PRODUCT SAFETY DATA SHEET Print date: 28 Mar 2008 1. PRODUCT AND COMPANY IDENTIFICATION Item Number / Product code: 0160711 & 0160719 Product name: LYSOL BRAND 4 in 1 ANTIBACTERIAL KITCHEN CLEANER, CITRUS SCENT (TRIGGER & REFILL) CANADIAN Validation / Revision Date: 26 March 2008 Formula Number: 1324-103A (0160711) 1384-055 (0160719) UPC Number and Size: 22 fl. oz. Trigger Spray & 144 fl. oz. Refill container. Product Description: Antibacterial kitchen cleaner, trigger spray. Manufacturer: Reckitt Benckiser (CANADA) Inc. 1680 Tech Avenue, Unit #2 Mississauga, Ontario L4W 5S9 CANADA Emergency Telephone Number: 1-800-338-6167 (Canada) Office Tel: 905-283-7000 Toll-Free: 1-800-665-1492 FAX: 905-283-7001 Transportation Emergencies: 1-800-424-9300 (U.S. & Canada) CHEMTREC Outside the U.S. and Canada (North America), call: 703-527-3887 2. COMPOSITION / INFORMATION ON INGREDIENTS Product code: 0160711 & 0160719 Product name: LYSOL BRAND 4 in 1 ANTIBACTERIAL KITCHEN CLEANER, CITRUS SCENT (TRIGGER & REFILL) - CANADIAN Page 1 of 7 Components: BENZALKONIUM CHLORIDE 80% 68424-85-1 BENZYLKONIUM CHLORIDE (50%) 63449-41-2 MONOETHANOLAMINE ICF GRDE 141-43-5 LAURYLDIMETHAMINEOXIDE30% 1643-20-5 Wt % 0-0.05 ACGIH: None OSHA: None 0-0.2 None None 0-1.0 TWA (TLV): 3 ppm @10 STEL: 6 ppm @10 TWA (PEL): 3 ppm @10 TWA (PEL): 6 mg/m³ @10 1-5 None None 3. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW CAUTION: IRRITATING TO EYES. DO NOT get in eyes. Wash thoroughly with soap and water after handling. Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals. KEEP OUT OF REACH OF CHILDREN 4. FIRST AID MEASURES Inhalation: Move to fresh air. Skin contact: Wash off immediately with soap and plenty of water. If irritation persists or an allergic reaction occurs, get medical attention. Eye contact: If splashed in eyes, IMMEDIATELY rinse eyes with water. Remove any contact lenses and continues rinsing eyes for at least 15 minutes. Call a doctor or Poison Control Center if symptoms persist. Ingestion: If swallowed, rinse mouth with water and seek IMMEDIATE medical advice. Show the container or product label to the medical personnel. Notes to physician: Contains Monoethanolamine. Contains Benzalkonium Chloride. Aggravated Medical Conditions: No information available. 5. FIRE-FIGHTING MEASURES Flash point: CLOSED CUP: Higher than 93.3º C (>200º F). [Tagliabue]. Flammability Limits in Air: Lower: Upper: No information available. No information available. Autoignition temperature: No information available. Suitable extinguishing media: As suitable for surrounding fire. Extinguishing media which must not No information available. be used for safety reasons: Specific hazards: Product code: 0160711 & 0160719 See Section 3, Hazards Identification. Product name: LYSOL BRAND 4 in 1 ANTIBACTERIAL KITCHEN CLEANER, CITRUS SCENT (TRIGGER & REFILL) - CANADIAN Page 2 of 7 Unusual hazards: None known Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus, pressure-demand, MSHA / NIOSH (approved or equivalent) and full protective gear. Specific methods: Standard procedure for chemical fires. Key: Personal Protection Index = B. (Also see Sections 3 & 8) 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Ensure adequate ventilation. Environmental precautions: Do not allow material to contaminate ground water system. Methods for cleaning up: Small spills: Soak up with absorbent material and dispose of in an appropriate waste container. Large spills should be diked, contained and collected for later disposal according to local, provincial, state or federal regulations. 7. HANDLING AND STORAGE Handling: Use with adequate ventilation. DO NOT use on eating/cooking utensils, glasses/dishes or cookware, unfinished, oiled or waxed wood floors. Rinse all food contact surfaces with potable water. Safe handling advice: Product is an eye irritant. Product is a sensitizer. Avoid contact with eyes, skin and clothing. Wash thoroughly with soap and water after handling. Wear suitable protective clothing, gloves and eye/face protection. Use only as directed on the container label. Trigger Container: Refill only with this product. If not refilling, rinse empty container throughly and discard in trash or recycle. Refill Container: Do not reuse container. Discard in trash or recycle. Storage: Keep tightly closed. Store in original container in areas inaccessable to small children and pets. KEEP OUT OF REACH OF CHILDREN Incompatible products: Do not mix with other household chemicals. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures to reduce exposure: For occupational exposures, ensure adequate ventilation. Personal Protective Equipment Respiratory protection: Product code: 0160711 & 0160719 None required under normal use conditions. Product name: LYSOL BRAND 4 in 1 ANTIBACTERIAL KITCHEN CLEANER, CITRUS SCENT (TRIGGER & REFILL) - CANADIAN Page 3 of 7 Hand protection: Wear impervious gloves where the potential for contact with the liquid is possible. Emergency responders should wear impermeable gloves. Skin and body protection: Usual safety precautions while handling the product will provide adequate protection against injury or irritation. Follow product label instructions. Eye protection: Avoid contact with eyes. Eye irritant, wear eye protection if the possibility of splashing exists. Emergency responders should wear full eye and face protection. Hygiene measures: Avoid contact with skin, eyes and clothing. Wash hands with soap and water after handling. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Appearance: Colour: Odour: pH: Flash point: Liquid. Trigger spray. Clear. Citrus. Lemon. 10.5 - 11.1 Greater than 93º C (>200º F) Specific gravity: 8.4 lbs/gal Vapour pressure: Solubility: Not determined. Completely soluble. Explosion limits: - upper: - lower: No data available. No data available. 10. STABILITY AND REACTIVITY Stability: Stable under recommended storage conditions. Polymerization: Hazardous polymerisation does not occur. Hazardous decomposition products: Oxides of carbon and unknown organic compounds. Materials to avoid: Do not mix with other household chemicals. Conditions to avoid: Store away from excessive heat and moisture. 11. TOXICOLOGICAL INFORMATION Acute toxicity Component Information: Product Information LC50/inhalation/4h/rat = LD50/dermal/rabbit = LD50/oral/rat = No information available. No information available. No information available. Local effects Skin irritation: None expected during normal conditions of use. Eye irritation: Eye irritant. Irritating to eyes. Product code: 0160711 & 0160719 Product name: LYSOL BRAND 4 in 1 ANTIBACTERIAL KITCHEN CLEANER, CITRUS SCENT (TRIGGER & REFILL) - CANADIAN Page 4 of 7 Inhalation None expected during normal conditions of use. Ingestion Health injuries are not known or expected under normal use. See Section 4 for First Aid instructions. Sensitization Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals. Chronic toxicity: No information available. Specific effects Carcinogenic effects: Not listed as carcinogenic by OSHA, NTP or IARC. Mutagenic effects: No information available. Reproductive toxicity: No information available. Target organ effects: No information available. Information is based on data on the components and the toxicology of similar products. 12. ECOLOGICAL INFORMATION Product Information Aquatic toxicity: No information available. Component Information: MONOETHANOLAMINE ICF GRDE 141-43-5 (0-1.0) Ecotoxicity: = 13.7 mg/L EC50 Photobacterium phosphoreum = 170.0 mg/L LC50 goldfish = 2070 mg/L LC50 fathead minnow flow-through Other information: Ozone depletion potential; ODP; (R-11 = 1) = Global warming potential (GWP) = No information available. No information available. Additional ecological information: Information given is based on data on the components and the ecotoxicology of similar products. 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products: Dispose of in accordance with local regulations. Contaminated packaging: Empty container can be disposed of as household trash or rinsed and recycled where appropriate. Waste Disposal: Small amounts of liquid waste: Wipe up with a wet paper towel and discard absorbed material in trash collection or flush waste to sink or sanitary sewer. Large quantities of waste liquid: Contain and collect for evaluation and disposal according to local, state, provincial and federal regulations. 14. TRANSPORT INFORMATION UN / Id No: Product code: 0160711 & 0160719 Not applicable Product name: LYSOL BRAND 4 in 1 ANTIBACTERIAL KITCHEN CLEANER, CITRUS SCENT (TRIGGER & REFILL) - CANADIAN Page 5 of 7 DOT: Classification: Proper shipping name: U.S. DOT - Hazard Class: Subsidiary risk: Packing Group: DOT RQ (lbs): ERG No: Not a DOT regulated material. (United States) Not applicable. Not applicable. Not applicable. Not applicable. Not applicable. Not applicable. TDG (Canada): Classification: Proper shipping name: Status: Packing Group: Not regulated under TDG Not applicable. Not applicable. Not applicable. IMDG / IMO Classification: Proper shipping name: Class: Subsidiary Risk: Packing group: IMDG page: Marine pollutant: EMS: MFAG: Not regulated under IMDG Not applicable. Not applicable. Not applicable. Not applicable. Not applicable. Not applicable. Not applicable. Not applicable. ADR / RID Classification: Proper shipping name: Class: Subsidiary risk: ADR/RID-labels: Hazard Identification Number: CEFIC Tremcard No: Not applicable. Not applicable. Not applicable. Not applicable. Not applicable Not applicable. Not applicable. ICAO / IATA: Classification: Proper shipping name: Class: Subsidiary Risk: Packing Group: Maximum quantity Not regulated under ICAO / IATA Not applicable. Not applicable. Not applicable Not applicable. Not applicable. 15. REGULATORY INFORMATION Components: BENZALKONIUM CHLORIDE 80% MONOETHANOLAMINE ICF GRDE LAURYLDIMETHAMINEOXIDE30% PICCS: Present TSCA: Present Present Present DSL: Present Present Present NDSL: ENCS: CHINA: Present Present Present AICS: Present Present Present EINECS-No 270-325-2 205-483-3 216-700-6 U.S. Regulations: Components: BENZALKONIUM CHLORIDE 80% - 68424-85-1 NJRTK: California Proposition 65 - Not Listed. None. Components: BENZYLKONIUM CHLORIDE (50%) - 63449-41-2 Product code: 0160711 & 0160719 Product name: LYSOL BRAND 4 in 1 ANTIBACTERIAL KITCHEN CLEANER, CITRUS SCENT (TRIGGER & REFILL) - CANADIAN Page 6 of 7 NJRTK: California Proposition 65 - Not Listed. None. Components: MONOETHANOLAMINE ICF GRDE - 141-43-5 NJRTK: California Proposition 65 - Not Listed. None. Components: LAURYLDIMETHAMINEOXIDE30% - 1643-20-5 NJRTK: California Proposition 65 CERCLA/SARA 313: Not Listed. None. None Canada WHMIS hazard class: Not determined. 16. OTHER INFORMATION Reason for revision: This is a new formulation of an existing product. Additional advice: This product should only be used as directed on the label and for the purpose intended. Prepared by: Reckitt Benckiser (U.S.) Inc. Product Safety Department 1 Philips Parkway Montvale, New Jersey 07646-1810 USA. Phone: 201-573-6391 FAX: 201-476-7770. Ms. Kathleen Hubert [email protected] Disclaimer: To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Product code: 0160711 & 0160719 Product name: LYSOL BRAND 4 in 1 ANTIBACTERIAL KITCHEN CLEANER, CITRUS SCENT (TRIGGER & REFILL) - CANADIAN Page 7 of 7
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