Journal of the Geological Society, London, Vol. 163, 2006, pp. 997–1010. Printed in Great Britain. Provenance of Cambrian conglomerates from New Zealand: implications for the tectonomagmatic evolution of the SE Gondwana margin M A R C U S G U T JA H R 1,2 , J O H N D. B R A D S H AW 1, S T E V E W E AV E R 1 , C A R S T E N M Ü N K E R 3;4 & T R E VO R I R E L A N D 5 1 Department of Geological Sciences, University of Canterbury, Private Bag 4800, Christchurch, New Zealand 2 Present address: Institute for Isotope Geochemistry and Mineral Resources, Department of Earth Sciences, ETH-Zentrum, NW81.2, Clausiusstrasse 25, 8092 Zürich, Switzerland (e-mail: [email protected]) 3 Institut für Mineralogie, Westfälische Wilhelms Universität Münster, Corrensstrasse 24, 48149 Münster, Germany 4 Present address, Universität Bonn, Mineralogisch-Petrologisches Institut, 53115 Bonn, Germany 5 Australian National University, Canberra, ACT0200, Australia Abstract: The oldest rocks in New Zealand are the Mid- to Late Cambrian intra-oceanic island arc rocks of the Takaka terrane (Devil River arc). The provenance of Cambrian conglomerates stratigraphically above the exposed arc succession was studied to constrain the late stages of arc evolution and its accretion to continental crust. The Dead Goat Conglomerate contains two distinct groups of igneous clasts: (1) intermediate to felsic volcanic clasts with moderately enriched light rare earth element (LREE) and high field strength element (HFSE) contents and positive ENd500 (+2.1) that were derived from a medium-K calc-alkaline source, probably the main sequence of the Devil River arc; (2) dioritic to metagranitic plutonic clasts strongly enriched in LREE and HFSE and with ENd500 of +3.5 to +5.9 that were derived from a high-K arc source, probably the uppermost units of the Devil River arc. This is consistent with a new U–Pb sensitive high-resolution ion microprobe age of 496 6 Ma. The Lockett Conglomerate also contains two distinct groups of igneous clasts: (1) ultramafic to intermediate igneous clasts identified as boninitic to transitional low-K calc-alkaline arcrelated rocks based on depleted REE and HFSE abundances; (2) ‘I’-type metagranitoid clasts derived from a distinct Andean type continental margin, as indicated by ENd500 as low as 7.1. Both conglomerates contain sandstone clasts derived from a common old, multi-cycle continental source with ENd500 of 14.2 to 15.7, and no suitable source has been found in present-day New Zealand. The new provenance data from these conglomerates constrain the time of accretion of the Devil River arc to the palaeo-Pacific Gondwana margin and provide new information on the structural evolution of the accretionary event. coherent internal stratigraphy that differs somewhat from that of adjacent slices, but that in some instances can be correlated (Cooper & Tulloch 1992; Rattenbury et al. 1998; Münker & Cooper 1999). Each slice contains igneous rocks of the Devil River Volcanics Group and associated Haupiri Group sediments. The Devil River Volcanics Group is divided into the older, back-arc tholeiitic Mataki Volcanics, the younger back-arc boninitic Cobb Igneous Complex, and the calc-alkaline arcrelated rocks of the Benson Volcanics, which evolved through time from low-K to high-K type magmas (Münker & Cooper 1995, 1999). Basaltic to andesitic compositions are typical in the Devil River arc (Münker & Cooper 1995, 1999) and felsic rocks are rare, largely being restricted to the latest stages of volcanism (McLean 1994; Funk 1996). Both the Benson and the Mataki Volcanics formations are interbedded with Haupiri Group sediments. Furthermore, the Mataki Volcanics are intruded by dykes of the Benson Volcanics type (Münker & Cooper 1999), supporting a close spatial relationship during the activity of the Devil River arc. The back-arc boninitic Cobb Igneous Complex was emplaced at shallow depths into Haupiri Group sediments and the Mataki Volcanics. Münker & Cooper (1999) reported the occurrence of boninitic volcanic clasts in early Mid-Cambrian (Floran) conglomerates of the Haupiri Group. Although similar in composition to rocks of the Cobb Igneous Complex, these boninitic clasts stratigraphically underlie the Cobb Igneous Complex and Mataki Volcanics. The oldest rocks of New Zealand are exposed in the Early to Mid-Palaeozoic Takaka terrane in NW Nelson and SW Fiordland (Fig. 1) (Cooper & Tulloch 1992), which are part of the Western Province (Landis & Coombs 1967). These oldest units comprise remnants of the late Mid- to Late Cambrian intra-oceanic Devil River arc and the associated Haupiri Group sediments, forming the western part of the Takaka terrane (Fig. 1). In the past two decades many of the individual sedimentary and igneous suites have been described in detail (e.g. Grindley 1980; Cooper 1989; Pound 1993; Münker & Cooper 1999; Jongens et al. 2003). A first reconstruction of the sequence was largely limited to the igneous units (Münker & Cooper 1999). However, a fully comprehensive reconstruction including the various sedimentary units in the Haupiri Group has yet to be established. The aim of the present study is to determine the provenance of igneous and sedimentary clasts in two major conglomerate units within the youngest sediments of the Devil River arc assemblage, to constrain the later stages of arc evolution and, if possible, the time of accretion. Regional geology The relics of the Cambrian Devil River arc are restricted to a north–south-trending belt less than 15 km wide near the western margin of the Takaka terrane (Fig. 1; Cooper 1989). The belt is made up of 10 tectonic fault-bounded slices, each with a 997 Fig. 1. (a) Generalized geology of West Nelson–North Westland, South Island, New Zealand, as given by Cooper & Tulloch (1992). The Anatoki Thrust separates the Western Buller terrane from the Eastern Takaka terrane. Cambrian arc-related rocks are restricted to the Central Belt. Grey box indicates position of the field area shown in (b). Inset: inferred offshore extent of Early Palaeozoic rocks of the Buller and Takaka terranes. Box in inset indicates location of map (a). MTZ, Median Tectonic Zone. (b) Schematic outcrop of the Lockett and Dead Goat conglomerates North of Cobb Valley. Map is compiled from Grindley (1980) and Pound (1993), and modified from new observations. Numbers in circles refer to component count locations where the data presented in Table 1 were collected. Topographic contour interval is 40 m. The simplified stratigraphic column shows the main sedimentary formations of the Devil River arc with the corresponding New Zealand Cambrian stages. Ages for New Zealand stages are taken from Cooper (2004). 998 M . G U T JA H R E T A L . L O C K E T T A N D D E A D G OAT C O N G L O M E R AT E S T U DY, N Z 999 ever, clear erosional discordant contacts between the Tasman Formation and the Lockett Conglomerate are not exposed. In most cases, later faulting disrupted the contacts between the two formations. The matrix of the Lockett Conglomerate contains detrital garnet and amphibole, which Coleman (1978) and Pound (1993) interpreted to be derived from metamorphic continental sources. The uppermost part of the Tasman Formation contains trilobites, including Dorypyge and Nepea cf. avara, that suggest a Boomerangian age (Fig. 1b) (Münker & Cooper 1999). The Lockett Conglomerate is regarded as Mindyallan. The conglomerate is over 1000 m thick (Grindley 1980) and the stratigraphic top is unknown. The Lockett Conglomerate is cut by the Balloon Mélange, interpreted as a tectonic diapir by Jongens et al. (2003). Both the Lockett Conglomerate and the Balloon Mélange are cut by dykes of Gendarme Dolerite with an 40 Ar/39 Ar age of 486 25 Ma (Münker & Cooper 1999). These clasts will be referred to hereafter as ‘pre-Devil River’ rocks. The Haupiri Group sediments are interbedded with and overlie the volcanic rocks and range in grain size from conglomerate to mudstone, reflecting the wide variety of sedimentary environments in the Devil River arc. The provenance of the Haupiri Group sediments is variable. Some units comprise predominantly arc-derived material. The Junction Formation, on the other hand, predominantly consists of continent-derived quartzo-feldspathic sandstone, siltstone and channel-fill conglomerate (Pound 1993; Roser et al. 1996; Wombacher & Münker 2000). The Haupiri Group comprises mainly intra-arc sediments, although the interlayering of back-arc tholeiitic Mataki Volcanics at a number of localities (Siebert 1998; Münker & Cooper 1999) suggests proximity to or gradation into a back-arc basin. The distinctly continental character of the Junction Formation has led to suggestions that the back-arc basin was bounded by the Gondwana continent (Cooper & Tulloch 1992; Pound 1993; Wombacher & Münker 2000). Sampling and analytical methods In our study, the relative abundance of the various components in the conglomerates was assessed at one location in the Dead Goat Conglomerate and eight well-separated sites in the Lockett Conglomerate (Fig. 1b, Table 1). Samples from the Dead Goat Conglomerate were taken from the section SW of Mount Lockett and samples from the Lockett Conglomerate were collected along strike between Cobb Valley and Mount Lockett (Fig. 1b). Major and trace element concentrations were determined by XRF using a Philips PW2400 system at the University of Canterbury and following the method of Norrish & Hutton (1969). All major element contents discussed below are given loss on ignition (LOI) free. REE and high field strength element (HFSE) analyses were made by inductively coupled plasma-mass spectrometry (ICP-MS) using a VG Plasmaquad PQ1 system and following the procedure of Garbe-Schönberg (1993) at the Universität Kiel, Germany. Cross-calibration of the two methods was ensured through a comparison of XRF data with ICP-MS data. Results agree within better than 30%. ICP-MS results are presented in Table 2. Detailed XRF results are available online at http://www.geolsoc.org.uk/ SUP18248. A hard copy can be obtained from the Society Library. Felsic igneous clasts and sandstone clasts were analysed for whole-rock Nd isotope composition and Sm–Nd concentrations by thermal ionization mass spectrometry (TIMS) at the Institut für Mineralogie, Universität Münster, Germany, using a VGSector54 multiple-collector system (Table 3). Samarium–neodymium concentrations were determined using a Geological setting of the Dead Goat and the Lockett conglomerates The Dead Goat Conglomerate (new name) is the thinner of the two conglomerate units and lies stratigraphically near the top of the Tasman Formation (see simplified stratigraphic column in Fig. 1b). The Dead Goat Conglomerate is a granule- to cobblesized conglomerate deposited in a broad channel in a marine environment. Pound (1993) included associated siltstones together with the conglomerate in the Dead Goat Member, the youngest part of the Tasman Formation. Other sections of the Dead Goat Conglomerate are likely to be exposed further to the north of the study area shown in Figure 1b. The stratigraphically overlying Lockett Conglomerate is more diverse than the Dead Goat Conglomerate, ranging from granuleto boulder-sized conglomerates, with single boulders reaching 1 m in diameter. At exposed contacts sandstone–siltstone lithologies of the Tasman Formation that are deposited above the Dead Goat Conglomerate coarsen upward into pebble–cobble conglomerate of the Lockett Conglomerate. The basal Lockett Conglomerate is marine, but the unit as a whole is regressive and grades upward into braided fluvial deposits (Pound 1993). How- Table 1. Summary of eight component counts for the Lockett Conglomerate (LC) and one count in the Dead Goat (DGC) Conglomerate Count number Volcanic clasts Qz-diorites, granitoids Gabbros, diorites Ultramafic clasts Pink granitoids Purple volcaniclastic breccia White, grey, black chert Red chert Sandstone clasts Laminated sediment Unidentifiable Total 1 (LC) 2 (LC) 3 (LC) 4 (LC) 5 (LC) 6 (LC) 7 (LC) 8 (LC) LC average (%) 9 (DGC) (%) 32 22 14 3 0 0 19 0 2 0 8 39 23 6 7 0 0 7 5 7 1 5 33 22 12 0 0 0 22 0 5 2 4 40 28 7 2 0 0 17 0 3 0 3 40 20 7 5 0 0 23 0 3 0 2 38 24 10 3 0 0 18 0 3 0 3 31 24 15 4 0 0 20 0 1 0 5 35 17 14 4 0 0 21 0 2 0 7 36 23 11 3 0 0 18 1 3 ,1 4 100 15 0 0 6 5 10 17 5 33 5 4 100 Locations of the individual counts are shown in Figure 1b. Fresh surfaces of at least 1 m2 were chosen. Count 6 was counted twice for the calculation of the average composition of the Lockett Conglomerate (observed surface for count 6 was 2.7 m2 ). The gabbroic and dioritic clasts occur only in the Lockett Conglomerate, whereas the pink granitoid and volcaniclastic clasts occur only in the Dead Goat Conglomerate. Sandstone clasts are much more abundant in the Dead Goat Conglomerate. The igneous and sandstone clasts were analysed petrographically and geochemically. 1000 M . G U T JA H R E T A L . Table 2. Individual major and trace element contents of the mafic to intermediate samples Unit: Rock type: Sample: Volatile-free (wt%) SiO2 TiO2 Al2 O3 Fe2 O3T MnO MgO CaO Na2 O K2 O P2 O5 Total LOI Original total ppm Li Sc Rb Sr Y Zr Nb Mo Cd Sb Cs Ba La Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm Yb Lu Hf Ta Tl Pb Th U Mg-no. CaO/Al2 O3 Th/Y Ti/Zr Zr/Y Th/Yb Ta/Yb LaN /SmN DyN /YbN Eu/Eu* LaN /YbN LC boninite LC94 LC boninitic andesite LC52 LC boninitic andesite LC49 LC hbmetapyroxenite LC85 LC hb–epidiorite LC130 LC hbmetadiorite LC71 LC hbmetadiorite LC123 LC hbmetadiorite LC63 DGC diorite DG102 DGC volcanic breccia DG150 55.15 0.17 12.43 10.65 0.15 10.60 6.69 0.94 3.19 0.02 100.00 2.39 100.21 56.46 0.30 14.32 10.16 0.17 6.56 7.12 3.21 1.67 0.03 100.00 2.06 100.10 58.05 0.27 14.44 7.72 0.09 7.22 5.65 3.43 3.09 0.04 100.00 2.09 100.45 50.40 0.35 18.50 11.46 0.11 6.70 7.19 0.35 4.92 0.02 100.00 2.63 99.94 52.86 0.23 20.01 7.14 0.13 6.63 6.90 1.39 4.64 0.06 100.00 3.16 100.30 53.83 0.19 19.07 7.99 0.14 8.62 3.80 0.54 5.78 0.03 100.00 3.36 100.20 55.97 0.70 18.01 10.12 0.15 5.48 3.34 1.14 5.02 0.07 100.00 2.07 99.32 56.22 0.32 15.35 8.95 0.15 7.97 6.15 1.23 3.61 0.04 100.00 2.41 100.25 56.49 0.83 13.38 14.67 0.11 4.81 4.41 3.81 1.25 0.26 100.00 7.41 100.40 53.30 1.16 14.90 11.95 0.14 2.99 8.38 6.24 0.59 0.36 100.00 3.98 99.97 11.1 41 108 59 6.0 9 0.45 0.10 0.01 0.18 1.45 693 1.03 2.53 0.34 1.61 0.51 0.16 0.69 0.13 0.97 0.23 0.71 0.11 0.82 0.13 0.33 0.05 0.36 0.67 0.32 0.09 58.4 0.54 0.05 110 1.5 0.39 0.06 1.27 0.77 0.80 0.85 9.7 40 49 269 9.6 15 0.56 0.12 0.02 0.18 1.13 751 2.59 4.70 0.61 2.68 0.82 0.31 1.14 0.21 1.56 0.36 1.09 0.17 1.18 0.18 0.54 0.06 0.26 1.55 0.56 0.17 47.7 0.50 0.06 121 1.6 0.48 0.05 2.00 0.86 1.00 1.49 6.4 28 99 148 7.0 27 1.58 0.15 0.07 0.15 2.28 537 3.92 9.14 1.00 4.09 1.02 0.22 1.13 0.19 1.25 0.26 0.77 0.11 0.78 0.12 0.81 0.16 0.48 0.93 1.43 0.41 56.9 0.39 0.20 60 3.8 1.84 0.21 2.43 1.05 0.64 3.40 7.5 45 197 96 5.0 8 0.46 0.10 0.26 0.16 1.52 444 1.99 3.4 0.49 2.12 0.54 0.30 0.65 0.11 0.80 0.18 0.56 0.09 0.60 0.10 0.27 0.05 0.81 1.69 0.25 0.11 45.2 0.39 0.05 269 1.6 0.42 0.08 2.32 0.86 1.54 2.23 9.2 32 119 158 5.6 20 1.50 0.08 0.06 0.12 3.37 451 4.6 7.85 0.92 3.5 0.74 0.31 0.84 0.14 0.94 0.20 0.59 0.09 0.59 0.09 0.65 0.13 0.63 2.23 1.13 0.31 56.7 0.34 0.20 70 3.5 1.91 0.22 3.87 1.02 1.21 5.17 13.4 30 101 118 5.0 15 1.01 0.13 0.04 0.23 8.1 896 2.90 6.77 0.77 3.1 0.73 0.17 0.81 0.14 0.93 0.19 0.57 0.08 0.56 0.08 0.50 0.10 0.44 1.03 0.73 0.13 60.4 0.20 0.15 74 3.0 1.30 0.17 2.49 1.07 0.66 3.48 10.9 33 136 78 9.8 35 2.30 0.24 0.07 0.24 2.66 745 5.6 12 1.40 5.5 1.33 0.39 1.49 0.26 1.69 0.36 1.04 0.15 1.04 0.16 1.10 0.21 0.48 3.12 2.09 0.43 43.4 0.19 0.21 119 3.6 2.02 0.20 2.64 1.06 0.85 3.62 6.2 40 134 129 8.7 30 2.25 0.75 0.07 0.14 1.47 505 5.6 12 1.31 5.0 1.14 0.34 1.29 0.22 1.42 0.31 0.89 0.13 0.87 0.14 0.99 0.19 0.51 2.62 1.97 0.42 55.7 0.40 0.23 63 3.5 2.27 0.22 3.08 1.06 0.87 4.33 12.3 11 14 345 51 337 37 1.32 0.19 1.24 0.60 2232 31 68 8.3 35 8.6 1.98 8.8 1.51 9.7 2.04 5.9 0.87 5.7 0.85 7.9 2.17 0.07 9.8 5.4 1.63 31.7 0.33 0.11 15 6.6 0.95 0.38 2.30 1.10 0.69 3.67 16.4 26 35 80 19 91 9.6 0.31 0.07 1.35 1.84 84 15 36 4.84 20 4.4 0.92 3.9 0.59 3.5 0.72 2.04 0.29 1.95 0.29 2.35 0.51 0.19 14.9 4.3 0.98 26.1 0.56 0.23 76 4.9 2.20 0.26 2.11 1.18 0.67 5.14 Major element concentrations were determined by XRF analysis, trace element concentrations by ICP-MS. LC, Lockett Conglomerate; DGC, Dead Goat Conglomerate. mixed 149 Sm– 150 Nd tracer. All isotope ratios for samples were calculated back to an age of 500 Ma. Uncertainties concerning the age of the granitic rocks (500 15 Ma) have a negligible effect on the initial isotopic ratios and are within the analytical uncertainty. Neodymium isotope results obtained by other workers and used here for correlation were corrected to a La Jolla value of 0.51186. A U–Pb zircon age was obtained for a metagranitic clast from the Dead Goat Conglomerate by sensitive high-resolution ion microprobe L O C K E T T A N D D E A D G OAT C O N G L O M E R AT E S T U DY, N Z 1001 Table 3. Whole-rock Sm and Nd isotope data for igneous and sandstone clasts of the Lockett and the Dead Goat Conglomerate Sample Rock type Dead Goat Conglomerate DG100 Metagranite DG107 Metagranite DG146 Metagranite DG147 Tuffaceous breccia DG150 Tuffaceous breccia DG97 Lithic arenite DG98 Lithic arenite DG148 Greywacke Lockett Conglomerate HL48 hbmetagranodiorite HL50 Metagranite HL66 Metagranite HL84 Metagranite HL138 Metagranite HL58 Lithic arenite HL120 Lithic arenite HL140 Lithic arenite 143 Nd/144 Ndmeas 147 Sm/144 Nd ENd500 TDM (Ga) Nd (ppm) Sm (ppm) 45.7 25.2 42.7 15.7 9.36 5.45 8.42 3.24 0.51270 0.51260 0.51264 0.51251 0.124 0.131 0.119 0.125 5.9 3.5 4.9 2.1 0.78 1.02 0.84 1.11 24.5 5.53 0.51255 0.136 2.1 1.20 33.5 28.5 28.5 6.17 5.18 5.18 0.51163 0.51161 0.51162 0.111 0.110 0.110 14.2 14.5 14.3 2.25 2.25 2.24 1.41 0.51236 0.123 0.7 1.33 2.50 2.54 4.12 3.73 4.36 5.45 3.66 0.51214 0.51203 0.51251 0.51253 0.51155 0.51155 0.51161 0.129 0.122 0.139 0.154 0.111 0.107 0.108 5.4 7.1 1.1 0.7 15.7 15.4 14.3 1.82 1.86 1.33 1.60 2.36 2.27 2.21 6.95 11.8 12.6 17.9 14.6 23.8 30.9 20.6 ENd500 was calculated using ºSm ¼ 6:543 3 1012 a1 with respect to a chondrite uniform reservoir with a present-day 143 Nd/144 Nd of 0.512638 and 147 Sm/144 Nd of 0.1966. 143 Nd/144 Nd (LaJolla) ¼ 0:511859 23 (2, n ¼ 28) Depleted mantle model ages TDM were calculated after Goldstein et al. (1984). Classification of the sandstone clasts after Pettijohn (1963). Over a period of 9 months, the La Jolla standard analysed at the University of Münster gave values of 0.511860 23 for 143 Nd/144 Nd (2, n ¼ 28). Sm/Nd concentrations were determined using a mixed 149 Sm– 150 Nd tracer to a precision of 1% for the respective concentrations and 0.1% for the elemental ratio. One analysed blank for Sm and Nd was 55 pg and 320 pg, respectively, and is negligible. (SHRIMP) using SHRIMP II at the Australian National University, Canberra. Methods have been described in detail by Muir et al. (1996). Results and a description of the detailed analytical procedure can be found in the Supplementary Publication (see p. 999). The Cambrian time scale used in this paper follows that of Davidek et al. (1998) and Encarnación et al. (1999). Absolute ages in the simplified stratigraphic column in Figure 1b are taken from a recent compilation by Cooper (2004) for the Cambrian stages in New Zealand. Detailed geochemical data for the igneous clasts are given in Table 2 and the Supplementary Publication. The classification of high-Mg rocks is after Le Bas (2000). To avoid misinterpretations for the ultramafic igneous clasts two samples in excess of 1000 ppm Cr and 200 ppm Ni were dismissed as ultramafic cumulates and excluded from the geochemical provenance analysis. Results Clast populations Besides quartzose sandstone clasts, which contribute about a third of the clast population in the Dead Goat Conglomerate, abundant chert and clasts of diverse igneous origin are present (count 9 in Table 1). The Dead Goat Conglomerate is dominantly poorly sorted and only sandstone and chert clasts exceed cobble size. Accessory amounts of clasts of laminated sandstone–siltstone occur, which resemble sediments of the Tasman Formation. The Lockett Conglomerate is dominated by igneous clasts, which make up almost three-quarters of the clast population (Table 1). In contrast to the Dead Goat Conglomerate, sandstone clasts are only a minor contributor (3%). Sorting is very variable in the Lockett Conglomerate, which Pound (1993) grouped into eight depositional facies. Several blocks of mafic to intermediate composition in the Lockett Conglomerate exceed 1 m in diameter, whereas only few granitic clasts reach more than 50 cm. The clast distribution in the Lockett Conglomerate is remarkably uniform in different parts of the conglomerate (Table 1). Petrology of the igneous and sandstone clasts Igneous clasts in the Dead Goat Conglomerate. Of the various types of igneous clasts that are present in the Dead Goat Conglomerate, only two types listed in Table 1 were sufficiently large to be analysed. The tuffaceous breccia clasts of intermediate to felsic compositions consist of dark red scoria and brown to white volcaniclastic fragments with rare plagioclase phenocrysts. Plutonic clasts are mainly pink metagranitic rocks with the exception of one fresh dioritic sample. Most metagranitic samples contain zones of granophyric intergrowth of quartz and partly metasomatically replaced alkali feldspar, indicative of either rapid cooling or chilling of the melts (Shelley 1993). Almost all analysed samples contain secondary calcite, quartz and chlorite. Comparison of the metamorphic mineral assemblage of the matrix and igneous clasts indicates post-depositional metamorphism of the lower greenschist facies. Igneous clasts in the Lockett Conglomerate. The majority of volcanic clasts in the Lockett Conglomerate are effusive rocks of mafic to intermediate composition. Cryptocrystalline hornblende and feldspar needles dominate the matrix of the mafic to intermediate samples, whereas the matrix of the rhyolitic samples contains mainly cryptocrystalline quartz, an opaque mineral (presumably magnetite), albitized feldspar and fibrous chlorite. Phenocryst phases, when present, are hornblende, augite, uralitized pyroxene (possibly opx), albitized and/or sericitized plagioclase in the mafic to intermediate samples, and quartz in the rhyolitic samples. The compositions of the plutonic clasts range from ultramafic to highly differentiated. Original ultramafic mineral assemblages are fully replaced by sericite pseudomorphs replacing pyroxene. Mafic to intermediate samples have a mineral assemblage of hornblende, sericite pseudomorphs and fibrous secondary actinolite. Intermediate samples contain increasing amounts of quartz, decreasing amounts of hornblende 1002 M . G U T JA H R E T A L . and actinolite, magnetite, calcite, chlorite and accessory epidote. Virtually all volcanic and plutonic clasts show evidence of lower greenschist facies metamorphism with the occurrence of albitized, sericitized, saussuritized and calcitized feldspars, uralitized pyroxenes (if present), abundant chlorite and calcite in most specimens, and epidote in a few samples. The common presence of sericitized and/or albitized feldspar and uralite suggests a high availability of water-rich fluids (Shelley 1993), contemporaneous with only minor strain, as indicated by the lack of preferred mineral orientations. The well-preserved state of alkali feldspars in the matrix, compared with the highly altered condition of alkali feldspars within igneous clasts, as well as the lack of secondary actinolite in the matrix, suggests that the greenschist metamorphism was pre-depositional. Sandstone clast petrography. The sandstone clasts in the Dead Goat Conglomerate and the Lockett Conglomerate are strikingly similar in terms of petrography, geochemistry and Nd isotope composition (see below). They are quartzose, medium-grained, dark greyish green, well-indurated sandstone clasts that resemble turbiditic sandstones. Biogenic material is absent. Monocrystalline, often undulose quartz grains and alkali felspar dominate the sandstone clasts. Plagioclase is of minor importance and accessory minerals include detrital muscovite, polycrystalline quartz, rare micritic limestone fragments, and an opaque phase in varying proportions. Secondary calcite and chlorite occur throughout. In the classification scheme of Dickinson et al. (1983), the sandstone clasts of the two conglomerates suggest a common, purely continental origin (Fig. 2). Geochemical compositions of clasts The igneous clasts have undergone greenschist-facies metamorphism during which the large ion lithophile elements (LILE: Na, K, Rb, Sr, Ba, Cs, U) were potentially mobilized. The primary total alkali contents, for example, were severely dis- Fig. 2. QFL diagram for two sandstone clasts of the Lockett Conglomerate (r) and the Dead Goat Conglomerate (d), respectively, compared with the modal composition of the Benson–Tasman Mélange sandstones and the Junction Formation examined by Pound (1993). Inferred tectonic settings are from Dickinson et al. (1983). Junction Formation sandstones contain a significant proportion of lithic fragments, indicating relative proximity to the Devil River arc during deposition. turbed during the metamorphic event (Fig. 3b). Therefore the geochemical discussion focuses on the REE, the HFSE (Zr, Nb, Hf, Ta), and the elements Th, Sc and Y because these are essentially immobile up to granulite-facies conditions (e.g. Wood et al. 1976; Humphris & Thompson 1978). Igneous clasts in the Dead Goat Conglomerate. The tuffaceous volcanic clasts have an andesitic composition, covering a relatively narrow range in SiO2 contents from 56 to 63 wt% at MgO contents between 1.5 to 3.9 wt%. Relative to the Lockett Conglomerate clasts they are enriched in HFSE and REE (Fig. 3). The analysed plutonic clasts have SiO2 contents above 65 wt% except for one diorite (53.3 wt% SiO2, 4.8 wt% MgO). A prominent feature of the plutonic clasts in the Dead Goat Conglomerate is the extreme enrichment in HFSE and REE (Figs 3 and 4a, b). Neodymium isotope ratios for the two volcanic and three metagranitic clasts are presented in Table 3. The two volcanic clasts have identical ENd500 of +2.1; the metagranitic clasts have higher ENd500 values of +3.5, +4.9 and +5.9. Uranium–lead SHRIMP age determinations were carried out on a set of 15 zircons from one metagranitic clast of the Dead Goat Conglomerate. The results obtained give a homogeneous age population of 496 6 Ma (2 SE) (Fig. 5 and Supplementary Publication). Igneous clasts in the Lockett Conglomerate. Plutonic clasts of the Lockett Conglomerate cover the entire spectrum from ultramafic to highly felsic compositions, whereas most volcanic clasts have an intermediate composition (Fig. 3). Incompatible trace element concentrations for both volcanic and plutonic clasts in the Lockett Conglomerate are much lower than those for the igneous clasts in the Dead Goat Conglomerate (Fig. 3c and d). The majority of the volcanic clasts have SiO2 contents between 53 and 63 wt% (Table 2 and Supplementary Publication). Because of their high MgO contents (from 11.3 to 5.6 wt%, respectively) most of the less evolved volcanic clasts can be classified as boninites and boninitic andesites. Volcanic clasts intermediate between dacitic and highly felsic compositions are notably absent in the Lockett Conglomerate (Fig. 3). Three pebble-sized rhyolitic samples have SiO2 contents between 73 and 75 wt%, but are depleted in incompatible trace elements to the same extent as the mafic to intermediate volcanic clasts (Fig. 3). The plutonic clasts in the Lockett Conglomerate range in SiO2 contents from 50 to 78 wt%. For the ultramafic to intermediate samples, the volcanic and plutonic clasts have similar MgO and trace element contents (Fig. 3). Relative to normal mid-ocean ridge basalt (N-MORB) both the volcanic and plutonic (ultra)mafic to intermediate clasts are depleted in incompatible elements (Fig. 4c–e). In the chondrite-normalized multi-element diagram the samples show either a slight light REE (LREE)-enriched pattern characteristic of subduction-related melts, or a V-shaped, middle REE (MREE)-depleted pattern typical of boninitic melts (Fig. 4f–h) (Crawford 1989). No clear covariation between REE concentrations and LaN /SmN , LaN /YbN or Eu/Eu* with increasing SiO2 concentration can be observed (Table 2), therefore the geochemical variation observed cannot simply reflect different degrees of melt evolution. Because of their relatively low Fe-number (i.e. Fe2 O3T/ (Fe2 O3T + MgO)) for a given SiO2 content the felsic clasts in the Lockett Conglomerate can be classified as magnesian metagranitoid rocks (Frost et al. 2001). Samarium–neodymium results obtained for five metagranitic samples of the Lockett Conglomerate gave ENd500 of 7.1 to +1.1 (Table 3). In recent L O C K E T T A N D D E A D G OAT C O N G L O M E R AT E S T U DY, N Z 1003 Fig. 3. Selected Harker variation diagrams for clasts of the Dead Goat Conglomerate compared with samples from the Lockett Conglomerate. Clasts in the Dead Goat Conglomerate are significantly enriched in HFSE and REE (as inferred from the Y concentration) compared with igneous clasts in the Lockett Conglomerate. Samples DG102 and DG150 from the Dead Goat Conglomerate, which were also analysed for REE and HFSE, are highlighted in (c). Most volcanic clasts in the Lockett Conglomerate have intermediate compositions, whereas plutonic clasts range in composition from ultramafic to highly felsic. intra-oceanic arcs, the range of ENd is generally confined to values between +2 and +9 (White & Patchett 1984). Whereas the ENd500 values of +1.1 to 0.7 for three of the measured clasts could appear realistic for an intra-oceanic setting, values of 5.4 and 7.1 for the remaining two clasts clearly imply a significant older crustal component. Sandstone clasts in the Dead Goat Conglomerate and the Lockett Conglomerate. Following the classification scheme of Bhatia & Crook (1986), trace element ratios such as Th/Sc and Ti/Zr in the quartzose sandstone clasts of both conglomerate units indicate an active continental margin tectonic setting of deposition (Th/Sc between 1.8 and 2.4; Ti/Zr between 11 and 15) (Bhatia & Crook 1986). ENd500 and depleted mantle model ages (TDM ) for Lockett Conglomerate sandstone clasts range from 15.7 to 14.3 and from 14.5 to 14.2 for sandstone clasts of the Dead Goat Conglomerate, corresponding to similar TDM of c. 2.2–2.3 Ga. Discussion Petrological, geochemical and isotopic lines of evidence point to an intra-Devil River arc source for the igneous clasts in the Dead Goat Conglomerate, as well as for the ultramafic to intermediate igneous clasts in the Lockett Conglomerate. Conversely, the metagranitic clasts in the Lockett Conglomerate and the sandstone clasts in the two conglomerates are exotic to the Devil River arc and derived from a different, continental source. A valuable feature for the identification of clast sources within the Devil River arc is the previously reported progressive change of igneous rock compositions through the evolution of the arc from low-K to high-K compositions (Münker 2000). Origin of the igneous clasts in the Dead Goat Conglomerate In Figure 6, the compositions of the igneous clasts in the Dead Goat Conglomerate are compared with volcanic samples from the Devil River arc (intermediate medium-K and high-K rocks (Benson Volcanic Suite) and felsic high-K rocks (Snowden Volcanic Suite) (Münker 2000). For the volcanic clasts, there is a close compositional similarity to the intermediate medium-K and high-K Devil River arc lavas, notably the enrichments in HFSE and REE, particularly LREE (see also Fig. 4b). The Nd isotope composition of the metavolcanic clasts (ENd500 of 2.1) matches that reported from medium-K to high-K mineral separates from within the Devil River arc (ENd500 of 2.1–4.1, Münker 2000). For the metagranitic clasts in the Dead Goat Conglomerate the agreement is not as good, as highly differentiated plutonic suites have not yet been reported from the Devil River arc. The high ENd500 values (3.5–5.9) of the metagranitic clasts in the Dead Goat Conglomerate strongly suggest an intra-Devil River arc origin, and the closest equivalents reported so far are felsic highK volcanic rocks emplaced in the latest stages of arc activity (i.e. Snowden Volcanic Suite, Münker 2000). The extreme enrichment in incompatible trace elements of the metagranitic clasts (Figs 4 and 6) points to a most feasible origin within the Devil River arc, produced either contemporary with or subsequent to the emplacement of the high-K Snowden Volcanic Suite. In comparison with the other plutonic clasts analysed from the Dead Goat Conglomerate, the dioritic sample plotted in Figure 4 (sample DG102) displays very high incompatible trace element contents. This clast could possibly be derived from a different within-arc source from the remaining more felsic plutonic clasts in the Dead Goat Conglomerate. Origin of the ultramafic to intermediate clasts in the Lockett Conglomerate The geochemical similarities of the volcanic and plutonic (ultra)mafic to intermediate clasts suggest a common petrogenetic history. Because a direct assessment of the alkalinity of the igneous clasts in the Lockett Conglomerate cannot be made, Th/ Yb v. Ta/Yb plots are employed because these elemental ratios mimic the compositional differences observed between low-K and high-K igneous suites (Fig. 7a; Pearce 1983). The compositional spread of the ultramafic to intermediate clasts in the 1004 M . G U T JA H R E T A L . Fig. 4. N-MORB- and C1-normalized multi-element plots for two clasts of the Dead Goat Conglomerate (a, b) and the Lockett Conglomerate (c–h), compared with several medium-K and high-K volcanic suites of the Devil River Volcanics (Peel, Cobb Flat, Circular Bush, Snowden Volcanic Conglomerate and Snowden Volcanic Suite formations). (c–e) N-MORB-normalized and (f–h) C1-normalized multi-element plots of mafic to intermediate clasts of the Lockett Conglomerate (LC) compared with samples of the ‘pre-Devil River’ source, the Cobb Igneous Complex and the low-K Benson Volcanic Suite. Literature data are from Münker (2000). Average N-MORB composition is from Hofmann (1988); chondrite composition is taken from Boynton (1984). L O C K E T T A N D D E A D G OAT C O N G L O M E R AT E S T U DY, N Z 1005 Lockett Conglomerate observed in Figure 7 corroborates the variability illustrated in Figure 4c–h of a mixture of boninitic and low-K subduction-related signatures. Within the Devil River arc the low-K arc-related suites, the boninitic ‘pre-Devil River’ rocks, and suites of the boninitic Cobb Igneous Complex presented by Münker (2000) are geochemically virtually identical to the ultramafic to intermediate clasts in the Lockett Conglomerate (Figs 4 and 7). On the other hand, the geochemical composition of the medium-K and high-K Devil River arcrelated rocks deviates substantially from that of the Lockett Fig. 5. Tera–Wasserburg plot for SHRIMP U–Pb zircon data for the cobble-sized metagranitic clast DG141 of the Dead Goat Conglomerate. Fig. 6. Trace element variation plots for the plutonic and volcanic clasts of the Dead Goat Conglomerate (DG), correlated with various medium-K and high-K rocks of the Benson Volcanic Suite (BV), and five samples of the high-K Snowden Volcanic Suite (SVS). Samples DG150 and DG102 were also analysed for REE and HFSE contents (see Fig. 4). Correlation data are from McLean (1994), Funk (1996) and Münker (2000). Fig. 7. Trace element variation plots for mafic to intermediate volcanic and plutonic clasts of the Lockett Conglomerate, compared with possible equivalents and sources. Clasts of the Lockett Conglomerate correlate best with boninitic samples of the ‘pre-Devil River’ source and the Cobb Igneous Complex (CIC), and moderately well with low-K Devil River arc-related samples. Medium-K and high-K Devil River arc-related volcanic rocks are generally more enriched in these elements. Comparative data are from Münker (2000). r, Most boninitic sample analysed by ICP-MS in the Lockett Conglomerate (LC94); m, sample of the Lockett Conglomerate showing the most typical low-K arc-related TE pattern (LC123); d, Lockett Conglomerate samples geochemically intermediate between the two end-member compositions. 1006 M . G U T JA H R E T A L . Conglomerate clasts. For this reason we propose a boninitic to low-K Devil River arc-related source as the origin of these clasts. (Fig. 9). On the other hand, data for comparison are scarce and the source might be either not exposed or no longer preserved. Origin of the sandstone clasts in the conglomerates Origin of the metagranitic clasts in the Lockett Conglomerate The metagranitic clasts in the Lockett Conglomerate are exotic to the intra-oceanic Devil River arc and require a nearby continental source area to supply these clasts. The palaeogeographical position of the Devil River island arc in the Mid- to Late Cambrian was outboard from the palaeo-Pacific margin of SE Gondwana. The Australian–Tasmanian–Antarctic section of the Cambrian palaeo-Pacific margin of Gondwana is the most proximal continent to the Devil River arc and the metagranitic clasts are most likely to have been derived from this craton. Despite the good Nd isotopic agreement between metagranitic clasts and igneous suites in different sections along this continental margin (Fig. 8) the observed wide range of Nd isotope compositions alone does not allow an unambiguous identification of the source area of these clasts. Moreover, only poor agreement is observed when using Zr and Y as additional proxies to ENd500 Combining the petrological, trace element and Nd isotope data, the sandstone clasts in the conglomerates can be described as being derived from a turbiditic quartzo-feldspathic sandstone suite deposited adjacent to an old cratonic province in which early Proterozoic rocks were extensively eroded. The very negative ENd500 values preclude a significant input of juvenile arcrelated material. In an earlier study of the Lockett Conglomerate, Pound (1993) inferred the sandstone clasts to be derived from the Junction Formation, a petrologically very similar quartzo-feldspathic sandstone suite exposed in a separate tectonic slice in the Takaka terrane (Münker & Cooper 1999). The results of the present study argue against this conclusion. The sandstone clasts analysed from the Dead Goat Conglomerate and the Lockett Conglomerate are petrologically more mature than those analysed by Pound (1993) (Fig. 2). Additionally, the Nd isotope composition of the sandstone clasts in the Dead Goat Conglomerate and the Lockett Conglomerate is less radiogenic (ENd500 in Fig. 8. Range in ENd500 of felsic clasts examined from the Lockett and Dead Goat conglomerates compared with published data for felsic igneous suites along the Australian–Tasmanian–Antarctic segment of the Cambrian palaeo-Pacific margin of Gondwana. d, individual results. All correlation samples depicted here are derived from igneous suites that were emplaced into continental crust. Data from Antarctica are geographically grouped. Literature sources: (1) Turner et al. (1993); (2) Foden et al. (2002); (3) Whitford et al. (1990); (4) Borg et al. (1987); (5) Armienti et al. (1990); (6) Cox et al. (2000); (7) Borg et al. (1990); (8) Wareham et al. (2001). L O C K E T T A N D D E A D G OAT C O N G L O M E R AT E S T U DY, N Z 1007 detritus from continental sandstones along the Cambrian palaeoPacific margin of Gondwana, following the approach of Wombacher & Münker (2000). Compared with a variety of sandstone suites from different sections along the palaeo-Pacific continental margin of Gondwana the sandstone clasts in the Dead Goat and Lockett conglomerates are the least radiogenic in Nd isotope composition, reflected in lowest ENd500 (Fig. 10). Although sandstone sequences of the Kanmantoo Group and the Adelaide Fold Belt in Australia geochemically and in Nd isotope composition correlate with sandstones analysed from the Junction Formation presented by Wombacher & Münker (2000), this agreement cannot be observed for sandstone clasts of the Dead Goat and Lockett conglomerates. The sandstone suites of the Wilson and Bowers terranes in Antarctica (Henjes-Kunst & Schüssler 2003) represent the closest equivalent. However, the sedimentary sequences in the Bowers terrane are unlikely to represent a possible source but rather are a probable lateral continuation of the Devil River arc sequence in present-day New Zealand (see Weaver et al. 1984; Bradshaw et al. 1985). Quartzo-feldspathic sandstone suites of Cambrian or older age are widely exposed along the Antarctic Cambrian palaeo-Pacific margin (Rowell et al. 2001; Goodge et al. 2002), but published Nd isotope data are scarce (Borg et al. 1990; Turner et al. 1993; Cox et al. 2000; Henjes-Kunst & Schüssler 2003). The sandstone clasts in the Dead Goat and Lockett conglomerates were fed from the Cambrian Gondwana palaeo-Pacific continental margin but an unequivocal source area cannot be nominated. Tectonic implications Fig. 9. Nd isotope ratios of the clasts examined from the Dead Goat and Lockett conglomerates plotted against Zr and Y concentrations, compared with several igneous suites from the Cambrian Australian– Tasmanian–Antarctic palaeo-Pacific margin of Gondwana. No satisfactory correlation between felsic clasts of the Lockett Conglomerate and other igneous suites can be observed. The intra-oceanic signature of igneous clasts deposited in the Dead Goat Conglomerate is reflected in the offset of this field from those of the other igneous suites. KGSA, Granites, Kanmantoo Group, South Australia (Turner et al. 1993); NVL, Granite Harbour Intrusives, Northern Victoria Land (Borg et al. 1987; Armienti et al. 1990); SVL, Dv1a and Dv1b suites, Southern Victoria Land (Cox et al. 2000); BGA, granitoids of the Beardmore Glacier Area, Central Transantarctic Mountains (Borg et al. 1990); LVG, Liv Volcanic Group, Central Transantarctic Mountains (Wareham et al. 2001). the range of 14.2 to 15.7) than that of the Junction Formation (ENd500 in the range of 9.7 to 11.2) (Fig. 10; Wombacher & Münker 2000). No other sandstone suite of appropriate age and similar source composition has been reported in New Zealand (see Cooper (1989) and Roser et al. (1996) for an overview). Hence, the source is either not exposed in present-day New Zealand, located in the Antarctic–Tasmanian section of the Cambrian palaeo-Pacific margin of Gondwana, or has been eroded and is no longer preserved. In Figure 10, a plot of ENd500 v. Th/Sc is used to discriminate Devil River arc-related sedimentary suites fed with volcaniclastic From consideration of tectonic models proposed in earlier studies and incorporating the data presented above, our results allow for a tighter reconstruction of the structural evolution of the Cambrian palaeo-Pacific margin of SE Gondwana. This region underwent profound deformation in the course of the Cambrian Ross–Delamerian orogenic event. Although still under debate, the favoured structural setting along the Cambrian palaeo-Pacific margin of Gondwana is that of eastward-dipping subduction in the SE Australian and Tasmanian segment (e.g. Flöttmann et al. 1998; Meffre et al. 2000; Foster et al. 2005) and westwarddipping subduction in the Antarctic segment of this continental margin (Kleinschmidt & Tessensohn 1987; Encarnación & Grunow 1996; Münker & Crawford 2000). Only a small fraction of the original island-arc sequence is preserved in New Zealand, but sufficient information is available to conclude that the Devil River intra-oceanic island arc was formed outboard of the Antarctic palaeo-Pacific margin. The Devil River arc-related sediments of the Haupiri Group are intruded by dykes of the back-arc tholeiitic Mataki Volcanics Formation (Fig. 11a) (Münker & Cooper 1999), providing strong support for the back-arc character of the Haupiri Group sediments. The Tasman Formation, which hosts the Dead Goat Conglomerate, is part of the Haupiri Group. Furthermore, at a few locations the Lockett Conglomerate rests conformably on sediments of the Tasman Formation (Fig. 1b), indicating that the sediments of the Haupiri Group and the Lockett Conglomerate were deposited in the same sedimentary basin. Both the Dead Goat Conglomerate and the Lockett Conglomerate contain clasts that are in part derived from the Devil River arc and the Gondwana continental margin (Fig. 11b and c), therefore the back-arc basin of the Devil River arc was situated between the Gondwana continental margin and the Devil River arc. For this reason subduction underneath the Devil River arc must have been westward-dipping. To accrete the Devil River intra-oceanic arc to 1008 M . G U T JA H R E T A L . Fig. 10. ENd500 v. Th/Sc for the sandstone clasts of the Lockett Conglomerate and the Dead Goat Conglomerate compared with the compositions of sandstones and shales from various sources within the Devil River arc and the Junction Formation (Wombacher & Münker 2000), Sandstone and shale sequences of the Kanmantoo Group and the Adelaide Fold Belt in SE Australia are shown for comparison (Turner et al. 1993), as well as compositions of various sandstone sequences in the Bowers terrane (BT), Robertson Bay terrane (RBT) and Wilson terrane in Antarctica (Henjes-Kunst & Schüssler 2003). The composition of the sandstone clasts of the Lockett Conglomerate (r) and the Dead Goat Conglomerate (d) are distinct from all other sedimentary suites shown here. The closest equivalent can be found in a few locations in the Bowers and Wilson terranes (see Henjes-Kunst & Schüssler (2003) for details). Fig. 11. Simplified schematic sketch map illustrating the late-stage tectonic evolution of the Devil River Arc complex and the final accretion to the Gondwana continental margin. Münker & Crawford (2000) have provided a detailed schematic model of the early stages in the evolution of the Devil River Arc. (See text for discussion.) L O C K E T T A N D D E A D G OAT C O N G L O M E R AT E S T U DY, N Z the Gondwana continental margin the back-arc basin between the arc and the continent had to be closed, either by strike-slip movement or by initiation of a second subduction zone between the arc and the continent. Subduction-related magmatism has been reported for the entire Cambrian Antarctic palaeo-Pacific margin (see references in Fig. 8 caption), hence the initiation of a second subduction zone is more feasible (Fig. 11b and c). The U–Pb SHRIMP age of 496 6 Ma for the metagranitic clast of the Dead Goat Conglomerate (Fig. 5) requires that highK igneous suites of the Devil River arc were uplifted and eroded immediately after emplacement. In addition, the Lockett Conglomerate contains boulder-sized ultramafic to intermediate clasts derived from older sequences of the Devil River arc (see above). To supply these clasts to the Lockett Conglomerate significant uplift and erosion was necessary to expose the boninitic to low-K igneous sequences of the Devil River arc to erosion (Fig. 11c), whereas at the same time the Antarctic continental margin was close enough to supply boulder-sized Andean-type metagranitic clasts. Accretion ended with the emplacement of the diapiric Balloon Mélange in the Latest Cambrian (Fig. 11d; see Jongens et al. 2003). We cannot pinpoint an exact location for the accretion of the Devil River arc to the Antarctic continental margin. However, the polarity of subduction of the different segments along the SE Gondwana Cambrian palaeo-Pacific margin (see above), the timing of events recorded by the Granite Harbour Intrusives in Antarctica (e.g. Encarnación & Grunow 1996), and the spatial and temporal distribution of deformational phases along the Transantarctic Mountains (e.g. Rowell et al. 2001) make the area of Southern Victoria Land or the northern Central Transantarctic Mountains the most likely location of accretion of the Devil River arc to the Cambrian palaeo-Pacific Gondwana margin. Conclusions Conglomerate clasts from Cambrian conglomerates in New Zealand provide important information relevant to tectonic events in SE Gondwana close to the Mid-Cambrian–Late Cambrian boundary. A back-arc basin (documented by the tholeiitic Mataki Volcanics Formation) separated the intra-oceanic Devil River arc from the Gondwana margin until the Mid-Cambrian. This backarc basin was subsequently closed by the onset of a second subduction system along the Gondwana margin, allowing Gondwana-derived material to be deposited in the intra-arc basins by the end of the Mid-Cambrian. The overlying conglomerates of late Mid-Cambrian age contain granitoids that were probably derived from the Ross–Delamerian continental margin and were deposited in a marginal marine to fluvial setting. The coarse sizes of this debris (.50 cm) imply a continuous subaerial slope of moderate gradient from continental margin to arc basin. The most likely position of accretion of the Devil River intra-oceanic arc to the Cambrian palaeo-Pacific margin was in the area of Southern Victoria Land or the northern Central Transantarctic Mountains. The Brian Mason Trust of the University of Canterbury is thanked for providing financial support for the fieldwork, the geochemical analysis and the SHRIMP dating. K. Mezger (ZLG Münster) generously provided access to the ZLG research facilities for the Sm–Nd isotope analysis. D. GarbeSchönberg in Kiel (Germany) facilitated REE and HFSE analyses. SHRIMP measurements were conducted at the Australian National University in Canberra. The research of M.G. was supported by a University of Canterbury’s Master’s Scholarship. The Department of Conservation, New Zealand, provided free accommodation facilities during the fieldwork in 1009 Cobb Valley, NW Nelson. We are grateful to T. Waight and J. Foden for their constructive reviews of the manuscript, and D. Peate is thanked for editorial handling and additional constructive reviews. References Armienti, P., Ghezzo, C., Innocenti, F., Manetti, P., Rocchi, S. & Tonarini, S. 1990. Isotope geochemistry and petrology of granitoid suites from Granite Harbour Intrusives of the Wilson Terrane, Northern Victoria Land, Antarctica. European Journal of Mineralogy, 2, 103–123. Bhatia, M.R. & Crook, K.A.W. 1986. Trace element characteristics of graywackes and tectonic setting discrimination of sedimentary basins. Contributions to Mineralogy and Petrology, 92, 181–193. Borg, S.G., Stump, E., Chappell, B.W., McCulloch, M.T., Wyborn, D., Armstrong, R.J. & Holloway, J.R. 1987. Granitoids of Northern Victoria Land, Antarctica: implications of chemical and isotopic variations to regional crustal structure and tectonics. American Journal of Science, 287, 129–169. Borg, S.D., DePaolo, D.J. & Smith, B.M. 1990. Isotope structure and tectonics of the Central Transantarctic Mountains. Journal of Geophysical Research, 95(B5), 6647–6667. Boynton, W.V. 1984. Cosmochemistry of the rare earth elements: meteorite studies. In: Henderson, P. (ed.) Rare Earth Element Geochemistry. Elsevier, Amsterdam, 89–94. Bradshaw, J.D., Weaver, S.D. & Laird, M.C. 1985. Suspect terranes and Cambrian tectonics in Northern Victoria Land, Antarctica. In: Howell, D.C. (ed.) Tectonostratigraphic Terranes of the Circum-Pacific Region. CircumPacific Council for Energy and Mineral Resources, Houston, TX, 467–479. Coleman, A.C. 1978. Composition of the Lockett Conglomerate Lake Sylvester Area, northwest Nelson. New Zealand Journal of Geology and Geophysics, 21, 549–552. Cooper, R.A. 1989. Early Paleozoic terranes in New Zealand. Journal of the Royal Society of New Zealand, 19, 73–112. Cooper, R.A. 2004. New Zealand Geological Timescale 2004/2 Wallchart. Institute of Geological & Nuclear Sciences Information Series, 64. Cooper, R.A. & Tulloch, A.J. 1992. Early Paleozoic terranes in New Zealand and their relationship to the Lachlan Fold Belt. Tectonophysics, 214, 129–144. Cox, S.C., Parkinson, D.L., Allibone, A.H. & Cooper, A.F. 2000. Isotopic character of Cambro-Ordovician plutonism, Southern Victoria Land, Antarctica. New Zealand Journal of Geology and Geophysics, 43, 501–520. Crawford, A.J. (ed.) 1989. Boninites. Unwin Hyman, London. Davidek, K., Landing, E., Bowring, S.A., Westrop, S.R., Rushton, A.W.A., Fortrey, R.A. & Adrain, J.M. 1998. New uppermost Cambrian U–Pb date from Avalonian Wales and age of the Cambro-Ordovician boundary. Geological Magazine, 135, 305–309. Dickinson, W.R., Beard, L.S., Brakenridge, G.R., Erjavec, J.L. & Fergusen, R.C. 1983. Provenance of North American Phanerozoic sandstones in relation to tectonic setting. Geological Society of America Bulletin, 94(2), 222–235. Encarnación, J. & Grunow, A. 1996. Changing magmatic and tectonic styles along the paleo-Pacific margin of Gondwana and the onset of Early Paleozoic magmatism in Antarctica. Tectonics, 15(6), 1325–1341. Encarnación, J., Rowell, A.J. & Grunow, A. 1999. A U–Pb age for the Cambrian Taylor Formation, Antarctica: implications for the Late Cambrian time scale. Journal of Geology, 107, 497–504. Flöttmann, T., Haines, P., Jago, J., James, P., Belperio, A. & Gum, J. 1998. Formation and reactivation of the Cambrian Kanmantoo Trough, SE Australia: implications for early Palaeozoic tectonics at eastern Gondwana’s plate margin. Journal of the Geological Society, London, 155, 525–539. Foden, J.D., Elburg, M.A., Turner, S.P., Sandiford, M., O’Callaghan, J.O. & Mitchell, S. 2002. Granite production in the Delamerian orogen, South Australia. Journal of the Geological Society, London, 159, 557–575. Foster, A.F., Gray, D.R. & Spaggiari, C. 2005. Timing of subduction and exhumation along the Cambrian East Gondwana margin, and the formation of Paleozoic backarc basins. Geological Society of America Bulletin, 117, 105– 116. Frost, B.R., Barnes, C.G., Collins, W.J., Arculus, R.J., Ellis, D.J. & Frost, C.D. 2001. A geochemical classification for granitic rocks. Journal of Petrology, 42, 2033–2048. Funk, T. 1996. Geologische und geochemische Untersuchung an kambrischen Vulkaniten Neuseelands. Diploma thesis, University of Göttingen. Garbe-Schönberg, C.-D. 1993. Simultaneous determination of thirty-seven trace elements in twenty-eight international rock standards by ICP-MS. Geostandards Newsletter, 17, 81–97. Goldstein, S.L., O’Nions, R.K. & Hamilton, P.J. 1984. A Sm–Nd study of atmospheric dusts and particulates from major river systems. Earth and Planetary Science Letters, 70, 221–236. Goodge, J.W., Myrow, P., Williams, I.S. & Bowring, S.A. 2002. Age and 1010 M . G U T JA H R E T A L . provenance of the Beardmore Group, Antarctica: constraints on Rodinia supercontinent breakup. Journal of Geology, 110, 393–406. Grindley, G.W. 1980. Sheet S13 Cobb, 1st. Geological Map of New Zealand 1:63 360, Department of Scientific and Industrial Research, Wellington. Henjes-Kunst, F. & Schüssler, U. 2003. Metasedimentary units of the CambroOrdovician Ross orogen in Northern Victoria Land and Oates Land: implications for the provenance and geotectonic setting from geochemical and Nd–Sr isotope data. Terra Antartica, 10(3), 105–128. Hofmann, A.W. 1988. Chemical differentiation of the Earth: the relationship between mantle, continental crust and oceanic crust. Earth and Planetary Science Letters, 90, 297–314. Humphris, S.E. & Thompson, G. 1978. Hydrothermal alteration of oceanic basalts by seawater. Geochimica et Cosmochimica Acta, 42, 107–125. Jongens, R., Bradshaw, J.D. & Fowler, A. 2003. The Balloon Mélange, northwest Nelson: origin, structure and emplacement. New Zealand Journal of Geology and Geophysics, 46, 437–448. Kleinschmidt, G. & Tessensohn, F. 1987. Early Paleozoic westward directed subduction at the Pacific margin of Antarctica. In: McKenzie, G.D. (ed.) Gondwana Six: Structure, Tectonics, and Geophysics. American Geophysical Union, Washington D.C. 89–105. Landis, C.A. & Coombs, D.S. 1967. Metamorphic belts and orogenesis in Southern New Zealand. Tectonophysics, 4, 501. Le Bas, M.J. 2000. IUGS reclassification of the high-Mg and picritic volcanic rocks. Journal of Petrology, 41, 1467–1470. McLean, D.R. 1994. The geology and geochemistry of the Cambrian Devil River Volcanics, Anatoki Range, northwest Nelson. Master’s thesis, University of Canterbury, Christchurch. Meffre, S., Berry, R.F. & Hall, M. 2000. Cambrian metamorphic complexes in Tasmania: tectonic implications. Australian Journal of Earth Sciences, 47, 971–985. Muir, R.J., Ireland, T.R., Weaver, S.D. & Bradshaw, J.D. 1996. Ion microprobe dating of Paleozoic granitoids: Devonian magmatism in New Zealand and correlations with Australia and Antarctica. Chemical Geology, 127, 191–210. Münker, C. 2000. The isotope and trace element budget of the Cambrian Devil River Arc system, New Zealand: identification of four source components. Journal of Petrology, 41, 759–788. Münker, C. & Cooper, R.A. 1995. The island arc setting of a New Zealand Cambrian volcano-sedimentary sequence: implications for the evolution of the southwest Pacific Gondwana fragments. Journal of Geology, 103, 687– 700. Münker, C. & Cooper, R.A. 1999. The Cambrian arc complex of the Takaka Terrane, New Zealand: an integrated stratigraphical, paleontological and geochemical approach. New Zealand Journal of Geology and Geophysics, 42, 415–445. Münker, C. & Crawford, A.J. 2000. Cambrian arc evolution along the SE Gondwana active margin: a synthesis from Tasmania–New Zealand–Australia–Antarctica correlations. Tectonics, 19, 415–432. Norrish, K. & Hutton, J.T. 1969. An accurate X-ray spectrographic method for the analysis of a wide range of geologic samples. Geochimica et Cosmochimica Acta, 33, 431–454. Pearce, J.A. 1983. The role of sub-continental lithosphere in magma genesis at destructive plate margins. In: Hawkesworth, C.J. & Norris, M.J. (eds) Continental Basalts and Mantle Xenoliths. Shiva, Nantwich, 230–249. Pettijohn, F.J. 1963. Chemical Composition of Sandstones. US Geological Survey, Professional Papers, N-40S. Pound, K.S. 1993. Geology of the Lower Paleozoic Haupiri Group rocks, Cobb Valley area, northwest Nelson, New Zealand. PhD thesis, University of Otago, Dunedin. Rattenbury, M.S., Cooper, R.A. & Johnston, M.R. 1998. Geology of the Nelson area. Geological map 9 (1:250 000). Institute of Geological and Nuclear Sciences, Lower Hutt. Roser, B.P., Cooper, R.A., Nathan, S. & Tulloch, A.J. 1996. Reconnaissance sandstone geochemistry, provenance, and tectonic setting of the lower Paleozoic terranes of the Weast Coast and Nelson, New Zealand. New Zealand Journal of Geology and Geophysics, 39, 1–16. Rowell, A.J., Van Schmus, W.R., Storey, B.C., Fetter, A.H. & Evans, K.R. 2001. Latest Neoproterozoic to mid-Cambrian age for the main deformational phases of the Transantarctic Mountains: new stratigraphic and isotopic constraints from the Pensacola Mountains, Antarctica. Journal of the Geological Society, London, 158, 295–308. Shelley, D. 1993. Igneous and Metamorphic Rocks under the Microscope: Classification, Textures, Microstructures, and Mineral-preferred Orientations. Chapman & Hall, London. Siebert, C. 1998. Geology and geochemistry of metavolcanic rocks in the Baton Valley area, northwest Nelson. Diploma thesis, Georg August University, Göttingen. Turner, S., Foden, J., Sandford, M. & Bruce, D. 1993. Sm–Nd evidence for the provenance of sediments from the Adelaide Fold Belt and southeastern Australia with implications for episodic crustal addition. Geochimica et Cosmochimica Acta, 57, 1837–1856. Wareham, C.D., Stump, E., Storey, B.C., Millar, I. & Riley, T.R. 2001. Petrogenesis of the Cambrian Liv Group, a bimodal volcanic rock suite from the Ross Orogen, Transantarctic Mountains. Geological Society of America Bulletin, 113(3), 360–372. Weaver, S.D., Bradshaw, J.D. & Laird, M.G. 1984. Geochemistry of Cambrian volcanics of the Bowers Supergroup and implications for the early Paleozoic tectonic evolution of northern Victoria Land, Antarctica. Earth and Planetary Science Letters, 68, 128–140. White, W.M. & Patchett, P.J. 1984. Hf–Nd–Sr isotopes and incompatible trace element abundances in island arcs: implications for magma origin and crust– mantle evolution. Earth and Planetary Science Letters, 67, 167–185. Whitford, D., Crawford, T., Korsch, M. & Craven, S. 1990. Mt. Read Volcanics: strontium and neodymium isotope geochemistry.In: IAVCEI Abstracts: Ancient Volcanism and Modern Analogues. 1, 122. Wombacher, F. & Münker, C. 2000. Pb, Nd, and Sr isotopes and REE systematics of Cambrian sediments from New Zealand: implications for the reconstruction of the Early Paleozoic Gondwana margin along Australia and Antarctica. Journal of Geology, 108, 663–686. Wood, D.A., Gibson, I. & Thompson, R.N. 1976. Element mobility during zeolite facies metamorphism of the Tertiary basalts of eastern Iceland. Contributions to Mineralogy and Petrology, 55, 241–254. Received 27 January 2005; revised typescript accepted 23 March 2006. Scientific editing by David Peate
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