Element of the Day http://www.youtube.com/watch?v=uTm_wWAEz1Q Re Rhenium (reeneeәm) is a chemical element with the symbol Re and atomic number 75. It is a silverywhite, heavy metal. With an average concentration of 1 part per billion (ppb), rhenium is one of the rarest elements in the Earth's crust. The free element has the third highest melting point and highest boiling point of any element. Rhenium resembles manganese chemically and is obtained as a byproduct of molybdenum and copper refinement. Rhenium shows in its compounds a wide variety of oxidation states ranging from −1 to +7. Discovered in 1925, rhenium was the last stable element to be discovered. It was named after the river Rhine in Europe. Nickelbased superalloys for use in jet engines contain up to 6% rhenium, making jet engine construction the largest use for the element, with chemical industry catalytic uses being nextmost important. Because of the low availability relative to demand, rhenium is among the most expensive metals, with an average price of approximately US$4,575 per kilogram. 4 What is the oxidation state of Re (aq)? 1 Chemistry 1. Element of the Day Re 2. Finish POGIL Activity 3. Laboratory Investigation Announcements Due Thursday: Finish Laboratory Investigation Be sure to turn in Det. of an Activity Series Lab Quiz on Redox Reactions Thursday 2 POGIL Activity 3 Electrochemical Cells Learning Targets • Experimentally explore electrochemical cells • Understand how redox reactions can generate electron flow (electricity) • Be able to use an activity series to predict whether a single replacement reaction will occur or not. • Be able to identify which reactants are being reduced, and which are being oxidized • Be able to write balanced half reactions for redox reactions. 4 Activity Series Most Reactive Mg Zn Pb Cu Ag Reactivity = likely to be oxidized. (give up electrons) Least Reactive Oxidized half reaction: 5 6 Chemistry Lab Groups Group 4 Group 1 Matthew R Alderson Daniel J Connelly Bill Lee Catherine E Edwards Dakota P Rice Tiffany P Lee Martin W van Drunen Group 5 Group 2 Dominique D'Onofrio Taylor Ahliquist Anthony H McMillan Sara Turpen Timothy D Taylor Annika J van Houte Group 3 Indigo M Larson Aidan K Moore Spencer T Alpaugh 7 Name: Type Lab Report Date: April 10, 2012 Title: Electrochemical cells Partners: ________________ I. Question: Why do combinations of metals produce different voltages? II. Procedure include diagram III. Data Table Ag Cu Mg Pb Zn Ag Cu Mg Pb Zn IV. Observations V. Analysis Questions: 1) Use info from your data table and your knowledge of reactivity to write half reactions for each pair of metals. Then write full reactions for each pair of metals and identify the cathode and the anode. 2) How is the difference in voltage similar to the relative positions of the metals in the activity series from the last lab? Explain your answer. 3) Briefly describe energy transfers and transformations during electrochemical reactions. 8 9 Sodium–sulfur battery 10 Exit Question At the anode of a galvanic cell _____________ occurs as electrons are transferred. Reminders Due Thursday: Finish Electrochemical Cells Lab Quiz on Redox Reactions Thursday 11
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