Chapter 8 Review Vocabulary 10. An ionic formula is always an ________. Match each word to the sentence where it best fits. 11. Some ________ are natural and are necessary for correct biological functioning, while others are sometimes taken as drugs. Section 8.1 12. Some of the highest calorie foods contain ________. brittle polyatomic ion electric current 1. Something that is ________ can be strong but still break easily. 2. If you have a ________ you have a small molecule with a charge. 3. When charge moves in a directed way you have an ________. Section 8.2 lipids copolymers steroids network covalent hydrocarbon empirical formula polymers molecular formula monomer organic molecule homopolymer 4. A ________ will tell you exactly how many atoms there are in an individual molecule. 5. Most of our fuels are one kind of ________ or another, because the carbon and hydrogen they contain have a large amount of chemical energy. 6. Molecules that are made from repeatedly bonding together smaller molecules are broadly called ________. 7. ________ are bonded together to form polymers. 13. Protein and DNA are molecules that are examples of ________. 14. The type of molecular substances that form very large interconnected molecules are called ________. Section 8.3 intermolecular attractions hydrogen bonding van der Waals attractions London dispersion attraction surface tension dipole-dipole attraction 15. ________ is a slightly stronger version of dipoledipole attraction, but it is not as strong as a covalent bond. 16. Two broad terms that describe why molecules condense into liquids and solids are ________ and ________. 17. When two polar molecules attract to each other you have an example of ________. 18. You can “float” a paper clip on water if you very carefully lay it flat on top of the water. This is due to what is known as ________. 19. ________ is particularly important for non-polar molecules. 8. Polypropylene is only made from one monomer, so it is a ________. Conceptual Questions 9. For a molecule to be an ________ it must be made primarily from carbon and hydrogen with the possibility of some other non-metals also part of the molecule. Section 8.1 256 20. What is one property shared by most ionic substances? A NATURAL APPROACH TO CHEMISTRY 21. Why do ionic substances not conduct electricity in their solid form, but will if they are dissolved or in their liquid form? 37. Which kinds of molecular substances most resemble ionic compounds and in what ways are they similar? 22. True or false. The positive ion in an ionic compound must have the same charge as the negative ion. Explain. 38. Describe the difference between an empirical formula and a molecular formula. 23. Describe the structure of an ionic crystal. Section 8.3 24. In what ways is an ionic crystal like a molecule and in what ways is it different? 39. What are the major categories of intermolecular attractions? 25. Describe why you sometimes need parentheses around a polyatomic ion when used in a formula. Give one example of when you need parentheses and one where you don’t. 40. Is a hydrogen bond more like a dipole-dipole attraction or more like a London dispersion attraction? Explain. 26. Why must the total positive and total negative charge in an ionic compound be equal? 27. Why do some ionic names need a Roman numeral, and some don’t. Give an example. Section 8.2 28. Describe a major difference between the properties of ionic compounds and molecular compounds. 41. Dipole-dipole attractions occur between which types of molecules: a. network covalent b. polar c. non-polar 42. Explain why water has a boiling point that is so much higher than most molecules that are so small. 43. List three special properties of water, not including its high boiling point. 29. What are some common properties of substances made from small molecules? 44. Describe the difference between London dispersion attraction and dipole-dipole attraction. 30. If two small molecules are about the same size, but one is polar, which one will have the higher boiling point? 45. How does the size of a molecule play a role in the strength of its intermolecular attractions? 31. Gasoline is a hydrocarbon. What does that mean? 46. How does the shape of a molecule play a role in the strength of its intermolecular attractions? 32. What is a common property of substances made from medium-sized molecules? 47. How does the polarity of a molecule play a role in the strength of its intermolecular attractions? 33. If you wanted to avoid lipids, what foods should you not eat? Section 8.4 34. Describe the relationship between a monomer and a polymer. 48. What does an empirical formula tell you? Give an example. 35. How many different monomers are used to make proteins? 49. Give an example of when a molecular formula is the same as its empirical formula. 36. What do we call a monomer that is used to make a protein? 50. Give an example when the molecular formula is different from the empirical formula. A NATURAL APPROACH TO CHEMISTRY 257 Chapter 8 Review. 51. Describe how the percent composition helps in determining the molecular formula of an unknown substance. Quantitative Problems Section 8.1 52. What does the formula BaCl2 tell you about the substance barium chloride? 53. Write the formula for each of the following names: a. lithium bromide b. magnesium fluoride c. calcium sulfide d. aluminum iodide e. aluminum sulfide 54. Write the formula for each of the following names: f. chromium(III) nitrate g. copper(I) oxide h. copper(II) oxide i. lithium phosphate j. iron(III) sulfate 55. Write the formula for each of the following names: a. barium hydroxide b. sodium sulfide c. tin(IV) carbonate d. cobalt(II) chlorate 56. Write the name for each of the following formulas: a. K2O b. BeI2 c. SrCl2 d. PbCl4 57. Write the name for each of the following formulas: 258 a. b. c. d. e. FeO Fe2O3 ZnBr2 AgNO3 K2CO3 58. Write the name for each of the following formulas: a. NaHCO3 b. Sn(NO3)2 c. (NH4)2SO4 d. Al(C2H3O2)3 e. CuSO4 Section 8.2 59. Write the formula for each of the following names: a. dinitrogen monoxide b. dichlorine hexoxide c. iodine tribromide 60. Write the formula for each of the following names a. iodine heptafluoride b. phosphorous trichloride c. chlorine monoiodide d. dinitrogen tetrafluoride 61. Write the names for each of the following formulas: a. SF2 b. P4O10 c. P2Cl4 62. Write the names for each of the following formulas: d. Cl2O7 e. PF5 f. S2F10 A NATURAL APPROACH TO CHEMISTRY Section 8.3 68. Calculate how many molecules are in the following a. 6.5 g of H2O b. 19.3 g of C8H10 69. Give the empirical formula for each of the molecular formulas: a. N2O4 b. P2O5 c. P4H10 d. H2O2 e. P3Cl5 70. Give three possible molecular formulas for the empirical formula CH2O. 71. If you had a sample of a substance that had 20.23g of aluminum and 79.77g of chlorine, what would the empirical formula be for this substance? 63. There are four DNA bases that are part of the nucleotide monomers that make up the DNA molecule. When two DNA strands wrap around each other they only stick together if there is an “A” on one strand across from a “T” on the other or a “G” on one strand across from a “C” on the other. Which pair do you think sticks together better and why? 64. Why does it make sense that “A” and “T” pair up and “G” and “C” pair up? Section 8.4 65. Calculate the molar mass for the following substances: a. H2O b. NaNO3 c. (NH4)2S d. Ca3(PO4)2 66. What is the percent composition by mass for each of the substances in the previous question? 67. If you add up all the % of each element in a compound you should get what number? A NATURAL APPROACH TO CHEMISTRY 72. What is the empirical formula for a substance with the following % composition: 40% carbon 6.7% hydrogen 53.3% oxygen 73. You have 16.0g of some compound and you perform an experiment to remove all of the oxygen. What is left is 11.2g of iron. What is the empirical formula? 74. After burning 1.5g of scandium in oxygen, a new compound is formed that has a mass of 3.1g. What is the empirical formula. 75. The empirical formula for cyclohexane is CH2, and its molar mass is 84.18g/mol. What is the molecular formula? 76. What is the molecular formula for a compound with a molar mass of 34.02g/mol and empirical formula HO? 77. A sample of an unknown compound was determined to be made from 8.56g of carbon and 1.44g of hydrogen. The molar mass of the compound was found to be 28.03g/mol. What is the molecular formula? 259
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