Hydrocarbon Gas Composition and Stable Isotopes Data and Interpretation Job #: Lab #: Client: Sample Name(s): 16090705 DIG‐009709 COGCC MC Farms 277080 ©2014 Dolan Integration Group, LLC, 2014 Analytical Report Job #: Lab #: Client: Sample Name: Date Sampled: Time Sampled: Sample Description: Sampling Notes: Date Received: Date Analyzed: Date Reported: Comments: 16090705 DIG‐009709 COGCC MC Farms 277080 09/20/16 1.:20 Water 09/21/16 Gas Composition: 9/22/16 10/25/16 Headspace created with UHP Helium Measured Values: Nitrogen (N2) Oxygen + Argon (O2+Ar) Carbon Dioxide (CO2) b Measured a HC 13C D ‰ VPDB ‰ VSMOW ‐ ‐ ‐ ‐ ‐ na nd nd d nd nd nd nd nd ‐ ‐ ‐ ‐ ‐ na ‐ ‐ ‐ ‐ ‐ ‐ ‐ ppm mol % mol % 430687 82.86 16.47 0.67 na nd 0.01 nd nd d nd nd nd nd nd ‐ ‐ ‐ ‐ ‐ 100.00 nd nd d nd nd nd nd nd 85627 3462 Helium (He) Hydrogen (H2) Methane (CH4) Ethane (C2H6) Propane (C P (C3H8) iso‐Butane (C4H10) n‐Butane (C4H10) iso‐Pentane (C5H12) n‐Pentane (C5H12) Hexanes + (C6H14) na nd 31 nd nd d nd nd nd nd nd Calculated Values: Total HCs (ppm) Gas Wetness (mol % C2+/C1+) C1/(C2+C3) (mol/mol) 31 0.00 #DIV/0! a Analyte Analyte concentrations normalized to 100% (Mol. % is approximately equal to Vol. % ) b Addition of helium negates the ability to detect native helium and may negate the ability to detect hydrogen. HC= Hydrocarbons nd = not detected na = not analyzed Stable isotope results based on multi‐point laboratory calibration Error 13C < 0.5 ‰ Error D < 5.0 ‰ ©2014 Dolan Integration Group, LLC, 2014 Comments Added Headspace Stable Isotope Interpretive Plots Methane 13C vs D Genetic Classification Plot Methane vs Gas Wetness Genetic ‐85 ‐110 MC Farms 277080 MC Farms 277080 80 ‐80 ‐100 ‐75 ‐90 ‐70 ‐80 Methane 13C (‰ ‰) Methane 13C (‰ ‰) ‐65 ‐60 ‐70 70 ‐55 ‐60 ‐50 ‐50 ‐45 ‐40 ‐40 ‐35 ‐30 ‐30 ‐20 ‐25 ‐10 ‐20 10 20 30 40 Gas Wetness (% C2+) 50 ‐400 400 60 ‐350 350 ‐300 300 ‐250 250 ‐200 200 Methane D (‰) Methane 13C vs C1/(C2+C3) Genetic Classification Plot 1.E+05 MC Farms 277080 1 E 04 1.E+04 1.E+03 C1/(C2+C3) 0 1.E+02 1.E+01 1.E+00 ‐100 ‐90 ‐80 ‐70 M th ‐60 ‐50 13C (‰) ‐40 ‐30 ‐20 ‐150 150 ‐100 100 Chain of Custody Form ©2014 Dolan Integration Group, LLC, 2014
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