Advection, 317 Alkalinity, definition, 67 Anions, control mechanism, 287 Antarctic bottom water (AABW) , 337 Anthropogenic tracers, 383 AOU: definition, 131 distribution, 131 Aragonite, solubilities, 63-64 Argon-39, deep sea ventilation, 377 Authigenic mineral, 45 formation of, 295 Barium: geographic pattern, 30 mean lifetime, 21 removal, 11 Benthic boundary layer, 88 Biogenic sediments: calcite, 47 opal, 47 Biointermediate constituents, 6,8,22 Biolimiting constituents, 6 Bioturbation, sediment, 257,562 Biounlimited constituents, 6,8 Boundary stagnant film: sea-air interface, model, 113 sediment-water interface, 86-88 Bubble entrainment, 127,130 Buoyancy flUX, 329 Cadmium, distribution in the sea, 216,218,222 Calcite: biogenic, 47 changes, glacial-interglacial, 456 compensation depth, 100 degree of saturation, 61 distribution in marine sediment, 58 pore water resaturation time, 84 solubilities, 63 solution, bioturbation model, 487 683 solution, controlling factors, 84 solution rates, 269 storage, compensation time, 456-457 Carbon: control mechanism, 280 fixation, ratio organic to CaCD3, 476 reservoir sizes, 455 Carbon-13: fractionation, 306 glacial-interglacial, 451-454,473 marine geochemistry of, 306 phosphate changes, 466 planktonic forams, 470 tree ring, 538 units, 306 . Carbon-14 (see Radiocarbon)' Carbon dioxide: anomalies, equatorial Pacific, 158 anthropogenic production, 500,501 atmospheric time history, 535 concentration in surface water, 149-150 equilibration times, 155 excess, equatorial surface water, 430 fossil fuel (see fossil fuel C02) future levels, prediction, 550 ice cores, 445 potential partial pressure, 161,443 release, forest & soil, 502-503 solubilities in sea water, 111,112,151,152 Carbonate chemistry, 69 Carbonate ion, variation, 62 Carbonate saturation: horizon, 71 spacial variation, 71 Carbonic acid: 1st apparent dissociation constants, 151,152 2nd apparent dissociation constants, 151,152 Calcium: distribution, 11 mean lifetime, 21 Cations, control mechanism, 289 Characteristic penetration depth, 319 Chemical composition: hydrothermal vents, 292,294 river and sea, 26-27, 290 saline lake, 293 Circulation pattern, deep water, 32,33 Conservative property, 334 Continental runoff, rate of, 247 Copper, distribution in the sea, 216,218,222 Dating: beryllium, 264 magnetic reversals, 267 684 potassium-argon, 264 radiocarbon, 255 uranium-helium, 312 uranium series, 257 Deep water, sources, 334 Denmark Straits Overflow Water (DSW), 335 Density gradient, 327-331 Detrital material, 45 Detritus accumulation rate, 45 Diapycnal mixing, 322,324 Diffusion, deep water, 317,319 Distribution coefficient, 230 e-folding time, 457 Element budget, earth's crust, 166,167 Element concentrations, river and ocean, 26-27, 290 Element, hydrolysis constants, 231 Element, removal times, 231 Film replacement model, 118 Flushing time, deep sea, 370 Foram, solution index, 98 Fossil fuel, reserves, 506 Fossil fuel C02: atmospheric levels, prediction, 550 calcite solution, 552 oceanic uptake, capacity, 511 oceanic uptake, kinetics, 524 oceanic uptake, numerical model, 526,529 production, 500, 501 Gas exchange rate, 113 Gas flux, 116 Gases: diffusivit s in sea water, 119 equilibrium concentration in surface water, 114 solubilities in sea water, 112, 113 volume partition coefficient, 112, 113 Gibbs Fracture Zone Water (GFZW), 337 Helium: excess, 147 hydrothermal vents, 295 Helium-3: anomalies, 149 distribution, deep Pacific, 331 distribution, thermocline, 432 Hydrothermal vents, 292,294 Igneous rocks, chemical compOSition, 167 Inorganic carbon, total dissolved, 67 Input rates, river to sea, 25 Iron, transport in the sea, 226 685 Isopycnal mlxlng, 322,324 Isopycnal surface, 322,391,392 Isotope fractionation, carbon, 236 Isotope ratios in reactive metals, 221 Keeling fraction, 514 Labrador Sea Water (LSW), 337 Lead: distribution in the sea, 218-222 isotope ratios, 223,226,227 Lead-210: depth profile, 174 distribution, 189 excess, sediment, 562-563 fallout rates, 191 production rates, 191 scavenging time, 189,199 Lysocline: definition, 75 glacial-interglacial, 485 transition zone, 89 Manganese, transport in the sea, 226 Manganese nodules, 98 Metal transport, model, 205 Mixing rates, deep sea, 325 Model: advection-diffusion, sea water, 318 biolimiting constituents, 15 stagnant film, 113 Mole, definition, 17 Molecular diffusion coefficients, 116,119 Neodymium, isotope ratios, 223-226 Nickel, distribution in the sea, 216,218,222 Nitrate: control mechanism, 284 consumption (denitrification), 142 distribution of, surface water, 47 geographic pattern, 31 Nitrous oxide cycle, 139 Northern Component Water (NCW): definition, 335 conservative properties of, 340, 341 feed for, 345 radiocarbon in, 343 Nutrient gradients in the deep sea, 312 Ocean chemistry, glacial-interglacial, 467 Oeschger model, 526 Opal: biogenic, 47 diffusion coeffiCient, pore water, 55 686 distribution of, 47 rain rate, 56 resaturation time, pore water, 55 solution rate, 49,56 Organic carbon in sediments, 47 Organic matter, chemical composition of, 8 Oxygen: concentration, surface water, 127 consumption, respiration, 134 control mechanism, 284 deficiencies, deep water, 131 deficiencies, surface water, 131 excess, photosynthesis, 127 geographic pattern, 31 glacial deep water, 484 Oxygen-18: in forams, 446-447 Outcropping isopycnals, 322 Paleolysocline, 98 Paleoocean: chemistry, recorder of, 301 indicator, 301,311 Particulate matter, composition of, 13 Partition coefficient, 384 Phosphate: changes, causes of, 479 changes, glacial-interglacial, 466 control mechanism, 275 Phosphorus: input rate, 25 mean lifetime, 20,21 residence time in mixed layer, 20 scavenging time, 175 Piston velocity, 121 Plant productivity, 130 Plutonium, distribution, 203 Polonium-210, distribution, 198 Potential temperature, 3,111 Potential C02 partial pressure, 161,443 Preformed values, 131 Protactinium-231: 231pa/230Th ratio, 184,189 rain rate, 186,187 Radiocarbon: 14C/C ratio definition, 245 cycle, deep sea, 368 decline, fossil fuel, 544 distribution in the sea, 245 production, temporal variation, 374 production rates, 236-238 production, sun-spot, 544 Radiocarbon, bomb-produced: distribution, thermocline, 412 687 distribution, surface water, 415 time history, air, 389 time history, surface sea, 389 Radium: marine geochemistry, 13 226 Ra , distribution, 200-203 226 Ra , flux from sediments, 204 226 Ra / Ba ratio, model distribution, 245 228 Ra , deep sea, 326 Radon-222, deep sea, 326 Red clay: definition, 45 chemical composition, 167 Redfield ratio, 9 Removal model, radionuclides, 171 Residence time, definition, 25 Revelle factor, 158,519 Salinity: controlling factors, 289 changes, glacial-interglacial, 448 Saturometer, 80,83 Scavenging constant, 171 Scavenging times, 172 Sea salt composition, 2 Sediment mixing, 562 Sediment recycling, model, 212 Sedimentation rates, methods, 253 Selenium, distribution of, 22 Shale, chemical composition, 167 Silica: (see als 0 Opal) atom ratio, mean sea water, 11 control mechanism, 280 distribution, surface water, 47 geographic pattern, 30 N-S vertical sections, 36-38 Solubilities of gases, 111,112 Southern component water (SeW), 349,359 Stagnant film: model, sea-air interface, 113 sediment-water interface, 562 thickness, radiocarbon method, 118 thickness, radon method, 122 Steady state, definition, 17 Strangelove ocean, 466, 472 Strontium, 13 Strontium-90: corals, 412,413 delivery mechanism, 385 deposition rate, 386 Suess effect, 544 Sverdrups, 382 Temperatures, glacial-interglacial, 446 688 Termination I, II, 454 Thermocline: definition of, 15 hydrology of, 388 Thorium: activities, 170 isotopes in the sea, 172-184 scaven~ing times, 175 228Th/ 28 Ra ratio, 175-179 Thorium-230: distribution coefficient, deep Pacific, 181 profile in sea water, 180 rain rate, 186,187 Trace metal, distribution, 215 Tracers, diapycnal and isopycnal mixing, 324 Tracers, purposeful, 438 Tritium: delivery mechanism, 384, 385 delivery rates, 386 distribution, thermocline, 399 penetration depth of, 402,403 temporal trends, 402 vertical distribution, 409 Two-box model, 15,240 Two-degree discontinuity (TDD) , 359 Upwelling: distributiton of, 158,319 bomb l~C, 422 carbon dioxide anomaly, 427 evidence for, 397 rates of, 425,429 Uranium content: of coral, 311 of saline lakes, 311 Uranium series, activities, 170 Ventilation of deep sea: source areas, 312,317 deep Atlantic, 359 deep Indian, 365 deep Pacific, 365 Vertical mixing, rate of, 236-243 Vital effect, 468 Volatile elements, distribution of, 288 Weddell Sea Bottom Water (WSBW), 353 Zinc, distribution in the sea, 216,218 689
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