Geological Society, London, Special Publications published online June 27, 2012 as doi: 10.1144/SP370.6 Reservoir properties and petrophysical modelling of carbonate sand bodies: outcrop analogue study in an epicontinental basin (Triassic, Germany) DENIS PALERMO1,2*, THOMAS AIGNER1, BJOERN SEYFANG1,3 & SERGIO NARDON2 1 Department of Geosciences, Centre of Applied Geosciences, University of Tübingen, Sigwartstr. 10, D-72076 Tübingen, Germany 2 Eni S.p.A. – Exploration & Production Division, via Emilia 1, 20097 San Donato Milanese, Italy 3 Present address: Centre Scientifique et Technique Jean Feger (CSTJF), Avenue Larribau, F-64018 Pau Cedex, France *Corresponding author (e-mail: [email protected]) Abstract: This paper represents the second part of an integrated study that is focussed on the development and distribution of reservoir bodies and properties in epeiric carbonate systems. It is based on outcrop analogue data from Triassic ‘layer-cake’ carbonates in the South German Basin, which were deposited along an epicontinental, very gently inclined carbonate ramp. The reservoir facies consists of skeletal and oolitic carbonate grainstones (Fmax 23%, Kmax 700 mD), which are organized in a pronounced hierarchy of stratigraphic cycles. Based on outcrops, cores, gamma ray (GR) logs and thin sections, a high-resolution, geocellular 3D facies model was generated, which covers the area of a Middle East giant gas field (25 × 36 km). The spatial distribution of reservoir properties was systematically investigated on different scales. The lateral distribution of reservoir properties remains in the same order of magnitude for hundreds of metres, within in the same stratigraphic position. However, on a kilometre scale, facies bodies, diagenetic trends and thus reservoir properties show gradual lateral changes. Vertically, in contrast, properties change commonly on a decimetre scale and are largely controlled by stratigraphic cycles. Petrophysical modelling enhanced the understanding of key factors and processes controlling both reservoir quality and quantity. Reservoir heterogeneity remains a significant issue in reservoir modelling and prediction of field performance. Outcrop analogues are ideal for establishing the possible geometries and property distributions at the inter-well scale. Quantitative data on carbonate rock bodies remain scarce (e.g. Handford 1988; Burchette et al. 1990; Grant et al. 1994; Harris & Kowalik 1994; Borgomano et al. 2002; Grammer et al. 2004; Kostic & Aigner 2004; Ruf & Aigner 2004; Rankey et al. 2006; Qi et al. 2007; Aigner et al. 2007; Palermo et al. 2008). Qualitative outcrop studies of geometry (e.g. Burchette et al. 1990; Gawthrope & Gutteridge 1990; Azerêdo 1998) and quantitative petrophysical studies carried out on outcrops at the appropriate scale (e.g. Kittridge et al. 1990; Senger et al. 1991; Eisenberg et al. 1994; Cavallo & Smosna 1997; Jennings 2000; Savary & Ferry 2004; Pranter et al. 2005, 2006) made useful contributions to the available data. Outcrop analogue studies of this nature are important in order to condition subsurface reservoir models to real data and concepts, thus significantly improving field appraisal work and development planning. The present work has resulted from a joint ENI E&P –University Research Consortium on the ‘Geometry of Carbonate Objects’. Within this project, the Triassic Upper Muschelkalk carbonates in the South-German Basin were studied as an analogue to the ‘layer-cake’-type reservoir systems of the Middle East. The Upper Muschelkalk was deposited on a gently inclined carbonate ramp, filling an epicontinental basin, and therefore represents an analogue to an important type of ‘nonreefal’ skeletal and oolitic carbonate sand reservoirs (e.g. Khuff, Hanifa, and Arab in the Middle East). A series of excellent quarries and natural outcrops in Southern Germany has been used to investigate the geometries within high-energy shoal water deposits along the margin of the Upper Muschelkalk Basin. Close outcrop spacing allows for lateral tracing of beds and mapping of lateral facies transitions. A hundred years of detailed From: Garland, J., Neilson, J. E., Laubach, S. E. & Whidden, K. J. (eds) 2012. Advances in Carbonate Exploration and Reservoir Analysis. Geological Society, London, Special Publications, 370, http://dx.doi.org/10.1144/SP370.6 # The Geological Society of London 2012. Publishing disclaimer: www.geolsoc.org.uk/pub_ethics Geological Society, London, Special Publications published online June 27, 2012 as doi: 10.1144/SP370.6 D. PALERMO ET AL. logging and mapping has resulted in a wellconstrained litho- and biostratigraphic framework (e.g. Wagner 1913; Vollrath 1938, 1955, 1957, 1958, 1970; Skupin 1969; Bachmann 1973; Aigner 1985; Ulrichs & Mundlos 1987, 1990; Hagdorn & Simon 1988; Ockert 1988; Geyer & Gwinner 1991; Braun 2003). This well-established stratigraphy provides the opportunity to transform the so far largely descriptive picture into a genetic, process-based analysis of the sedimentary bodies and packages. A detailed outcrop, core and well logging programme was carried out (e.g. GR logs, cores, porosity and permeability), allowing an analysis of the sedimentology, petrophysical characteristics, internal architecture and reservoir properties, within a 3D geocellular model. Palermo et al. (2010) have recently reported on the facies modelling aspects of this project. This companion paper focusses on reservoir properties and petrophysical modelling. Geological setting During the Triassic, rifting and disintegration of the Pangean supercontinent caused the western extension of the Tethys Ocean. This regional crustal extension induced the subsidence of a complex network of grabens and troughs in Western and Central Europe (e.g. Ziegler 1990) and formed the Triassic basins including the South German Muschelkalk Basin (Fig. 1). This basin extended roughly from Poland to the North Sea and from the Alpine foothills to Denmark. During the Middle Triassic (≏240– 231 Ma), the Muschelkalk Basin was covered by an epicontinental, semi-enclosed marginal sea that was separated by the Vindelician/Bohemian High from the open Tethys ocean in the SE. Temporary connections existed only through three narrow shifting seaways (Ziegler 1990; Dercourt et al. 1993). In the early Anisian a relative sea-level rise induced the Lower Muschelkalk transgression from the open Tethys ocean via the Silesian–Moravian and EastCarpathian Gates into the Germanic Basin with fully marine conditions. The open communication became restricted during the later Anisian, resulting in hypersaline conditions and formation of evaporites of the Middle Muschelkalk. Finally the fully marine carbonates of the Upper Muschelkalk were deposited during a transgression in the uppermost Anisian, connecting the Germanic Basin with the open Tethys realm via the three gates. The Upper Muschelkalk succession (Middle/Late Ladinian) represents one overall transgressive/regressive third-order sea-level cycle (Aigner 1985). The transgressive part is represented by an overall fining-upward sequence of crinoidal/shelly shoal water carbonates grading into Fig. 1. Palaeogeography of Central Europe in the Middle Triassic modified after Ziegler (1990), Hagdorn (1991) and Palermo et al. (2010) (AAPG # 2010, reprinted by permission of the AAPG, whose permission is required for further use). Geological Society, London, Special Publications published online June 27, 2012 as doi: 10.1144/SP370.6 CARBONATE SAND BODIES IN GERMANY muddy carbonates and marlstones. The upper regressive section is represented by an overall coarseningupward sequence, grading from the muddy sediments around maximum transgression into shelly/oolitic shoal carbonates and muddy backshoal sediments. The boundary between the Muschelkalk and the overlying, mainly siliciclastic Keuper is considered as maximum regression (Aigner et al. 1999). Generally, five major facies belts can be distinguished in the Upper Muschelkalk: (a) a narrow zone of coastal siliciclastics; (b) an irregular backshoal zone dominated by (partly dolomitized) peloidal mudand wackestones; (c) a high energy belt of skeletal/ oolitic pack- to grainstones; (d) shallow-ramp sediments dominated by skeletal storm sheets; and (e) a deeper ramp characterized by mud- and marlstones. The facies belts are modified by subtle structural trends that define subtle palaeo-highs and palaeolows, which are well known in the regional geology and can also be recognized by thickness variations (isopach maps) in various stratigraphic levels (e.g. Geyer & Gwinner 1991). These are probably reactivated basement blocks, inducing slight variations in differential subsidence. Study area, methods and database The SW German Hohenlohe area provides numerous quarries and natural outcrops in the Upper Muschelkalk (Fig. 2). The shoal water carbonates represent a major target for the raw-material industry in this region. Therefore, the closest spacing of quarries can be observed in areas where the clean and porous skeletal/oolitic grainstone bodies show their thickest development. Furthermore, natural exposures along river gorges allow a lateral tracing of individual bodies and property transitions. The database consists of 50 measured outcrop sections, supplemented by six cores and wireline logs (1787 m). Thirty-one of these sections (711 m) were integrated from previous work (Aigner 1985; Kostic 2001; Ruf 2001; Braun 2003; Allgöwer 2006; Dmitrieva 2006; Looser 2006; Seyfang 2006). For the investigation of diagenetic and petrophysical properties 568 cylinder-shaped plugs were extracted from rock samples and cores. The plugging focused on potential reservoir rocks, areas with visual porosity or dolomite content. The plugs have a diameter of four centimetres and Fig. 2. Composite map of the study area indicating the data points and the thickness of the Upper Muschelkalk; modified after Palermo et al. (2010). Geological Society, London, Special Publications published online June 27, 2012 as doi: 10.1144/SP370.6 D. PALERMO ET AL. were cut to a depth between 4.5 cm and 3 cm. Additionally, four rock columns (1 m × 0.2 m × 0.2 m) were derived from a block (2.1 m × 1.1 m × 1.0 m) in order to investigate the distribution of permeability within an individual reservoir body on different scales. Porosity and density measurements were carried out with two devices in two separate steps: (a) The determination of net volume (netVol) and net density (without pores) was carried out with a calibrated helium pycnometer. (b) Gross volume (grossVol) of the sample was measured with a powder pycnometer. This device calculates the rock density and the percentage porosity (F) with the formula: F = (grossVol − netVol) × 100/grossVol. Permeability was measured with a gas minipermeameter. Eight measurements were carried out on every sample, to provide the mean horizontal and the mean vertical permeability. The device is controlled by special automatic software, which adjusts the contact pressure, regulates the flow rate and calculates the permeability from the gas-flow rate. The measuring error of the mini-permeameter is around 0.5 mD. For the reconstruction of the diagenetic history and the deeper understanding of reservoir properties, 451 stained thin sections were investigated. For a systematic semi-quantitative analysis of several parameters (e.g. amount of components, mud content, cement generations, pore types) the comparison charts of Flügel (2004) were applied. The petrography and cement-types were investigated with transmission light and cathodoluminescence microscopy. The pore types were categorized and analysed by using mainly the concepts of Choquette and Pray (1970) and Lucia (1983). In order to quantify the results with the porosity and permeability measurements, the thin sections were commonly derived from the trim ends of the plugs. The 3D petrophysical modelling was carried out using industry-standard software within a high resolution 3D facies model described in Palermo et al. (2010). Facies and diagenesis Palermo et al. (2010) and thus do not need to be further discussed here. The facies types are interpreted to be deposited within a shallow epeiric carbonate ramp setting, characterized by a very gentle depositional gradient (between 0.0028 to 0.38). The carbonate ramp can be subdivided into three major subenvironments (cf. Burchette et al. 1990): (1) low energy inner ramp or backshoal; (2) highenergy mid-ramp with carbonate sands in shoreline detached shoals; and (3) low energy foreshoal and outer ramp with mud-dominated successions (Fig. 3). Figure 4 shows a generalized depositional model with the main reservoir facies types and their petrographic composition. Diagenetic history The diagenetic history of the Upper Muschelkalk grainstones has been subject to several previous studies (e.g. Bachmann 1973; Kostic 2001; Braun 2003; Seyfang 2006). Bachmann (1973) differentiated two major diagenetic stages with several cementation and leaching phases: (1) (2) Within the early diagenetic stage under shallow burial, isopachous circum-granular crust cement (A1 cement; Fig. 5.1) consolidated the original sedimentary grains. This process was followed by leaching of the aragonitic components and the precipitation of secondary isopachous crust cement (A2 cement; Fig. 5.2) of similar appearance, grown exclusively on the fringes inside the dissolved pores. The late diagenetic stage was refined by observations of Braun (2003), who recognized an additional phase of late diagenetic dog tooth cement (B1 cement) grown in irregular rims of isopachous prismatic spar, which was followed by the precipitation of equant drusy calcite-spar (B2 cement; Fig. 5.3). Finally, a minor amount of scattered dolomite cement precipitated in remnant separate vug pore space. The present investigation of 442 thin sections from different locations and stratigraphic intervals, using standard petrographic, cathodoluminescence and fluorescence microscopy, resulted in slight revisions of some aspects of the so far established late diagenetic history (Table 1). Facies types Based on lithology, Dunham texture, particle size, sorting, sedimentary structures and environmentindicative allochems such as for example ooids, oncoids and black pebbles 16 different lithofacies types were distinguished in the Upper Muschelkalk of the study area. These have been described in Discussion: controlling factors of diagenesis Facies. Facies types and their primary composition seem to have a major impact on diagenesis and reservoir development since both leaching and dolomitization are selective with respect to the mineralogy of components. For instance, the Geological Society, London, Special Publications published online June 27, 2012 as doi: 10.1144/SP370.6 CARBONATE SAND BODIES IN GERMANY Fig. 3. Facies types with key attributes, depositional environment and colour code. semi-quantitative analysis of 442 thin sections (Figs 5 & 6) shows a negative correlation between mud content and the intensity of early diagenetic A-type cements (correlation coefficient, 20.7; standard deviation, 0.19). However, apart from the depositional energy and mud content, the growth intensity of A1 cements is also controlled by the type of associated components. For example, A1 cements are often pore filling in ooid dominated grainstones, while they from only thin seams around crinoid ossicles. In general, however, the relationship between primary facies and diagenesis is complex (see below). Stratigraphy. The systematic semi-quantitative investigation of thin sections in their stratigraphic context showed that diagenetic alteration is also controlled by stratigraphic cycles. This is Geological Society, London, Special Publications published online June 27, 2012 as doi: 10.1144/SP370.6 D. PALERMO ET AL. Fig. 4. Facies distribution and petrographic composition, based on the semi-quantitative analysis of 442 thin sections. particularly important for the prediction of systematic changes of reservoir properties within individual facies bodies. An example for these variations within the reservoir facies of one regressive medium-scale hemicycle is depicted in Figure 6. In particular, the mud content and primary A cements change systematically within the cycle. Generally, the sum of mud content and A cements constitutes a more or less constant petrographic volume fraction together (arithmetic mean of mud content and A cement, 40.9 Vol%; standard deviation, 17.3; n ¼ 442 thin sections). As displayed in the column ‘Cumulative Vol %’ of Figure 6, upwards decreasing mud content is compensated by a systematic increase in B-type cements. Both A-type and B-type cement combined show a clear upward increasing fracture towards the mediumscale regressive maximum. Maximum values of interparticle and mouldic porosity are commonly located around the regressive maximums of the medium-scale cycles in shoal facies associations, following an upward decreasing fraction of matrix mud (Fig. 7b). However, intense late diagenetic B cements can partially plug the pore space in the upper portion the regressive hemi cycles, shifting the maximum porosity and permeability values towards the middle part (Fig. 6). The upward decreasing mud content reflects the vertically increasing depositional energy of a prograding shoal complex and seems to be a major controlling factor in the reservoir properties. The carbonate mud in the lower portion of the regressive Geological Society, London, Special Publications published online June 27, 2012 as doi: 10.1144/SP370.6 CARBONATE SAND BODIES IN GERMANY Fig. 5. Thin section photographs. (1) Thin section Crailsheim, parallel Nichols, stained: blue indicates porosity. Pel-oolitic grainstone: the peloids are surrounded by A1 cement (A1) forming typical circum-granular crusts of fibrous to bladed calcite crystals. Note the preserved primary interparticle porosity between the grains (Ip). The black opaque inclusions within the peloids are probably pyrite crystals (Py). (2) Thin section Sattelorf-Bölgental, parallel Nichols, stained: blue indicates porosity. Crinoidal grainstone: shape-preserving micritic envelope of a dissolved aragonitic bioclast (M). A1 cement (A1) forms a more regular seam of fibrous to bladed crystals compared with the more irregular A2 cement (A2) grown inside the biomouldic pore (Bm). (3) Thin-section Steinbächle, parallel Nichols. Bioclastic grainstone: a mosaic of drusy, equant B2 cement (B2) overgrows the earlier generation of B1-‘dog tooth’ cement (B1). (4) Thin-section Crailsheim, parallel Nichols, stained: blue indicates porosity. Oolitic grainstone: the dolomitization of ooids and coated grains occurs preferentially by replacing the cortical layers with a sub- to anhedral crystal mosaic (D). Note the undisturbed primary A1 cement (A1) surrounding the grains. Note the preserved primary porosity (Ip). (5a, b) Thin-section Steinbächle, parallel Nichols (1); crossed Nichols (2), stained: blue indicates porosity. Oolitic grainstone: patchy saddle dolomite cement with typical curved crystal faces (S) and sweeping extinction (E). (6) Thin section Satteldorf Bölgental, parallel Nichols, stained: blue indicates porosity. Crinoidal grainstone: limonitic crusts of leached saddle dolomites (LC), and partly leached dolomite crystals (LD) with rusty limonitic fractures. Remaining A1 cement has grown in the mould of an early diagenetic leached possibly aragonitic coated grain-core (A1). The cortical layers were dolomitized and subsequently leached during the second leaching phase (L2). hemicycles reduced the primary porosity and the circulation of diagenetic fluids, which enhanced the porosity in later diagenetic stages. However, in cases with intense B cementation at the top of the regressive hemicycles, the best reservoir properties tend to be located below the regressive maxima (Fig. 6). Reservoir properties In order to quantify the reservoir properties, 442 thin sections and 570 porosity and permeability plugs from outcrop samples and cores were analysed. Porous intervals are generally restricted to discrete reservoir bodies, composed of high-energy shoal and shoal fringe facies types. However, the internal petrophysical characterization of these reservoir bodies turned out to be complex. During diagenesis, several cementation and leaching phases led to a stepwise alteration of the pore-space, which resulted in a complex relationship between reservoir properties and reservoir-facies types. Nevertheless, owing to the selective character of the diagenetic processes, the initial sediment composition and Geological Society, London, Special Publications published online June 27, 2012 as doi: 10.1144/SP370.6 D. PALERMO ET AL. Table 1. Overview of the diagenetic history and the impact on pore-space Diagenetic stage Early marine, shallow burial diagenesis Diagenetic phase Impact on pore space Circum granular crust cement (A1 cement) First leaching phase Protection and reduction of primary porosity Late diagenetic, deep burial dolomitization Circum granular crust cement (A2 cement) Dog tooth cement (B1 cement) Patchy calcite spar cement (B2 cement) Patchy dolomitization and recrystallization Uplift and meteoric alteration Second leaching phase Late marine, deeper burial cementation mineralogy remains one of the most important controlling factors. The investigated Upper Muschelkalk reservoir bodies have average reservoir properties of 11.5% porosity (standard deviation, 4.9) and 30.8 mD permeability (standard deviation 72.4) with a correlation coefficient of 0.41. Pore-types Lucia (1983) developed commonly used concepts for reservoir characterization of carbonate rocks by subdividing the pore-space into the three major pore- Creation of biomouldic porosity owing to selective leaching of aragonite Slight reduction of complete plugging of biomouldic porosity Slight reduction of complete plugging of biomouldic and primary porosity Slight reduction of complete plugging of biomouldic and primary porosity Slight reduction of complete plugging of biomouldic and primary porosity, dolomitization of ooids, coated grains and crinoidal columnar plates Creation of Oo- and crino-mouldic porosity type classes: (a) touching vug porosity; (b) separate vug porosity; and (c) interparticle porosity. The Upper Muschelkalk is dominated by separate vug porosity (SV, 60%). Touching vug (TV) and interparticle porosity (IP, 20%) constitute the minor part, but are important factors controlling permeability. However, the touching vugs observed in the Upper Muschelkalk are smaller (up to several millimetres; Fig. 8) than those described by Lucia (1983). Using the fabric-selective concept for the classification of carbonate pores after Choquette and Pray Fig. 6. Diagenesis and the resulting petrography are controlled by stratigraphic cycles. Generally, mud content and A cements constitute a more or less constant petrographic volume fraction, as displayed in the column ‘Cumulative Vol %’; upwards decreasing mud content is compensated by a systematic increase of A cement. Geological Society, London, Special Publications published online June 27, 2012 as doi: 10.1144/SP370.6 CARBONATE SAND BODIES IN GERMANY Fig. 7. (a) Cross section through two reservoir bodies (yellow/orange) along the depositional gradient, highlighting facies distribution, sedimentology and reservoir properties. Within the individual facies bodies, the lateral porosity and permeability distribution is mostly marked by gradational transitions. (b) Cross section highlighting the qualitative distribution of cement types and mud content. The vertical sections depict the cumulative petrographic composition of the shoal bodies, combined with petrophysical properties. Both properties show laterally gradational transitions and are strongly influenced vertically by stratigraphic cycles. (1970), biomouldic porosity comprises the largest pore-fraction. Most of the investigated samples belong to one of the following combined pore-types: (1) (2) (3) biomouldic (BM, 27%); biomouldic and interparticle (BM + IP, 42%); biomouldic, interparticle and Oomouldic (BM + IP + OM, 23%); (4) biomouldic, and oomouldic (BM + IP + OM, 8%). Porosity and permeability relationships Pore types after Choquette and Pray (1970) v. porosity and permeability (Fig. 9a). Generally, the samples with pure mouldic porosity show less Geological Society, London, Special Publications published online June 27, 2012 as doi: 10.1144/SP370.6 D. PALERMO ET AL. Fig. 8. Thin section photographs, stained: blue indicates porosity, parallel Nichols: typical pore-types in the Upper Muschelkalk reservoir bodies. Pore-types after Lucia (1983): touching vugs, TV; separate vugs, SV; interparticle porosity, IP. Pore-types after Choquette & Pray (1970): biomouldic porosity, BM; oomouldic porosity, OM. (a) Oolitic grainstone with preserved primary interparticle porosity. (b) Bioclastic grainstone showing two pore generations of biomouldic porosity. Upper left corner: leached dolomite recrystallization. Middle right corner: early diagenetic biomouldic pore with several cement generations. (c) Bioclastic pack- to grainstone with touching vugs owing to leached dolo-cement. The dissolution enlarged touching vugs of the Upper Muschelkalk reservoir bodies are much smaller (several millimetres) than those described by Lucia (1983). Furthermore, remnants of collapsed biomouldic porosity are visible in the upper middle part. (d) Oolitic grainstone. Typical oomouldic separate vug porosity, enhanced by a large touching vug of leached dolo-cement and small amounts of interparticle porosity. (e) Bioclastic grainstone: oomouldic porosity of leached dolomite recrystallizations combined with early diagenetic biomouldic separate vug porosity and large interparticle pores. (f) Bioclastic grainstone: early diagenetic biomouldic separate vug porosity. permeability than samples where both, mouldic- and interparticle porosity are combined. Regarding the pore type distribution within the Lucia classes, samples with biomouldic, oomouldic and interparticle porosity tend to class 2, while samples with biomouldic and interparticle porosity plot slightly more towards Lucia’s class 1. Reservoir rock types and classes using Lucia (1983) classification (Fig. 9b). Several studies on the Upper Muschelkalk carbonates have shown that porosity – permeability relationships show strong scattering (e.g. Braun 2003; Kostic & Aigner 2004; Ruf & Aigner 2004; Dmitrieva 2006; Seyfang 2006). However, Lucia (1999) was able to categorize porosity – permeability relationships in discrete petrophysical classes by the definition of rock-fabric types, which are a combination of both Dunham texture and pore-type. His rockfabric petrophysical classes were mainly developed for non-vuggy carbonates with interparticle porosity. As the fraction of vuggy porosity within the investigated reservoir bodies amounted to 80%, the Lucia classes could only be applied to a certain extent. Most of the porosity and permeability values plot in class 2 of Lucia, followed by class 1. The values above 3 mD permeability show a relatively linear trend within a certain range of scatter. The values plot relatively close together between Lucia classes 1 and 2. As Geological Society, London, Special Publications published online June 27, 2012 as doi: 10.1144/SP370.6 CARBONATE SAND BODIES IN GERMANY Fig. 9. Porosity and permeability relationships keyed to (a) pore type according to (a) Choquette & Pray (1970), (b) Lucia (1983), (c) approximated pore-throat size measured in thin sections and (d) pore size. expected, samples with only separate vugs have generally lower permeability. When touching-vug porosity is present, permeability is higher. The highest porosity and permeability values occur when all pore types are present (Table 2). However, biomouldic pores compose the largest part of porosity and occur, independent of Dunham texture, in all reservoir rock types. This fact implies that the distribution of biomouldic porosity could be an additional key controlling factor for the reservoir properties. Pore-throat size v. poro-perm (Fig. 9c). The porethroat diameters presented in this study have been measured in 2D thin sections and represent therefore just a limited approximation to the real 3D pore-throat distribution. Nevertheless, Figure 9c depicts a clear increase of both permeability and porosity with larger pore-throats (Table 4). The remaining data scatter could be due to the fact that pore-throat diameters were measured in 2D. Pore size v. porosity and permeability (Fig. 9d). Despite considerable scattering, permeability generally increases with an increasing pore-size (Table 2). Relationship facies association: reservoir properties As can be observed in many carbonate systems, facies and reservoir properties of the Upper Muschelkalk do not show a direct relationship. This is mainly due to the susceptibility of carbonates to diagenetic alteration, but also to the higher complexity of primary sedimentary parameters in addition to measuring inaccuracies. Nevertheless, the primary lithofacies plays a fundamental role for the distribution of reservoir properties in the Upper Muschelkalk, since porous shoal bodies are exclusively formed of high energy shoal and shoalfringe facies types. Furthermore, the diagenetic leaching and dolomite cementation phases proceeded very selectively according to the mineralogy of the components, a parameter that is in turn mainly facies controlled. Therefore, despite considerable data scattering, a certain relationship between facies association and reservoir properties can be observed. Shoal-fringe facies association (pel-ooidal packto grainstone, oncoidal pack- to grainstone, intraclastic packstone). The facies types forming the shoal-fringe facies association show a strong scattering, in particular within the range below 3 mD permeability and 3% porosity (Fig. 10a, Table 3). A possible explanation for the strong data scatter could be a scale-dependent measuring inaccuracy, which occurs specifically with the mini-permeameter. Vugs and large bioclastic moulds may act as direct flow-connection through the plug-sample. Intraclastic packstones have low porosities, predominantly in the form of large vugs. This facies Geological Society, London, Special Publications published online June 27, 2012 as doi: 10.1144/SP370.6 D. PALERMO ET AL. Table 2. Correlation coefficients, standard deviation and arithmetic mean between porosity/permeability and selected parameters (pore size, pore throat size and pore types), based on the semi-quantitative analysis of thin sections Correlation coefficient Poro/micro n ¼ 222 Mean Standard deviation Perm H/meso n ¼ 222 Mean Standard deviation Perm H/macro n ¼ 222 Mean Standard deviation Poro/TV n ¼ 222 Mean Standard deviation Poro/SV n ¼ 222 Mean Standard deviation Poro/IP n ¼ 222 Mean Standard deviation Perm H/TV n ¼ 222 Mean Standard deviation Perm H/SV n ¼ 222 Mean Standard deviation Perm H/IP n ¼ 222 Mean Standard deviation Poro/pore-throats n ¼ 168 Mean Standard deviation Perm H/pore-throats n ¼ 168 Mean Standard deviation Poro (%) 12.0 4.6 Perm H 32.5 58.1 Perm H 32.5 58.1 Poro (%) 12.0 4.6 Poro (%) 12.0 4.6 Poro (%) 12.0 4.6 Perm H (mD) 32.5 58.1 Perm H (mD) 32.5 58.1 Perm H (mD) 32.5 58.1 Poro (%) 12.0 4.6 Perm H (mD) 32.5 58.1 type shows the most extreme scatter combined with the poorest reservoir properties. In contrast, peloidal- and oncoidal pack- to grainstones have additionally small amounts of regularly distributed primary porosity and commonly smaller vugs. The limited reservoir properties (Fmax ¼ 13%; Kmax ¼ 12 mD) of the shoal-fringe facies types could be explained by the combination of a high mud content, occluding the primary interparticle pore space and the dominance of mostly calcitic, relatively leaching-resistant components (e.g. oncoids, peloids, intraclasts), and preventing the creation of vuggy porosity (Fig. 10a). Mid-shoal facies association (crinoidal pack- to grainstone, poorly sorted pack- to grainstone, amalgamated packstone). These facies types constitute the largest part of the reservoir bodies and show relatively similar porosities and permeability trends Within this group, amalgamated packstones have Micro-pores (%) 2.2 1.8 Meso-pores (%) 6.5 3.8 Macro-pores (%) 3.2 3.8 TV (%) 2.6 2.7 SV (%) 7.1 3.0 IP (%) 2.2 3.1 TV (%) 2.6 2.7 SV (%) 7.1 3.0 IP (%) 2.2 3.1 Pore-throats (mm) 177.8 94.6 Pore-throats (mm) 177.8 94.6 20.07 0.17 0.55 0.63 0.47 0.50 0.58 0.00 0.30 0.57 0.52 the best correlation between porosity and permeability (Fig. 10b, Table 4). Amalgamated packstones are dominated by biomouldic porosity; the high mud content plugs the potential interparticle porespace. Therefore, permeability is probably due to the occurrence of solution-enlarged touching vugs. Consequently, diagenetic leaching is the most important controlling factors on pore space within this facies type. In contrast, crinoidal pack- to grainstones have additionally substantial amounts of interparticle porosity. They show the overall best reservoir properties (Fmax ¼ 25%; kmax ¼ 710 mD), but also a strong scattering of data points. The scattering within the porosity and permeability relationship is thus mainly controlled by the interplay of different pore-systems (interparticle and vuggy). Nevertheless, also scaledependent measuring inaccuracy (see above) can be observed within the poorly sorted pack- to grainstone facies, where vugs of large shells are common, dispersing the values towards higher permeability. Geological Society, London, Special Publications published online June 27, 2012 as doi: 10.1144/SP370.6 CARBONATE SAND BODIES IN GERMANY Fig. 10. (a) Porosity–permeability cross-plot depicting the reservoir properties of shoal fringe facies types. Strong scattering towards low permeability is mainly interpreted as scale-dependent measuring inaccuracy, since vugs of large shells may act as direct flow connection through the plug sample. (b) Porosity– permeability cross-plot depicting the reservoir properties of mid-shoal facies types. Strong scattering towards low permeability within the poorly sorted packto grainstone facies is interpreted as scale-dependent measuring inaccuracy. Amalgamated packstones are dominated by vuggy porosity and show an excellent fit into the main cluster, whereas crinoidal pack- to grainstones tend to a stronger scattering, but overall better reservoir properties. The stronger scattering can be explained by two different interacting pore-systems owing to a combination of interparticle and vuggy porosity. (c) Porosity–permeability cross-plot depicting the reservoir properties of inner-shoal facies types. Facies types of the mid-shoal facies association have a higher fraction of oomouldic porosity and fewer solution enlarged touching vugs, which results in a scattering towards higher porosities. Inner-shoal facies association (oolitic grainstone, well-sorted pack- to grainstone). These facies types, in particular oolitic grainstones, show a tendency towards higher porosities (Fig. 10c, Table 5) and comparably low permeability. Vugs and larger bioclastic moulds which interconnect Geological Society, London, Special Publications published online June 27, 2012 as doi: 10.1144/SP370.6 D. PALERMO ET AL. Table 3. Correlation coefficients, arithmetic mean and standard deviations of shoal-fringe facies types Facies type Oncoidal WP n ¼ 14 Pelo-ooidal P n¼7 Intraclastic P n ¼ 12 Mean Standard deviation Mean Standard deviation Mean Standard deviation Porosity Permeability 7.6 3.8 5.5 3.1 3.9 2.9 4.4 6.6 7.4 11.1 0.6 0.8 the pores are rare in this grain-dominated, commonly well sorted facies association. Thus, this facies association is characterized by relatively high amounts of oomouldic porosity, which is, however, not accompanied by higher permeability values. If biomouldic pores are present, they are commonly surround by thick cement crusts. These cements are commonly not affected by selective diagenetic alteration and are an additional reason for reduced pore connectivity. As observed in thin sections, solution-enlarged touching vug porosity is present but not very abundant, which could be the result of the more stable pore-framework preventing the circulation of late diagenetic fluids and associated porosity creation. Distribution of reservoir properties on different scales The final aim of a reservoir characterization is to predict the spatial distribution of reservoir properties on a field scale. In this outcrop study, the geometries of the facies bodies show a remarkable lateral continuity on a kilometre-scale (for details see Palermo et al. 2010). In contrast to one-dimensional well data, the outcrops have the advantage that the individual facies bodies and the presence of porosity can be traced laterally in a qualitative way, since millimetre- to centimetre-sized mouldic macroand meso-pores can be observed easily with a hand lens. In order to calibrate these observations, plug measurements and thin sections were taken Correlation coefficient 0.34 0.14 20.25 along vertical sections. Different scales of reservoir heterogeneities in one selected shoal body were investigated in a hierarchical way (for details see Seyfang 2006). Decimetre scale (tens of centimetres) In order to investigate the distribution of permeability on a decimetre scale, four rock columns from the central part of a major shoal body were cut from a 2.1 × 1.1 m-sized block from the quarry Neidenfels. The investigated shoal portion consists of the poorly sorted pack- to grainstone facies and shows a variable mud content. The twodimensional permeability distribution was measured with a mini-permeameter by covering each rock column (1 × 0.2 m) with a grid of 7 × 50 data points spaced at 2 cm intervals (Fig. 11). The porosity values of the investigated samples range between 15 and 23%. The values were interpolated with the software Surfer TM using a kriging algorithm and a logarithmic colour scheme. Sedimentary structures are not recognizable at this scale (Fig. 12) and the facies appeared as a moderately bioturbated, massive unit; therefore the interpolation was carried out without preferential direction. The resulting permeability is rather patchily distributed, which can be partly related to unidirectional algorithm. Nevertheless, the values show a clear upward increasing trend in all four rock columns. The values follow a small-scale regressive hemicycle with an upward decreasing fraction of matrix mud. The permeability ranges in the order of 10 mD (green) in the Table 4. Correlation coefficients, arithmetic mean and standard deviations of mid-shoal facies types Facies type Crinoidal PG n ¼ 55 Poorly sorted PG n ¼ 103 Amalgamated P n ¼ 63 Mean Standard deviation Mean Standard deviation Mean Standard deviation Porosity Permeability Correlation coefficient 14.2 4.0 10.5 5.1 11.8 3.4 63.2 123.2 28.2 56.0 38.7 77.7 0.26 0.51 0.60 Geological Society, London, Special Publications published online June 27, 2012 as doi: 10.1144/SP370.6 CARBONATE SAND BODIES IN GERMANY Table 5. Correlation coefficients, arithmetic mean and standard deviations of inner-shoal facies types Facies type Oolitic G n ¼ 33 Well sorted PG n ¼ 38 Mean Standard deviation Mean Standard deviation Porosity Permeability Correlation coefficient 12.9 3.7 13.1 4.7 7.9 13.2 25.9 49.6 0.45 lower part and reaches up to several 100 mD (orange to red) in the top part (Fig. 12). Thin sections document that this trend is combined with an upwards increase in interparticle porosity. Metre scale For the determination of the metre-scale heterogeneities in permeability, a 2.1 × 1.1 m-sized block from the quarry Neidenfels was investigated for sedimentary structures. The positions of the above-described rock columns within the block are marked in Figure 13. The individual rock columns appeared as massive units, whereas the entire block reveals some subtle, irregular low-angle cross-beds. They consist of crudely graded and shell-rich laminae above an erosive base and are intercalated into moderately bioturbated poorly sorted pack- to grainstones. Generally, slight differences in texture, sorting and mud content seem to follow the orientation of the cross bedding on this larger scale. The photograph of the block (Fig. 13) depicts the predominant inclination of the sets to the left, traced with yellow lines. The heterogeneities in permeability are mainly due to variations in the amount of mouldic porosity and the shape of the leached components. Portions with leached shells make a better contribution to permeability than those with ooids and crinoidal columnar plates. The shells are often connected by solution-enlarged touching vugs and build an interconnected framework with primary interparticle 0.42 pores. Based on the observed sedimentary structures, the interpolation of permeability values between the four measured columns was carried out with a directional kriging algorithm, characterized by an elevated horizontal range. The resulting permeability distribution is displayed as an overlay with logarithmic colour gradient (Fig. 13). An important result is the systematic upward increase in permeability that follows a small-scale regressive hemicycle and the upward decreasing mud content. This systematic vertical trend results in a laterally continuous highly permeability zone in the upper portion of the block. Note also that the lowpermeability lower part is laterally continuous, as well as some high permeability streaks in the middle part, which seem to be controlled by the sedimentary structures. The permeability distribution shows that the highly permeable areas are often vertically interconnected. Tens of metres scale. For the determination of porosity and permeability trends within the shoal body on a tens of metre scale, two vertical sections were investigated along a 25 m-long outcrop wall that was previously mapped for facies. The outcrop wall panel, log positions and the corresponding porosity and permeability histograms are depicted in Figure 14. The reservoir body can be subdivided into four layers (A –D) consisting of alternating well-sorted pack- to grainstone (Lft 2e) and poorly sorted bioclastic pack- to grainstone (Lft 2e) Fig. 11. Measurements of the two-dimensional permeability distribution with the mini-permeameter. Each rock column is covered (1× 0.2 m) with a grid of 7× 50 data points. Geological Society, London, Special Publications published online June 27, 2012 as doi: 10.1144/SP370.6 D. PALERMO ET AL. Fig. 12. Rock-columns from the central part of a major shoal body were derived for a 2.1× 1.1 m sized slab which was previously mapped for sedimentary structures. Permeability shows a patchy distribution but also a clear upward increasing trend in all four rock columns. facies types. The well-sorted pack and pack- to grainstones (A) of the bottom part have about 10% porosity and low permeability, which can be explained by comparably high mud content, occluding parts of potential primary interparticle porespace. In contrast, the upper well-sorted grainstone sheet (C) has lower mud content and higher amounts of interparticle porosity, resulting in better porosity and permeability values. The poorly sorted bioclastic pack- to grainstones also show textural differences, but are additionally controlled by the amount of biomodic porosity of leached shells. Generally, the porosities in the investigated poorly sorted pack- to grainstone beds (B, D) range between 11.3 and 18.2%. The moderate permeability in bed B ranges between 7.6 and 32.9 mD, while the average permeability in the upper bed (D) varies between 90.1 and 202.0 mD. Thus, lateral changes in porosity and permeability within an individual facies body remain in the same order of magnitude within a similar stratigraphic position. These changes seem to correspond generally to the vertical textural changes that seem to follow the observed stratigraphic cycles. Moreover, also the lateral differences in porosity and permeability within the individual layers seem to be accompanied by slight lateral variations in the Dunham texture. The general occurrence of laterally continuous reservoir bodies is commonly controlled by medium-scale cycles, since porous units occur preferentially around their regressive maxima. In contrast, internal porosity and permeability variations are often controlled by small-scale cycles. The best reservoir properties are found around small-scale regressive maximum. This effect is most likely the result of stratigraphically controlled variations in mud content, and additional complex diagenetic overprints of cementation and selective leaching (see previous section). Regarding the entire flow unit, the lateral pattern of the permeable layers along the same stratigraphic cycles indicates that the observed centimetre-scale heterogeneities owing to sedimentary structures play a subordinate role. Geological Society, London, Special Publications published online June 27, 2012 as doi: 10.1144/SP370.6 CARBONATE SAND BODIES IN GERMANY Fig. 13. A 2.1×1.1 m sized block sampled from a major shoal-body in quarry Neidenfels with subtle low-angle cross bedding (1) and the resulting permeability distribution (2). Permeability was interpolated from the rock columns along the major sedimentary structures. Note the systematic upward increase of permeability following a small-scale regressive hemicycle and the resulting lateral continuity of the highly permeable zone in the upper portion of the block. Kilometre scale Three sections through two shoal bodies, with a lateral spacing of 1 km each, were investigated for the distribution of facies, diagenetic changes and petrophysical properties along the depositional gradient. The cross-section in Figure 7a displays the geometries of facies-bodies combined with porosity and permeability values of medium- and small- scale cycles. Within the individual facies bodies, the porosity and permeability distribution shows gradual lateral changes. The cross-section of Figure 7b depicts the gradational lateral changes of mud content and cement-types, which are held as key indicators for the relationship between the diagenetic overprint and the resulting reservoir properties. The overall distribution of petrographic trends and reservoir properties shows similar patterns. Both properties show laterally gradational transitions and are strongly influenced by stratigraphic cycles. The vertical distribution of reservoir properties is mainly controlled by medium-scale cycles, whereas the smaller internal variations seem to be controlled by small-scale cycles. Petrophysical modelling Three-dimensional geological modelling software offers a wide range of different possibilities for the distribution of petrophysical properties. However, in contrast to the subsurface, outcrop analogue studies allow a direct determination of the spatial distributions of reservoir properties. Furthermore, outcrop data can be used to constrain different conditioning factors and algorithms that are applied in the modelling process. As documented above, the lateral distribution of reservoir properties Geological Society, London, Special Publications published online June 27, 2012 as doi: 10.1144/SP370.6 D. PALERMO ET AL. Fig. 14. Outcrop wall panel with stratigraphic cycles, sedimentology and the reservoir properties. Lateral changes in porosity and permeability within the individual facies bodies remain in the same order of magnitude within a similar stratigraphic position. The red arrows indicate a common trend in the Dunham texture (mud content) and the reservoir property values, following the stratigraphic cycles. (Dunham Textures: G, grainstone; PG, pack- to grainstone; P, packstone; W, wackestone; M, mudstone. Particle size: L, lutite; S, siltite; A, arenite; R, rudite.) Geological Society, London, Special Publications published online June 27, 2012 as doi: 10.1144/SP370.6 CARBONATE SAND BODIES IN GERMANY Fig. 15. Fence diagram of the 3D facies model (200× vertical exaggeration), which was used as the trend for the spatial distribution of the reservoir properties. within a facies body, in the same stratigraphic position, remains in the same order of magnitude for hundreds of metres. On a kilometre scale, facies bodies, reservoir properties and diagenetic trends show gradual lateral changes, whereas the mostly stratigraphic cycle-controlled vertical differences vary commonly on a decimetre scale. These observations within this particular setting were considered for the construction of the geological model. The detailed, deterministic geomodel of Palermo et al. (2010) was used as a main input for geostatistical data analysis and the distribution of reservoir properties. It covers an area on the scale of a Middle East giant gas-field (25 × 36 km) and provides both (a) high resolution sequence stratigraphic reservoir layering and (b) a detailed facies distribution (Fig. 15). It is composed of 619 layers and 3.5 million cells. This high vertical resolution provides the possibility to model detailed variations of reservoir properties within individual reservoir bodies. Furthermore, these observations and the data distribution suggest a deterministic approach for modelling reservoir properties. With respect to the palaeogeographic positions and the resulting differences in facies distribution, the well spacing in this study is commonly similar or smaller than the minimum dimension (commonly dip width) of the major reservoir bodies (cf. Kerans & Tinker 1997). Input data The investigation of thin sections showed that preservation and creation of pore space is restricted to high-energy shoal and shoal-fringe facies types and is modified by the selective diagenetic history. Therefore, the primary facies types can be clearly subdivided into reservoir and non-reservoir facies. Furthermore, structural influences (e.g. fractures) on the reservoir properties are generally negligible. These observations and the software-dependent necessity for a constant sampling rate led to the following steps in preparing the dataset for 3D modelling: after the insertion of the plug measurements as point values, all portions of reservoir facies without corresponding plug-data were set to ‘undefined’ (2999.2). Subsequently, the porosity and permeability values of all non-reservoir facies types were set to zero. The step of data preparation was furthermore used for a quality control of the dataset. The upscaling process transfers porosity and permeability plug measurements to the grid cells neighbouring Geological Society, London, Special Publications published online June 27, 2012 as doi: 10.1144/SP370.6 D. PALERMO ET AL. Table 6. Results from the sample-variogram analysis for porosity and permeability, which are the main input parameters for petrophysical distribution algorithms (sequential Gaussian simulation and kriging) Results from sample variograms Porosity (F) Variogram type Nugget (random values) Vertical range Major direction Range Bandwidth Number of lags Search radius Minor direction Range Bandwidth Number of lags Search radius Permeability (K) Variogram type Nugget (random values) Vertical range Major direction Range Bandwidth Number of lags Search radius Minor direction Range Bandwidth Number of lags Search radius Shoal fringe Mid-shoal Inner shoal Gaussian 27% 0.6 m 2938 3991 m 2211 m 10 9000 m 2038 2029 m 1624 m 10 6000 m Gaussian 27% 1.5 m 2888 4702 m 2612 m 15 10230 m 1988 2843 m 15 6292 m Gaussian 29% 1.8 m 2158 1930 m 1101 m 15 6580 m 1258 1732 m 1004 m 15 5070 m Gaussian 53% 1.1 m 1168 920.7 m 1121.7 m 15 4254 m 268 728 m 1121 m 25 4096 Gaussian 24% 0.8 m 2238 4552.3 m 1975 m 20 12844.4 m 1258 1732 m 1610 m 15 8310.4 m Spherical 36% 3.2 m 1498 4721 m 2585 20 14070 598 2568 1858 17 8000 the wells. In contrast to porosity, permeability tends to change exponentially and requires a different averaging method for the upscaling process: (1) Porosity: arithmetic average of point data upscaled on neighbour cells. (2) Permeability: geometric average (e.g. Warren & Price 1961; Jensen 1991) of point data upscaled on neighbour cells. However, owing to the extraordinary high vertical resolution (average 0.1 m) of the 3D grid, which corresponds to the sampling rate of the plug measurements, the upscaling had no considerable impact on the quality of the model. Geostatistical data analysis Variograms are geostatistical models for the 3D distribution of reservoir heterogeneity and fundamental input parameters for the most common modelling algorithms, for example sequential Gaussian simulations and kriging. Variograms are defined as the semi-variance of the difference between field values at two locations across realizations of the field (Cressie 1993). In order to establish the necessary input parameters, a geostatistical variogram analysis (Gringarten & Deutsch 2001) was carried out on the complete dataset with the original log data spaced between 10 m and a few kilometres. Based on the observations described above, the reservoir properties were analysed for each facies type and each association with various lag-sizes, ranges, and so on. A reasonable variogram model could only be found for the facies associations, by using relatively large bin sizes and large ranges that are in the order of the observed facies changes (Palermo et al. 2010). The results and the used parameters are summarized in Table 6. The vertical semi-variance was determined within decimetre-sized lags and the resulting ranges for porosity result in 0.6 m for shoalfringe, 1.6 m for mid-shoal and 1.8 m for inner-shoal facies associations. The lateral semi-variance of porosity results in Gaussian variogram models for all three facies associations with high random values (Nugget effect, after Eisenberg et al. 1994) slightly below 30% in all three cases. The lateral ranges are remarkably high and reach values in the major direction of 1930 m for the inner-shoal, 3991 m for shoal Geological Society, London, Special Publications published online June 27, 2012 as doi: 10.1144/SP370.6 CARBONATE SAND BODIES IN GERMANY fringe and 4702 m for mid-shoal facies associations. The semi-variance of the permeability is generally characterized by higher random values in the shoal fringe (53%) and the inner shoal (36%) facies types, whereas the random factor of the mid-shoal (24%) is comparably low. Compared with the porosity, the computed permeability ranges are significantly lower for the shoal fringe, similar for the mid-shoal and higher for the inner-shoal facies associations. The results of the variogram analysis for both porosity and permeability are summarized in Table 6. Effect of input data As described in the sections above, the major portion of the effective porosity within the system was created at an early stage and is mostly linked to either primary porosity or cycle-controlled early diagenetic leaching. In the upper described qualitative and quantitative outcrop observations, two major scales of lateral heterogeneities could be observed: (a) small-scale heterogeneities on centimetre to decimetre scale; and (b) large-scale, smooth transitions in the order of the lateral facies association extensions. A reasonable variogram model could only be found for the largest scale. The intermediate scale, tens to hundreds of metres and the centimetre scale did not provide enough data to make a sufficient variogram analysis. According to the previous observations, the remarkably high lateral porosity ranges can be related to the subtle gradational transitions of mud content along the depositional slope, reflecting the depositional energy of a flat and very gently inclined epeiric carbonate ramp. Owing to the continuous character of the porosity that can be traced visually along the outcrop walls, the predominantly Gaussian semi-variogram models and the resulting ranges were considered as the most probable scenario. However, the possibility of other scenarios cannot be generally excluded. Follow-up sampling as performed by, for example, Pranter et al. (2005) is planned to better quantify the small-scale heterogeneities. Conditioning and modelling algorithms In order to compare the impact of stratigraphy and facies (Palermo et al. 2010) on the distribution of reservoir properties, three different approaches were used for the petrophysical modelling. (1) Unconditioned. The grid used here is a relatively simple 3D cube that was subdivided into 180 conformable layers. Only the top and base of the model were defined by stratigraphic surfaces. Unrelated to facies or stratigraphy, the modelled reservoir properties were directly interpolated between the data points using different algorithms. (2) Conditioned to stratigraphic cycles. In this approach, the petrophysical properties were conditioned to the zones based on stratigraphic cycles. Each reservoir bearing zone was subdivided into eight layers and the average vertical resolution was around 10 cm. Therefore, vertical variations of reservoir properties within single reservoir units could also be displayed with a high level of detail. (3) Conditioned to stratigraphic cycles and facies associations. In this scenario the entire information from the geological model (Fig. 17) was used to model the spatial distribution of reservoir properties. Each reservoir facies association was modelled individually, and tight facies types were set to zero. To avoid unrealistically sharp contacts between the lateral facies boundaries the properties were slightly smoothened. Three different modelling algorithms were tested for the distribution of the reservoir properties in the upper described scenarios and compared with the outcrop observations (Table 7): (1) Moving average. This interpolation algorithm is based on the average values of the input data and weights the distribution according to the distance from data points without a spatial preference (Chou 1975). (2) Kriging. This is a deterministic interpolation method developed by Matheron (1963) and D. G. Krige. The algorithm distributes a property with a spatial preference that has to be defined by an input variogram. The estimated variables are then calculated by the linear combination of the input data points. In contrast to the moving average, the kriging algorithm uses a weighting function and honours both distance and direction. (3) Sequential Gaussian simulation (SGS). This variogram based stochastic simulation technique is based on kriging and allows multiple equiprobable realizations of a property (Alabert 1987; Deutsch & Journel 1992). Kriging calculates the weighted mean and the standard deviation at each estimated point. SGS, however, represents the variable as a random deviate from the Gaussian normal distribution, which represents the input data and trends better than most of the kriging algorithms. Porosity distribution with sequential Gaussian simulation (Fig. 16) Porosity – unconditioned. According to the randomity of the algorithm, the distribution of porosity appears very patchy and the general geological Porosity Permeability Sequential Gaussian simulation Porosity Permeability Kriging Porosity Permeability Vertical range 1m 1m Point weighting Exponent: 4 Exponent: 4 Variogram settings Parameters from variogram analysis Parameters from variogram analysis Variogram settings Parameters from variogram analysis Parameters from variogram analysis Direction Distribution Trends Follow layers Follow layers Transformations Normal score Normal score Transformations Normal score Normal score normal Logarithmic Distribution Linear Logarithmic Distribution Linear Logarithmic Facies Facies, porosity Trends Facies Facies, porosity Trends Facies Facies, porosity D. PALERMO ET AL. Moving average Geological Society, London, Special Publications published online June 27, 2012 as doi: 10.1144/SP370.6 Table 7. Parameters and algorithms used for the spatial distribution of reservoir properties Geological Society, London, Special Publications published online June 27, 2012 as doi: 10.1144/SP370.6 CARBONATE SAND BODIES IN GERMANY Fig. 16. Different porosity distributions with the Sequential Gaussian simulation algorithms conditioned to: (a) a simple layering – the porosity values are vertically scattered and form laterally simple bulls eye patterns; (b) stratigraphic cycles – vertical distribution matches better with the outcrop observations, although unconnected bulls eyes are still present; (c) stratigraphic cycles and facies – the smoothened distribution shows the best match with the outcrop continuities. pattern is not recognizable. Additionally, the reservoir bodies are relatively small with low lateral continuity. Both kriging and moving average provided better results than SGS in this scenario. Porosity – conditioned to stratigraphic cycles. The resulting reservoir bodies follow the stratigraphic trends and have acceptable dimensions. However, compared with the results produced with the moving average algorithm, many artefacts are visible, especially in the tight middle part. Porosity – conditioned to cycles and facies associations. The modelled porosities follow the stratigraphic trends and the outline of the facies bodies. Compared with the results with the moving average Fig. 17. Different permeability distributions with the Sequential Gaussian simulation algorithms conditioned to (a) a simple layering – the porosity values are vertically scattered and laterally isolated flow units, (b) stratigraphic cycles – more realistic vertical connectivity, but the flow units are laterally still isolated, and (c) stratigraphic cycles and facies – the smoothened distribution shows a good match with the outcrop observations. Geological Society, London, Special Publications published online June 27, 2012 as doi: 10.1144/SP370.6 D. PALERMO ET AL. algorithm and kriging, the reservoir bodies modelled with a slightly smoothed sequential Gaussian Simulation show a better connectivity and more reasonable dimensions. Analysing this final scenario, the resulting net/gross ratio of the modelled Upper Muschelkalk area amounts to 7%, with a theoretical storage capacity of 419 490 000 m3. Permeability distribution with sequential Gaussian simulation (Fig. 17, Fig. 18) Permeability – conditioned to porosity. Like the porosity, the distribution of permeability appears patchy and the general geological pattern is not recognizable. The reservoir bodies are comparably small and highly compartmentalized. Permeability – conditioned to stratigraphic cycles and porosity. Comparable to the distribution of porosity, the resulting flow units follow the general stratigraphic trends. Although there are no artefacts in the middle part visible, the distribution of permeability remains patchy, especially in the upper part. Permeability – conditioned to cycles, facies associations and porosity. The modelled permeability follows the stratigraphic trends and the outline of the facies bodies. Both dimensions and connectivity of the flow units seem to be more reasonable in this case. Modelling results The outcrop analogue studies of Palermo et al. (2010) could show that the shoal facies associations show remarkable lateral extensions of up to several tens of kilometres whereas vertical facies changes range within the order of decimetres. Another part of the study shows that lateral facies changes are characterized by very subtle and gradual transitions within the range of up to a few kilometres. Therefore, the Palermo et al. (2010) study suggests Fig. 18. Filtered permeable reservoir bodies (cut-off 1 mD) distributed with sequential Gaussian simulation, conditioned to stratigraphic cycles and facies and processed with a smoothing algorithm. All three hierarchies of stratigraphic cycles had an impact on quality and presence of the flow units: (a) large scale cycle – controls the lateral extension, retro- and progradation, (b) medium scale cycles – control the stratigraphic presence of a flow unit, and (c) small-scale cycles – control the body internal vertical heterogeneities. Furthermore the distribution of palaeohighs and -lows is important for the general localization of the reservoir bodies. Geological Society, London, Special Publications published online June 27, 2012 as doi: 10.1144/SP370.6 CARBONATE SAND BODIES IN GERMANY encoding facies as a continuous rather than discrete property. The thin section observations and petrophysical measurements confirm theses observations. Mud content in the matrix changes laterally and vertically in a gradual way and reflects the depositional energy of the epeiric system with a very gentle depositional gradient. The outcrop observations above show that mud content has a significant impact on the presence of primary porosity. However, early diagenetic mouldic porosity also seems to increase with increasing matrix mud content. The petrophysical investigations on multiple scales showed two major scales of reservoir heterogeneities: (1) (2) Small-scale heterogeneities on centimetre to several decimetre scales mostly controlled by sedimentary structures and diverse mouldic pore types from different components were observed. Similar small-scale heterogeneities have been described by several studies (e.g. Jennings et al. 1998; Pranter et al. 2005) However, the quantity of samples in this study was insufficient to perform a solid variogram analysis that could quantify the 3D lateral ranges of the small-scale heterogeneities. On a large scale, relatively smooth transitions on the order of a few kilometres were observed and could be confirmed by the variogram analysis. However, the resulting lateral long range features are significantly higher compared with the dolomitized platform carbonates investigated by Jennings et al. (1998), which can reach up to 800 m. Apart from the different depositional settings and diagenetic histories, which make a direct comparison difficult, the possibility of additional nested heterogeneities as observed and described by Pranter et al. (2005) cannot be excluded. At least one smaller heterogeneity scale is most likely hidden within the high random effect and could be an interesting subject for further investigations. Extensive lateral sampling is foreseen for a future study to investigate the presence of additional meso-scale heterogeneities. with subtle gradational transitions. The main part of the porosity in the shoal bodies has been created at an early stage and is mostly linked to either cycle-controlled (a) primary porosity triggered by a systematically changing mud content or (b) early diagenetic leaching around maximum regressions. Two major scales of lateral heterogeneities could be observed: (a) small-scale heterogeneities on centimetre to decimetre scale, mainly related to sedimentary structures and different mouldic pore types which are represented by high random values (30%) within the geostatistical variogram model; and (b) large-scale heterogeneities of up to 4700 m lateral range. The remarkably high lateral porosity and permeability ranges can be partly related to subtle gradational transitions of mud content along the depositional slope, which reflect the depositional energy of a flat and very gently inclined epeiric carbonate ramp. Different petrophysical modelling scenarios could show the impact and necessity of geological constraints for the geostatistical distribution of porosity and permeability. The following factors help in predicting and modelling the spatial distribution of reservoir properties within the Upper Muschelkalk, which may be transferred to similar epeiric carbonate reservoirs (Fig. 15): (1) (2) Conclusions This outcrop analogue study documents the reservoir properties in the Upper Muschelkalk formation as an outcrop analogue for epeiric carbonates. Average porosity is 9–23%, and average permeability is 21 –700 mD. The net/gross ratio of the Upper Muschelkalk amounts to 7%, with a theoretical storage capacity of 419 490 000 m3. Laterally, units with high porosity and permeability show a kilometre-scale lateral continuity (3) Facies associations. The reservoir properties show a close relationship to the lithofacies and the associated matrix mud content. Porous facies types are restricted to the highenergy shoal facies, whereas both muddy inner and outer ramp facies are commonly tight since the muddy matrix protects the sediment from diagenetic fluids and associated mouldic porosity creation. Reservoir heterogeneities within the shoal bodies can be mainly related to the mud content and early diagenesis. Statigraphic cycles. All three hierarchies of stratigraphic cycles have an impact on quality and presence of the flow units: (a) large-scale cycle – controls the lateral extent, as well as retro- and pro- gradation of the reservoir bodies; (b) medium-scale cycles – control the stratigraphic presence of the reservoir facies associations; and (c) small-scale cycles – control the mud content and early mouldic porosity creation in facies types with primary porosity. which are considered as key drivers for systematic vertical changes in porosity and permeability within the reservoir bodies. Palaeo-relief. Gross volume and dimensions of the reservoir bodies seem to be mainly controlled by the combination of both stratigraphic cycles and a subtle palaeo-relief, Geological Society, London, Special Publications published online June 27, 2012 as doi: 10.1144/SP370.6 D. PALERMO ET AL. induced by slight differential subsidence of inherited structural grains. In particular, palaeo-highs are important for the presence of reservoir facies. Authors Denis Palermo studied geology at the University of Tübingen and completed his MSc thesis in 2004 on carbonate reservoir sedimentology at the Nederlandse Aardolje Matschapij (NAM) in the Netherlands. He then joined the Sedimentary Geology Group at the University of Tübingen to do a Ph.D. on outcrop analogue modelling and reservoir characterization in cooperation with Eni E&P. In 2007 he joined Eni E&P as sedimentologist and member of the Eni E&P carbonate research team. Thomas Aigner studied geology at the universities of Stuttgart, Tübingen, Reading and Miami. After working for 6 years with Shell Research, he has been a professor and head of the sedimentary geology group at the University of Tübingen since 1991. His research group focuses on reservoir geology, carbonate reservoir characterization and 3D modelling. He was an AAPG European Distinguished Lecturer in 1996. In 2007–2008 he spent a sabbatical with Petroleum Development Oman and Qatar Shell. Björn Seyfang studied geology at the University of Tübingen and finished his M.Sc. on outcrop analogue studies for carbonate shoal reservoirs in 2006. In 2009, he completed his Ph.D. on facies and reservoir modelling at the Sedimentary Geology Group of Tübingen University, initiated by GDF-SUEZ and conducted in cooperation with ExxonMobil, Wintershall and RWE-Dea. In September 2009, he joined Total as an operations geologist. Sergio Nardon graduated in geology at the University of Trieste, Italy, in 1982 and joined Eni (former Agip) in 1984 as clastic sedimentologist. His experience spans from fractured reservoir characterization to carbonate sedimentology and he has worked on several projects in Middle East, Europe and North Africa. His main interests are the integration of carbonate architecture, outcrop data and geological concepts into the 3D environment. He is currently technical leader of the research and development team at the geology department of Eni E&P. This work is part of an integrated research and development project funded by Eni E&P. We want to express our thanks to Eni Management for their support and the permission to publish. We are grateful for discussions with many colleagues working on the German Muschelkalk, notably H. Hagdorn, T. Simon, M. Urlichs and R. Borkhataria. Assistance was provided by members of the Sedimentary Geology group at the University of Tübingen (A. Allgöwer, E. Dmitrieva, M. Looser, A. Schmid-Röhl, C. Schneider, M. Zeller) and A. Satterley, B. White and K. Mair from Eni E&P. P. Jeiseke produced the thin sections. Several quarry companies, for example Schön & Hippelein, Hohenloher Schotterwerke, Schotterwerk Schuhmann, J. Heumann and SHB Schotterwerke Hohenlohe generously allowed access to their quarries. The Geological Survey of Baden-Württemberg and Bayern supplied us with borehole cores and well data. We wish to thank A. Glocke and Schlumberger for the access to Petrel (TM of Schlumberger) and to A. Henriette (ALT) for access to WellCAD. References Aigner, T. 1985. Storm Depositional Systems. Dynamic Stratigraphy in Modern and Ancient Shallow Marine Sequences. Lecture Notes in Earth Sciences, Vol. 3, Springer, Berlin. Aigner, T. 1999. Dynamische Stratigraphie des Oberen Muschelkalks am Beispiel Südwestdeutschlands, 115–128. Aigner, T., Braun, S., Palermo, D. & Blendinger, W. 2007. 3D geological modelling of a carbonate shoal complex: reservoir analogue study using outcrop data. First Break, 25, 65–72. Alabert, F. 1987. The practice of fast conditional simulations through the LU decomposition of the covariance matrix. Mathematical Geology, 19, 369–386. Allgöwer, A. 2006. Stratigraphy, petrophysics and facies analysis of epeiric carbonates in the Upper Muschelkalk. An outcrop analogue study for skeletal/ oolitic carbonate sand bodies in the Middle East (Upper Muschelkalk, South German Basin). Diploma thesis, University of Tübingen. Azerêdo, A. C. 1998. Geometry and facies dynamics of Middle Jurassic carbonate ramp sandbodies. In: Wright, V. P. & Burchette, T. P. (eds) Carbonate Ramps. Geological Society, London, Special Publications, 149, 281– 314. Bachmann, G. H . 1973. Die karbonatischen Bestandteile des Oberen Muschelkalks (Mittlere Trias) in SüdwestDeutschland und ihre Diagenese. Arbeiten des Instituts für Geologie und Paläontologie der Universität Stuttgart, 68, 1 –99. Borgomano, J. R. F., Masse, J.-P. & Al Maskiry, S. 2002. The lower Aptian Shuaiba carbonate outcrops in Jebel Akhdar, northern Oman: Impact on static modelling for Shuaiba petroleum reservoirs. AAPG Bulletin, 86, 1513–1529. Braun, S., 2003. Quantitative analysis of carbonate sandbodies: outcrop analogue study from an epicontinental basin (Triassic Germany). PhD thesis, University of Tübingen. Burchette, T. P., Wright, V. P. & Faulkner, T. J. 1990. Oolitic sandbody depositional models and geometries, Mississippian of southwest Britain: implications for petroleum exploration in carbonate ramp settings. Sedimentary Geology, 68, 87–115. Cavallo, L. J. & Smosna, R. 1997. Predicting porosity distribution within oolitic tidal bars. In: Kupecz, J. A., Gluyas, J. & Bloch, S. (eds) Reservoir Quality Prediction in Sandstones and Carbonates. Geological Society, London, Special Publications published online June 27, 2012 as doi: 10.1144/SP370.6 CARBONATE SAND BODIES IN GERMANY American Association of Petroleum Geologists, Tulsa, OK, Memoirs, 69, 211–229. Choquette, P. W. & Pray, L. C . 1970. Geologic nomenclature and classification of porosity in carbonates. Bulletin AAPG, 54, 107–250. Chou, Y. 1975. Statistical Analysis with Business and Economic Applications. Elsevier, Amsterdam. Cressie, N. 1993. Statistics for Spatial Data. Wiley, New York. Dercourt, J., Ricou, L. E. & Vrielynck, B. (eds) 1993. Atlas Tethys Paleoenvironmental Maps. GauthierVillars, Paris. Deutsch, C. V. & Journel, A. G. 1992. GSLIB: Geostatistical Software Library and user’s Guide. Oxford University Press, New York. Dmitrieva, E. 2006. Facies distribution, sequence stratigraphy and poroperm analysis of carbonate shoal bodies in the Upper Muschelkalk (middle Jagst valley, South German Basin). An outcrop analogue study for carbonate reservoirs in the Middle East. Diploma thesis, University of Tübingen. Eisenberg, R. A., Harris, P. M., Grant, C. W., Goggin, D. J. & Conner, F. J. 1994. Modeling reservoir heterogeneity within outer ramp carbonate facies using an outcrop analog, San Andres formation of the Permian Basin. AAPG Bulletin, 78, 1337–1359. Flügel, E. 2004. Microfacies of Carbonate Rocks. Analysis, Interpretation, Application. Springer, Heidelberg. Gawthorpe, R. L. & Gutteridge, P. 1990. Geometry and Evolution of Platform-Margin Bioclastic Shoals, Late Dinantian (Mississippian). International Association of Sedimentologists, Derbyshire, Special Publications, 9, 39–54. Geyer, O. F. & Gwinner, M. P. 1991. Geologie von Baden-Württemberg. E. Schweizerbart’sche Verlagsbuchhandlung, Stuttgart Grammer, G. M., Harris, P. M. & Eberli, G. P. 2004. Integration of outcrop and modern analogs in reservoir modeling. American Association of Petroleum Geologists, Tulsa, OK, Memoirs, 80. Grant, C. W., Goggin, D. J. & Harris, P. M. 1994. Outcrop analog for cyclic-shelf reservoirs, San Andres formation of Permian Basin: stratigraphic framework, permeability distribution, geostatistics, and fluid-flow modeling. AAPG Bulletin, 78, 23– 54. Gringarten, E. & Deutsch, C. V. 2001. Variogram interpretation and modeling. Mathematical Geology, 33, 507–534. Hagdorn, H. 1991. The Muschelkalk in Germany – An introduction. In: Hagdorn, H. (ed.) Muschelkalk, A Field Guide. Goldschneck, Korb. Hagdorn, H. & Simon, T. 1988. Geologie und Landschaft des Hohenloher Landes. Thorbecke, Sigmaringen. Handford, R. C. 1988. Review of carbonate sand-belt deposition of ooid grainstones and application to Mississippian Reservoir, Damme Field, Southwestern Kansas. AAPG Bulletin, 72, 1184–1199. Harris, P. M. & Kowalik, W. S. 1994. Satellite images of carbonate depostional settings, examples of reservoir- and exploration-scale geologic facies variation. AAPG Methods in Exploration Series, 11, 147. Jennings, W. J. Jr. 2000. Spatial Statistics of Permeability Data from Carbonate Outcrops of West Texas and New Mexico: implications for Improved Reservoir Modelling. Bureau of Economic Geology. Report of Investigations no. 258. University of Texas. Jennings, J. W., Ruppel, S. C. & Ward, W. B. 1998. Geostatistical analysis of petrophysical data and modelling of fluid-flow effects in carbonate outcrops. Society of Petroleum Engineers Annual Technical Conference and Exhibition, New Orleans, 27–30 September, SPE Paper 49025. Jensen, J. L. 1991. Use of the geometric average for effective permeability estimation. Mathematical Geology, 23, 833 –840. Kerans, C. & Tinker, S. W. 1997. Sequence Stratigraphy and Characterization of Carbonate Reservoirs. OSEPM Short Course Notes, 40. Kittridge, M. G., Lake, L. W., Lucia, F. J. & Fogg, G. E. 1990. Outcrop/subsurface comparison of heterogeneity in the San Andres Formation. Society of Petroleum Engineers Formation Evaluation, 5, 233– 240. Kostic, B. 2001. Sedimentäre Strukturen, Fazies und Poroperm-Eigenschaften in ausgewählten ‘Karbonatsanden’: Quaderkalk, Oberer Muschelkalk. Diploma thesis, University of Tübingen. Kostic, B. & Aigner, T. 2004. Sedimentary and poroperm anatomy of shoal-water carbonates (Muschelkalk, South German Basin): an outcrop-analogue study of interwell spacing scale. Facies, 50, 113 –131. Looser, M. 2006. Facies and poroperm parameters of epeiric carbonates in the Upper Muschelkalk of the middle Kocher valley. Diploma thesis, University of Tübingen. Lucia, F. J. 1983. Petrophysical parameters estimated from visual description of carbonate rocks: a field classification of carbonate pore space. Journal of Petroleum Technology, 3, 626–637. Lucia, F. J. 1999. Carbonate Reservoir Characterization. Springer, Berlin. Matheron, G. 1963. Principles of Geostatistics. Economic Geology, 58, 1266–1963. Ockert, W. 1988. Lithostratigraphie und Fossilführung des Trochitenkalks (Unterer Hauptmuschelkalk, mo1) im Raum Hohenlohe. In: Hagdorn, H. (ed.) Neue Forschungen zur Erdgeschichte von Crailsheim. Sonderbände der Gesellschaft für Naturkunde in Württemberg, Goldschneck, Korb, 1, 43–69. Palermo, D., Aigner, T., Geluk, M., Poppelreiter, M. & Pipping, K. 2008. Reservoir potential of a lacustrine mixed carbonate/siliciclastic gas reservoir: The Lower Triassic Rogenstein in the Netherlands. Journal of Petroleum Geology, 31, 61–96. Palermo, D., Aigner, T., Nardon, S. & Blendinger, W. 2010. 3D facies modelling of carbonate sand bodies: outcrop analogue study in an epicontinental basin (Triassic, SW Germany). AAPG Bulletin, 94, 475–512. Pranter, M. J., Hirstius, C. B. & Budd, D. A. 2005. Scales of lateral petrophysical heterogeneity within dolomite lithofacies as determined from outcrop analogs: Implications for 3-D reservoir modelling. AAPG Bulletin, 89, 645 –662. Pranter, M. J., Reza, Z. A. & Budd, D. A. 2006. Reservoir-scale characterization and multiphase fluidflow modelling of lateral petrophysical heterogeneity within dolomite facies of the Madison Formation, Sheep Canyon and Lysite Mountain, Wyoming, USA. Petroleum Geoscience, 12, 29–40. Geological Society, London, Special Publications published online June 27, 2012 as doi: 10.1144/SP370.6 D. PALERMO ET AL. Qi, L., Carr, T. R. & Goldstein, R. H. 2007. Geostatistical three-dimensional modelling of oolite shoals, St. Louis Limestone; southwest Kansas. AAPG Bulletin, 91, 69–96. Rankey, E. C., Riegl, B. & Steffen, K. 2006. Form, function, and feedbacks in a tidally dominated ooid shoal, Bahamas. Sedimentology, 53, 1191–1210. Ruf, M. 2001. Facies distribution, petrophysics and mapping of selected carbonate sand bodies in the Upper Muschelkalk, South German Basin: a reservoir analogue investigation. Diploma thesis, University of Tübingen. Ruf, M. & Aigner, T. 2004. Facies and poroperm characteristics of a carbonate shoal (Muschelkalk, South German Basin): A reservoir analogue investigation. Journal of Petroleum Geology, 27, 215– 239. Savary, B. & Ferry, S. 2004. Geometry and petrophysical parameters of a calcarenitic turbidite lobe (Barremian-Aptian, Pas-de-la-Cluse, France). Sedimentary Geology, 168, 281– 304. Senger, R. K., Lucia, F. J., Kerans, C. & Ferris, M. A. 1991. Dominant control on reservoir-flow behavior in carbonate reservoirs as determined from outcrops studies. In: Burchfield, T. E. & Wesson, T. C. (eds) Third International Reservoir Characterization Technical Conference. National Institute for Petroleum and Energy Research and US Department of Energy, Tulsa, OK, l, 107–150. Seyfang, B. 2006. Sedimentary and Poroperm Heterogeneities of Carbonate Shoals from Centimetre- to Kilometre-Scales. An Outcrop Analogue Study For Skeletal/Oolitic Carbonate Sand Reservoirs in the Middle East. Diploma thesis, University of Tübingen. Skupin, K. 1969. Lithostratigraphische Profile aus dem Trochitenkalk des Neckar-Jagst-Kocher-Gebietes. Jahresberichte und Mitteilungen des Oberrheinischen Geologischen Vereins, 63, 1– 173. Ulrichs, M. & Mundlos, R. 1987. Revision der Gattung Ceratites de Haan 1825 (Ammonoidea, Mitteltrias), I.Stuttgarter Beiträge zur Naturkunde, 128, 36. Ulrichs, M. & Mundlos, R. 1990. Zur CeratitenStratigraphie im Oberen Muschelkalk (Mitteltrias) Nordwürttembergs. Jahreshefte der Gesellschaft für Naturkunde in Württemberg, 145, 59–74. Vollrath, A. 1938. Zur Stratigraphie und Bildung des Oberen Hauptmuschelkalks in Mittel- und Westwürttemberg. Mitteilungen aus dem MineralogischGeologischen Institut der TH Stuttgart, 33, 69–80. Vollrath, A. 1955. Zur Stratigraphie des Hauptmuschelkalks in Württemberg. Jahreshefte des Geologischen Landesamtes Baden-Württemberg, 1, 79–168. Vollrath, A. 1957. Zur Entwicklung des Trochitenkalks zwischen Rheintal und Hohenloher Ebene. Jahreshefte des Geologischen Landesamtes Baden-Württemberg, 2, 119–134. Vollrath, A. 1958. Beiträge zur Paläogeographie des Trochitenkalks in Baden-Württemberg. Jahreshefte des Geologischen Landesamtes Baden-Württemberg, 3, 181–194. Vollrath, A. 1970. Ein vollständiges Profil des oberen Muschelkalks und ein neues Mineralwasser bei Ummenhofen, Gemeinde Untersontheim, Landkreis Schwäbisch Hall. Jahresberichte und Mitteilungen des Oberrheinischen Geologischen Vereins, 52, 133–148. Wagner, G. 1913. Beiträge zur Stratigraphie und Bildungsgeschichte des Oberen Hauptmuschelkalks und der Unteren Lettenkohle in Franken. Geologische und Paläontologische Abhandlungen, 2, 31–180. Warren, J. E. & Price, H. S. 1961. Flow in heterogeneous porous media. SPE Journal, 1, 153–169. Ziegler, P. A. 1990. Geological Atlas of Western and Central Europe, Shell International Petroleum Maatschappij. 2nd edn. Elsevier, Amsterdam.
© Copyright 2026 Paperzz