Real World Chemistry Students were able to authentically connect concepts which bridged scientific and artistic content areas. Curriculum/State Standards K-12 Science Benchmarks By the end of the 11-12 program: Physical Sciences - A. Explain how variations in the arrangement and motion of atoms and molecules form the basis of a variety of biological, chemical and physical phenomena. Scientific Inquiry - A. Make appropriate choices when designing and participating in scientific investigations by using cognitive and manipulative skills when collecting data and formulating conclusions from the data. Scientific Ways of Knowing - A. Explain how scientific evidence is used to develop and revise scientific predictions, ideas or theories. Academic Content Standards Grade Eleven Science and Technology 1-3 Scientific Inquiry 1-5 Scientific Ways of Knowing 1-3, 5, 11 Grade Twelve Physical Sciences 5 Science and Technology 3 Scientific Inquiry 1-5 Scientific Ways of Knowing 1-5, 9 Overview Students were given five tasks which are described in the Objectives section below. The tasks were open ended and required students to apply previously learned knowledge and problem solving skills to a real world application. A hands-on inquiry approach was used to connect the following concepts: • Stoichiometry and propulsion (2 projects) •P olarity, Fabric chemistry and art (2 projects) • Electrochemistry, Adhesion and art Project Objectives 11-12 GRADE LEVEL • The students will develop critical thinking skills to project 20 years into the future and create their own Materials Soda Bottle Boats: baking soda and vinegar Fuel Cell Football: PVC pipe, PVC adapters, bbq grill igniter, butt connectors, speaker wire, Plexiglass Radial Chromatography T-Shirts: Sharpie markers and 99% rubbing alcohol Anodized Aluminum: aluminum flashing and Rit dye Reactive Fabric Dyes: dye fixer, Urea, Ludigol, gloves, reactive dyes Readiness Activity This project was implemented in a second year chemistry course. “Soda Bottle Boats” was a hands on, inquiry based review of first year stoichiometry. “Fuel Cell Football” was a discovery activity preceding a unit on gas laws to break things down in the simplest terms: 2 parts hydrogen gas + 1 part oxygen gas + 1 water molecule (and a whole lot of fun!) “Radial Chromatography” was a crossover topic from properties of solutions into on organic chemistry. “Anodized Aluminum” was a culmination of a unit on electrochemistry. “Reactive Fabric Dyes” was a culmination of a unit on organic chemistry. 5 WEEKS Continued... $500 TOTAL BUDGET THIS WINNING PROJECT IDEA WAS SUBMITTED BY: Jeff Ungerer Fairbanks High School 11158 State Route 38, Milford Center, OH 43045 “Real World Chemistry” project continued... Strategies/Activities Soda Bottle Boats: • A reaction between baking soda and vinegar was demonstrated. • The following question and directive was posed to students: “Can you and your lab partner build a “boat” from a 20 oz. bottle powered only by baking soda and vinegar that will travel the length of 10 feet in under 60 seconds? GO!” The answer to, “How long do we have?” was, “How long do you need? GO! Have fun! Make something fabulous! GO!” This is a very open ended activity and will be descibed as such. In pairs, students will construct a boat powered only by the reaction produced by baking soda and vinegar. Each group will have access to glue guns, scissors, electronic balances, utility knives, baking soda, vinegar, and flexible straws. Other materials may be used in the construction process. Creativity is expected. It is expected that no two groups will merge to prepare identical construction plans. This will force partners to work as partners, and no informal groups of four will have an advantage. In addition, students will have to optimize the “fuel” ratio. Boats will be launched outside in a 10 foot gutter filled with water. Each group will have 3 launch attempts. Between launches, modifications to the “fuel” ratio or the “fuel” delivery method will be allowed. Students will record time, distance, and amounts of baking soda and vinegar for each trials. Radial Chromatography T-Shirts: Radial Chromatography Students will provide a prewashed, white, cotton clothing item. Each student will have access to Sharpie markers, rubbing alcohol, disposable pipets, rubber bands, and empty cans of assorted diameters. By stretching a section of fabric over the can and securing with a rubber band, a circular pattern of dots can be made with the markers. Rubbing alcohol is dropped in the center of the dots. The effulent separates the marker dyes into a unique, beautiful radial pattern. Students will explore color combinations, patterns, and marker dye composition. Students will be able to take home their creation, iron it to set the dyes, and wear it forever. Although one objective may be to teach chromatography as a method to separate mixtures, there is an extension to a culminating event after teaching the topics of polarity and chemical bonding. Reference: http://chemmovies.unl. edu/chemistry/beckerdemos/BD038c. html Anodized Aluminum: Aluminum can be a anodized by immersion into a boiling water bath containing Rit dye. The dye permanently bonds with the surface layer of aluminum oxide. Students will use the internet to research procedures of surface preparation to maximize the formation of aluminum oxide. Students will submit a written proposal to prepare the surface. Upon approval from the instructor, the student will receive a one square foot piece of aluminum flashing and scissors. Various colors of Rit dye will be available. Students will test various color combinations and immersion times. The expectation is that students will create unique shapes, colors, and patterns during the project. The outcome of this project could, certainly, be a fabulous mobile or chandelier. In a 1-L beaker, heat 1 package of powdered Rit-Dye® until it nearly boils. Immerse aluminum flashing into the mixture until the flashing is coated with the dye. The coating is a permanent bond between the dye and the aluminum oxide layer on the surface. Fuel Cell Football: A scaled version of an NFL goal post can be constructed with PVC pipe and connectors. A BBQ grill igniter can be modified with Butt Connectors and Speaker Wire to create an ignition source for an exothermic reaction. The exothermic reaction is generated inside of a jumbo pipet bulb between hydrogen gas and oxygen gas. These gases are generated as such: Hydrogen: Mossy Zinc and 2 M hydrochloric acid Oxygen: Bakers yeast and 3% hydrogen peroxide Students use water displacement in the jumbo pipet bulb to create a 2:1 ratio. Students experiment to determine the proper amount of water to leave in the jumbo pipet bulb for maximum propulsion. Reactive Fabric Dyes: Students soak a 100% white cotton T-shirt in dye fixer for 5 – 10 minutes. During this time, students will prepare work surfaces with plastic coverings and newspaper. They will, also, gather previously prepared (by the instructor) dye solutions according to their color scheme. (Details on preparing dyes can be found at www.bestdye.com). Students fold and tie their shirts according to the pattern that they desire. Dye is applied with pipets. Continued... “Real World Chemistry” project continued... Culminating Activity Soda Bottle Boats: Introduction to second year stoichiometry Fuel Cell Football: PV = nRT Radial Chromatography T-Shirts: Evaluation by the art department Anodized Aluminum: Evaluation by the art department Reactive Fabric Dyes: “Shock and awe” as juniors and seniors parade the halls of Fairbanks High School clothed in tie-dyed beauty. Evaluation Method Soda Bottle Boats: Times, daily progress, and project summary Radial Chromatography T-Shirt: Exam question: You are given an orange M&M. Describe how you would determine the composition of the dye. Anodized Aluminum: Students will present their final anodized aluminum project to the class for peer review. In doing so, they will be expected to describe their methodology. Fuel Cell Football: This is very performance based … did it go through the goal or not? I used this activity for bonus points to create excitement at the beginning of a unit and the end of a grading period. I followed up with post lab questions describing in the original grant application. Reactive Fabric Dyes: Exam question: Consider the following structures of a cotton and Procion Brilliant Blue RS dye. Cotton: Explain how the dye fixer (sodium carbonate) allows the Procion Brilliant Blue RS dye to react with the cotton.”“Consider the structure of the ester monomer used to make polyester. Would Procion Brilliant Blue RS dye react with polyester? Explain your reasoning.
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