Topic 5: The Periodic Table Key Concept Definitions and facts 1. Periodic Law Properties of the elements Elements are are periodic function of arranged in order of their atomic number increasing atomic # 2. Period The horizontal arrangements of the elements . elements in the same period have the same # of electrons shells . Period number indicates # of electron shells 3. Group (families) Properties of elements The vertical arrangement of the element . Elements in the same Group have same # of valance electrons, therefore, same chemical reactivity Examples Mg and Si (both in Period 3) have the same number of electron shells (3) O and S (both in Group 16) have similar chemical reactivity b/c they each have 6 valance electrons. 4. Malleable able to be hammered into Gold is malleable a thin sheet 5. Ductile able to be drawn into wire Copper is ductile 6. Brittle shatters easily when struck Sulfur is brittle 7. Luster shininess Silver has luster 8. Conductivity able to conduct heat and electrical current Copper has high conductivity 9. Electronegativity ability to attract (or gain) e- Values for these 10. Ionization Energy energy to remove (lose) the most loosely bound e12. Density mass per unit volume 13. Atomic Radius size of a neutral atom 14. Ionic Radius size of an ion four properties can be found on Reference Table S . 1 Topic 5: The Periodic Table 15. Types of elements and locations Black: Solids Blue: Liquids 16. Properties of the elements 2 Orange: Gases 17. Groups on the Periodic Table . 3 Topic 5: The Periodic Table 18. Group names and Properties: Summary Table 4 Topic 5: The Periodic Table Selected Properties Selected Elements Examples 19. Very reactive elements. Obtain from fused salts. Not found in nature in free (elemental) state. Group 1 (alkali metals ) Group 2 (alkaline earth) Fluorine K Ca F 20. The most active metal (lowest ionization energy) Francium (Fr) 21. The most active nonmetal (highest electronegativity) Fluorine (F) 23. Radioactive elements (no stable isotope) All Element with atomic number 83 and above Bi (# 83) Ra (# 88) 24. Monatomic (one-atom) elements All Group 18 noble gases Ne Ar He 25. Diatomic (two-atoms) elements H2 N2 O2 F2 Cl2 Br2 I2 26. Element with a double bond oxygen O2 O=O 27. Element with a triple bond nitrogen N2 N=N 28. Elements that form colorful compounds Transition elements (Group 3-12) Cu Fe Mn Na Mg CuSO4 is bluish color Oxygen allotropes Air (O2) Ozone (O3) 29. Allotropes: Same element in solid state with . Different molecular forms . Different physical and chemical properties Topic 2: The Carbon allotropes Diamond Graphite Phosphorus allotropes Black Red Periodic Table White . 5 Topic 5: The Periodic Table Key Property Period Trend (Left to Right) Group Trend (Top to Bottom) 30. Atomic Radius Decreases (due to an increase in + nuclear charge) Increases (due to an increase in number of electron shells ex. Li (+3 nuclear charge) is bigger than Be (+4 nuclear charge) ex. O (2 electron shells) is smaller than S (3 electron shells) 31. Electronegativity Increases (due to decreasing atomic size) Decreases (due to increasing atomic size) ex. Li has a smaller electronegativity value (1.0) than Be (1.6) 32. Ionization energy Increases (due to decreasing atomic size) ex. Li has a smaller ionization energy value (520) than Be (900) ex. O has a higher electronegativity value (3.4) than S (2.6) Decreases (due to increasing atomic size) ex. O has a higher ionization energy value (1314) than S (1000) 34. Metallic Properties Decreases Increases 35. Nonmetallic Properties Increases Decreases 36. Summary of Trends 6
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