) The Academic Support Center @ Daytona State College (Chem-Up 1, Page 69 of 128) Mass Useful relationships between units of mass include: 1 kg = 1000 g 1 kg = 2.205 lb 453.6 g = 1 lb The Academic Support Center @ Daytona State College (Chem-Up 1, Page 70 of 128) Temperature Temperature, a measure of how hot or cold an object feels, • is measured on the Celsius (ºC) scale • is measured on the Kelvin (K) scale in the SI system • is 18 ºC or 64 ºF on this thermometer © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 71 of 128) Time Time is based on an atomic clock and is measured in units of seconds (s) in both the metric and SI systems. © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 72 of 128) Learning Check For each of the following, indicate whether the unit describes (a) length, (b) mass, or (c) volume 1. 2. 3. 4. A bag of onions has a mass of 2.6 kg. A person is 2.0 m tall. A medication contains 0.50 g of aspirin. A bottle contains 1.5 L of water. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 73 of 128) Solution For each of the following, indicate whether the unit describes (a) length, (b) mass, or (c) volume 1. 2. 3. 4. A bag of onions has a mass of 2.6 kg. A person is 2.0 m tall. A medication contains 0.50 g of aspirin. A bottle contains 1.5 L of water. (b) (a) (b) (c) The Academic Support Center @ Daytona State College (Chem-Up 1, Page 74 of 128) Learning Check Identify the measurement that has an SI unit. 1. John’s height is _____. (a) 1.5 yd (b) 6 ft (c) 2.1 m 2. The mass of a lemon is _____. (a) 12 oz (b) 0.145 kg (c) 0.6 lb 3. The temperature is _____. (a) 85 ºC (b) 255 K (c) 45 ºF The Academic Support Center @ Daytona State College (Chem-Up 1, Page 75 of 128) Solution Identify the measurement that has an SI unit. 1. John’s height is______. (c) 2.1 m 2. The mass of a lemon is _____. (b) 0.145 kg 3. The temperature is _____. (b) 255 K The Academic Support Center @ Daytona State College (Chem-Up 1, Page 76 of 128) Measurements 5) Prefixes and Equalities Learning Goal Use the numerical values of prefixes to write a metric equality. © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 77 of 128) Prefixes In the metric and SI systems of units, a prefix attached to any unit increases or decreases its size by some factor of 10. The relationship of a prefix to a unit can be expressed by replacing the prefix with its numerical value. 1 kilometer (1 km) = 1000 meters © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 78 of 128) Metric, SI Prefixes that Increase © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 79 of 128) Metric, SI Prefixes that Decrease © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 80 of 128) Measuring Length, Prefixes When the prefix centi is used with the unit meter, it becomes a centimeter, a length that is onehundredth of a meter (0.01 m). When the prefix milli is used with the unit meter, it becomes a millimeter, a length that is onethousandth of a meter (0.001 m). © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 81 of 128) Measuring Length, Equalities An equality shows the relationship between two units that measure the same quantity. For example, 1 m is the same length as 100 cm. The equality is written as: 1 m = 100 cm = 1 × 102 cm 1 m = 1000 mm = 1 × 103 mm 1 cm = 10 mm = 1 × 101 mm © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 82 of 128) Measuring Volume A volume of 1 L or smaller is common in the laboratory. When a liter is divided into 10 equal parts, each is called a deciliter (dL). 1 L = 10 dL = 1 × 101 dL 1 L = 1000 mL = 1 × 103 mL 1 dL = 100 mL = 1 × 102 mL © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 83 of 128) Measuring Volume The cubic centimeter (cm3 or cc) is the volume of a cube with the dimensions 1 cm × 1 cm × 1 cm. A cube measuring 10 cm on each side has a volume of 1000 cm3, or 1 L; a cube measuring 1 cm on each side has a volume of 1 cm3, 1cc, or 1 mL. © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 84 of 128) Measuring Volume A cubic centimeter has the same volume as a milliliter. 1 cm3 = 1 cc = 1 mL A cube measuring 10 cm on each side has a volume of 1000 cm3, or 1 L; a cube measuring 1 cm on each side has a volume of 1 cm3, 1cc, or 1 mL. © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 85 of 128) Measuring Mass When measuring the mass of • your body, the mass is measured in kilograms (kg) • laboratory samples, mass is reported in grams, milligrams (mg), or micrograms (μg) 1 kg = 1000 g = 1 × 103 g 1 g = 1000 mg = 1 × 103 mg 1 mg = 1000 μg = 1 × 103 μg © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 86 of 128) Measuring Mass, Equalities Equalities can be written for mass in the metric (SI) system. When metric equalities are used, 1 gram is the same mass as 1000 mg and 0.001 kg. 1 kg = 1000 g 1 g = 1000 mg 1 mg = 0.001 g 1 mg = 1000 µg © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 87 of 128) Metric Conversions Video http://youtu.be/ptoig7YfPHw The Academic Support Center @ Daytona State College (Chem-Up 1, Page 88 of 128) Learning Check Indicate the unit that completes each of the following equalities: 1. 1000m = ________ (a) 1mm (b) 1 km (c) 1 dm 2. 0.01m = _________ (a) 1 mm (b) 1 cm (c) 1 dm © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 89 of 128) Solution Indicate the unit that completes each of the following equalities: 1. 1000 m = _____ (b) 1 km 2. 0.01 m = _____ (b) 1 cm © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 90 of 128) Learning Check Complete each of the following equalities: 1. 1 kg = _____ (a) 10 g (b) 100 g 2. 1 mm = _____ (a) 0.001 m (b) 0.01 m (c) 1000 g (c) 0.1 m © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 91 of 128) Solution Complete each of the following equalities: 1. 1 kg = _____ (c) 1000 g 2. 1 mm = _____ (a) 0.001 m © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 92 of 128) Measurements 6) Writing Conversion Factors Learning Goal Write a conversion factor for two units that describe the same quantity. © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 93 of 128) Equalities on Food Labels The contents of packaged foods • are listed in both metric and U.S. units • indicate the same amount of a substance in two different units In the United States, the contents of many packaged foods are listed in both U.S. and metric units. © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 94 of 128) Writing Conversion Factors Equalities • use different units to describe the same quantity • can be between units of the metric system, or U.S. units, or between metric and U.S. units 1m = 1000 mm 1 lb = 16 oz 2.205 lb = 1 kg © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 95 of 128) Writing Conversion Factors Two Conversion Factors for the Equality 60 min = 1 h Numerator Denominator These conversion factors are read as 60 minutes per hour and 1 hour per 60 minutes. The per means “divide.” © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 96 of 128) Writing Conversion Factors © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 97 of 128) Metric Conversion Factors We can write conversion factors for any metric relationship. Both conversion factors represent the same quantity; one is just the inverse of the other. © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 98 of 128) Metric – U.S. System Conversion Factors We can write conversion factors between the U.S. system and metric quantities. © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 99 of 128) Conversion Factors with Powers Sometimes we can use a conversion factor that is squared or cubed. Distance = length Area = length × length = length2 Volume = length × length × length = length3 © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 100 of 128) Conversion Factors with Powers To square the equality 1 m = 100 cm, we square both the number and the unit on each side. Equality: 1 m = 100 cm Area: (1 m)2 = (100 cm)2 or 1 m2 = (100)2 cm2 Conversion factors: © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 101 of 128) Conversion Factors with Powers Both the number and the unit must be squared. © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 102 of 128) Learning Check Write conversion factors for each pair of units: A. liters and milliliters B. meters and kilometers © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 103 of 128) Solution Write conversion factors for each pair of units: A. liters and milliliters (1 L = 1000 mL) B. meters and kilometers (1 km = 1000 m) © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 104 of 128) Learning Check Write the equality and conversion factors for the relationships between the following units: A. grams – milligrams B. square inches – square centimeters © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 105 of 128) Solution Write the equality and conversion factors for the relationships between the following units: © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 106 of 128) Equalities, Conversion Factors in Problems An equality may also be stated within a problem that only applies to that problem. 1. The car travels at 85 km/h © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 107 of 128) Equalities, Conversion Factors in Problems 2. The tablet contains 500 mg Vitamin C. © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 108 of 128) Conversion Factors, Percentage Ppm and Ppb When scientists represent very small quantities, they use ppm and ppb. © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 109 of 128) Conversion Factors, Percentage Ppm and Ppb A percent (%) is written as a conversion factor by choosing a unit and expressing the numerical relationship of the parts of this unit to 100 parts of the whole. • For example, a person has 18% body fat by mass. • Equality: 18 mass units of fat per 100 mass units of body mass © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 110 of 128) Measurements 7) Problem Solving Using Unit Conversions Learning Goal Use conversion factors to change from one unit to another. © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 111 of 128) Problem-Solving Process The problem-solving process begins by analyzing the problem in order to • identify the given unit and needed unit • write a plan that converts the given unit to the needed unit • identify one or more conversion factors that cancel units and provide the needed unit • set up a calculation © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 112 of 128) Setting up the Problem Suppose you need to convert 18.2 mm to meters. • First, identify the given and needed units. Given: 18.2 mm Need: meters • Write a plan that will convert the given unit to the needed unit. millimeter Given Conversion factor meters Need © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 113 of 128) Setting up the Problem • Look for the connection between millimeters and meters. 1 m = 1000 mm • From this equality, we can write two conversion factors. © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 114 of 128) Setting up the Problem • Select the conversion factor that cancels the given unit, which is the millimeter. • Complete the calculation and round off to the needed significant figures. millimeters conversion factor meters © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 115 of 128) Guide to Problem Solving Using Conversion Factors © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 116 of 128) Learning Check • How many minutes are in 2.5 h? © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 117 of 128) Solution How many minutes are in 2.5 h? Step 1 State the given and needed quantities. Given: 2.5 h Need: minutes Step 2 Write a plan to convert the given unit to the needed unit. hours Given Conversion factor minutes Need © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 118 of 128) Solution How many minutes are in 2.5 h? Step 3 State the equalities and conversion factors. 1 h = 60 min Step 4 Set up the problem to cancel units and calculate. © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 119 of 128) Using Two or More Conversion Factors • Often, two or more conversion factors are required to obtain the unit needed for the answer. Unit 1 Unit 2 Unit 3 • Additional conversion factors are placed in the setup to cancel each preceding unit. Given unit × factor 1 × factor 2 = needed unit © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 120 of 128) Sample Problem How many minutes are in 1.4 days? Step 1 Given 1.4 days Need minutes Step 2 Plan days hours minutes Step 3 Equalities 1 day = 24 h 1 h = 60 min Conversion Factors © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 121 of 128) Sample Problem How many minutes are in 1.4 days? Step 4 Set up problem, cancel units. © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 122 of 128) Learning Check A bucket contains 4.65 L water. How many gallons of water is that? © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 123 of 128) Solution A bucket contains 4.65 L water. How many gallons of water is that? Step 1 Given 4.65 L Need gallons Step 2 Plan liters quarts gallons Step 3 Equalities 1 L = 1.057 qt 1 gal = 4 qt Conversion Factors © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 124 of 128) Solution Step 4 Set up problem, cancel units. © 2014 Pearson Education, Inc. The Academic Support Center @ Daytona State College (Chem-Up 1, Page 125 of 128) Time For Lesson 3 Unit Conversions & Dimensional Analysis The Academic Support Center @ Daytona State College (Chem-Up 1, Page 126 of 128) SNEAK PEEK…AGENDA FOR DAY 2 Atoms & Elements •Elements & Symbols •The Periodic Table •Atoms •Atomic # and Mass # •Isotopes •Valence Electrons •Ions The Academic Support Center @ Daytona State College (Chem-Up 1, Page 127 of 128) Questions Compiled by J. Picione (Chemistry Faculty) D. Leonard, R. Wendt, J. Brown, E. Scott, and A. Kandefer (Learning Specialists) The Academic Support Center @ Daytona State College http://www.daytonastate.edu/asc/ascsciencehandouts.html The Academic Support Center @ Daytona State College (Chem-Up 1, Page 128 of 128)
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