Oceanography 10, T. James Noyes, El Camino College 13A-1 Ocean Resources The ocean provides us with many things: fresh water to drink 1, over half of the oxygen we breathe, a cheap way to transport goods, recreation (sailing, swimming, etc.), and so on. (It also takes a lot of things from us, typically waste products.) According to the National Oceanic and Atmospheric Administration (NOAA), in 2008 at least 28 million jobs in the United States were related directly or indirectly to the ocean, which was about 1 in 6 jobs! In this section, we will examine the things that we take from the ocean. I will split the things-wetake-from-the-ocean into two major categories, living and mineral resources, but first we must discuss ownership rights. Human Populations and the Ocean Right now, more than 50% of our population lives in coastal counties (that cover 17% of the land in the lower 48 states), so that doesn’t even count the population of the counties that are just a little bit inland like San Bernadino and Riverside. The same holds true worldwide: over half the world’s population lives in a narrow strip of land (say, within 60 miles) of a large body of water, and most of the rest lives only a little farther inland. The ocean has always provided enormous benefits to humans, so most people live near the ocean. You can tell that most people in the United States live close to the coast from the presidential election results in 2000 and 2004. In 2000, both Bush and Gore got about 48% of the vote, with Gore getting about ½ million more actual votes (as opposed to votes in the electoral college). In 2004, Bush got 51% of the vote, and Kerry got 48% of the vote. Thus, in both races about half of the people voted for the Republican candidate and half voted for the Democratic candidates. If you look at the electoral maps, though, you will see that most of the country looks pretty red (Republican), except for the west coast, New England, and the states bordering the Great Lakes. Thus, even though “red” covers more than twice the area covered by “blue,” its population is not any larger; well over half our population has to be living near the coast. Great Lakes 2004 Presidential Election 1 Water evaporates from the ocean, leaving the salt behind, and eventually condenses in the atmosphere, falling as rain. Oceanography 10, T. James Noyes, El Camino College 13A-2 Who Owns the Oceans? Early ocean law was based around the simple facts that the ocean is really big, and no one could really enforce rules. Thus, the idea of “freedom of the seas” developed: everyone has the right to travel across the ocean unhindered. This includes an attitude of “finders keepers” (whatever you find – fish or treasure – are yours) which is still enshrined in ocean law. For example, in November 2003, a salvage company found a sunken Civil-War-era ship with about $150 million 2 in gold onboard (it was being sent from the “North” to the “South” for reconstruction after the war). Even though the gold originally belonged to the federal government, the company only had to pay taxes on it; the rest was theirs. Since the ocean is so big and there is no easy way to place markers of “ownership” (fences, signs, etc.) – and our ability to extract fish and minerals from it was so limited in the past – the attitude developed that everyone should be able to take as much as they want from the ocean. To people in the past, it did not seem possible that we could remove all of the fish (or other organisms), and this led to sayings like “there are plenty of fish in the sea.” When you break up with your significant other (e.g., boyfriend or girlfriend) and your friend tells you this, do you believe them? It certainly is no longer true in our oceans. For example, we have successfully eliminated about 90% of the large fish in the ocean. Until the early 20th century, the idea of a “territorial sea” was the primary idea guiding ocean law. A nation could claim any and all resources within about 3 miles from land, roughly the range of an old-fashioned cannon mounted at the shoreline. (I consider this to be a “mightmakes-right” kind of law. If I could sink you if you try to take it, then it must be mine.) After World War II, President Truman declared that the United States owned all of the resources and territory out to the edge of its continental shelf (in part for the resources and in part as a buffer against attack with newly-invented nuclear weapons mounted on submarines sneaking up to the coast). Inspired by his example, more and more nations began claiming territory farther and farther from their shores which led to many disputes between countries. To help end the growing disputes, in the 1960’s the United Nations stepped in to try to get all nations to agree on a set of rules. The result is what is known as the “Law of the Sea.” It was held up for a long time – until 1982 – because nations had particular difficulty agreeing on deepsea mining rights and where submerged submarines could go. Although the United States has always obeyed the Law of the Sea, President Reagan refused to sign it, because he (like the leaders of many other developed countries including England, France, the Soviet Union, Japan, etc.) believed that companies should be able to take minerals off the deep-ocean floor in areas which no one owned. Developing nations like India and Brazil disagreed, arguing that the United Nations should set up a company to harvest the resources, and the profits should be shared equally among all the people of the world. After some concessions, the United States signed the Law of the Sea under President Clinton, but it has still not been ratified by our Senate, because some senators think that the United States should not sign any “unnecessary” 2 Companies still have to pay taxes, of course, and when things are found on the ocean floor, other people will often try to make a claim for them. For example, a company called Odyssey Marine Exploration is currently being sued in U.S. courts by the government of Spain for gold coins that it recovered from sunken treasure galleons (gold that Spain “stole” from Central and South America originally, as far as I am concerned). In particular, Spain and others want to force the company to reveal the location of the sunken ships in court to justify the company’s claim to the gold (is the gold in a place where anyone can salvage it?), but if the company does so, it is worried that other people will rush to the location and take any remaining gold. The company wants to go back and look for more gold itself. After all, it spent a lot of the time and money searching for the sunken ships in the first place. Oceanography 10, T. James Noyes, El Camino College 13A-3 agreements with foreign countries which restrict our freedom of action. Ironically, high-level business interests, environmentalists, and military leaders 3 all agree that it should be signed so that the rules will be clear – even if not perfect from our perspective – and further development can proceed without risk of the rules being changed suddenly. So what does the Law of the Sea say? (What is so terrible, according to those senators?) All ships should be allowed free, unrestricted passage through the ocean. All countries have a 12mile “territorial sea” around their coast in which their own laws apply, and a 200-nautrical-mile 4 “exclusive economic zone” (EEZ) in which the nation owns all the economically valuable resources (e.g., fish, oil) and can enforce pollution laws, but otherwise have no special rights. International bodies regulate deep-sea mining, and all nations agree to U.N. arbitration of disputes (i.e., they will not go to war over a deep-sea oil deposit). Of course, the Law of the Sea has not settled all problems. The United States and Canada regularly fight over how many “American” and “Canadian” salmon are caught in one another’s EEZ. There are lots of disputes over potential oil and gas deposits. For example, China, Taiwan, Vietnam, Philippines, and Malaysia all claim the Spratly Islands, desolate little rocks where no one lives (aside from some military personnel 5 – and tourists! – sent there to stake claims). The word “exclusive” in EEZ implies that the economic resources (fish and minerals) are the property of our nation, that we alone can use them. It is like being in an “exclusive” relationship with your significant other: they cannot date other people; they are “yours.” If your boyfriend or girlfriend does cheat on you, then I guess that they are just E-Z. ☺ The Law of the Sea greatly expanded the area under the control of nations. For example, the size of the United States more than doubled, thanks in part to the large number of small islands taken from the Japanese during World War II that became U.S. “territories.” This is a vast area, to a large extent still unexplored in any detail. Canada has sent military ships up to Arctic islands where no one lives to make sure that it is clear that the islands are theirs and that their EEZ extends as far as possible out into the Arctic Ocean. As global warming melts the North Pole, we will be able to get at the oil deposits on the sea floor and shipping will have a shorter route from Europe to the west coast of North America and East Asia (by 2020). The Canadians want to make sure that they are well-positioned for this eventuality (legally and on the ground). In 2007, the Russians sent a submarine to plant a flag at the North Pole for similar reasons. 3 I find it amazing that legislation cannot get passed when all 3 of these groups agree on something. The United States may be signing the Law of the Sea soon, though. Once we do so, we can officially begin to set our EEZ. The ice in the Arctic is melting and oil companies are buying up land for refineries, ports, etc. We need to stake our claim (and oppose other countries that have already signed the Law of the Sea) for the oil resources that we will soon be able to access owing to global warming. 4 It can be larger if the continental shelf is larger. However, it is not always clear exactly where the continental shelf “ends.” There are several bitter disputes about oil deposits where the size of the continental shelf is the key issue. 5 A few examples: In 1988, Chinese troops killed 70 Vietnamese sailors. In 2002, Vietnamese forces fired on a Philippine jet. After the last incident, all sides agreed to resolve the conflict through peaceful means. Hence, tourists are being sent to the islands. In 2010, a Chinese fishing boat rammed a Japanese coast guard vessel. Oceanography 10, T. James Noyes, El Camino College 13A-4 International Trade: Beyond the Reach of the Law As in the past, few laws govern international shipping (few enforceable laws, at least). There are about 40,000 cargo ships crisscrossing the oceans, mostly run by shadowy, offshore companies flying “flags of convenience” from countries that tax and regulate them lightly (a huge number are ostensibly “from” nations like Panama and land-locked Bolivia!). There is no way that the 50,000 men and women of the U.S. Coast Guard can properly inspect all the cargo and crew of the 60,000 calls made at U.S. ports by huge cargo ships. Pirates are still a problem in some parts of the world, especially the east coast of Africa and the South China Sea. Somali pirates tend to hold the crews, ships, and cargos for ransom. In the South China Sea, the ships’ crews, mainly from poor countries, are marooned if they are lucky, killed if they are not. The pirates operate “phantom ships:” they re-paint and re-name the ships at sea, and quickly unload cargo in ports and take on more, disappearing before local authorities realize who and what they really are. Mineral Resources The most valuable mineral resources that we extract from the ocean are petroleum products like oil and natural gas. These “fossil fuels” not only power our vehicles and appliances, but are part of many manufactured items like plastics. Currently, about 1/3rd (33%) of the oil and natural gas that we use are extracted from the ocean. In the past, I would have said that this is likely to rise, but with the development of “fracking” technology, more and more oil and natural gas production is taking place on land in the United States. The second most valuable mineral resource that we take from the ocean (about 5% of the total) are sediments like Oil Drilling Platform. sand and gravel that are used in the construction of roads Courtesy of Andrew Schmidt and buildings (e.g., in concrete), beach restoration, (public domain). building levees, and so forth. In a few places, sediments even have enough gems or precious metals (e.g., gold, silver) mixed in with them to make them worth mining from the sea floor, but very, very, very little of our precious metals come from the ocean. Dredging Sediments. National Oceanic and Atmospheric Administration, Department of Commerce Oceanography 10, T. James Noyes, El Camino College 13A-5 The concrete all around you Pound for pound, concrete is the second most common substance used by humans (the most commonly used substance is water). It is all around you: roads, sidewalks, the walls and foundations of buildings, and in many other things. Concrete is composed of bits of rock like sand and gravel held together by a “binder” material called a cement. One of the key ingredients for cement is calcium. Thus, sea floor sediments are important sources for the ingredients for concrete: Sand and gravel are often found on the continental shelves, and the calcium carbonate shells of plankton pile up on the ocean floor and over time become the sedimentary rock limestone. The limestone we mine on land to make cement was once the ocean floor. (About 10% of all sedimentary rock is limestone.) Unfortunately extracting the calcium in limestone to make cement releases a lot carbon dioxide into the atmosphere. The production of the cement is the third largest human activity that increases the Earth’s greenhouse effect and contributes to global warming (electrical power plants and transportation like cars and trucks are top two). The third most valuable mineral resource, salt, was much more important in the past when it was essential for preserving foods (very important before refrigerators). For example, during the independence movement in India, Mahatma Gandhi famously led the “march to sea” in which people made their own salt from ocean water so that they would not have the pay the British taxes for this essential item 6. Salt is used for much more than flavoring and preserving food nowadays. For example, salt is used in a variety of industries (e.g., dying fabrics, making soaps) and in products (e.g., fireworks, in the walls of your home as “wallboard” or “sheetrock”). Much of the salt mined on land was originally in the ocean, and was left behind when the water evaporated away. Salt Mining. Courtesy of Rhodian (public domain). Evaporation Ponds for making salt south of the Dead Sea. NASA. 6 No one wants to pay taxes that will be used to pay for the police and troops that oppress them. Oceanography 10, T. James Noyes, El Camino College 13A-6 There are several mineral resources that are not currently taken from the ocean (because it costs more to remove them from the ocean than one can get for selling them), but as technology improves in the future, they may one day become economically valuable. Probably the most valuable potential mineral resource is “gas hydrates,” also known as “methane hydrates.” Dead bodies of ocean organisms like plankton accumulate in ocean sediments, and when they are decomposed (“broken down”) by some bacteria, methane (CH 4 , “natural gas”) is released. In the deep, cold, high-pressure waters of the ocean, methane often bonds strongly with water molecules in the sediments, and forms muddy chunks of ice with natural gas trapped inside. Gas hydrates are of interest to many people, because they are another potential source of fossil fuels, and oceanographers estimate that there are so many gas hydrates in ocean sediments, they would triple our supplies of fossil fuels (a 200% increase in the amount of fuel!). Gas Hydrates: Ice on Fire. Unfortunately, gas hydrates are hard to retrieve, US Office of Naval Research / USGS because they cannot be pumped up to the surface (they are solid, not a fluid) and as soon as they are brought upwards into warmer, lower-pressure water, they begin to melt. Another potentially valuable mineral resource from the ocean are phosphorite deposits, ocean sediments (or sedimentary rocks) that are rich in phosphorus. As you know, phosphorus is a “nutrient,” so these deposits can be made into fertilizers. Some phosphorite deposits that are mined on land were once underwater in the ocean. Like gas hydrates, the phosphorus (nutrients) comes from the bodies of organisms that fall to the bottom of the ocean and decompose in the sediments, but unlike gas hydrates, the richest phosphorite deposits are typically found on continental shelves. Phosphorite. USGS. Oceanography 10, T. James Noyes, El Camino College My final example of a potentially-valuable, ocean mineral resource is manganese nodules. These are small (up to the size of a tennis ball) nuggets of metal that form when chemicals (“salts”) solidify (congeal, “precipitate”) out of ocean water over millions of years on the cold, high-pressure floor of the deep ocean. They are primarily made of manganese and iron, but have small amounts of copper, nickel, and cobalt. The United States has expressed particular interest in the cobalt, since our main supplies – needed for militarily and economically important applications like high-powered magnets and jet engine parts – come from southern Africa, a potentially “politically unstable” part of the world. 13A-7 Manganese Nodule Mining Rare Earth Minerals from the Sea Floor? Japanese researchers recently (2010) announced the discovery of large deposits of “rare earth minerals” on the ocean floor. The minerals are needed to manufacture a variety of high tech items including solar panels, cell phones, TVs, cars, and more. China is currently the major exporter of rare earth minerals, but it recently stopped selling them to Japan, probably in part because of their dispute over fishing grounds and seafloor oil and gas deposits. Like Japan, the United States does not want to rely on China as their primary source for these essential minerals. Mineral Resource or Living Resource? Fossil fuels like oil, natural gas, coal, methane hydrates, etc. are typically considered “mineral” resources, because we dig them out of the Earth. However, fossil fuels are the remains of onceliving organisms who bodies have partially decomposed and been chemically altered. (That is why they are called “fossil” fuels: fossils are the remains of organisms.) Since they derive from living things, you might consider them to be living resources instead of mineral resources. Diatomaceous Earth Diatoms are phytoplankton. Their silica shells are full of tiny holes and do not interact chemically with most substances. (This is why we use glass as a container for our liquids.) Sedimentary rock composed of diatom shells is useful for “filtering” and “cleaning”. Diatomaceous earth is used in a variety of products and processes, including: refining sugar, straining yeast from beer, swimming pool filters (which remove “gunk” from the water), toothpaste, household cleaners, kitty litter, to clean up chemical spills, and much, much more. Oceanography 10, T. James Noyes, El Camino College 13A-8 Living Resources The main living resources that we extract from the ocean are animals and algae for food. A “fishery” is any wild population (group) of organisms that we harvest (take from the ocean), thus people talk about shrimp and oyster fisheries even though shrimp are crustaceans and oysters are mollusks, not fish. Conveniently, most fisheries are located close to the coasts, so fishermen do not have to travel too far to reach most animals. Fish and other animals caught from the ocean are worth a lot of money. In 2004, the shrimp fishery in Mississippi (just one kind of animal in one state) was worth about $500 million. In 2001, $80 billion in marine animals were harvest from the ocean, and over 70,000 people were employed in catching and processing them just in the United States. NOAA, Dept. of Commerce On average, humans get about 1/6th (16%) of their protein from the ocean. People in some countries, of course, eat more than others (e.g., the Japanese). Not all of the fish that are caught are used for human consumption. About 1/3rd (33%) of the catch is ground up and fed to “farmed” fish and ordinary farm animals 7 like cows, pigs, chickens, and so forth to help them grow faster. In this way, the ocean provides a much larger proportion of our protein than the figure of 16% that I quoted at the beginning of the paragraph. Fish Meal: Ground up fish. National Oceanic and Atmospheric Administration, Dept. of Commerce. 7 Grinding up animals and feeding them to other, non-carnivorous animals is a common practice in big-business agriculture. (Maybe the chicken that you ate last night really was “chicken of the sea.”) It is also how illnesses like “mad cow disease” are spread through a food supply: diseased animals are ground up and fed to other animals. Waste not, want not, I suppose. Oceanography 10, T. James Noyes, El Camino College 13A-9 An important but often overlooked use of ocean organisms is as a source of useful chemical compounds, particularly those with medicinal uses. As you may or may not know, many of the drugs that we use (e.g., aspirin) were originally found in nature, and then later we learned how to make (“synthesize”) them with advanced chemistry. Scientists are now “bioprospecting” throughout the world, looking for animals and plants with special chemicals that they use for attack, defense, mating, camouflage, and so on to see if they might have a practical use (e.g., medicines). Given the vast number of unknown and chemically unique ocean organisms (e.g., like those found near hydrothermal vents), there is good reason to hope that we might find amazing cures out there in the ocean. For example, recently (2008) scientists discovered that a species of “sponge” secretes a chemical which destroys the ability of bacteria to resist antibiotics. Hundreds of marinebased compounds have already been patented. Of particular interest are places in the ocean with high biodiversity (a large number of different species all in one spot), like coral reefs and deep-ocean sediments. Sources of New Medical Drugs? National Oceanic Bioprospecting is not just a search for medical and Atmospheric Administration, Dept. of Commerce. drugs, though. For example, recently a scientist studying dead bacteria in seafloor mud Sponges used his research to develop a way to catch athletes who cheat by taking synthetic/artificial testosterone, a popular (and banned) anabolic steroid. Another team of scientists studied how an ocean worm makes a strong glue that can harden underwater, and learned how to make it themselves. Many scientists hope to find chemicals that will help them create “biofuels,” fuels derived from the remains of plants or algae. An example of a biofuel that you may have heard about is ethanol 8. Currently, the “holy grail” of biofuel research is to go from dead plant matter to hydrogen fuel. (When hydrogen fuel is burned in fuel cells, the exhaust is pure, clean water. There is no air pollution or greenhouse gases that contribute to global warming.) Scientists have developed a fast, efficient technique for making hydrogen from starch using enzymes from living organisms (enzymes are special proteins that cause specific chemical reactions, some of the enzymes had to be genetically engineered). The major goal now is to figure out how to make hydrogen from cellulose and other waste materials. We do not want to produce fuel from the parts of plants that people to eat (and thus reduce our food supply). 8 Unfortunately, we cannot produce ethanol from corn efficiently enough yet. Brazil can produce ethanol at a competitive price, because they use a better plant (sugarcane). Oceanography 10, T. James Noyes, El Camino College 13A-10 Bioprospecting: Why sponges? Sponges are huge-colonies of individual cells that work together to survive. They wiggle tiny “tails” (flagella) to bring water in through their sides, and plankton in the water get trapped in small holes. Sponges are soft-bodied organisms that cannot move. Their only defense against predators are the chemicals that they produce. Sponges appear to be the earliest form of “animal” life (or something close to it) and the only way they have been able to survive as a species is to evolve the ability to make potent and unique chemicals at least as fast as predators have evolved ways around them. In this “evolutionary arms race,” each side drives the other to develop bigger and better weapons. Ocean life is useful for more than chemicals. “Silicon valley” in particular may owe something to the ocean in the not-too-distant future. Tiny, silica-shelled phytoplankton and zooplankton are helping scientists build “nanotechnology” like very tiny semiconductor chips, crystals for lightbased computers, and chips for making chemicals or analyzing DNA. The shells of some organisms (e.g., diatoms, sea urchin shells) have been used as “molds” for these microscopic objects. Scientists are also learning how silica-shelled organisms grow their shells and hope to use the same methods to assemble their microscopic devices or genetically engineer organisms to “grow” the devices for them. Manufacturing silicon chips and other electronic devices requires harsh chemicals and generates dangerous wastes, but these organisms achieve similar results with no pollution. Perhaps they can teach us a thing or two. Scientists also study swimming dolphins, penguins 9, whales, and other ocean organisms for better ways to design ships and submarines to maneuver, move quickly through the water while expending less energy, or remain stable in turbulent waves and currents. They are also learning how plankton swim for medical purposes: to build tiny swimming machines to inject into our bodies. The machines could carry chemotherapy drugs to tumors, break up clots in blood vessels, and much more. Scientists are also studying the structure of dolphin’s brains to learn how to design better SONAR systems (which use sound to “see” objects underwater). Bioprospecting Your Way to a Nobel Prize In 2008, the Nobel Prize for chemistry was given to Osamu Shinomura, Martin Chalfie, and Roger Tsien, researchers who engaged in marine bioprospecting. In 1962, Dr. Shinomua isolated green fluorescent protein (GFP) from the jellyfish Aequorea victoria, the substance that makes it bioluminescent (in other words, allows it to generate light, to “glow”). Later, Dr. Chalfie figured out how to insert the gene for making GFP into other organisms’ DNA so that the cells in the organisms “glowed” when the genes it is next to were “turned on” in the cells. This made it much easier to carry out genetic research; instead of needing to carry out careful and time consuming tests, scientists could literally “see” when and where genes were being activated in organisms’ bodies during experiments. His technique led to faster progress in medical research, and is now standard throughout the world. Dr. Tsien made the technique even more useful. He discovered similar proteins in corals that produced different colors, so now scientists can test multiple genes at one time (different genes produce different colors). Most importantly, they can study genes’ interactions and effects on one another more easily & quickly. 9 Penguins must generate huge forces for their size to jump out the water and onto the ice. Oceanography 10, T. James Noyes, El Camino College 13A-11 Power from the Ocean Like hydroelectric and geothermal power, the ocean is a potential source of renewable electric power: tides, winds, waves, even the temperature difference between the mixed layer and the deep ocean. In some places in the world, tides are already being used to generate electrical power. All you need to do is to build a dam that blocks the flow of the water into or out of an estuary. Then, once the water on one side is at its highest, let the water run through, just like hydroelectric power on a river. The flowing water spins turbines containing magnets (spinning a magnet produces electricity). This is only economical in big estuaries with narrow entrances (smaller dams are cheaper to build and maintain) and large tidal ranges (more water = more electricity). Tidal Power. Barrage de la Rance, France. Courtesy of Tswgb (public domain). Winds blow strongly and steadily across large parts of the ocean. In some places (e.g., Denmark), offshore “wind farms” are already in use. It is more expensive to place and maintain wind turbines in the ocean than on land, but there is lots of space in the ocean. Often the main objection to offshore wind farms is that they would spoil the view. I do not disagree, but some argue that there is something beautiful about looking at wind turbines and knowing that your community has less air pollution and is contributing less to global warming. In 2006, the U.S. Congress added an amendment to a Coast Guard bill that “killed” the first, large offshore wind farm in the United States near Cape Cod in Massachusetts. Offshore Wind Power, Denmark. Courtesy of Leonard G., Creative Commons Sharealike 1.0 Oceanography 10, T. James Noyes, El Camino College 13A-12 Wave power has enormous potential. The Department of Energy has estimated that the wave power along the east coast of the United States is at least 10 times the wind power available in the Midwest. For island countries or nations with large coastlines, fully 1/5th (20%) of their power needs could come from wave and tidal power. The biggest problem with wave power is the ocean itself: the generators are damaged by storms or slowly corroded. Maintenance and repair costs quickly eat into the profits and efficiency of power generation. Also, waves are too slow to generate power efficiently. To create electricity, you need to make a magnet accelerate (move faster). Waves provide lots of motion, but do not produce a lot of acceleration; the motion is “too gentle.” Since the 1970’s, many improvements have been made to deal with both of these issues, so you may read more about “wave power” in the not-too-distant future. Wave Power. Portugal. Courtesy of S. Portland (public domain). Some scientists hope that we can make biofuels from algae. They are searching for good candidates and attempting to genetically engineer algae to make the conversion process efficient enough to compete with oil. We could grow the algae in large tanks. Better still, if they are ocean algae, then they will grow in seawater, so we could create biofuels without using up any of our limited supply of fresh water!
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