Grain size analysis as a means to establish factors for determination of ecological settings Keith Chojnacki Stony Brook University, Stony Brook, NY Abstract Numerous studies have been performed to analyze the loess found on Long Island. The processes that formed it are however, still poorly understood. The purpose of this study was to look at grain size distribution of loess as a determining factor of ecological settings found on Long Island. Soil samples were taken from four different sites: Stony Brook University (SBU), Suffolk County Farm (SCF), North Street (NS), and the Dwarf Pine Plains (DPP). Each of the samples taken from varying depths were analyzed using the both the Mastersizer 2000 and a Gradistat program. The sample revealed an abundance of silt and gravel at both the SBU and SCF locations but found the NS location to include medium sand along with silt and some gravel and the DPP location is predominantly very coarse sand with some silt. There appears to be a correlation between the ecological settings and grain sizes at the SBU and SCF sites as well as a correlation between the NS and DPP sites. With there being similarities between sites it can be reasoned that the processes that lead to the deposition of sediments are similar if not the same. The presence of a diamict however, leads one to believe that the processes that lead to the deposition of these sediments are more complex. They may be the result of an impact event such as the one thought to have caused the Younger Dryas approximately 13,000ya. With factors such as precipitation and temperature are the same at all four sites, it can be argued that the grain size of the loess found at these sites is the determining factor of ecological settings across Suffolk County. 1 Introduction Loess is a geologically recent deposit of silt or material which is usually yellowish or brown in color and consisting of tiny mineral particles brought by wind to the places where they now lie. It is found world-wide in places such as northern China, central Europe, and parts of Russia. The thickest deposits of Loess are found in the Midwest along the Missouri River. Recently though, the discussion of the existence of ‘pebbly loess’ on Long Island has arose. By definition, one would expect the windblown sediments to be well sorted and lack sediments larger than 2mm in diameter. But an analysis of loess at various sites found in Suffolk County, New York show that the loess is actually poorly sorted and contains large clasts ranging in sizes up to 10mm. This is not characteristic of typical loess. Another characteristic of Loess is that it helps to form very fertile soil. In areas where loess is found, one would see flourishing farms, forests and various other ecosystems. During a recent study, grain size analysis was performed on soil taken from four different sites in Suffolk County. The results of the analysis showed that each of the four sites contains vastly different grain sizes. Among the sites are different ecosystems as well. This is in contrast to the findings of a previous study by Champey in the Pine Barren region. It concluded that there weren’t any distinct physical characteristics that accounted for differences in plant settings and the differences were most likely due to abiotic and biotic interactions and not the grain sizes (Champey). The data in a study by Adler et al show similarities in grain sizes and distribution in the Dwarf Pine Plains region with the predominance of gravelly sands with silt sized particles present (Adler et al). Considering all things, grain size seems to be a characteristic to consider when discussing a factor contributing to the selection of ecological settings. Some factors that determine types of ecosystems include temperature, rainfall, altitude, pollution, sunlight, and wind. With all of these things equal between the four sites this studies purpose was to see if there is a correlation between the soil grain sizes near the surface of the sites and types of ecosystems that inhabit them. Even though the four sites are found within the same climate, the ecosystems are vastly different. It is believed that the various grain sizes are responsible. Methods Samples were collected from four different sites across Suffolk County, New York. The four sites include Suffolk Country Farm (SCF) (40°49'40.02"N 72°55'31.44"W), Stony Brook University Campus (SBU) (40° 54'51.78"N 73° 7'44.64"W), North Street (NS)(40°52'15.96"N 72°50'17.58"W), and the Dwarf Pine Plains (DPP)( 40°52'18.12"N 72°39'17.40"W) (Figure 1). 2 At each of the four locations, the research team dug at sites that appeared to be undisturbed. At each site soil samples were taken at varying depths and placed into labeled bags. Samples were collected from each of the labeled regions shown in the figures below. Layers were determined based upon differences in apparent coloring. Fig. 2B- SCF section, 40.64cm depth Fig. 2A-SBU section, 124 cm depth Fig. 2C- NS section, depth 60.96cm Fig. 2D- DPP section, 68.58cm depth 3 After samples were collected, they were brought back to Stony Brook University and prepped for analysis using the following method outlined by Timothy Clare (2013): After collection, the samples were taken into the lab and laid out on clean sheets of white paper to dry for 24 hours. The next day each sample was prepped for grain-size analysis using the following procedure: 1. Large pebbles and organic matter removed from sample 2. 10 minute paper folding method to remix sample, as sediments will naturally sort overnight 3. 10 grams of sample is weighed out into a small cup (cup is weighed first) 4. 10 g sample is sifted through a 1mm sieve 5. Larger particles (≥1𝑚𝑚) are removed, weighed and put aside 6. Particles <1𝑚𝑚 are weighed and placed into a small plastic bottle *Steps are repeated for each sample 7. Each bottle is then filled with a (NaPO3)6 solution that acts as a dispersant 8. Bottle is shaken vigorously for 30 seconds after dispersant is added 9. Samples are left to sit for 24 hours Once samples are prepared in the manner detailed above, they can be run through Mastersizer 2000 particle size analyzer. As detailed by the manufacturer Malvern (2014), the Mastersizer 2000 uses laser diffraction to measure the size of particles by measuring the intensity of light scattered as a laser beam passes through a dispersed particulate sample. The instrument software analyzes the data and calculates the size of the particles that created the scattering pattern. The samples were prepared for the Mastersizer 2000 in the following manner detailed by Clare (2013): 1. (NaPO3)6 solution is run through the machine as a background for the particulate sample 2. Sample is shaken for 30 seconds using a vibration machine to complete mix the particles 3. Small amount of sample is drawn out of bottle with a pipette and dropped into solution to an obscuration of ~15% (measured by computer software) 4. Sample is passed through Mastersizer 3 times The Mastersizer instrument software averages the three tests to yield a mean, mode, and percent of silt versus sand and clay for each of the samples. For the purposes of this study, this information was then input into a program called Gradistat to run grain size statistics for each sample. Gradistat provides rapid grain size statistics by arithmetic, geometric and logarithmic moments and methods (Blott and 4 Pye, 2001). Gradistat assumes sieves are used to measure the amount of sediment retained in a number of size fractions, which serves as the input data for the program (Blott and Pye, 2001). Sample statistics including mean, mode(s), sorting, skewness, kurtosis, and a range of cumulative percentile values (Blott and Pye, 2001). According to Blott and Pye (2001), the following parameters are used to define a grain size distribution from gradistat: the average size of grains, sorting, skewness, and kurtosis. Sorting refers to the spread of the sizes around the average. The preferential spread of grains to one side of the average is known as the skewness. Lastly, kurtosis refers to the degree of concentration of grains relative to the average or is considered the measure of “peakedness” in a distribution curve (Blott and Pye, 2001). A normal distribution, or symmetrical curve is considered mesokurtic. An excessively peaked distribution curve, better sorted in the central portion of the graph rather than the outer tails is leptokurtic. If the opposite holds true, and sorting is better on the tail ends, the sample is platykurtic. Results For the purposes of the study, only the upper two layers (A and B) are used for each of the four sites. Stony Brook Campus Figure 3A- SBU A 5 Figure 3B- SBU B According to the phi values on figure 3A, in the upper layer at SBU there are two modes present which represent the presence of silt and gravel. Figure 3B shows the same modes for both silt and gravel. Stony Brook Ecology The setting for this site is a deciduous forest that is predominantly Acer rubrum, Quercus alba, and Vibernum acerifolium that is adjacent to a stream bed (Chojnacki, 2013). There is the presence of leaf litter on the forest floor that is mainly leaves from the previously mentioned Acer rubrum and Quercus alba. 6 Suffolk County Farm Figure 4A- SCF A Figure 4B- SCFB 7 As shown in figure 4A, there are three distinct modes present that represent silt, coarse sand and pebbles. However, in figure 4B, only two modes are present. Those are representative of silt and gravel. Suffolk County Farm Ecology The setting for this site was a section of deciduous forest that is adjacent to farmland. The area where the samples were taken was away from the farm in an undisturbed portion of the forest. This forest consisted of Acer rubrum, Prunus serotina and Quercus alba. North Street and Dwarf Pine Plains Figure 5- Ecology Maps: The Nature Conservacy, 2003 8 North Street Figure 6A- NS A Figure 6B- NS B 9 The grain size analysis in figure 6A shows three distinct modes which are representative of silt, medium sand, and gravel. Figure 6B however only shows two modes of silt and medium sand. North Street Ecology The ecological setting for this site is shown the ecological map provided in figure 5 which classifies this region as an Oak-Pine forest. The predominant plants here include Quercus alba, Pinus rigida, and Quercus prenoides. This setting also includes a nearby river. Dwarf Pine Plains Figure 7A (top)- DPP A, Figure 7B (bottom)- DPP B 10 Figure 8- Soil texture diagrams for Stony Brook site, (top left) Suffolk County Farm, (top right) North Street, (bottom left) and Dwarf Pine Plains (bottom right). (Dominguez, 2014) 11 Figure 9- Soil analysis of Oak-Pine Forest, Brookhaven National Lab and Air National Guard. (Champey) 12 Figure 10- Grain size distributions of Long Island Pine Barren soil samples (Adler). 13 The grain size analysis of the DPP A site shows two distinct modes that represents both silt and very coarse sand. Figure 7B also shows two modes but is predominantly very coarse sand and little of silt. Dwarf Pine Plains Ecology The ecological setting for this site is described as Pitch Pine forest, as shown in the ecology maps shown in figure 5. The predominant plants of this site are Pinus rigida and Quercus prenoides. This site, like the North Street site, are both found within the boundary of the Long Island Pine Barrens. Discussion Based on the data that was collected during this study, it is evident that the grain size of loess may be the determinant for the various ecological settings discussed in both western and eastern Suffolk County. There appears to be a transition from predominantly all the way to very coarse sand as we move west the east along the four sites (figure 8). Although each of these sites are only miles apart, the western and eastern ends differ drastically on the ecological scale, despite the fact that they are exposed to the same climatic conditions. Starting in the west at the SBU site, we find modes that are of silt and gravel. These grain sizes found in the upper layers of soil are consistent with the requirements for seed germination of the dominant plant species found there. Those include the V. acerifolium, Q. alba, and A. rubrum, all of which prefer a leaf litter layer and plenty of moisture (Hutnick, 1961) which would be present here due to the predominance of silt found at the SBU site. The Quercus alba prefers looser soils Minckler, 1961) which is also found at the SBU site due to the presence of gravel with silt. This would provide the conditions necessary for such an ecosystem to exist. Progressing eastward to the SCF site, there are similar ecological settings. Much like the SBU site, there are Quercus alba and Acer rubrum found in abundance at the SCF. This would make sense since the grain analysis shows similar composition. Just like at the SBU site, the SCF site is found to be predominantly both silt and gravel. The fact that the two sites are so strikingly similar it would be safe to assume that the processes that deposited the loess were the same, likely glacial processes that created the moraine and tunnel valley where we find these two sites. Although that it is likely glacial processes responsible for the deposition, there are other processes that may have contributed to the nature of the sediment. This makes sense considering the classification of these sediments as a diamict. A diamict is defined as non-sorted, or poorly sorted, unconsolidated sediment containing a wide range of particle sizes (Flint, 1971: Frakes, 1978; Eyles et al., 1983). The processes that created this diamict may be the result of an impact event that occurred on the Laurentide Ice Sheet that caused the Younger Dryas event that took place approximately 13,000ya (Firestone, 2007). From the SCF moving further eastward, changes in ecological settings become more apparent. This may be due to the fact that the processes that deposited the sediments were different. Both the NS and DPP sites are on what are believed to be outwash plains. This would explain the fact that we find more sand here and less gravel and pebbles. 14 The NS site is dominated by Quercus alba, Pinus rigida, and Quercus pleniodes. One would expect not to see Q. alba present but the presence of silt in the upper layers of this region are still very good conditions for seed germination. Species that were not seen west of here are the P. rigida and Q. plenoides. Both of these species, especially the P. rigida, prefer sites with little or no leaf litter and soils with a sandy or gravelly texture (Little, 1953). The difference in grain size appears to be the determining factor here in the transition between ecosystems with climatic conditions remaining the same. Moving further eastward to the final site the ecological transition continues. At the DPP site we find a predominance of very coarse sand. We also see the absence now of Quercus alba but Pinus rigida is now the dominant plant species. This is possibly due to the change in grain size. Quercus alba require an adequate amount of moisture for seedlings to survive whereas the Pinus rigida require little to no leaf litter and well drained soils such as the DPP site. Although the DPP and NS sites have their differences, they also have similarities. Those would be the transition to a predominance of larger grain sizes at or near the surface and thus both have Pinus rigida inhabiting them. With these similarities, one would assume again that the processes that resulted in the deposition of sediments would be the same. These findings have both similarities and differences compared to studies done previously by Champey and Adler in the Pine Barren region. The study performed by Champey shows that samples analyzed from both an Oak-Pine and Dwarf Pine setting similar to those performed in this study at North Street and Dwarf Pine Plains. The results of the Champey study show do not show the bimodal nature of sediment size that this study does. The Champey results show a greater distribution of sand grains ranging from very fine to very coarse without the presence of much silt (figure 9). This study shows the presence of two distinct modes at very coarse sand and silt. It may be the presence of the silt allowing for the moisture retention necessary for the survival of the oak seeds. Based on the data, Champey concluded that physical characteristics of the soil were not responsible for the ecological settings, but rather a combination of both biotic and abiotic factors such as wind pruning and competition (Champey). From the data obtained by Adler et al, they concluded that the analyzed soil samples from the Long Island Dwarf Pine Plains may be classified as slightly gravelly (pebbly) sands, with up to nearly 10% silt-sized and finer particles (figure 10) (Adler et al). These finding are similar to those obtained in this current study. The similarities shown in grain sizes could support the idea that soil composition help to determine the ecological settings in Suffolk County. The contrasting findings between this current study and Champey may be due to the fact that this study incorporates physical characteristics of soils outside the Pine Barren region. It may be necessary for further sampling to be done to draw any concrete conclusions in relating the importance of grain sizes in determining ecological settings across Suffolk County. Differences in findings may also be because analysis of the soil was also performed differently. The results of this study used the Mastersizer 2000 for grain size analysis whereas the previous study utilized sieves for analysis. It is possible that the more precise measurements of the Mastersizer could be the difference in grain size analysis. It is also possible that flaws in this current study exist. It would be beneficial to take additional samples to be analyzed from the same areas and extend the samples to other regions east of the areas sampled. It is apparent that further investigation is necessary to support any findings in this study. 15 Conclusion Ecological settings are typically determined by a multitude of factors such as wind, temperature, precipitation and pH of soil. But when all of these factors are the same and we find different ecological settings within miles of each other, another factor must be as play. Based on the results of this study it is apparent that the grain size of the soil should be considered as a factor in the determination of ecological settings on Long Island. The four sites that were used in this study show a progression from a silty loam to a sandy loam moving west to east (figure 8). The change in the grain sizes found at each site is what allows for the successful germination of seedlings at those sites. Also, although it is likely glacial processes that are responsible for the differences in sediment sizes, there may be other processes at play that would explain the diamict nature of the loess at these sites. 16 References Champey, Christine. "Chemical and Physical Characteristics of the Sediment in the Pine Barrens of Central Suffolk County, N.Y." Web. 20 Aug. 2014. Clare, T.D., 2013, Grain Size Analysis of Loess and Glacial Sediments atStony Brook University, Stony Brook University, 9p. Eyles, N., Eyles, C.H., and Miall, A.D., 1983, Lithofacies types and vertical profile models; an alternative approach to the description and environmental interpretation of glacial diamict and diamictite sequences: Sedimentology, v. 30, 395-410. Firestone, R.B., et al., 2007, Evidence for an extraterrestrial impact 12,900 years ago that contributed to the megafaunal extinctions and the Younger Dryas cooling: Proceedings of the National Academy of Sciences in the United States of America, vol. 104, no. 41, 16016-16021. Flint, R.F., Sanders, J.E., and Rodgers, J., 1960, Symmictite: a name for nonsorted terrigenous sedimentary rocks that contain a wide range of particle sizes: Geological Society of America Bulletin, vol. 71, 507-509. Hutnick, Russell J., and Harry W. Yawney. 1961. Silvical characteristics of red maple (Acer rubrum). USDA Forest Service, Station Paper 142. Northeastern Forest Experiment Station, Upper Darby, PA. 18 p Little, S., and E. B. Moore. 1953. Severe burning treatment tested on lowland pine sites. USDA Forest Service, Station Paper 64. Northeastern Forest Experiment Station, Broomall, PA Minckler, Leon S. 1965. White oak (Quercus alba L.). In Silvics of forest trees of the United States. p. 632637. H. A. Fowells, comp. U.S. Department of Agriculture, Agriculture Handbook 271. Washington, DC. 17
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