Safety Data Sheet Lithium Chloride Section 1 Product Description Product Name: Lithium Chloride Recommended Use: Synonyms: Distributor: Science education applications Hydrochloric acid, Lithium Salt Carolina Biological Supply Company 2700 York Road, Burlington, NC 27215 1-800-227-1150 800-227-1150 (8am-5pm (ET) M-F) 800-424-9300 (Transportation Spill Response 24 hours) Chemical Information: Chemtrec: Section 2 Hazard Identification Classification of the chemical in accordance with paragraph (d) of §1910.1200; WARNING Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. Harmful to aquatic life. GHS Classification: Skin Corrosion/Irritation Category 2, Serious Eye Damage/Eye Irritation Category 2A, Specific Target Organ Systemic Toxicity (STOT) Single Exposure Category 3, Hazardous to the aquatic environment - Acute Category 3, Acute Toxicity - Oral Category 4 Acute Toxicity Dermal Contains Acute Toxicity Inhalation Gas Contains Acute Toxicity Inhalation Vapor Contains Acute Toxicity Inhalation Dust/Mist Contains Section 3 Chemical Name Lithium Chloride Section 4 100 % of the mixture consists of ingredient(s) of unknown toxicity 100 % of the mixture consists of ingredient(s) of unknown toxicity 100 % of the mixture consists of ingredient(s) of unknown toxicity 100 % of the mixture consists of ingredient(s) of unknown toxicity Composition / Information on Ingredients CAS # 7447-41-8 % 100 First Aid Measures Emergency and First Aid Procedures Inhalation: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Eyes: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin Contact: IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Ingestion: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Section 5 Extinguishing Media: Lithium Chloride Firefighting Procedures Use media suitable to extinguish surrounding fire. Page 1 of 4 Safety Data Sheet Fire Fighting Methods and Protection: Fire and/or Explosion Hazards: Hazardous Combustion Products: Section 6 Spill or Leak Procedures Steps to Take in Case Material Is Released or Spilled: Exposure to the spilled material may be irritating or harmful. Follow personal protective equipment recommendations found in Section 8 of this SDS. Additional precautions may be necessary based on special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred. Also consider the expertise of employees in the area responding to the spill. Avoid creating dusts. Cover material with absorbent and moisten and collect for disposal. Avoid breathing dust/fume/gas/mist/vapors/spray. Avoid contact with material. Prevent the spread of any spill to minimize harm to human health and the environment if safe to do so. Wear complete and proper personal protective equipment following the recommendation of Section 8 at a minimum. Dike with suitable absorbent material like granulated clay. Gather and store in a sealed container pending a waste disposal evaluation. Ventilate the contaminated area. Isolate area. Keep unnecessary personnel away. Vacuum or sweep up material and place in a disposal container Section 7 Handling: Storage: Storage Code: Firefighters should wear full protective equipment and NIOSH approved self-contained breathing apparatus. N/A Hydrogen chloride, Lithium Handling and Storage Avoid breathing dust/fume/gas/mist/vapors/spray. Wash thoroughly after handling. Do no eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. Keep container tightly closed in a cool, wellventilated place. Keep away from ... (incompatible materials to be indicated by the manufacturer). Readily absorbs moisture from air. Store in a well-ventilated place. Keep container tightly closed. Store locked up. Suitable for any general chemical storage. Green - general chemical storage Section 8 Protection Information ACGIH Chemical Name No data available Control Parameters Engineering Measures: Personal Protective Equipment (PPE): Respiratory Protection: Eye Protection: Skin Protection: Gloves: Section 9 Formula: LiCl Molecular Weight: 42.39 Appearance: White Crystals Odor: None Odor Threshold: No data available pH: 6.0 Melting Point: No data available 608 C Boiling Point: 1355 C Flash Point: No data available Flammable Limits in Air: N/A Lithium Chloride (TWA) N/A OSHA PEL (STEL) N/A (TWA) N/A (STEL) N/A No exposure limits exist for the constituents of this product. General room ventilation might be required to maintain operator comfort under normal conditions of use. Lab coat, apron, eye wash, safety shower. No respiratory protection required under normal conditions of use. Wear chemical splash goggles when handling this product. Have an eye wash station available. Avoid skin contact by wearing chemically resistant gloves, an apron and other protective equipment depending upon conditions of use. Inspect gloves for chemical break-through and replace at regular intervals. Clean protective equipment regularly. Wash hands and other exposed areas with mild soap and water before eating, drinking, and when leaving work. Nitrile, Natural rubber, Neoprene, PVC or equivalent. Physical Data Vapor Pressure: 1 mmHg at 547°C Evaporation Rate (BuAc=1): N/A Vapor Density (Air=1): N/A Specific Gravity: 2.07 Solubility in Water: Soluble Log Pow (calculated): -2.66 Autoignition Temperature: No data available Decomposition Temperature: No data available Viscosity: No data available Percent Volatile by Volume: N/A Page 2 of 4 Safety Data Sheet Section 10 Reactivity Data Reactivity: Chemical Stability: Conditions to Avoid: Incompatible Materials: Hazardous Decomposition Products: Hazardous Polymerization: No data available Stable under normal conditions. Exposure to moisture Acids, Halogens HCl, Will not occur Section 11 Routes of Entry Symptoms (Acute): Delayed Effects: Toxicity Data Inhalation, ingestion, eye or skin contact. N/A No data available Acute Toxicity: Chemical Name Lithium Chloride CAS Number 7447-41-8 Oral LD50 Oral LD50 Rat 1530 mg/kg Oral LD50 Mouse 1165 mg/kg Dermal LD50 Not determined Inhalation LC50 Not determined Carcinogenicity: Chemical Name No data available CAS Number 7447-41-8 IARC Not listed NTP Not listed OSHA Not listed Chronic Effects: Mutagenicity: Teratogenicity: Sensitization: Reproductive: Target Organ Effects: Acute: Chronic: No evidence of a mutagenic effect. No evidence of a teratogenic effect (birth defect). No evidence of a sensitization effect. No evidence of negative reproductive effects. See Section 2 N/A Section 12 Overview: Mobility: Persistence: Bioaccumulation: Degradability: Other Adverse Effects: Ecological Data Moderate ecological hazard. This product may be dangerous to plants and/or wildlife. Keep out of waterways. No data No data No data No data No data Chemical Name N/A Section 13 Disposal Methods: Waste Disposal Code(s): Section 14 Ground - DOT Proper Shipping Name: N/A Lithium Chloride CAS Number 7447-41-8 Eco Toxicity Disposal Information Dispose in accordance with all applicable Federal, State and Local regulations. Always contact a permitted waste disposer (TSD) to assure compliance. Not Determined Transport Information Air - IATA Proper Shipping Name: Not regulated for air transport by IATA. Page 3 of 4 Safety Data Sheet Section 15 TSCA Status: Regulatory Information All components in this product are on the TSCA Inventory. Chemical Name CAS Number § 313 Name § 304 RQ CERCLA RQ § 302 TPQ CAA 112(2) TQ No data available 7447-41-8 No No No No No Section 16 Revised: 09/09/2015 Additional Information Replaces: 09/03/2014 Printed: 10-29-2015 The information provided in this (Material) Safety Data Sheet represents a compilation of data drawn directly from various sources available to us. Carolina Biological Supply makes no representation or guarantee as to the suitability of this information to a particular application of the substance covered in the (Material) Safety Data Sheet. Glossary ACGIH CAS CERCLA DOT IARC N/A American Conference of Governmental Industrial Hygienists Chemical Abstract Service Number Comprehensive Environmental Response, Compensation, and Liability Act U.S. Department of Transportation International Agency for Research on Cancer Not Available Lithium Chloride NTP OSHA PEL ppm RCRA SARA TLV TSCA IDLH National Toxicology Program Occupational Safety and Health Administration Permissible Exposure Limit Parts per million Resource Conservation and Recovery Act Superfund Amendments and Reauthorization Act Threshold Limit Value Toxic Substances Control Act Immediately dangerous to life and health Page 4 of 4
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