Rate in Thermal Systems Overview Rate in Thermal Systems 1 Fundamental Concepts • What is the prime mover in the thermal system? – • What does rate measure in the thermal system? – • temperature difference ( T) heat flow (QH) How does heat flow? – from areas of high temp to low temp Rate in Thermal Systems 2 Heat Flow • Why does heat flow? – molecules with high temperature vibrate faster than molecules at lower temperature – more kinetic energy – when the molecules bump into one another, energy is transferred from the high energy molecule to the low energy molecule – this continues until all the molecules have equal energy levels Rate in Thermal Systems 3 Heat vs Temperature? • What is heat? – Heat is a form of energy relating to the vibrating motion of atoms and molecules • What is temperature? – Temperature is a measure of the average kinetic energy of the molecules of a substance Rate in Thermal Systems 4 Calculation of Heat Flow (QH) • How do we calculate heat flow? – Heat Flow = Heat energy transferred/elapsed time – Quantity of heat = amount of heat energy moved per unit time – QH = H/t Rate in Thermal Systems 5 Units of Heat Flow - Metric • What are the units for heat flow? – any unit of heat / any unit of time – common units – J/s; cal/s; Btu/hr • What is a calorie? – amount of heat required to raise the temperature of one gram of water one degree Celsius; – Often a kilocalorie = 1000 cal is used – SI (metric) unit of heat flow Rate in Thermal Systems 6 Units of Heat Flow - British • What is a Btu? – British thermal unit – amount of heat required to raise the temperature of one pound of water one degree Fahrenheit Rate in Thermal Systems 7 Specific Heat • What is specific heat? – every substance has a unique specific heat – it is a fixed quantity and is the amount of heat required to raise one gram of a specific substance by one degree Celsius – used to determine the amount of heat required to change the temperature of a mass of a substance – Symbol is c Rate in Thermal Systems 8 Calculation of Heat Energy • What is the equation for calculating heat energy during a temperature change? – H = (m)(c)( T), where • H = amount of heat • m = mass of sample • c = specific heat of substance, and T = Final temp – initial temp Rate in Thermal Systems 9 Example - Specific Heat Calculations • What is the specific heat of water? – 1 cal/gm-oC or 1 Btu/lb-oF • Example – How much heat is required to heat 417 pounds of water from 70oF to 130oF? – – – – H = (m)(c)( T) H = (417 lbs)(1 Btu/lb-oF)(130-70) H = (417)(1)(60) H = 25,020 Btu Rate in Thermal Systems 10 Heat Exchange - Hot to Cold • Suppose you heat a metal ball and place it in a cup of cold water. How does the heat flow? – heat will flow from the ball to the water – the amount of heat lost by the metal is equal to the amount of heat gained by the water • This is an example of conservation of energy Rate in Thermal Systems 11 Example of Heat Exchange • Example – A 25kg brass ball at 100C is placed in a container of water at 10C. When the brass-water system has stabilized the final temperature is 30C. – How much heat (H) was removed from the brass ball and added to the water? (c for brass = 0.091 kcal/C˚) – What is the mass of water in the container? Rate in Thermal Systems 12 Calculations of Heat Transfer • Part 1 – H = mc T – H = 25 (0.091)(100-30) – H = 159.3 kcal = 159,300 cals • Part 2 – heat lost by ball was added to water – H = mc T – 159,300 = m(1)(30-10) – 159,300 = 20m – m = 159300/20 – m = 7965 gm Rate in Thermal Systems 13 Heat Flow Rating • An air conditioner is rated at 10,000 Btu. – What does this mean? • The unit can remove heat at a rate of 10,000 Btu per hour • This removal of heat will cause a change in temperature Rate in Thermal Systems 14 Calculation of Heat Flow Rating • Example – A 5000 Btu heater runs for 5 hours and 30 minutes. – How much (what quantity of) heat is moved? • QH = H/t • 5000 Btu/hr = H/5.5 hrs • H = 27,500 Btu Rate in Thermal Systems 15 Heat flow Rate & Thermal Conductivity • What factors affect the heat flow rate (QH) across a material of thickness (l), temp difference ( T), area (A) and thermal conductivity (k)? – QH = kA T/l, where • QH is measured in units such as Btu/hr, or cal/sec Rate in Thermal Systems 16 Thermal Conductivity Examples • Examples of thermal conductivity, in British units, are: – Air = 5.7 x 10-4 – Corkboard = 0.30 – Aluminum = 1400 Heat Amount vs Heat Flow Rate • H = The amount of heat that can be added to or removed from a body • QH = the rate of heat flow through a material due to a temperature difference across the material, for example: – Inner and outer walls on a house, – ski jacket, etc Rate in Thermal Systems 18 Change of State • What is a change of state? – changing a substance from a solid to a liquid or a gas – Solid-liquid = melt – Liquid-gas = vaporize Rate in Thermal Systems 19 Types of Heat • What is sensible heat? – Applied heat that changes the temperature of a substance • What is latent heat? – Applied heat that does not change the temperature of a substance – the applied heat causes the substance to change state (from a solid to liquid) Rate in Thermal Systems 20 Latent Heat Schematic Rate in Thermal Systems 21 Rate in the Thermal System • Example – A sample of ice at -10oC is heated until it becomes steam at 110oC. – Classify the heat changes as latent or sensible. – -10oC ice to 0oC ice sensible – 0oC ice to 0oC water latent – 0oC water to 100oC water sensible – 100oC water to 100oC steam latent – 100oC steam to 110oC steam sensible Rate in Thermal Systems 22 Temperature measuring devices • Thermometers – Celsius (C) – Fahrenheit (F) • Thermocouples – The temperature of the junction of 2 different metals translates to voltage Rate in Thermal Systems 23
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