1. What is the oxidation number of iodine in KIO 4? A) +1 B) –1 C) +7 9. Given the unbalanced ionic equation: D) –7 2. Which half-reaction correctly represents reduction? A) B) C) D) When this equation is balanced, both Fe3+ and Fe have a coefficient of Mn 4+ ® Mn 3+ + e – Mn 4+ ® Mn 7+ + 3e – Mn 4+ + e – ® Mn 3+ Mn 4+ + 3e – ® Mn 7+ 3. In a redox reaction, the total number of electrons lost is A) B) C) D) less than the total number of electrons gained greater than the total number of electrons gained equal to the total number of electrons gained equal to the total number of protons gained 4. Given the electrochemical cell reaction: Zn(s) + Ni2+ (aq) ® Zn2+ (aq) + Ni(s) Which species is the reducing agent? A) Zn B) Ni 2+ C) Zn2+ D) Ni 5. When a redox reaction occurs, there must be a transfer of A) electrons C) protons B) neutrons D) ions 6. Which half-reaction correctly represents reduction? A) Ag ® Ag+ + e – C) Au 3+ + 3e – ® Au B) F2 ® 2 F– + 2e – D) Fe 2+ + e – ® Fe 3+ 7. Which reaction occurs spontaneously? A) B) C) D) Cl 2(g) + 2NaBr(aq) Br2( ) + 2NaCl(aq) Cl 2(g) + 2NaF(aq) F2(g) + 2NaCl(aq) I 2(s) + 2NaBr(aq) Br 2( ) + 2NaI(aq) I 2(s) + 2NaF(aq) F2(g) + 2NaI(aq) 8. Which metal is more active than Ni and less active than Zn? A) Cu B) Cr C) Mg D) Pb A) B) C) D) 1, because a total of 6 electrons is transferred 2, because a total of 6 electrons is transferred 1, because a total of 3 electrons is transferred 2, because a total of 3 electrons is transferred 10. Given the balanced equation representing a reaction: 2Fe + 3Cu2+ ® 2Fe 3+ + 3Cu When the iron atoms lose six moles of electrons, how many moles of electrons are gained by the copper ions? A) 12 moles C) 3 moles B) 2 moles D) 6 moles 11. A voltaic cell differs from an electrolytic cell in that in a voltaic cell A) B) C) D) energy is produced when the reaction occurs energy is required for the reaction to occur both oxidation and reduction occur neither oxidation nor reduction occurs 12. Given the balanced equation representing the reaction occurring in a voltaic cell: Zn(s) + Pb2 +(aq) Zn2 + (aq) + Pb(s) In the completed external circuit, the electrons flow from A) B) C) D) Pb(s) to Zn(s) Pb2+(aq) to Zn2+(aq) Zn(s) to Pb(s) Zn2+(aq) to Pb 2+(aq) 13. The diagram below shows a key being plated with copper in an electrolytic cell Given the reduction reaction for this cell: Cu2+(aq) + 2e- Cu(s) This reduction occurs at A) B) C) D) A, which is the anode A, which is the cathode B, which is the anode B, which is the cathode Answer Key Topic 12 - Electrochemistry 1. C 2. C 3. C 4. A 5. A 6. C 7. A 8. B 9. B 10. D 11. A 12. C 13. B
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