Where is the equator? A definition based on atmospheric composition and its chemical implications Christopher Holmes - Florida State University Michael Prather - UC Irvine Methane ? ? CFC-11 ? HIPPO I, Jan 2009 (Wofsy et al., 2011,Wecht et al., 2012) ? ITCZ = Atmospheric equator Textbook picture of ITCZ • Surface convergence • Convection & Rainfall • Divergence in upper troposphere Real circulations • Variation across meridians • Double/Complex ITCZ • Regions without deep convection • ITCZ ill-defined over land (Satymurty et al., 1998) • Surface convergence ≠ Rainbelt (Nicholson et al., 2009) NOAA GridSat, Knapp et al., 2011 Hemispheric tracers defined Emissions: e90N, e90S – Constant, 90-day lifetime “Atmospheric equator”: where e90N = e90S Model: Meteorology: UCI CTM ECMWF (cy. 36) T42 (~2.8°) Sample Days Surface-layer hemisphere tracers Atmospheric equator • moves with the sun • Monsoons (Eq. @ 30°N in S. Asia) Atmospheric Equator & ITCZ Atmospheric equator & IR Brightness temperature (proxy for cloud top height) Tracer method : • Corresponds with ITCZ, where it’s well defined • Works over continents & monsoon regions • Large daily variability, esp. in Asian monsoon NOAA GridSat, Knapp et al., 2011 Implications for atmospheric chemistry: Which hemisphere are emissions in? SF6 emissions, 2008 Region where emissions may be miscategorized TransCom (Patra et al., 2009) Emission Ratio, NH/SH Geographic 32 Atmospheric 25 4% slower interhemispheric exchange Implications for atmospheric chemistry: CH4+OH oxidation gradient Background: Observations of CH3CCl3 imply that CH4 oxidation is faster in the SH than NH (Montzka et al., 2000) CTMs/GCMs predict +28 ± 10% faster CH4 oxidation in the NH (Naik et al., 2013) CH4 oxidation by OH (UCI CTM) In UCI CTM… • CH4 oxidation is 25% faster in geographic NH, but only 5% faster in the atmospheric NH. • MCF obs. constrain the atmospheric ratio, so CTMs and GCMs need consistent tests GEOS-Chem vs. CH4 oxidation constraints UCI CTM GEOS-Chem Observations v9-01-02 v9-02 v10-01 RCP Standard Emissions RCP Resolution T42 (~2.8°) 2°x2.5° 4°x5° 4°x5° τCH4+OH, years 8.5 10.1 8.7 9.5 Geographic 25% 27% 23% 23% Atmospheric 5% 12% 6.8% 6.7% 11.2 ± 1.3 (Prather et al., 2012) NH/SH kCH4* -15 ± 10% (Montzka et al., 2000) -3 ± 12% (Patra et al., 2014) Model developments in the last 2 years have improved NH/SH kCH4, but not τCH4. *Mass-weighted OH ratios differ from kCH4 ratios by ~5% Conclusions • The atmospheric equator is not synonymous with the ITCZ • 2-Box models should define hemispheres consistent with the atmosphere • 3-D CTMs/GCMs should diagnose hemispheric properties consistent with the atmosphere Vertical structure of the atmospheric equator Eastern Pacific The winter hemisphere typically undercuts the summer hemisphere India Filamentary intrusions into opposite hemisphere Over India, cause monsoon dry spells (Krishnamurthi et al., 2010) CH4 vs. Hemispheric tracers HIPPO I Southbound, Jan 2009 Hemispheric tracers gradients align with gradients in CH4 Including slopes in upper troposphere Contours: log(e90N/e90S) Model sampled at 160W, not along flight track & day Kort et al., 2011; Wecht et al., 2012 Where does air cross the atmospheric equator? Smallest fluxes over equatorial continents (Africa, S America) and W. Pacific Largest fluxes in in S. Asian monsoon & E. Pacific (shallow ITCZ)
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