Vojtech Ettler, artin Mihaljevic, Ondrej Sebek, et.al
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`Cd Pb
Zn
`3.5
`Pb`
>`99.5
`1`
/
`2`
`SO2`
/
Birkefeld`
`1`
`1 m
20 m`
5 m`
33
`1`a`
`2`
NL
`1`
`1cm`
`60
`Pb`
`3`
WHC
`1`
`4 8 24 48 96 144 216 312
408`
`504 h`
`0.45 m.`
`SCHOTT Handylab`
`pH`
Schott
Eh`
`Pr1ibram`
`GEOMON`
`3`
`FA`
[
`Pb 24.0 wt
Zn 5 020 mg/kg
`3`
`I`
L.
]
`L.
`Cd 4490 mg/
`II`
`III`
`pH`
kg
`3.4
5.6
[Na3Pb2 SO4 3Cl]
`Dystric`
NaCl
`40`cm`
KPb 2Cl 5
`Cd`
`Zn`
`Zn`
`Cd`
`FA`
Zn`
`Zn`
`Fritsch Analysette 22 NanoTec
<`0.5 m 17.3
1.0
1.5 m
`21.3
`OI
0.5 1.0 m 32.9
1.5
2.0 m 11.6
`B
`AP1 AP2`
`B
Oh A`
`2 mm`
`15 cm`
>`2 m 16.9
`3`
`FA`
3`cm
0.5
0.000 5 g`
NYTREL TI`
2`cm
6`cm`
`1`a`
`6`
`2008`
`6`
`1 384 mm
4`cm`
,`1 m`
`2007`
,
`6`
`Buisine`
1a`
`Nace t 1 n
200
300`cm3`
Krusn e hory [Ore] Mountains
`GEOMON`
`20`
B`
0.000 1`g
`80`
`FA`
`200`g`
<`2`mm
`X'Pert`
34
`FA`
`X
XRD
Cu K
80
40`
30`
`0.008
2
`5
DOC
`350`s X'Celerator`
ICP MS
`ICDD PDF 2
`X`
`NIST1940`
Rietveld`
`Bruker AXS Topas
`3
`Cd`
`ICSD`
`FA`
RSD
<`7
PbSO3
`PB 4 SO 4
`2 mm`
OH
2
2 mm`
`35360
`56101
CO 3
SEP
leadhillite
2
pH`
CEC
`pH`
ICSD`
`64807
CEC
`1`
`R`
RWP
`2`
`PbSO 3`
001
101
110
`X`
`March-Dollase`
o
<`3
`XRD`
ICSD`
ICSD`
`Pb`
`Zn`
ICSD`
`109432
ThermoScientific
XseriesII
`PANalytical X Pert HighScore`
`1.0`D
SKALAR`
FormacsHT DOC`
<`2.5
CuK
<`1.5
<`7 29.2 30.2 33.8 34.1 2
`5
80
40`
30`
`0.02
2
`150`s`
`X'Celerator`
`2`
pH`
`X`
EDS
CEC
`Eltra`
`CS530`
`JEOL
Eltra`
Corg
JEM3010`
STOT
/
`300`kV LaB6
`1.7 A
`1 024
1 024`
`TEM`
HFHClO4 HNO3
`CCD`
`ICP OES`
`ICP MS`
`1`
`EDS`
`INCA`
`NIST 2710`
`2711`
/
SAED
`Cd`
`Pb`
`X Max 50 EDS`
<
`Zn`
RSD
<`3
`TESCAN VEGA`
SEM
`7
SEP
`Rauret`
`BCR`
`100`mL PE`
P
`SpectrAA280 FS`
`Varian
`ThermoScientific`
`iCAP6500`
ICP
OES
`2
v/v
`Zn`
`ICP MS`
`Cd Pb`
`BCR CRM 483
ThermoScientific
`SEP`
`Dionex ICS 2000`
`FA
`SKALAR
`SEP`
`Pb`
`Pb`
35
`Pb`
208
206
Pb/ 206Pb
Pb/207Pb
`FA`
FA`
<`1 m`
`Pb`
5
g/L`
25
`ICP MS`
`NIST
981`
206
Pb`
`0.3
33
`FA`
<`1 m`
`2`
207
`50
`17
`2
5 m`
>`5 m`
Pb/
`TEM`
` 208Pb/ 206Pb`
RSD
`Pb`
`FA`
`20 m
Wilcoxon Sign-Rank
`NCSS`
NCSS Kaysville UT
`P <0.05
`61
`FA
pH`
`PHREEQC 2`
R =0.54 P=
0.089
DOM
`T
xs4all.nl/
H.dat`
pH`
`http://www.
Augusto`
appt`
`DOC`
Strobel`
LMWOAs`
`FA`
`FA`
`pH`
0.1 Cd`
`Zn`
`1.3`
pH`
`4.4
`FA`
`96`h`
`550 g/ L
`76 g/L
`FA`
[ 2
21
66.2
`24`h
g/L
63.7%
`Pb`
`6.2 g/L]
`Cd`
`Zn`
/
KPb 2Cl 5
`PbS
`FA`
MeSO `
0
4
`MeCl `
+
Cd`
Me=`
`48`h`
`Pb`
`51
`TEM`
PbSO4
>`58
> 22
`61
PbSO 4
L/ S
`FA`
SI=0.23
FeOOH
36
3.5
10
`FA`
Bataillard`
`FA`
PbSO 3
`Cd Nowack`
`Cd`
`PbSO3`
`FA`
Cd
PM
`FA`
SO4
CO3
2
Pb 4
OH
Denaix`
`Citeau`
Cd
`L/S`
2
`FA`
`B`
`FA`
Ettler`
PbCO3
`pH`
`Birkefeld`
`2`
`Cd`
`PbO`
`Zn FA`
Na K
`Zn`
`Cd`
`Zn`
`1.8`
0.005
`FA`
mol/a`
`Cd
`FA`
`70%
76.4%`
`70%
76.4%
`14
`Cd
P=
Zn`
15.3 mol/a
`Zn 14
`Zn`
`Cd`
`Cd FA`
15.3 mol/a
`Cd`
`Zn`
`Pb`
Pb`
`8.8
`1.8%
154 mol/`a
32
R = 0.63 P = 0.038
`pH`
`FA`
P =0.001 5
R =0.65
2.3
P = 0.032
15.5
`Pb`
FA`
[ 1`208
419 mg Pb/kg]
`Cd`
<`0.6`mg/ kg
P <0.004
1.0
1.7
`Cd`
4
R=0.78 P=0.005
248
74.3
`Pb`
19.5 mg/kg`
R =0.92 P = 0.001
`Cd`
Pb`
`FA`
`Cd`
`Chrastny`
`Cd`
`Zn`
`pH`
pH`
5.5
37
`FA`
` 206Pb/ 207Pb`
`Pb`
`1.163
1.190`
`FA`
`Northern Bohemia`
pH`
`Pb`
`FA`
206
Pb/ 207Pb = 1.159
0.003
Cd`
`A`
P =0.005
`Zn`
`pH`
R = 0.73
`Pb`
p = 0.010
`3`
`SEP`
`206Pb/207Pb`
FA`
`FA`
`Pb`
`3`
48 h pH`
`SEP`
`Cd`
`Zn`
`Pb`
`Oh
`Pb`
pH`
Pb`
`pH`
1 m
`FA`
Experimental in Situ Transformation of Pb Smelter Fly Ash in Acidic Soils.
Environmental Science & Technology , 2012, 46:10539 10548.
38