AP Chemistry Summer Assignment Due Date: Thursday, September 1st, 2011 Directions: Show all of your work for full credit. Include units and labels. Record answers to the correct number of significant figures. Part I: Chemical Formulas Write the chemical formulas for each of the following substances. Write the name of each of the following compounds. 1. Barium sulfate __________ 1. CuSO4 ______________________________ 2. Ammonium chloride __________ 2. PCl3 ______________________________ 3. Chlorine monoxide __________ 3. Li3N ______________________________ 4. Silicon tetrachloride __________ 4. BaSO3 ______________________________ 5. Sodium oxide __________ 5. KClO4 ______________________________ 6. Sodium peroxide __________ 6. NaH ______________________________ 7. Copper (I) iodide __________ 7. (NH4)2Cr2O7 ______________________________ 8. Zinc sulfide __________ 8. HNO2 ______________________________ 9. Potassium carbonate __________ 9. Sr3P2 ______________________________ 10. Hydrobromic acid __________ 10. Mg(OH)2 ______________________________ 11. Perchloric acid __________ 11. Al2S3 ______________________________ 12. Lead (II) acetate __________ 12. H2O2 ______________________________ 13. Sodium permanganate __________ 13. AgBr ______________________________ 14. Lithium oxalate __________ 14. P4O10 ______________________________ 15. Potassium cyanide __________ 15. CH3COOH ______________________________ 16. Copper (II) chloride dihydrate __________ 16. CaI2 ______________________________ 17. Silicon dioxide __________ 17. MnO2 ______________________________ 18. Pentanitrogen nonafluoride __________ 18. Li2O ______________________________ 19. Calcium chlorate __________ 19. FeI3 ______________________________ 20. Sodium thiocyanate __________ 20. Cu3PO4 ______________________________ 21. Cobalt (III) nitrate __________ 21. MgSO4 ______________________________ 22. Nitrous acid __________ 22. NaCN ______________________________ 23. Ammonium phosphate __________ 23. Zn(NO3)2 ______________________________ 24. Hypochloric acid __________ 24. HF ______________________________ 25. Potassium chromate __________ 25. HClO2 ______________________________ 1|P ag e Part II: Chemical Equations For each equation below, identify the type of chemical reaction (synthesis, decomposition, single replacement, double replacement, or combustion), predict the products and write the balanced equation. 1. Ammonium sulfate reacts with barium nitrate. Reaction Type: _____________________ 2. Zinc metal is added to a solution of copper (II) chloride. Reaction Type: _____________________ 3. Propane gas (C3H8) is burned in excess oxygen. Reaction Type: _____________________ 4. Solid calcium chlorate is heated strongly. Reaction Type: _____________________ 5. Magnesium and nitrogen gas are heated together. Reaction Type: _____________________ 6. Chlorine gas is bubbled through a solution of sodium bromide. Reaction Type: _____________________ 7. Solutions of lead nitrate and calcium iodide are combined. Reaction Type: _____________________ 8. Sulfuric acid is combined with sodium hydroxide. Reaction Type: _____________________ 9. Isopropyl alcohol (C3H7OH) is burned in oxygen. Reaction Type: _____________________ 10. Iron metal shavings are added to hydrochloric acid. Reaction Type: _____________________ 11. Solid sodium carbonate is heated in a crucible. Reaction Type: _____________________ 12. Sodium metal is added to distilled water. Reaction Type: _____________________ 2|P ag e Part III: Stoichiometry 1. Find the mass percent of nitrogen in each of the following compounds. a. NO b. NO2 c. N2O4 d. N2O 2. Benzene contains only carbon and hydrogen and has a molar mass of 78.1 g/mol. Analysis shows the compound to be 7.74% hydrogen by mass. Find the empirical and molecular formulas of benzene. 3. Calcium carbonate decomposes upon heating, producing calcium oxide and carbon dioxide gas. a. Write a balanced chemical equation for this reaction. b. How many grams of calcium oxide will be produced after 12.25 g of calcium carbonate is completely decomposed? c. What volume of carbon dioxide gas is produced from this amount of calcium carbonate at STP? 3|P ag e 4. Hydrogen gas and bromine gas react to form hydrogen bromide gas. a. Write a balanced chemical equation for this reaction. b. 3.20 g of hydrogen gas and 9.50 g of bromine gas react. Which is the limiting reagent? c. How many grams of hydrogen bromide gas can be produced using the amounts in (b)? d. How many grams of the excess reactant is left unreacted? e. What volume of HBr, measured at STP, is produced in (b)? 5. When ammonia gas, oxygen gas and methane gas (CH4) are combined, the products are hydrogen cyanide gas and water. a. Write a balanced chemical equation for this reaction. b. Calculate the mass of each product produced when 225 g of oxygen gas is reacted with an excess of the other two reactants. 4|P ag e c. If the actual yield of the experiment in (b) is 105 g of HCN, calculate the percent yield. 6. When solutions of potassium iodide and lead (II) nitrate are combined, the products are potassium nitrate and lead (II) iodide. a. Write a balanced equation for this reaction, including (aq) and (s). b. Calculate the mass of precipitate produced when 50.0mL of 0.45M potassium iodide solution and 75mL of 0.55M lead (II) nitrate solution are mixed. c. Calculate the volume of 0.50M potassium iodide required to react completely with 50.0mL of 0.50M lead (II) nitrate. Part IV: Structure of Matter Describe how you would separate and recover into four separate containers the following four components of a mixture: liquid water (H2O (l)) + iron filings (Fe (s)) + sodium chloride dissolved in water (NaCl (aq)) + beach sand grains (SiO2 (s)). Part V: E-mail E-mail me at [email protected] with the e-mail address you prefer me to contact you at throughout the year. Include the name of the AP Chemistry review book you have purchased to use throughout the year. 5|P ag e
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