2/13/2015 Chapter Outline 10.1 10.2 10.3 10.4 10.5 10.6 10.7 10.8 10.9 10.10 10.11 10.12 The Properties of Gases Effusion and the Kinetic Molecular Theory of Gases Atmospheric Pressure Relating P,T, and V: The Gas Laws The Combined Gas Law Ideal Gases and the Ideal Gas Law Densities of Gases Gases in Chemical Reactions Mixtures of Gases Solubilities of Gases and Henry’s Law Gas Diffusion: Molecules Moving Rapidly Real Gases Ideal Gas Equation Boyle’s law: V a 1 (at constant n and T) P Charles’ law: V a T (at constant n and P) Avogadro’s law: V a n (at constant P and T) 1 2/13/2015 Standard Temperature and Pressure (STP). Experiments show that at STP, 1 mole of an ideal gas occupies 22.414 L. PV = nRT Sample Exercise 10.7: Applying the Ideal Gas Law Bottles of compressed O2 carried by climbers ascending Mt. Everest are designed to hold one kilogram of the gas. What volume of O2 can one bottle deliver to a climber at an altitude where the temperature is -38 oC and the atmospheric pressure is 0.35 atm? Assume that each bottle contains 1.00 kg of O2. 2 2/13/2015 Chapter Outline 10.1 The Properties of Gases 10.2 Effusion and the Kinetic Molecular Theory of Gases 10.3 Atmospheric Pressure 10.4 The Gas Laws 10.5 The Combined Gas Law 10.6 Ideal Gases and the Ideal Gas Law 10.7 Densities of Gases 10.8 Gases in Chemical Reactions 10.9 Mixtures of Gases 10.10 Solubility of Gases and Henry’s Law 10.11 Gas Diffusion: Molecules Moving Rapidly 10.12 Real Gases Densities and Molecular Weights of Gases Using PV = nRT PV = nRT 3 2/13/2015 Sample Exercise 10.8: Calculating the Density of a Gas According to the U.S National Weather Service, the air temperature in Phoenix, AZ reached 78 oF on January 1, 2012, when the atmospheric pressure was 1024 millibars. What is the density of the air? Assume the average molar mass of air is 28.8 g/mol, which is the weighted average of the molar masses of the various gases in dry air. Example: Calculating the Molecular Weight from PV = nRT 1.018 g of Freon-113 gas is trapped in a 145 mL container at 760 mmHg and 50.0°C. What is the molar mass of Freon-113? 4 2/13/2015 Chapter Outline 10.1 The Properties of Gases 10.2 Effusion and the Kinetic Molecular Theory of Gases 10.3 Atmospheric Pressure 10.4 The Gas Laws 10.5 The Combined Gas Law 10.6 Ideal Gases and the Ideal Gas Law 10.7 Densities of Gases 10.8 Gases in Chemical Reactions 10.9 Mixtures of Gases 10.10 Solubility of Gases and Henry’s Law 10.11 Gas Diffusion: Molecules Moving Rapidly 10.12 Real Gases Gas Laws & Stoichiometry 5 2/13/2015 Example: Combining Stoichiometry and the Ideal Gas Law Chlorine gas can be prepared in the laboratory by the reaction of manganese dioxide with hydrochloric acid: MnO2(s) + 4 HCl(aq) MnCl2(aq) + 2 H2O(l) + Cl2(g) How many grams of MnO2 should be added to excess HCl to obtain 275 mL of chlorine gas at 5.0°C and 650 mmHg? 6
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