Borehole Paleothermometry Uses a calibrated thermistor suspended on a cable. Obtained from boreholes drilled in continental rock and ice sheets Terrestrial Boreholes: The temperature profile through a terrestrial borehole is influenced by ground surface temperature, subsurface fluid flow, vertical and lateral inhomogeneities in bedrock properties, snow cover, and variable topography Ice Sheet Boreholes: The temperature profile through an ice sheet provides a record of past air temperature, modified by heat diffusion and ice flow, and by the small and well characterized heat generation from ice deformation Borehole Paleothermometry Because temperature changes at the surface affect the distribution of temperature in the subsurface, ground temperatures comprise an archive of signal of past climate. http://www.ncdc .noaa.gov/paleo/borehole/approach.html 1 Calibrating Greenland δ 18O using borehole measurements δ18 O = αTs + β Optimal model: δ18 O = 0.327Ts – 24.8 Smoothed curve: isotope history is filtered to mimic the thermal averaging in ice sheets Cuffey et al., 1995 Calibrating Greenland ∆T using borehole measurements 0.5‰/°C for Holocene, and 0.33‰/°C for glacial ∆T glacial-interglacial > 20°C Uses a forward thermal model incorporating conductive and advective heat fluxes, forced by T = aδ18O +b. Invert for optimal values of a and b by comparing model equation solutions with borehole T data (estimated error is ±0.001‰/°C for a, and ± 0.05‰ for b) Cuffey et al., 1995; Johnsen et al ., 1995 2 Terrestrial Borehole Paleothermometry Huang et al., 2000 The numbers of boreholes on each continent are respectively 245 (North America), 16 (South America), 146 (Europe), 92 (Africa), 60 (Asia), and 57 (Australia). 1.0 K warming over past 500 years (1.2 K NH, 0.8 K SH), 0.5 K in 20th century alone à generally higher than other proxy based estimates Shaded areas represent 1 standard error about the mean. Superimposed are the corresponding series of instrumental surface air temperatures (SAT) Comparison with other proxy indicators Mann et al., 2003 Huang et al. [2000] borehole show NH T increases of ~1 K over the past 500 years Mann et al. [2003] “optimized” borehole show NH T increases of ~0.5 K over the past 500 years 3 Advantages/Disadvantages of Borehole Paleothermometry Advantages: “Direct” temperature study Extensive geographic coverage (tens of thousands of boreholes throughout the world) Can be used to calibrate other paleoclimatic indicators Disadvantages: Low resolution and comparatively “short memory” Signal damped by heat diffusion processes and do not contain high frequency details Relationship between surface and below-ground temperature is not simple, and varies geographically Ability to resolve details of the surface temperature history diminishes with time Noble Gas Paleothermometry in Groundwaters Atmospheric noble gas abundances and isotope ratios have remained essentially constant for at lest the last 3 million years [Phillips, 1981] He is not used because of sources in the aquifer related to α decay of U and Th. 4 Temperature dependence of solubility High temperature sensitivity The dissolved noble gas concentration ratios of water in solubility equilibrium with the atmosphere deviate significantly from those in the atmosphere as a result of the different solubilities of different gases. Low temperature sensitivity Stute et al., 1992 Ground water dynamics Gases exchanged continuously between water and ground air Gas exchange is limited to diffusion across the water table in the saturated zone 5 Noble gases record mean annual temperature at the water table Below 10 m, there is almost no seasonal variation (Ta < 0.2°C) Stute and Schlosser, 1993 “Excess Air” Noble gas concentrations are determined mainly by: 1) Solubility equilibrium (temperature) 2) Amount of “excess air” “Excess air”: Dissolution of small air bubbles by very rapid infiltration or fluctuation of the water table. Assumed that gases of excess air are not fractionated relative to the atmosphere (unlike due to solubility) à can correct for excess air component using a set of equations with the ground T and amount of excess air as unknowns (1 − F ) Az C (T , S, P, A, F ) = C (T , S , P ) + FAz 1+ C * i i t i * t i = Ne, Ar, Kr, Xe; T = temperature, S = salinity, P = atmospheric pressure, A = initial amount of excess air, F = fraction of excess air, zi = noble gas fractions in dry air, C *t = solubility equilibrium concentrations as a function of T, S, and P 6 Dating Groundwater 14C dating up to ~30,000 ya •May be biased high (old) due to secondary exchange with CaCO3 minerals (can estimate using measured variables such as alkalinity, total dissolved carbon, and δ13 C) •Error of ±2,000 years 14C: •Sufficient for last glacial – present interglacial differences τ1/2 = 5730 years ∆Tglacial-interglacial using noble gas paleothermometry 9°C 5.4°C 5.5°C 7 Advantages/Disadvantages of Noble Gas Paleothermometry Advantages: Based on a simple physical principle (temperature dependence of the solubility of noble gases in water) Reflects mean annual temperature Accuracy of ~±0.5°C (1 σ error) Disadvantages: Uncertainty of 14C dating in groundwater Loss of high frequency climate signals due to dispersion during transit (low temporal resolution) à used to determine reliable temperature differences between the last glacial and present interglacial which can be used to calibrate other paleothermometers with higher time resolution. Dendroclimatology The use of tree rings as a proxy indicator of climate Earlywood (light): large, thin-walled cells Latewood (dark): densely packed, thickwalled cells 1. variation in total ring width: a light and a dark band 2. variation in latewood width: just the dark bands 3. variation in latewood density: darkness of dark band Variation in these rings is due to variation in environmental conditions when they were formed. Thus, studying this variation leads to improved understanding of past environmental conditions and is the basis for many research applications of dendrochronology. from the Univ. of Arizona’s Laboratory of Tree Ring Research 8 Principles of Dendroclimatology The principle of limiting factors: states that rates of plant processes are constrained by the primary environmental variable that is most limiting e.g., precipitation is often the most limiting factor to plant growth in arid and semiarid areas. e.g., in the higher latitudes, temperature is often the most limiting factor that affects tree growth rates. The principle of site selection: This principle states that sites useful to dendrochronology can be identified and selected based on criteria that will produce tree-ring series sensitive to the environmental variable being examined. http://web.utk.edu/~grissino/principles.htm Calibration of Tree Ring Data The principle of aggregate tree growth: Any individual tree growth series can be decomposed into an aggregate of environmental factors that affected the patterns of tree growth over time. Rt = At + Ct +δD1t + δD2t + Et t = any one year; A = age related growth trend due to normal physiological aging processes; C = climate; D1 = disturbance factors within the forest stand; D2 = disturbance factors from outside the forest stand (e.g. insects); δ = 0 for no disturbance, 1 for a disturbance; E = random error processes not accounted for in the other processes Climate (C) = f(sunshine, precipitation, temperature, wind speed, humidity, and their distribution throughout the year) Principle components analysis is used to select variables that account for most of the variance in the measured data. http://web.utk.edu/~grissino/principles.htm 9 Sample collection Coring a live tree Sampling a dead tree Archeological samples http://web.utk.edu/~grissino/gallery.htm Dating Tree Rings Ring counting is done by crossdating •matching ring-growth characteristics across many samples from a homogeneous area (area of similar environmental conditions) •permits identification of exact year of formation for each ring •Can eliminate errors from: Locally absent rings and false bands http://www.ltrr.arizona.edu/skeletonplot/introcrossdate.htm 10 The Principle of Crossdating The procedure of matching ring width variations among trees that have grown in nearby areas, allowing the identification of the exact year in which each ring formed. Nash, 2002 Climatic Information Climate information is obtained from measurements of: 1) Ring width 2) Ring density (measured on x-ray negatives of prepared core sections) 3) Isotopic variations The 3 approaches are complementary from Bradley, 1999 11 Uniformitarian Principle This principle states that physical and biological processes that link current environmental processes with current patterns of tree growth must have been in operation in the past. In other words, "the present is the key to the past”. Precipitation reconstruction for Northern New Mexico Calibration period Rigorous statistical methods are used to determine the relations hip between climatic variables and the proxy. Temperature Reconstructions Land only extratropical expression of NH temperature variability Anomalies from 1900-1999 instrumental mean Recent annual temperatures have exceeded earlier reconstructed warm intervals by ~0.3ºC Cook et al ., 2004 12 Temperature Reconstructions Based on tree ring width and density data “Late 20th century warmth is unprecedented at hemispheric, and likely, global scales” Jones and Mann, 2004 Isotope Dendroclimatology Empirical studies have demonstrated that variations in the isotopic content of tree rings (δ13 C, δ18O, δD) can be highly correlated to climate. For example, δD in modern plants is strongly correlated with δD in associated environmental waters. δD in plants can provide a proxy for spatial variations in δD of meteoric precipitation, assuming this holds constant over time. Problem: additional isotopic fractionation occurs within trees during the synthesis of woods material and these biological fractionations are themselves dependent on many factors, including temperature, humidity, and wind speed. 13 Advantages/Disadvantages of Dendroclimatology Advantages: Through cross-dating of multiple cores, the absolute age of a sample can be established (unique in this way). Long tree ring series are so accurate that they are used to calibrate the radiocarbon scale. Disadvantages: Limited in time (up to several millenia) Biological processes within the tree are extremely complex, making interpretation difficult CO2 fertilization effect? Snow Lines (Glacial Moraines) Moraines = bodies of glacially eroded and transported rock left behind when a body of ice advances and then retreats http://www.fettes .com/Cairngorms/moraine.htm 14 Glacier Fluctuations Glacier fluctuations result from changes in the mass balance of glaciers à Increases in net accumulation leads to glacier thickening and advance àIncreases in net ablation leads to glacier thinning and recession (Ablation = reduction in volume of glacial ice by the combined processes of melting, evaporation and calving ) There are many climate conditions which can lead to a net change in glacier mass balance Glacier Response Time Changes in mass balance are not immediately transformed into changes in glacier front positions. Glacier front positions will lag behind climatic fluctuations with varying response times (10s of years to millenia). The response time depends on a number of factors including the glacier length, basal slope, ice thickness and temperature, and overall geometry of the glacier itself. Glacier front variations are thus a rather complex integration of both short and long term climatic fluctuations, so that one should not be surprised to see some larger glaciers (longer response times) advancing at the same time that smaller glaciers (shorter response times) are retreating. The south cascade glacier (WA) has a response time of 25-30 years 15 Dating Glacial Moraines Absolute dating: 14C dating of organic material in sediments (in some cases not much organic material present) Surface exposure dating: 10Be, 26Al, and rock surfaces (102 to 107 years) 36Cl surface exposure dating of Terrestrial in situ cosmogenic nuclides (TCN) (distinct from nuclides produced in the atmosphere) Gosse and Phillips, 2001 Problems with surface exposure dating Atmospheric/meteoric contamination: Erosion will make it appear younger than it is must take steps to ensure the atmospheric component doesn’t contaminate the terrestrial component e.g. 10Be is produced in the atmosphere ~103 times greater than the average rate of production in rocks on Earth, and is highly reactive with mineral surfaces (in contrast to 36Cl) Gosse & Phillips, 2001 16 Some considerations for surface exposure dating Estimating production rates via geological calibration, experimentally, and numerical simulation can give very different results Snow coverage Must determine altitude and latitude dependence Shielding of sloping surface (topographic obstructions) Surface coverage (snow, sand, soil, peat) Surface exposure dating with 26Al, and 36Cl 10Be, Gosse & Phillips, 2001 17 Last Glacial Maximum Climate The boundary between elevations where snow and ice persist for the entire year and elevations experiencing only seasonal snow cover corresponds roughly to the position of the mean annual 0ºC isotherm. 950 ± 70 m Using today’s lapse rate of 5°C km-1, estimate ~5°C cooler in LGM than today 45°N 45°S Figure from “ The Glacial World According to Wally” Problems Interpreting Paleotemperatures from Snowlines Difficulty in identifying the response of snowlines to temperature Snowline elevation also depends on: - Variation of accumulation with elevation (accumulation gradient) - Radiation balance - Wind speed - Humidity - Variation of albedo with temperature Lapse rates – may not be a reasonable assumption to use modern lapse rates, as both temperature and moisture conditions in the past would have been different from today. Imprecise dating of glacial deposits Snowlines in different regions are controlled by different climatic parameters and that these must first be understood in order to use paleosnowlines in paleoclimatic reconstructions. 18 Pollen Analysis (Palynology) Where pollen has been preserved over time, in lakes, bogs, estuaries, etc., it provides a record of past vegetation changes that may be due to changes in climate. Methods: requires rigorous chemical treatment by hydrochloric, sulfuric and hydrofluoric acid. Pollen grains and spores are stained and mounted on slides for microscopic analysis. Uniformitarian principal: By using spatial relationships in modern pollen distribution and their relationship to modern climate as a guide to interpreting pollen patterns recorded in the past, paleoclimatic reconstructions can be made. Paleoclimatic Reconstruction using Pollen Grains 4 basic attributes of pollen grains making paleoclimatic reconstruction possible: 1) they possess morphological characteristics that are specific to a particular genus or species of plant 2) they are produced in vast quantities by wind-pollinated plants, and are distributed widely from their sources 3) they are extremely resistant to decay in certain sedimentary environments 4) they reflect natural deposition at the time of pollen deposition Pollen falling on sites where organic or inorganic sediments are accumulating will become part of the stratigraphic record. The principal sources of paleoclimatic information are peat from bogs and marshes. 19 Dating and Resolution Dating: • 14C analysis Resolution: •Time lag response of vegetation to climate change on the order of 100-1500 years à represents a running mean of climatic variation •Complications due to burrowing worms and other mud dwellers, or resuspension and redeposition during periods of turbulent mixing Pollen Diagram A pollen spectrum consists of the number of different pollen grains at a particular level expressed as a percentage of the total pollen count. In the pollen diagram, changes in the percentage of one species are assumed to reflect similar changes in the vegetation composition. 20 Quantitative Paleoclimatic Reconstructions More quantitative reconstructions of past climate can be obtained by mathematically relating modern climatic conditions to modern pollen rain, and using these relationships to convert the fossil pollen record into specific paleoclimate estimates. Multiple linear regression of modern conditions: Cm = Tm *Pm (m = modern) Cm = modern climate data; Tm = transfer function; Pm = modern pollen rain Former climatic conditions use modern transfer function: Cf = Tm *Pf (f = fossil) Quantitative Paleoclimatic Reconstructions Relationships not always linear July Tmean (ºC) = 17.76 + 1.73(Quercus)0.25 + 0.09(Juniperus) + 0.51(Tsuga)0.25 – 0.41(Pinus)0.5 – 0.12(Acer) – 0.04(Fagus) As more pollen types are added, the number of possible climate options becomes more limited. Bartlein et al . [1984] July temperatures 6 ka BP over the north-central US and southern Canada were 1-2ºC warmer than modern temperatures 21 Advantages/Disadvantages of using Pollen for Paleoclimatic Recontstruction Advantages: Large databases of surface pollen are available covering a large geographical range Pollen analysis can provide climate information and, in archeological sites, can be used to understand human activities. Disadvantages: Must eliminate anthropogenic interferences such as disturbance and CO2 fertilization. No-analogue problem (uniformitarian principle may not apply) Vegetation responds to many climate (temperature, precipitation,soil moisture) and non-climate variables (humans, insect infestations, fire, plant successional change) Pollen spectra may depend on preceding vegetation state, as well as climate variables (autocorrelation in that is not accommodated by the transfer or response function approaches) 22
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