Soil Physics Evaluation of Wind Erosion Emissions Factors for Air Quality Modeling The exposure to airborne particulates and surface deposition are important pathways for many human health assessments. Our primary focus is on air quality modeling issues associated with the emission of airborne particulates from contaminated surfaces via wind erosion and the subsequent deposition onto other areas. In this context, the analysis is directed at long-term impacts associated with wind-erosion-induced movement from a contaminated area onto residential and other property. For this type of application, detailed inputs on soil moisture, armoring, and other factors are typically not known as a function of time. The defined scope and data limitations generally render more detailed and data-intensive approaches impractical compared with more simplified empirical models. We compare and contrast selected empirical models to show the central tendency as a function of the type of applications (flat–regional and flat–local) as examples. This review demonstrates the importance of applying empirical wind erosion equations in a manner that is consistent with their development and with due consideration of sitespecific features and the specific air quality analysis under evaluation. Of importance to this review are: the scale of analysis, flat vs. pile (elevated) sources, and an appropriate representation of uncertainty. Without consideration of such factors within dispersion modeling analyses of airborne particulate concentrations or surface deposition rates, the exposure analysis can be substantially biased. David A. Sullivan Sullivan Environmental Consulting, Inc. 1900 Elkin St., Suite 200 Alexandria, VA 22308 Husein A. Ajwa* Dep. of Plant Sciences Univ. of California-Davis 1636 E. Alisal St. Salinas, CA 93905 Abbreviations: TSP, total suspended particulates. W ind erosion produces an episodic source of suspendible particles from erodible surfaces. Wind erosion is a complex process. Until the wind speed reaches a critical threshold to initiate particulate movement within the saltation range, which is a function of the erodible material (Chepil, 1956), the erodible particles remain at rest. Particle movement requires a wind speed that is strong enough to overcome the cohesive force of the adsorbed water films surrounding the soil particles at the surface as well as gravitation forces (Toy, 2002). The distribution of particles at the surface that are available for wind erosion processes is dynamic, which includes a two-part process of abrasion: (i) disintegration of nonerodible units into erodible particles, and (ii) the wearing away of erodible particles into suspendible particles (Chepil, 1958). The suspendible fraction of an eroding surface cannot be well represented by in situ particle size distributions (Lu and Shao, 1999). As the critical wind speed approaches and then surpasses the wind erosion threshold, some of the saltation-size particles, in the range of 60 to 2000 mm (Greeley and Iversen, 1985) with a major contribution from 100 to 500 mm (Lyles, 1977; Shao, 2001; Canada Department of Agriculture, 1943), first begin to oscillate at frequencies consistent with the peak frequency of atmospheric turbulence, approximately 2 Hz (Lyles, 1977), and ultimately the saltation particles, which are large enough to protrude into the turbulent layer above the viscous surface layer, begin to move to heights of tens of centimeters above the surface. The specific range of particles involved in wind erosion is a function of wind speed and surface conditions; particles as large as 2 to 3 mm can be involved under exceedingly high wind speed conditions (Beasley et al., 1984; Chepil, 1941). The size fraction >500 mm Soil Sci. Soc. Am. J. 75:2011 Posted online 23 June 2011 doi:10.2136/sssaj2010:0132 Received 16 Mar. 2011. *Corresponding author ([email protected]). © Soil Science Society of America, 5585 Guilford Rd., Madison WI 53711 USA All rights reserved. No part of this periodical may be reproduced or transmitted in any form or by any means, electronic or mechanical, including photocopying, recording, or any information storage and retrieval system, without permission in writing from the publisher. Permission for printing and for reprinting the material contained herein has been obtained by the publisher. SSSAJ: Volume 75: Number 4 • July–August 2011 1271 is generally associated with surface creep. The ranges of particles in suspension, saltation, and surface creep overlap considerably as a function of wind speed (Canada Department of Agriculture, 1943). The lowest wind speed to produce wind erosion for a smooth, dry, and highly erodible surface is approximately 4.4 m s−1 at 0.30 m above the surface (Chepil, 1958), which is a wind speed of approximately 7 m s−1 at a 10-m reference wind speed and 1-cm roughness length. Because of the nonstationary nature of atmospheric turbulence, wind erosion can occur with mean wind speeds below the wind erosion threshold as measured in a wind tunnel (Fan and Disrud, 1977). Saltating particles are generally lifted only a short distance above the surface along a generally parabolic trajectory and then bounce from the surface at a higher angle than the incident angle because of imparted spin (up to 200 to 1000 times per second) when launched (Chepil, 1945). The saltating particles also move surface particles that are too large to move in the air stream, which is the surface creep process involving particles in the range of 500 to 2000 mm or more (Chepil, 1941; Canada Department of Agriculture, 1943). Small particles have interparticle forces that produce cohesion. These forces include the effects of moisture, van der Waals forces, electrostatic charges, and forces between adsorbed films (Iversen and White, 1982). Without saltation, small particles do not erode spontaneously because such particles do not protrude above the viscous, nonturbulent layer of air next to the surface (Chepil, 1958). The saltating particles release smaller particles through sandblasting bombardment, which separates suspendible particles from larger clusters, and also through direct displacement of suspendible dust caused by saltating particles as they plow craters into the eroding surface (Lu and Shao, 1999). This process is highly complex, with different forces releasing and sustaining the horizontal flux of large particles (by saltation and surface creep) than those for vertical flux of suspendible particles. Suspendible particles are <60 mm and include silt (39–62 mm) and clay particles (<39 mm), with the fine dust fraction (2–10 mm) and smaller that, absent precipitation events, can remain in suspension for long periods of time (Greeley and Iversen, 1985). Suspendible dust can be transported great distances because these relatively light particles move well above the saltation layer as they are transported and dispersed with the ambient flow. Starting with the upwind edge of an erodible surface, the mass of saltating particles, which are contained within the first meter above the surface, increases to an equilibrium point, with the effective surface roughness length increasing and, thereby, also the surface stress. The distance to equilibrium is a function of the erodibility of the surface as well as the wind speed and associated turbulent intensity acting on the erodible surface. Particles >30 and <70 mm can be suspended for relatively short distances, with particles <30 mm referred to as the total suspended particulate fraction. In some cases, only the fraction of suspended particulates that are £2.5 or £10 mm, which are referred to as PM2.5 or PM10, respectively, are evaluated in terms of ambient air quality standards. The actual size limit and horizontal extent of move1272 ment of saltating particles is a function of particle diameter, particle shape, and density (Lyles, 1977). The release of suspendible dust occurs, as a function of the intensity of the saltation process, from the start of saltation all along the fetch across the eroding field. In other words, the vertical flux of suspended particulate matter needs to be integrated across the fetch across an erodible surface to estimate the total mass loss of suspendible particulates from the field. In comparison, the horizontal flux results in a net loss of particles from the eroding field only at the downwind edge. This results in the significance of the horizontal and vertical fluxes, relative to total loss from the field, being very different. Wind erosion can be an important source of airborne particulate loadings as well as of specific toxic constituents. Wind erosion can also produce environmental degradation through the deposition of contaminants onto surfaces (land and water), leading to secondary exposures. There can be considerable uncertainty associated with the use of wind erosion emission factors within air quality modeling analyses. The scale of analysis and the degree of exposure are important factors for the evaluation of airborne exposure from wind erosion. Such issues are particularly important when wind erosion emission rates are input to dispersion modeling analysis of airborne and surface deposition impacts of particulates and their toxic constituents. It is also necessary to consider the temporal variability and episodic nature of wind erosion releases and the variability and uncertainty in the application of such formulas. It is important to apply empirical wind erosion equations in a manner that is consistent with their development and with due consideration for the site-specific features and the specific air quality analysis that is under evaluation. The applicability of this review is to long-term average air pollution applications with the use of relatively simple empirical formulas that rely on readily available data. It is important to define the terms scale of analysis and degree of exposure within the context of the wind erosion process. Suspendible dust can be transported great distances because these relatively light particles move well above the saltation layer and are transported and dispersed with the general wind flow. The scale of analysis refers to the modeling domain to which the emission rates will be applied. Scales range from near field (e.g., within 1 km) to a more regional scale (e.g., tens of kilometers or more). Suspendible particles can travel relatively great distances, but as travel time and distance increase, much of the mass is lost through gravitational settling and filtration effects (Watson and Chow, 2000). The scale of analysis to which the emissions are applied, therefore, is an essential consideration. The degree of exposure and wind speeds also determine the magnitude of the surface stress on erodible particles. For example, the enhanced turbulent intensity in the vicinity of a dune or pile increases the magnitude of emissions and lowers the threshold wind speed for wind erosion relative to flat terrain (Frank and Kocurek, 1996; Xuan and Robins, 1994; Xuan, 2004). Flat surfaces, therefore, have much lower exposure to wind erosion forces than surfaces such as sand dunes and storage or waste piles. SSSAJ: Volume 75: Number 4 • July–August 2011 Based on the above, there is a need to estimate the best fit and 95th percentile range for scenarios where it is necessary to reconstruct airborne concentrations and deposition from contaminated surfaces. This type of analysis generally is done several to many years after the event. Unlike a planned experiment where soil moisture, crusting conditions, etc., can be monitored and input to an analysis, in this case it is necessary to make best approximation based on simple empirical formulas. The objective of this review was to determine central tendency values for differences in scale and exposure, i.e., for flat terrain with regional and localized exposures that can occur for flat source areas and waste piles, for example, that may be heavily contaminated by heavy metals. In our judgment, it is important to: (i) specify the best fit but acknowledge the uncertainty in the estimates; and (ii) recognize the differences in scales of analysis and degrees of exposure (flat vs. vertical exposure) because failure to consider such factors leads to a biased analysis in terms of air quality modeling. TECHNICAL APPROACH Detailed models are available to estimate wind erosion as a function of time based on consideration of site-specific conditions. In many applied dispersion modeling analyses, however, detailed surface conditions as a function of time are not available. In these circumstances, relatively simple empirical formulas can be used to estimate wind erosion on an annual basis, with any subsequent temporal allocation based on surface data such as precipitation conditions, snow cover, and wind speed relative to a threshold value. The focus of this study was on empirical emission rate formulas, which are summarized below. Empirical Formulas Considered Many of the empirical formulas considered here use the terms threshold friction velocity (u*th) or threshold wind speed (uth) to parameterize the relationship between wind erosion and wind conditions. Friction velocity, u* (m s−1), is related to shear stress (Panofsky and Dutton, 1984): u* = t r [1] where t is shear stress (g m−1 s−2) and r is air density (g m−3). An advantage of using friction velocity to parameterize wind erosion is that this term incorporates both wind speed and surface roughness length into the empirical functions. Friction velocity also has the advantage, relative to the use of wind speed, of being approximately constant in the surface layer. For this reason, the use of a friction velocity term relative to the threshold friction velocity is a common basis for empirical wind erosion formulas. As wind speed and, thereby friction velocity, increases, the force of the wind increases exponentially. This is why many of the empirical formulas show some form of A(u* − u*th)B, where A and B are constants. These considerations enhance the extrapolation of empirical functions based on friction velocity beyond their direct locations of development. SSSAJ: Volume 75: Number 4 • July–August 2011 The u*th value for any particular location may be simplified as a constant; however, it is only a simplification because this term is a function of surface conditions. For example, as the moisture content of an erodible surface increases, so does u*th because intercapillary forces on soil grains reinforce soil cohesion (Fecan et al., 1999). In addition, for some surfaces the degree of surface crusting is another variable that influences the specific value of u*th as a function of time. Relative humidity also influences the potential for wind erosion (Park and In, 2003) and thereby the variability of u*th as a function of time. These factors result in significant temporal and spatial variation in u*th (Shaw et al., 2008). Soil moisture and vegetation cover correction terms can be used to help refine empirical formulas if sufficient input data are available. As an alternative, a form such as A(u − uth)B can also be used to describe a function for wind erosion emissions as a function of wind speed. The direct applicability of this approach, however, is limited to surfaces with comparable surface roughness. Therefore, extrapolation to other surfaces (e.g., natural surfaces, material piles, or waste piles) is limited. Table 1 provides an overview of the empirical methods considered here. All of these emission factors are applicable to bare, uncrusted soils. As a first approximation, each function could be multiplied times a vegetation factor (g) ranging from 0 to 1 to account for the vegetation cover percentage (Shaw et al., 2008). Distance Scale Wind-generated emissions of particulate matter involve the release of a wide range of particle sizes with greatly differing settling velocities and other plume depletion characteristics. Only a small fraction of suspendible particles from wind erosion sources are regionally transportable particles. The airborne particulate distributions are variable and are a strong function of travel time and, thereby, also of distance. In addition to gravitational settling, fine particles are depleted by filtering and electrical effects as a function of travel distance (Pace, 2003). The regional-scale vertical dust flux for a large-scale transport model, therefore, applies only to particles that are not deposited in the same grid cell from which they are emitted (Countess, 2001). The application of emission factors to local scales of analysis (e.g., <1000 m from a source area) must account for the heavy end of the particle distribution, which can be a dominant contributor to localized airborne exposures and surface deposition, as well as the fine particle fraction before depletion at the regional scale. Hypothetical sources (flat and piles) were modeled using a nominal total suspended particulates (TSP) emission rate of 1.0 mg m−2 s−1 for the scenario of neutral stability and a wind speed of 8.94 m s−1. A default particle size distribution based on USEPA (1988) is listed in Table 2. We used these values for demonstration purposes only. On a case-specific basis, actual airborne distributions could be substantially different and can be estimated as a function of the particle size distribution of the source material, if known (Shaw et al., 2008). 1273 Table 1. Summary of annualized empirical wind erosion equations for total sus- and not to predict total soil erosion. An adpended particulates (TSP). Method Regional Specific vs. local to storage Size range scale piles addressed TSP adjusted formula† mm g m−2 s−1 Wind erosion equation (USEPA, 1988) regional no TSP aIC K¢L¢V¢ ´ 7.12 ´ 10−6 Gillette and Passi (1988) regional no <20 mm 1.4 ´ 10−3 u*3(u* − u*th)1.25 Tegen and Fung (1994) regional no TSP [0.7 ´ 10−6 (u2)(u − uth) Claiborn et al. (1998) regional no PM10‡ 1.2(5.6 ´ 10−3)10−2 u*3(u* − u*th)2 Draxler et al. (2001) regional no PM10 (120.8)(K)u*(u*2 − u*th2)2§ local no PM10 (1 ´ 10−14)u*4 (1 − u*th/u*)2¶ Shaw et al. (2008) ditional set of simulations was modeled with initial dispersion set to represent a 40-m-high hemispheric pile, with all inputs set to the same values except for the following to represent the (hypothetical) large pile: 3 Height of pile = 40 m 8 =15 m above ground level which is the centroid of a hemisphere, and 2 40 m 2.15 = 37.2 m Initial vertical dispersion = (USEPA, 1999). Figure 1 shows an example of these hypothetical analyses for 8.94 m s−1 Limited reservoir thresholds for flat and pile surfaces for the asmethod local yes TSP sumed particulate emissions in comparison to (USEPA, 1988)# an ideal gas without any loss of particles en Nickling and local no TSP 1.4 ´ 10−2 u*4.38 Gillies (1993) route along the trajectory. As shown, the ratio Continuous active of near-field to regional-scale modeled conpile method local yes TSP (USEPA, 1988) centrations is a function of the degree of ex† Bold type indicates factors used to normalize formulas to TSP. Variables are: a, fraction of posure. The ratios of concentrations without soil loss in the form of suspendible particulates (dimensionless); I, erodibility (U.S. tons acre−1 deposition effects to those with deposition efyr−1); C, climatic factor (dimensionless); K¢, surface roughness factor to account for surface fects in this example were approximately 14.4 resistance to wind erosion (dimensionless); L¢, field length (m); V¢, vegetation cover factor (flat) compared with approximately 4.4 (pile (dimensionless); u*, friction velocity (m s−1); u*th, threshold friction velocity for continuous wind erosion (m s−1); u, wind speed (m s−1); uth, threshold wind speed for continuous wind scenario). This figure shows that an emission erosion (m s−1); K, surface soil texture coefficient (dimensionless). rate appropriate for near-scale modeling can‡ PM10, fraction of suspended particulates £10 mm. not directly represent regional-scale impacts § K applicable to soils studied by Draxler et al. (2001) is 5.6 ´ 10−4 m−1. This value is because the fraction of emitted particulates applicable only to sandy soils (Gillette et al., 1996; Draxler et al., 2001). available for regional-scale transport is much ¶ u* and u*th (cm s−1). smaller than what is available for near-field # The limited reservoir method computes the mass loss per wind erosion event based on the daily fastest mile of wind (g m−2). impacts and vice versa. Figure 1 demonstrates that emission methods suitable for regional The model-based comparisons were made using the USEPA analysis can substantially understate localized impacts of TSP ISCST3 dispersion model (USEPA, 1999), which accounts for near specific sources, up to a factor of nearly 15 in this example. gravitational settling and dry deposition loss as a function of travel distance, wind speed, and atmospheric stability. Although this model is representative of a large eroding dust source field, a hypothetical portion of an erodible area was modeled as an area source set to 100 m2 and with no initial vertical extent to represent flat source regions. A portion of the erodible area was used only as an example to demonstrate the differences in modeling a flat area (area source) in comparison to a pile (volume source) Choi and Fernando (2008) local no PM10 (1 ´ 10−14)u*4 ´ 2 Table 2. Hypothetical particle size distribution for total suspended particulates before depletion (USEPA, 1988). Aerodynamic particle diameter Percentage of mass mm <2.5 2.5–9.9 10–14.9 15–30 % 20 30 10 40 1274 Fig. 1. Ratios of modeled concentrations of no-deposition treatment to deposition treatment for flat and pile (elevated) sources at a wind speed of 8.94 m s−1. SSSAJ: Volume 75: Number 4 • July–August 2011 Importance of Source Exposure (Flat vs. Dunes and Piles) It has been widely recognized since the early work of Bagnold (1941) that an increase in surface stress and enhanced wind erosion is associated with perturbations to airflow. Research has identified the importance of terrain obstructions (e.g., dunes or piles) to modify the intensity of wind speeds and thereby affect the assessment of wind erosion (Bagnold, 1941; Arya and Stunder, 1988). Of equal or greater importance, however, is the increase in the stress on surface particles that is created by the increase in turbulent intensity near the surface of an obstruction. Research has shown that the standard measurement of wind speed, such as that measured at 11 m above ground level in the Arya and Stunder (1988) study, provides an insufficient basis to evaluate the wind erosion potential across the aerodynamically complex surfaces created by obstructions (Neuman et al., 1997; Wiggs et al., 1996; Lancaster et al., 1996; Frank and Kocurek, 1996; Badr and Harion, 2005; Xuan and Robins, 1994; Xuan, 2004; Burkinshaw and Rust, 1993). Surface stress estimates based on wind speed measurements collected at heights >1 m above the ground level of an obstruction do not represent the surface stress that can lead to enhanced wind erosion from the toe to the top of an obstruction to flow (Frank and Kocurek, 1996). Field and wind tunnel studies have demonstrated that at the toe of a dune, where wind speeds have been reduced to the point that wind erosion would not be expected relative to the expected threshold wind speed for flat terrain, wind erosion can still occur because of the large increase in turbulent intensity near the obstruction (Wiggs et al., 1996; Lancaster et al., 1996). Research has also demonstrated that wake vortices can generate sufficient surface stress to produce intermittent wind erosion within the turbulent wake zone in the leeward area of an obstruction to flow (Badr and Harion, 2005). Considering the total surface area of a dune or pile projected onto a flat surface of comparable horizontal dimension and the enhanced wind erosion potential within the turbulent environment immediately adjacent to the exposed surface, it would be expected that an obstruction, such as a pile or dune, would produce substantially greater wind erosion than a comparable source located on flat terrain. These conclusions are consistent in principal with the “knoll factor” associated with the fundamental soil loss equation, where up to a sevenfold increase in soil loss at the peak of a more exposed area has been recorded relative to flat terrain (Woodruff and Siddoway, 1965). Increases in relative wind erosion from the toe of the pile all the way up the upwind slope of an obstruction have been shown to be in the range of 1.5- to twofold or more. A pile with a hemispheric shape also has twice the surface area of an equivalent projection onto a flat base area. During subsequent dispersion modeling of emissions from exposed piles, the increase in surface area should be considered on a case-by-case basis to ensure that airborne exposures and deposition are not underestimated. SSSAJ: Volume 75: Number 4 • July–August 2011 Temporal Allocation Factors Wind erosion is not a continuous process. The emissions of suspended particulates by wind erosion are episodic events that are not appropriately represented within a dispersion modeling analysis as a constant source (Watson and Chow, 2000). A large percentage of annual emissions generally are released within a relatively small number of hours. For an air quality analysis of wind erosion, the computation of emission rates is not an end result but an input to a model-based evaluation of airborne and deposited particulates, including toxic constituents. Proper temporal allocation of these emissions, therefore, is an essential step in the modeling of wind erosion impacts. Some emission factors produce total annual emissions, such as the revised wind erosion equation (RWEQ) (USEPA, 1988), the limited reservoir method (USEPA, 1988), and the continuous active pile method (Cowherd, 1974). In cases where the goal is to allocate wind erosion to specific hours within a dispersion modeling analysis, three conditions need to be satisfied: 1. Friction velocity > threshold friction velocity 2. The surface should be dry (no measurable precipitation within the preceding 24 h) 3. The surface should not be covered with snow or ice Li et al. (2006), for example, showed that when the soil moisture content was 13% or greater for the soil tested, duststorm conditions did not occur. Table 3 presents examples of wind erosion estimates where these three conditions were met using 3 yr of meteorological data generally representative of three locations. In other words, wind erosion was only computed when the friction velocity exceeded the threshold friction velocity, there was no precipitation >0.254 mm during the preceding 24 h, and there was no snow or ice cover. Three meteorological data sets were compiled and processed to represent the southwestern United States (Midland, TX), the southeastern United States (Macon, GA), and the north-central United States (Lansing, MI). Each data set included 3 yr of hourby-hour records for the following parameters: wind speed, precipitation amount (water equivalent), snow and ice cover (daily basis), and the fastest mile of wind (actual data or by converting the fastest minute of wind on a daily basis). The anemometer heights were 6.7 m for Midland, 7.0 for Macon, and 6.1 m for Lansing. It was assumed in these examples that the surfaces were free of vegetation, were comprised of loose soil or material, and were not crusted. These data were used as the basis for Tables 3 through 8. Using Claiborn et al. (1998), an assumed friction velocity threshold of 0.55 m s−1, and 1-cm surface roughness length Table 3. Number of hours to attain 50th and 90th percentile of annual mass loading. Region Lansing, MI Macon, GA Midland, TX Time to reach percentile 50th 90th —————————— h —————————— 66 268 4 10 119 537 1275 1276 3.52 ´ 10−6 2.84 ´ 10−7 3.08 ´ 10−8 5.91 ´ 10−8 9.88 ´ 10−7 1.84 ´ 10−9 2.05 ´ 10−8 2.70 ´ 10−9 0.69 Macon, GA 11.9 2.14 ´ 3.87 ´ 4.37 ´ 1.98 ´ 0.69 Lansing, MI 11.9 3.39 ´ 2.58 ´ 2.45 ´ 5.54 ´ 3.21 ´ 10−5 10−6 10−6 6.59 ´ 6.48 ´ 2.64 ´ 10−6 10−7 10−6 4.38 ´ 10−7 0.69 Midland, TX 11.9 5.76 ´ 10−6 6.49 ´ 3.80 ´ 10−5 5.97 ´ 10−6 NA 10−5 10−5 1.29 ´ 10−6 3.26 ´ 10−7 10−6 10−6 2.81 ´ 10−7 1.06 ´ 10−6 10−5 10−7 2.17 ´ 10−7 10−7 0.55 Macon, GA 9.5 2.86 ´ 10−8 5.11 ´ 10−8 1.79 ´ 10−5 NA 4.40 ´ 10−5 1.42 ´ 10−5 9.38 ´ 10−6 2.13 ´ 10−6 1.82 ´ 10−6 9.45 ´ 10−6 1.24 ´ 10−6 0.55 Lansing, MI 9.5 2.92 ´ 10−5 NA 6.20 ´ 2.03 ´ 1.32 ´ 2.84 ´ 0.55 Midland, TX 9.5 1.78 ´ 1.35 ´ 2.97 ´ NA 5.22 ´ 10−5 10−5 10−5 1.78 ´ 1.25 ´ 1.38 ´ 10−5 10−6 1.19 ´ 0.41 Macon, GA 7.1 1.56 ´ 10−6 3.74 ´ NA 10−6 10−5 10−6 7.38 ´ 10−5 3.85 ´ 10−5 10−6 10−6 1.66 ´ 10−5 2.28 ´ 10−6 10−6 10−7 2.56 ´ 10−5 10−7 0.41 Lansing, MI 7.0 3.37 ´ 10−6 6.89 ´ 10−6 NA 9.68 ´ 10−5 5.15 ´ 10−5 2.16 ´ 10−5 3.03 ´ 10−5 1.00 ´ 10−5 3.42 ´ 10−5 4.50 ´ 10−6 7.1 0.41 Midland, TX ———————————————————————————————— g m−2 s−1 ———————————————————————————————— Claiborn et al. Tegen and Fung Revised wind (1998) (1994) erosion equation Gillette and Passi (1988) uth at 10 m —— m s−1 —— Local–pile Continuously active pile (Cowherd, Nickling and Limited reservoir 1974) Gillies (1993) equation (USEPA, 1988) u*th To compare the results of the models using various regional data, it is first necessary to make certain assumptions. First, surface roughness length was assumed to be 1 cm to allow for the computation of the friction velocity (u*) based on wind speed (referenced to the specific monitoring height above ground level). Second, it was assumed that the roughness length at the locations of the meteorological data and the source material are the same (1 cm). The logarithmic wind profile equation was then used to compute friction velocity. For those functions that compute the emission rate as a function of wind speed or friction velocity relative to threshold values, only the hours that exceeded threshold wind speeds and had dry conditions for the preceding 24 h and no snow cover were considered as non-zero emissions. Table 4 presents the emission rate estimates for the three example regions for each of the emission methods. To compare the various formulas on a common basis, the total emissions during the full 3-yr period in each formula were divided by the total number of hours in the composite periods, i.e., the emissions were annualized for the basis of comparison. In Table 4, there are large differences in emission rates among the three regions reviewed. Areas that are relatively dry, windy, and with minimal snow cover (e.g., Midland, TX) show substantially greater emissions. Hypothetical threshold friction velocities were assumed as follows: 0.4 m s−1 (fine sand), 0.55 m s−1 (fine coal dust, sandy soil), and 0.7 m s−1 (coal pile, scraper tracks) (USEPA, 1988). Note that the wind erosion equation is not directly based on threshold friction velocity. The following regression analysis was therefore used to compute comparable soil erodibility values (I) Region Comparison of Emission Rates across Empirical Emission Factors Empirical emission rate Local–flat Choi and Fernando Shaw et al. (2008) (2008) The three data sets were used, in conjunction with the emission factors summarized above, to compare annualized TSP emission rates per square meter per second, which is used for comparative purposes only. The three areas provide contrasts as follows. Midland, TX, is a dry dusty area. Macon, GA, is a wetter environment but has relatively light wind speeds. Lansing, MI, on the other hand, has a cool climate with substantial snow cover in the winter. Collectively, these data sets provide a range of conditions with which to compare the various empirical wind erosion formulas. Regional–flat CASE STUDIES Table 4. Comparison of annualized emission rates at the regional and local scales for flat and pile (elevated) sources, with the threshold friction velocity (u*th) and the threshold wind speed (uth) at 10 m for continuous wind erosion. as an example, Table 3 summarizes the number of hours needed to reach the 50th and 90th percentile annual mass loadings. Table 3 points to the importance of accurately allocating emissions on a temporal basis because the wind direction and deposition velocity terms generally can be quite different during periods with high wind erosion potential than those representative of typical wind speed conditions. In other words, the direction of transport as well as deposition velocities computed within a dispersion model will be mischaracterized if the wind erosion emissions are not properly allocated to account for highwind-speed periods. SSSAJ: Volume 75: Number 4 • July–August 2011 for the assumed threshold friction velocities, where u*th is the dependent variable and I is the independent variable: u *th = I m +b where m = −0.010 and b = 2.542 (R2 [unadjusted] = 0.74). This regression analysis is based on Table 5 (USEPA, 1988; Gillette, 1980). The friction velocity of 0.55 to 0.56 m s−1 is representative of sandy soils. The continuous active pile equation (Table 1) is limited in this table to surfaces representative of sand because the empirical factor does not include consideration of threshold wind speed or threshold friction velocity. The limited reservoir equation is limited to threshold friction velocities of 0.7 m s−1 or greater. Table 5. Comparison of the soil erodibility (I) term in the revised wind erosion equation (RWEQ) and threshold friction velocity (u*th). Typical content Soil type Loam Sand Clay loam Clay Loamy sand Sandy loam Loam Sandy clay loam Sandy clay Silt loam Silt Silty clay loam I† 56 220 47 86 134 86 56 38 56 47 38 38 Silt Sand —————— % —————— 40 60 5 100 35 65 20 80 10 90 20 80 40 60 85 15 10 50 65 35 90 10 50 50 u*th 1.9 0.6 1.8 1.6 0.9 1.3 1.9 3.4 0.9 2.7 3.6 2.3 † I values were extracted from USEPA (1988). These estimates assume that the correction factor for nonerodible particles is zero. Statistical Analysis of Variability and Uncertainty Some of the differences in the constants in Table 6 can be explained by surface roughness, soil texture, magnitude of the wind, topography, the degree of moisture on the surface, and vegetation cover. Other differences result from uncertainty and should be considered when applying empirical formulas for wind erosion and interpreting model results. We discuss the variability found within specific models below. Examples of uncertainty are provided to evaluate wind erosion estimates. The emission rates computed based on these models should not be considered as precise values, but as best estimates within specified uncertainty ranges. It is important to consider the difference between variability and uncertainty in emission estimates. Variability is related to the heterogeneity of the emission rates across time and space, an inherent property of nature. Uncertainty, on the other hand, is a lack of knowledge of the “true” emission rates (Cullen and Frey, 1998). The variability in emission rates can be described in these formulas as a function of surface characteristics and meteorological conditions. An expected difference between the actual emission rates and estimates obtained from these formulas involves uncertainty. Variability within Specific Methods As an example of uncertainty, Table 6 provides a brief summary of the differences observed in the fitted constants for four On a day-to-day basis, an empirical emission factor would empirical emission formulas by soil type. Claiborn et al. (1998) be expected to show substantial variability because of differences and Draxler et al. (2001), for example, showed order of magin soil moisture, surface crusting (if present), organic matter nitude differences within common soil types. Tegen and Fung concentrations, degree of vegetation sheltering, and other fac(1994) on the other hand, showed a smaller range; however, tors. A range of emissions (around a best estimate) more fully the scale of their research was quite large, which may have averexpresses this variability and uncertainty rather than a single aged out some of the differences. It should be noted that Tegen point estimate. The most definitive basis to estimate such uncerand Fung (1994) used a global-scale model with emphasis on tainty would be to conduct numerous field trials across sites with sandy desert conditions. Also, the K term used in Draxler et al. common soil and surface characteristics and then to evaluate the (2001) was shown to be a linear function of the ratio of vertidistribution of emission estimates within each common soil catcal to total flux (F/Qtotal ). The values shown in this table show egory. Because this degree of testing is not generally available for the range of F/Qtotal, which provides an indication of the degree of variability ex- Table 6. Range of constants used in the empirical formulas. pected in the K term. The differences in Constant in empirical Sample Empirical function Soil type formula size these constants are an example of the unTegen and Fung (1994) sand 0.4–1.2 certainty in both time and space that can 2 sandy loam 1.5 ´ 10−3–9.6 ´ 10−3 be observed in empirical emission rates. Claiborn et al. (1998) Draxler et al. (2001) sand 28 3.0 ´ 10−5–9.0 ´ 10−4 Table 6 shows large variability across clay 7 3.0 ´ 10−5–5.0 ´ 10−5 different soil types for a given formula, loamy sand 2 1.2 ´ 10−4–7.0 ´ 10−3 as well as substantial differences within Nickling and Gillies (1993) sand 1.94 ´ 10−3 common soil types because of uncertainsilt 4.46 ´ 10−1 ty and other factors. mixed agricultural 1.4 ´ 10−2 SSSAJ: Volume 75: Number 4 • July–August 2011 1277 Fig. 2. Cumulative distribution of the ratio of vertical to total flux (F/ Qtotal) for sand. the empirical formulas investigated, a simplified procedure was subsequently used here for demonstration purposes. The uncertainty in a selected input value is used here as an example to help express uncertainty in the computed emission rates. Other inputs could be addressed in a similar fashion, if suitable data were available, to further evaluate the sensitivity of the emission factor to the uncertainty of various inputs. In Draxler et al. (2001), the K term was shown to be a linear function of F/Qtotal. The term F/Qtotal was replaced by a probability density function to provide a means of demonstrating the variability that could be expected when applying an emissions formula such as that of Draxler et al. (2001) within a common source type. Gillette (1986) provided extensive data on F/Qtotal for sand, which aids in describing the uncertainty in the K term that is used in the empirical function that was established through Draxler et al. (2001). The uncertainty in this “constant” in the empirical equation provides a default basis to consider the effect of uncertainty on emission estimates. There were 28 samples shown in Gillette (1986), which can be used to provide a default estimate of the percentile distribution of emission rates because the computed emission rates are a linear function of K in Draxler et al. (2001). Figure 2 shows the percentile of F/Qtotal on this basis. Figure 3 presents an example of the expected differences in emission rates for a sand surface based on the Lansing data set (monitoring height of 6.1 m), assuming 8.94 m s−1 as the assumed threshold and the use of Monte Carlo sampling within the range of the 2.5 to 97.5 percentiles of F/Qtotal for input to the Draxler et al. (2001) emission factor. Greater than 10-fold variability is shown. Especially on a short-term basis, such variability would be expected to lead to large differences in predicted vs. observed results. On a seasonal or annual basis, however, much of this scatter would be averaged out. Uncertainty among Emission Methods The preceding demonstration addressed the expected uncertainty with time in the application of a single emission factor to a common surface type. The following considers the uncertainty on an annualized basis across the range of emission factors reviewed. As demonstrated by the range in results among the alternative empirical formulas, estimates of particu1278 Fig. 3. Comparison of best estimate emission rates and Monte Carlo sampling of uncertainty using the Draxler et al. (2001) empirical function (Lansing case study with threshold wind speed of 8.94 m s−1 and top-ranked 150 values during 3 yr). late emission rates are approximations with a substantial range of estimates. Dispersion modeling based on central tendency values is preferred, but also quantifying the 95th percentile range in the mean emission rates provides perspective to help interpret the results. The empirical emission methods in Table 1 are divided into two major groups: a group that is directly applicable to the local scale of analysis and another group that is directly representative of the regional scale of analysis. Table 7 shows emission rates for data sets grouped to represent local–flat and regional–flat scenarios. Table 7 shows median emission rates based on very small sample sizes. Preferably, 8 to 10 or more direct emission factors would be available for each scenario being evaluated. As a surrogate, the emission factors were factored to be representative of a common scale and common exposure for the two scenarios evaluated: flat–regional and flat–local. The ratios shown in Fig. 1 and summarized above provide a basis to factor between the local and regional scales of analysis, with approximately a 14.4 difference between the local and regional scales. Claiborn et al. (1998) used a factor of 4.2 to distinguish between local and regional scales based on a 1-km grid distance and Fig. 1. The emission rates factored to a common scale of analysis were generally within a factor of two of the directly characterized emission rates. The direct and factored emission rates were, therefore, combined into common sets of emission factors as an example to represent the expected confidence range in the computed emission rates, as shown in Table 8. More definitive best-fit values and 95% confidence ranges could be established if more empirical functions are available in the future to directly represent each scenario. By showing the best fit and 95th percentile range when presenting modeling results of predicted airborne concentrations or deposition to surfaces from wind erosion of contaminated surfaces, the expected impacts, and uncertainty range, provides greater perspective. SSSAJ: Volume 75: Number 4 • July–August 2011 Table 7. Emission rates based on emission factors directly applicable to the scale of analysis for 0.55 m s−1 threshold friction velocity. Erosion rate Method Lansing, MI Nickling and Gillies, 1993 Shaw et al. 2008 Choi and Fernando, 2008 Median Tegen and Fung, 1994 Gillette and Passi, 1988 Woodruff and Siddoway, 1965 (WEQ) Median USEPA, 1988 (continuously active method) Macon, GA ————— mg m−2 s−1 ————— Local exposures from flat source 4.40 ´ 10−5 1.42 ´ 10−5 9.38 ´ 10−6 1.42 ´ 10−5 Regional exposures from flat source 1.82 ´ 10−6 1.24 ´ 10−6 2.13 ´ 10−6 1.82 ´ 10−6 Local exposures from pile source 1.79 ´ 10−5 Midland, TX 1.28 ´ 10−6 3.26 ´ 10−7 2.81 ´ 10−7 3.26 ´ 10−7 6.20 ´ 10−5 2.03 ´ 10−5 1.32 ´ 10−5 2.03 ´ 10−5 5.11 ´ 10−8 2.86 ´ 10−8 1.06 ´ 10−6 5.11 ´ 10−8 2.97 ´ 10−6 1.78 ´ 10−6 2.84 ´ 10−5 2.97 ´ 10−6 5.97 ´ 10−6 2.92 ´ 10−5 Table 8. Ninety-five percent confidence intervals for emission rates based on emission factors directly applicable to the local or regional scale of analysis at a 0.55 m s−1 threshold friction velocity; factors scaled to the scale of the analysis and computed using directly applicable field studies and factored studies. 95% confidence level Region n SD Lansing, MI Macon, GA Midland, TX 7 7 7 1.42 ´ 10−5 9.49 ´ 10−7 2.02 ´ 10−5 Lansing, MI Macon, GA Midland, TX 7 7 7 9.87 ´ 10−7 6.60 ´ 10−8 1.40 ´ 10−6 Mean Median Lower bound Upper bound ——————————————— g m−2 s−1 ——————————————— Local exposures from flat source 2.29 ´ 10−5 1.79 ´ 10−5 9,.74 ´ 10−6 3.61 ´ 10−5 −7 −7 −7 9.90 ´ 10 7.35 ´ 10 1.12 ´ 10 1.87 ´ 10−6 3.36 ´ 10−5 2.56 ´ 10−5 1.49 ´ 10−5 5.23 ´ 10−5 Regional exposures from flat source 1.59 ´ 10−6 1.24 ´ 10−6 6.76 ´ 10−7 2.50 ´ 10−6 −8 −8 −9 6.88 ´ 10 5.11 ´ 10 7.81 ´ 10 1.30 ´ 10−7 2.34 ´ 10−6 1.78 ´ 10−6 1.04 ´ 10−6 3.63 ´ 10−6 CONCLUSIONS Empirical wind erosion formulas need to be applied with due consideration of the scale of analysis (e.g., near-field vs. regional) and the degree of exposure (e.g., flat surfaces vs. piles). Both of these factors can substantially affect the representativeness of wind erosion formulas for specific applications within dispersion models. Large differences in emission rates were shown among the three regions reviewed, with areas that are relatively dry, windy, and with minimal snow cover (e.g., Midland, TX) showing substantially greater emissions. An important use of wind erosion emissions is to serve as input to subsequent dispersion modeling of airborne exposures and surface deposition. It is essential for air quality modeling purposes that the allocation of the wind erosion emissions be applied to hours that: (i) have wind speeds that exceed the wind erosion threshold, (ii) are associated with dry surface conditions (no recent or ongoing precipitation), and (iii) have no significant snow or ice cover. Otherwise, bias in the modeled airborne concentration and deposition impacts as a function of wind direction can be anticipated. Considering the variability and uncertainty across empirical wind erosion emission formulas, and within the application of a single formula to different settings, the most informative way to present emission rates for wind erosion is in the form of a best-fit estimate and a 95th percentile confidence range of expected values SSSAJ: Volume 75: Number 4 • July–August 2011 rather than as a single point estimate. Furthermore, a great deal of scatter is expected when estimating emission rates on an hourly or daily basis because of the variability in surface conditions on a temporal basis, which are generally averaged out in the longer term. The empirical emission factors that were compared here converged to generally similar magnitudes in each region, with differences in the means generally within a factor of two between the sets of formulas that were directly used to estimate the 95% confidence range of the mean emissions. 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