Safety Data Sheet
according to Regulation (EU) 2015/830
Fervent Mangaan
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1.
Product identifier
Product form
: Substance in aqueous solution
Trade name
: Fervent Mangaan
Synonyms
: Spoor Mangaan
EC FERTILISER
: Manganese-based fertiliser solution
1.2.
Relevant identified uses of the substance or mixture and uses advised against
1.2.1.
Relevant identified uses
Main use category
: Professional use
Use of product
: Use as raw material for fertilizer solutions in agriculture and horticulture
1.2.2.
Uses advised against
Restrictions on use
1.3.
: No supplementary information available
Details of the supplier of the safety data sheet
Van Iperen BV
Smidsweg 24
3273 LK Westmaas - Nederland
T +31 (0)186 578888 - F +31 (0)186 573452
[email protected] - www.iperen.com
1.4.
Emergency telephone number
Country
The Netherlands
Official advisory body
Nationaal Vergiftigingen
Informatie Centrum
Address
Huispostnummer B.00.118,
PO Box 85500
3508 GA Utrecht
Emergency number
+31 30 274 88 88
Comment
National Institute for Public Health
and the Environment
NB this service is only available to
health professionals
SECTION 2: Hazards identification
2.1.
Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixture/Substance: SDS EU 2015: According to Regulation (EU) 2015/830
Serious eye damage/eye irritation, Category 1
H318
Calculation method
Specific target organ toxicity — Repeated exposure, Category 2
H373
Calculation method
Hazardous to the aquatic environment — Chronic Hazard, Category 2 H411
Calculation method
Full text of hazard classes and H-statements : see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2.
Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayExtra classification(s) to display
Hazard pictograms (CLP)
:
CLP Signal word
:
Danger
Hazardous ingredients
:
Manganese(II)sulfate
Hazard statements (CLP)
:
H318 - Causes serious eye damage
H373 - May cause damage to organs (brain) through prolonged or repeated exposure (if inhaled)
H411 - Toxic to aquatic life with long lasting effects
Precautionary statements (CLP)
:
P273 - Avoid release to the environment
P280 - Wear protective gloves, eye protection
P305+P351+P338+P310 - IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or
doctor/physician
P314 - Get medical advice/attention if you feel unwell
P391 - Collect spillage
GHS05
2.3.
GHS08
GHS09
Other hazards
This substance/mixture does not meet the PBT- and/or vPvB- criteria of REACH regulation, annex XIII
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Safety Data Sheet
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Fervent Mangaan
SECTION 3: Composition/information on ingredients
3.1.
Substance
Not applicable
3.2.
Mixture
Name
Product identifier
%
Classification according to
Regulation (EC) No.
1272/2008 [CLP]
Manganese(II)sulfate, monohydrate
(CAS No) 10034-96-5
(EC no) 232-089-9
(EC index no) 025-003-00-4
(REACH-no) 01-2119456624-35
35 - 40
Eye Dam. 1, H318
STOT RE 2, H373
Aquatic Chronic 2, H411
Full text of H-statements: see section 16
SECTION 4: First aid measures
4.1.
Description of first aid measures
First-aid measures general
: Check the vital functions. Unconscious: maintain adequate airway and respiration.
Respiratory arrest: artificial respiration or oxygen. Cardiac arrest: perform resuscitation.
Victim conscious with laboured breathing: half-seated. Victim in shock: on his back with legs
slightly raised. Vomiting: prevent asphyxia/aspiration pneumonia. Prevent cooling by covering
the victim (no warming up). Keep watching the victim. Give psychological aid. Keep the victim
calm, avoid physical strain. Depending on the victim's condition: doctor/hospital.
First-aid measures after inhalation
: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Respiratory problems: consult a doctor/medical service.
First-aid measures after skin contact
: Remove victim from polluted area. Rinse with water. Soap may be used. Remove all
contaminated clothing and footwear. Take victim to a doctor if irritation persists.
Wash contaminated clothing before reuse.
First-aid measures after eye contact
: Remove victim from polluted area. Immediately flush eyes with plenty of water (> 15min),
occasionally lifting the upper and lower eyelids . Remove contact lenses, if present and easy to
do. Continue rinsing. Take victim to an ophthalmologist.
First-aid measures after ingestion
: Rinse mouth with water. Immediately after ingestion: give lots of water to drink. Do NOT induce
vomiting. Do not give an unconscious person anything to drink. Get medical advice/attention.
4.2.
Most important symptoms and effects, both acute and delayed
Symptoms/injuries after inhalation
: May cause irritation to the respiratory tract. Danger of serious damage to health by prolonged
exposure through inhalation.
Symptoms/injuries after skin contact
: Tingling/irritation of the skin. Allergic skin rash.
Symptoms/injuries after eye contact
: Causes serious eye damage.
Symptoms may include: redness of the eye tissue, irritation of the eye tissue, blurred vision.
Symptoms/injuries after ingestion
: Nausea. Abdominal pain. Vomiting. After absorption of high quantities: methemoglobinemia,
blue/grey discolouration of the skin, feeling of weakness, dizziness, respiratory difficulties.
4.3.
Indication of any immediate medical attention and special treatment needed
Follow the advices in chapter 4.1. Treat symptomatically.
SECTION 5: Firefighting measures
5.1.
Extinguishing media
Suitable extinguishing media
5.2.
: All extinguishing media allowed. Preferably: water.
Use fire extinguishing methods suitable to surrounding conditions.
Special hazards arising from the substance or mixture
Fire hazard
: Direct fire hazard: Non combustible.
Explosion hazard
: No direct explosion hazard.
Hazardous decomposition products in case of
fire
: On heating/burning: release of toxic and corrosive gases/vapours (sulphur oxides) and
formation of metallic fumes
5.3.
Advice for firefighters
Precautionary measures fire
: Exposure to fire/heat: keep upwind, consider evacuation and have neighbourhood close doors
and windows.
Firefighting instructions
: Dilute toxic gases with water spray.
Protection during firefighting
: Fire-fighters should wear appropriate protective equipment and selfcontained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for firefighters (including helmets, protective boots and gloves) conforming to European standard EN
469 will provide a basic level of protection for chemical incidents.
Other information
: Do not allow run-off from fire-fighting to enter drains or water courses.
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Safety Data Sheet
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Fervent Mangaan
SECTION 6: Accidental release measures
6.1.
Personal precautions, protective equipment and emergency procedures
General measures
6.1.1.
: Ensure adequate air ventilation. Do not get in eyes, on skin, or on clothing.
Keep away from naked flames/heat.
For non-emergency personnel
Protective equipment
: Wear protective gloves/protective clothing/eye protection as adviced in section 8.
Emergency procedures
: Mark the danger area. Keep containers closed. Wash contaminated clothes.
Keep unnecessary and unprotected personnel from entering.
6.1.2.
For emergency responders
Protective equipment
6.2.
: Wear protective gloves/protective clothing/eye protection as adviced in section 8.
Environmental precautions
Prevent spreading in sewers. Prevent soil and water pollution. Inform the relevant authorities if the product has caused environmental pollution
(sewers, waterways, soil or air).
6.3.
Methods and material for containment and cleaning up
For containment
: Any spillage should be cleaned up immediately. Collect spill in closed and suitable containers
for disposal. Take up rest of liquid spill into absorbent material sand, earth, vermiculite. Scoop
absorbed substance into closing containers.
Methods for cleaning up
: Clean contaminated surfaces with an excess of water.
Wash clothing and equipment after handling.
Other information
: Do not wash out with water in a sensitive environment.
6.4.
Reference to other sections
See section 1 for emergency contact information.
See section 8 for information on appropriate personal protective equipment.
See section 13 for additional waste treatment information
SECTION 7: Handling and storage
7.1.
Precautions for safe handling
Precautions for safe handling
: Use sufficient ventilation. Do not get in eyes, on skin, or on clothing. Wear protective
gloves/protective clothing/eye protection as adviced in section 8. Avoid spillage / leakage.
Hygiene measures
: Always wash hands after handling the product. Do not eat, drink or smoke during use. If on
skin, take off contaminated clothing. Do not discharge the waste into the drain.
7.2.
Conditions for safe storage, including any incompatibilities
Technical measures
: Store in a dry, well ventilated place away from sources of heat, ignition and direct sunlight.
Storage conditions
: Store in original container.
Storage temperature
: -5 - 30 °C
Storage area
: Store in dry, cool, well-ventilated area. Keep out of direct sunlight. Meet the legal requirements.
Special rules on packaging
: Meet the legal requirements. correctly labelled.
Secure fragile packagings in solid containers. closing.
Packaging materials
: Suitable material: polyethylene, polypropylene, stainless steel
7.3.
Specific end use(s)
Fertilizers. Component of mixed fertilisers.
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Fervent Mangaan
SECTION 8: Exposure controls/personal protection
8.1.
Control parameters
Manganese(II)sulfate, monohydrate (10034-96-5)
DNEL/DMEL (Workers)
Long-term - systemic effects, dermal
0.00414 mg/kg bodyweight/day
Long-term - systemic effects, inhalation
0.2 mg/m³
DNEL/DMEL (General population)
Long-term - systemic effects, inhalation
0.043 mg/m³
Long-term - systemic effects, dermal
0.0021 mg/kg bodyweight/day
PNEC (Water)
PNEC aqua (freshwater)
0.0128 mg/l
PNEC aqua (marine water)
0.0004 mg/l
PNEC aqua (intermittent, freshwater)
0.03 mg/l
PNEC (Sediment)
PNEC sediment (freshwater)
0.0114 mg/kg dwt
PNEC sediment (marine water)
0.0004 mg/kg dwt
PNEC (Soil)
PNEC soil
25.1 mg/kg dwt
PNEC (STP)
PNEC sewage treatment plant
56 mg/l
8.2.
Exposure controls
Appropriate engineering controls
: No particular/specific measures required. Good practice advice: ensure good ventilation of the
work station, care for eyewashstations at the workplace.
Personal protective equipment
: Protective clothing. Gloves. Safety glasses.
Hand protection
: Gloves
Material selection gloves
: Non suitable materials are leather gloves. Take advice to your gloves' supplier.
Replace damaged gloves
Type
Material
Permeation
Thickness (mm)
Standard
Reusable gloves
Chloroprene rubber (CR), Butyl rubber,
Polyvinylchloride (PVC)
6 (> 480 min)
0,5
EN 374
Reusable gloves
Nitrile rubber (NBR)
6 (> 480 min)
0,35
EN 374
Reusable gloves
Fluoroelastomer (FKM)
6 (> 480 min)
0,4
EN 374
Eye protection
: Safety glasses
Skin and body protection
: Wear suitable protective clothing
Respiratory protection
: Mist formation: aerosol mask with filter type P2
Environmental exposure controls
: In some cases proces modifications will be necessary to reduce emissions to acceptable levels.
Emissions from ventilation or work process equipment should be checked to ensure they
comply with legislation.
Other information
: Do not eat, drink or smoke when using this product. Use good personal hygiene practices.
See section 7. Make sure the installation and workplace are correctly labelled.
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Safety Data Sheet
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Fervent Mangaan
SECTION 9: Physical and chemical properties
9.1.
Information on basic physical and chemical properties
Physical state
: Liquid
Appearance
: Liquid.
Colour
: Rose.
Odour
: Odourless.
pH
: 1-3
Crystallization temperature
Boiling point
: -10 °C
: ± 100 °C
Flash point
: > 100 °C
Explosive limits
: No data available
Vapour pressure
: 23 hPa (as water)
Density
: 1.40 kg/l
Solubility
: Soluble in water.
Water: complete
Log Pow
: No data available
Decomposition temperature
: No data available
Viscosity, kinematic
: No (test)data available
Explosive properties
: Not explosive.
Oxidising properties
: Not oxidising.
9.2.
Other information
Other properties
: Clear.
Additional information
: Refer to product datasheet
SECTION 10: Stability and reactivity
10.1.
Reactivity
The product is not considered as reactive.
10.2.
Chemical stability
The product is stable at normal handling and storage conditions.
10.3.
Possibility of hazardous reactions
This product can react with strong reducing or oxidizing agents.
10.4.
Conditions to avoid
Avoid high temperatures. Temperatures lower than -5°C. Unstable on exposure to light.
10.5.
Incompatible materials
Forms gypsus with calcium-, barium-, strontium-, phosphate-salts and with (strong) bases.
10.6.
Hazardous decomposition products
On burning: release of toxic and corrosive gases/vapours (sulphur oxides) and formation of metallic fumes.
SECTION 11: Toxicological information
11.1.
Information on toxicological effects
Acute toxicity
: Not classified (Based on available data, the classification criteria are not met)
Manganese(II)sulfate, monohydrate (10034-96-5)
LD50 oral rat
2150 mg/kg Testmethod: Indian Journal of Pharmacology, 23(3): 153-159. REACH dossier
information
LC50 inhalation rat (mg/l)
> 4.45 mg/l/4h Testmethod: OECD 403. REACH-dossier information
Skin corrosion/irritation
: Not classified
(Based on available data, the classification criteria are not met)
Serious eye damage/irritation
: Causes serious eye damage.
Respiratory or skin sensitisation
: Not classified (Based on available data, the classification criteria are not met)
Germ cell mutagenicity
: Not classified (Based on available data, the classification criteria are not met)
Carcinogenicity
: Not classified (Based on available data, the classification criteria are not met)
Manganese(II)sulfate, monohydrate (10034-96-5)
NOAEL (chronic, oral, animal/male, 2 years)
615 mg/kg bodyweight
NOAEL (chronic, oral, animal/female, 2 years)
715 mg/kg bodyweight
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Fervent Mangaan
SECTION 11: Toxicological information
11.1.
Information on toxicological effects
Reproductive toxicity
: Not classified (Based on available data, the classification criteria are not met)
Specific target organ toxicity (single exposure)
: Not classified (Based on available data, the classification criteria are not met)
Specific target organ toxicity (repeated
exposure)
: May cause damage to organs (brain) through prolonged or repeated exposure (if inhaled).
Aspiration hazard
: Not classified (Based on available data, the classification criteria are not met)
Other information
: Information on Effects: refer to section 4.
SECTION 12: Ecological information
12.1.
Toxicity
Ecology - general
: Toxic to aquatic life with long lasting effects.
Manganese(II)sulfate, monohydrate (10034-96-5)
LC50 fish 1
14.5 mg/l (LC50; 96h, as Mn). OECD203. Onchorhynchus Mykiss (rainbow trout)
EC50 Daphnia 1
8.28 mg/l (EC50; 48 h)
EC50 other aquatic organisms 1
61 mg/l (EC50, 72h, as Mn). OECD201. Desmodesmus subspicatus
LC50 fish 2
33.8 mg/l (LC50; 96 h)
EC50 Daphnia 2
9.8 mg/l (EC50; 48h, as Mn). Read-across data of Manganese (II) chloride
NOEC chronic fish
0.6 mg/l (120 d, Oncorhynchus mykiss (rainbow trout))
Threshold limit algae 2
61 mg/l (ErC50; OECD 201: Alga, Growth Inhibition Test; 72 h; Desmodesmus subspicatus;
Static system; Fresh water; Experimental value, anhydrous)
12.2.
Persistence and degradability
Fervent Mangaan
Persistence and degradability
In accordance with column 2 of REACH Annex VII, the ready biodegradability test does not
need to be conducted as the substance is inorganic.
Manganese(II)sulfate, monohydrate (10034-96-5)
Persistence and degradability
In accordance with column 2 of REACH Annex VII, the ready biodegradability test does not
need to be conducted as the substance is inorganic.
Biochemical oxygen demand (BOD)
Not applicable
Chemical oxygen demand (COD)
Not applicable
ThOD
Not applicable
12.3.
Bioaccumulative potential
Fervent Mangaan
Bioaccumulative potential
Bioaccumulation: not applicable.
Manganese(II)sulfate, monohydrate (10034-96-5)
Bioaccumulative potential
Bioaccumulation: not applicable.
12.4.
Mobility in soil
Fervent Mangaan
Ecology - soil
Soluble in water.
Manganese(II)sulfate, monohydrate (10034-96-5)
Ecology - soil
Soluble in water.
12.5.
Results of PBT and vPvB assessment
Fervent Mangaan
This substance/mixture does not meet the PBT and/or vPvB criteria of REACH regulation, annex XIII
12.6.
Other adverse effects
Additional information
Version: 3.2
: Avoid release to the environment
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Fervent Mangaan
SECTION 13: Disposal considerations
13.1.
Waste treatment methods
European List of Waste (LoW) code
: 06 03 14 - solid salts and solutions other than those mentioned in 06 03 11 and 06 03 13
Depending on branch of industry and production process, also other EURAL codes may be applicable,
The EURAL code must be assigned by the user, preferably in consultation with the (environmental) authorities concerned
Regional legislation (waste)
: Disposal must be done according to official regulations.
Waste treatment methods
: Do not discharge into drains or rivers. Dispose the product, depending on the degree and type
of contamination, either as fertilizer or in an authorized waste disposal site. Empty and rinsed
containers can be disposed as non-hazardous material or be returned for recycling.
Waste disposal recommendations
: Remove waste in accordance with local and/or national regulations. Care should be taken
when handling emptied containers that have not been cleaned or rinsed out.
Ecology - waste materials
: Avoid release to the environment.
SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
ADR
14.1.
3082
IMDG
UN number
3082
14.2.
UN proper shipping name
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Transport document description
UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (CONTAINS manganese sulfate), 9, III, (E)
UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S., 9, III
14.3.
9
Transport hazard class(es)
9
14.4.
III
Packing group
III
14.5.
Environmental hazards
Dangerous for the environment : Yes
Dangerous for the environment : Yes
Marine pollutant : No
No supplementary information available
14.6.
Special precautions for user
- Overland transport
Classification code (ADR)
: M6
Special provisions (ADR)
: 274, 335, 601, 375
Limited quantities (ADR)
: 5l
Excepted quantities (ADR)
: E1
Packing instructions (ADR)
: P001, IBC03, LP01, R001
Special packing provisions (ADR)
: PP1
Mixed packing provisions (ADR)
: MP19
Portable tank and bulk container instructions
(ADR)
: T4
Portable tank and bulk container special
provisions (ADR)
: TP1, TP29
Tank code (ADR)
: LGBV
Vehicle for tank carriage
: AT
Transport category (ADR)
: 3
Special provisions for carriage - Packages
(ADR)
: V12
Special provisions for carriage - Loading,
unloading and handling (ADR)
: CV13
Hazard identification number (Kemler No.)
: 90
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Fervent Mangaan
SECTION 14: Transport information (continue)
14.6.
Special precautions for user
Orange plates
:
Tunnel restriction code (ADR)
: E
- Transport by sea
Special provisions (IMDG)
: 274, 335, 969
Limited quantities (IMDG)
: 5L
Excepted quantities (IMDG)
: E1
Packing instructions (IMDG)
: P001, LP01
Special packing provisions (IMDG)
: PP1
IBC packing instructions (IMDG)
: IBC03
Tank instructions (IMDG)
: T4
Tank special provisions (IMDG)
: TP2, TP29
EmS-No. (Fire)
: F-A
EmS-No. (Spillage)
: S-F
Stowage category (IMDG)
: A
14.7.
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
SECTION 15: Regulatory information
15.1.
Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1.
EU-Regulations
Contains no REACH substances with Annex XVII restrictions
Fervent Mangaan is not on the REACH Candidate List. Contains no substance on the REACH candidate list
Contains no REACH Annex XIV substances
15.1.2.
National regulations
Netherlands
Waterbezwaarlijkheid
: 7 - Toxic to aquatic organisms
SZW-lijst van kankerverwekkende stoffen
: Manganese(II)sulfate, monohydrate is listed
SZW-lijst van mutagene stoffen
: Manganese(II)sulfate, monohydrate is listed
NIET-limitatieve lijst van voor de voortplanting
giftige stoffen – Borstvoeding
: None of the components are listed
NIET-limitatieve lijst van voor de voortplanting
giftige stoffen – Vruchtbaarheid
: None of the components are listed
NIET-limitatieve lijst van voor de voortplanting
giftige stoffen – Ontwikkeling
: None of the components are listed
15.2.
Chemical safety assessment
Chemical safety assessments for substances in this preparation were carried out
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Fervent Mangaan
SECTION 16: Other information
Version
: 3.2
Revision date
: 25/04/2016
according to Regulation (EU) 2015/830
Date of issue
: 24/03/2009
Supersedes
: 15/07/2015
Indication of changes
: Revised safety data sheet in accordance with commisssion regulation (EU) No 2015/830.
Abbreviations and acronyms:
ADN
European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways
ADR
European Agreement concerning the International Carriage of Dangerous Goods by Road
ATE
Acute Toxicity Estimate
CLP
Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008
DNEL
Derived-No Effect Level
EC50
Median effective concentration
IATA
International Air Transport Association
IMDG
International Maritime Dangerous Goods
LC50
Median lethal concentration
LD50
Median lethal dose
NOAEL
No-Observed Adverse Effect Level
NOEC
No-Observed Effect Concentration
OECD
Organisation for Economic Co-operation and Development
PBT
Persistent Bioaccumulative Toxic
PNEC
Predicted No-Effect Concentration
REACH
Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation (EC) No 1907/2006
RID
Regulations concerning the International Carriage of Dangerous Goods by Rai
SDS
Safety Data Sheet
STP
Sewage treatment plant
TLM
Median Tolerance Limit
vPvB
Very Persistent and Very Bioaccumulative
Data sources
: ECHA Website: Information on Registered Substances.
Handbook of Chemistry and Physics CRC Press Inc.
Information from suppliers.
BIG-database.
Training advice
: Normal use of this product shall imply use in accordance with the instructions on the packaging.
Before using/handling the product one must read carefully the MSDS.
Full text of H- and EUH-statements:
Aquatic Chronic 2
Eye Dam. 1
STOT RE 2
H318
H373
H411
Hazardous to the aquatic environment — Chronic Hazard, Category 2
Serious eye damage/eye irritation, Category 1
Specific target organ toxicity — Repeated exposure, Category 2
Causes serious eye damage
May cause damage to organs through prolonged or repeated exposure
Toxic to aquatic life with long lasting effects
Company disclaimer
This information has been prepared in good faith, based upon the details communicated to us (also by the manufacturer).
As far as we know, the information is correct and complete. It is exclusively intended for the product and use as stated in the
documents provided by us. Van Iperen BV shall not be held liable for any detrimental impact on persons or goods, in the unlikely
event that this information eventually proves not to be entirely correct. For the sake of completeness, we emphasise that any
liability shall be restricted by the applicable general terms and conditions filed with the Rotterdam district court on 2 July 2015 under
file number AL 39/2015.
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