SAFETY DATA SHEET
according Regulation EC No 1907/2006 and
Regulation EU No 453/2010
Date of issue:
Revision:
Date of revision:
BLACK ART INK
1.
1.1.
1.2.
15.3.2013
Page 1 of 8
Identification of the substance/mixture and of the company/undertaking
Product identifier
Product name:
Black art ink
Code K2:
Registration number:
V014176100000, V014170200000, V014172100000
not registered (mixture)
Relevant identified uses of the substance or mixture and uses advised against
Identified uses of the substance or mixture: For drawing and drafting on tracing and drafting
paper by retractable knife and flux cored pen, airbrush and paintbrush.
Uses advised against:
1.3.
Details of the supplier of the safety data sheet
Supplier identification
Trade name:
Address:
1.4
KOH-I-NOOR HARDTMUTH a.s.
F. A. Gerstnera 21/3, 370 01 České Budějovice
Závod 1, 289 03 Městec Králové
Vat number:
CZ 26055996
Phone number:
+420 325 643 241-2
E-mail:
[email protected]
Responsible person for the
Name:
Trade name:
Address:
Phone number:
E-mail:
1.4.
Not suitable for use in technical pens.
safety data sheet
Ing. Lukáš Trávníček
EKONOX, s.r.o.
V Ráji 501, 530 02 Pardubice
+420 466 415 010
[email protected]
Emergency telephone number
Emergency telephone number
+420 602 414 051 or Toxicological information centre, Na Bojišti 1, 128 08 Prague 2,
non-stop telephone 224 919 293, 224 915 402, or (only during the day 224 914 575)
2.
Hazards identification
2.1.
Classification of the substance or mixture
Mixture is not classified as a dangerous.
Classification of the mixture according Directive 67/548/EEC:
Danger property:
R-phrases:
-
Classification of the mixture according Directive 1272/2008/EC:
Danger property:
H-phrases:
-
The most important adverse physicochemical effects: not known
The most important adverse for human health:
not known
The most important adverse for the environment:
not known
Date of issue:
Revision:
Date of revision:
SAFETY DATA SHEET
according Regulation EC No 1907/2006 and
Regulation EU No 453/2010
BLACK ART INK
2.2.
15.3.2013
Page 2 of 8
Label elements
Mixture is not classified as a dangerous.
The mixture contains disodium tetraborate decahydrate (CAS 1303-96-4), which was placed on
June 18, 2010 at SVHC candidate list of substances.
Classification of the mixture according Directive 67/548/EEC:
Hazard pictogram(s):
not assigned
R-phrases:
S-phrases:
-
Classification of the mixture according Directive 67/548/EEC– packaging smaller than
125 ml :
Hazard pictogram(s):
not assigned
R-phrases:
S-phrases:
-
Classification of the mixture according Directive 1272/2008/EC: obligation of classification since
1.6.2015
Hazard pictogram(s):
Signal word:
H-phrases:
P-phrases:
2.3.
-
Other hazard
not known
3.
Composition/information on ingredients
3.1.
Substance
Product name:
Registration number:
product is the mixture
Other identification data of substance:
3.2.
CAS
ES
Chemical name
Concentration
-
-
-
-
Classification
according
67/548/EEC
-
Classification
according
1272/2008/EC
-
Mixtures
Product name:
Registration number:
Chemical characteristic:
Black art ink
not assigned, mixture
Mixture of shellac and casein water solution with dye.
Other identification data of substances:
The mixture contains disodium tetraborate decahydrate (CAS 1303-96-4), which was placed on
June 18, 2010 at SVHC candidate list of substances.
SAFETY DATA SHEET
according Regulation EC No 1907/2006 and
Regulation EU No 453/2010
Date of issue:
Revision:
Date of revision:
BLACK ART INK
15.3.2013
Page 3 of 8
Classification
Classification
according
according
67/548/EEC
1272/2008/EC
Irritant (R36),
Repr. cat. 1B
disodium
(H360), Eye
Toxic for
1303-96-4
005-011-01-1
tetraborate
2 % by weight*
Irrit. cat. 2
reproduction
decahydrate
(H319)
(R60, 61)*
* In accordance with the requirements of EC Regulation No. 1272/2008 is the use of R60-61 for C ≥ 8.5%
CAS
EC
Chemical name
4.
First aid measures
4.1.
Description of first aid measures
General information:
Inhalation:
Skin contact:
Contact with eyes:
Ingestion:
Concentration
Symptomatic treatment. In case of health problems consult a doctor.
Remove person from contaminated area to fresh air. In case of non-standard
expressions seek physician.
Wash with plenty of soap and water. In case of non-standard expressions
seek physician.
Immediately flush eyes with plenty of flowing water minimally 15
minutes holding eyelids apart. Check and removal of contact lenses.
Seek physician.
Let to drink plenty of water, do not provoke vomiting. Seek physician
immediately.
Other data:
Other information concerning the delivery of first aid measures, especially in serious cases of health
damage, the attending physician can consult the procedure with Toxikologické informační středisko, Praha,
Czech Republic, phone (continually): +420 224 919 293, 224 915 402, fax 224 914 570.
4.2.
Most important symptoms and effects, both acute and delayed
Not known
4.3.
Indication of any immediate medical attention and special treatment needed
See section 4.1
5.
Firefighting measures
5.1.
Extinguishing media
Suitable extinguishing media:
Foam, dry chemical powder, carbon dioxide, water spray jet
Unsuitable extinguishing media:
Not known.
5.2.
Special hazards arising from the substance or mixture
Not known.
5.3.
Advice for firefighters
Depending on character of fire use protective clothing and self-breathing apparatus.
6.
6.1.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
For non-emergency personnel:
Use suitable personal protective equipment. Handle in accordance with good industrial hygiene and safety
practice.
For emergency responders:
Depending on character of fire use protective clothing and self-breathing apparatus, ev. other protective
SAFETY DATA SHEET
according Regulation EC No 1907/2006 and
Regulation EU No 453/2010
Date of issue:
Revision:
Date of revision:
BLACK ART INK
15.3.2013
Page 4 of 8
personal means.
6.2.
Environmental precaution
Prevent spreading of spilled preparation into drains/surface water/ground water.
6.3.
Methods and material for containment and cleaning up
Methods of contaiment of leakage:
Not required.
Methods for cleaning up:
Remove spilled product with sorbent, which then store in container labeled as waste. See section 13.
Other information:
Are not to disposition
6.4.
Reference to other section
See Section 8 and 13.
7.
Handling and storage
7.1.
Precautions for safe handling
Do not smoke, drink and eat. Use suitable personal protective means. After work and always before
eating, drinking, smoking and using toilet wash your hands thoroughly with soap and water.
7.2.
Conditions for safe storage, including any incompatibilities
Store in a tightly closed labelled container, protect them from damage. Store in original containers or in
containers provided for this purpose. Do not expose the product freeze.
Incompatible materials: Not known.
7.3.
Specific end use(s)
See point 1.2.
8.
Exposure controls/personal protection
8.1.
Control parameters
The mixture not includes substances for which the following occupational concentration limits
are set (NV361/2007 Coll., as amended) (maximum permissible exposure limit = PEL; maximum
permissible concentration = MPC).
8.2.
Exposure control
Appropriate engineering controls:
Provide good ventilation of working area (local exhaust ventilation, if necessary).
Do not smoke, drink and eat. After the work is always thoroughly wash and treat with a suitable skin
cream.
Individual protection measures, such as personal protective equipment:
Eye/face protection:
Safety glasses/face shield
Skin protection:
Suitable protective gloves, protective clothing, footwear.
Respiratory protection: In case of good ventilation is not required.
Thermal hazard:
Not known.
Environmental exposure controls: Prevent contamination of soil and water.
9.
Physical and chemical properties
9.1.
Information on basic physical and chemical properties
Appearance:
Odour:
Odour threshold:
black liquid
weak
not determined
SAFETY DATA SHEET
according Regulation EC No 1907/2006 and
Regulation EU No 453/2010
Date of issue:
Revision:
Date of revision:
BLACK ART INK
pH:
Melting point/ freezing point:
Initial boiling point and boiling range:
Flash point:
Evaporation rate:
Flammability (solid, gas):
Upper/lower flammability or explosive limits:
Vapour pressure:
Vapour density:
Relative density:
Solubility:
Partition coefficient: n-octanol/water:
Auto-ignition temperature:
Decomposition temperature:
Viscosity:
Explosive properties:
Oxidising properties:
9.2.
15.3.2013
Page 5 of 8
7,5 – 8,5
data are not available
data are not available
data are not available
data are not available
not flamable
not explosive
data are not available
data are not available
data are not available
miscible with water
data are not available
data are not available
data are not available
data are not available
data are not available
data are not available
Other information
Data are not available.
10.
Stability and reactivity
10.1. Reactivity
Product is not reactive under normal conditions of use.
10.2. Chemical stability
Product is chemical stable under normal conditions of use.
10.3.
Possibility of hazardous reactions
Not known.
10.4. Conditions to avoid
Do not expose the product freeze.
10.5. Incompatibles materials
Not known.
10.6. Hazardous decomposition products
Under normal conditions of storage and use, there is no formation of hazardous decomposition products.
11.
Toxicological information
11.1. Information on toxicological effects
Acute toxicity:
Skin corrosion/irritation:
Serious eye damage/irritation:
Respiratory or skin sensitisation:
Germ cell mutagenicity:
Carcinogenicity:
Reproductive toxicity:
STOT-single exposure:
STOT-repeated exposure:
Information on likely routes of exposure:
data are not available
data are not available
data are not available
data are not available
data are not available
data are not available
data are not available
data are not available
data are not available
SAFETY DATA SHEET
according Regulation EC No 1907/2006 and
Regulation EU No 453/2010
Date of issue:
Revision:
Date of revision:
BLACK ART INK
15.3.2013
Page 6 of 8
Not determined
Symptoms related to the physical, chemical and toxicological characteristics:
Not known.
Delayed and immediate effects as well as chronic effects from short and long-term exposure:
Not known.
12.
Ecological information
12.1. Toxicity
Data are not available.
12.2. Persistence and degrability
Data are not available.
12.3. Bioaccumulative potential
Data are not available.
12.4. Mobility in soil
Data are not available.
12.5. Results of PBT and vPvB assessment
Assessment was not carried out.
12.6. Other adverse effects
Not known
13.
Disposal considerations
13.1. Waste treatment methods
Substance treatment methods:
Product has to be disposed in accordance with law of wastes in valid version and with
connecting on legal directives.
Contaminated container treatment methods:
Contaminated container has to be disposed in accordance with law of wastes in valid version
and with connecting on legal directives.
Other information:
Not known.
14.
Transport information
14.1. UN number
The product is not classified as hazardous for transport.
14.2. UN propper shipping name
14.3. Transport hazard class(es)
14.4. Packing group
14.5. Environmental hazards
-
SAFETY DATA SHEET
according Regulation EC No 1907/2006 and
Regulation EU No 453/2010
Date of issue:
Revision:
Date of revision:
BLACK ART INK
15.3.2013
Page 7 of 8
14.6. Special precautions for user
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
14.8. Other information
15.
Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
REGULATION (EC) No 1907/2006 of 18 December 2006 concerning the Registration, Evaluation,
Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency,
amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission
Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives
91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC
REGULATION (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008
on classification, labelling and packaging of substances and mixtures
COMMISSION REGULATION (EU) No 453/2010 of 20 May 2010 amending Regulation (EC) No
1907/2006 of the European Parliament and of the Council on the Registration, Evaluation, Authorisation
and Restriction of Chemicals (REACH)
CZECH NATIONAL LEGISLATION (Safety, health and environmental regulations):
Act no. 350/2011 Coll., on chemical substances and chemical preparations
Decree No. 402/2011 on the assessment of the hazardous properties of chemical substances and
mixtures, and packaging and labeling of dangerous chemical compounds
15.2. Chemical safety assessment
It has been not done, mixture.
16.
Other information
List of relevant R- and S-phrases (Sections 2. and 3.):
R 36
Irritating to eyes.
R 60
May impair fertility.
R 61
May cause harm to the unborn child.
S
-
List of relevant H- and P-phrases (Sections 2. and 3.):
H 319
H 360
Causes serious eye irritation.
May damage fertility or the unborn child.
P- phrases
-
Advices for training:
Acquaint the workers with this Safety Data Sheet and with general rules of handling with chemical
substances/ mixtures. Training carry out once time per year.
The details in this safety data sheet are based on our status of knowledge and experience at the time of
date issue. They are not a contractual assurance of quality properties of the product, and they apply only in
SAFETY DATA SHEET
according Regulation EC No 1907/2006 and
Regulation EU No 453/2010
Date of issue:
Revision:
Date of revision:
BLACK ART INK
15.3.2013
Page 8 of 8
conjunction with correct and proper handling of the product under normal conditions, and according to the
details of specified use on the packing and/or in the technical instructions. The user himself is fully
responsible for every other use of the product such as in combination with other products or with other
processes.
Wellspring of information for elaboration of Safety Data Sheet:
Safety Data Sheets of raw materials
MSDS Tuš umělecká černá, 15.3.2013, supplier KOH-I-NOOR HARDTMUTH a.s.
Database of registered substances ECHA (www.echa.eu) for 15.3.2013
Regulatory information (see 15.1)
Abbreviations:
UVCB
Unknown or variable composition
PBT
Persistent, bioaccumulative and toxic
vPvB
Very persistent and very bioaccumulative
REACH
Registration, Evaluation, Authorisation and Restriction of Chemicals
CSR
Chemical Safety Report
ECHA
European Chemical Agency
PEL
Permissible exposure limit
NPK-P
Maximum avalaible concentration
BCF
Bioconcentration factor
CAS
Chemical Abstracts Service
EINECS
Existing Commercial Chemical Substance
DNEL
Derived No Effect Level
PNEC
Predict No-Effect Concentration