MATERIAL SAFETY DATA SHEET January, 2009 TOWELETTE, PRE-MOISTENED, LEMON-SCENTED -------------------------------------------------------------------------------------Section I: Identification Identity (As used on Label and List): MOIST TOWELETTE WITH LEMON FRAGRANCE Ingredients: 98.8% water 1% lemon fragrance .2% soap Physical Description: A pre-moistened towelette made with virgin paper, individually packaged in a moisture-proof pouch. Manufacturer's Name: SANFACON VIRGINIA, INC. Address: PO Box 600 18097 US Hwy 501 Brookneal, VA 24528 -------------------------------------------------------------------------------------Section II: Hazardous Ingredients Hazardous components: N/A -------------------------------------------------------------------------------------- …2 Section III: Physical/Chemical Characteristics Boiling Point: N/A Vapour Pressure: N/A Vapour Density: N/A Specific Gravity: +/- 1.0 Melting Point: N/A Evaporation Rate: N/A Solubility in Water: Complete Appearance and Colour: Clear liquid with lemon scent -------------------------------------------------------------------------------------Section IV: Fire and Explosion Hazard Data Flash Point: N/A Extinguishing Media: Flammable Limits: N/A N/A Special Fire Fighting Procedures: Unusual Fire & Explosion Hazards: NONE NONE -------------------------------------------------------------------------------------Section V: Health Hazard Data Routes of Entry: Inhalation: N/A Skin: Topically applied Ingestion: N/A Health Hazards: Carcinogenicity: N/A N/A Information/Emergency: Monday through Friday, 8 a.m. to 5 p.m., (800) 463-5591 or contact the local Poison Control Centre. Caution: If accidentally splashed in eyes, rinse thoroughly with cold water; may cause discomfort. No need for first aid if swallowed or inhaled. Signs and Symptoms of Exposure: SAFE AS A TOPICAL SKIN CLEANSER -------------------------------------------------------------------------------------- …3 Disclaimer: Sanfacon acknowledges that the information contained herein is assumed accurate and complete, and illustrates the product to the best of their knowledge. No warranty, expressed or implied, is made and Sanfacon assumes no legal responsibility or liability resulting from its use. SAFETY DATA SHEET 1. Product and Company Identification Emergency Road Flare / Fusee / Railway Flare Use: Emergency signal NSN#: 1370-01-009-2593 Backfire Torches NSN#: 1370-00-294-1279 Forest fire control SAR Signal Flare / Campfire Starter Emergency signal / campfire starter Orion Safety Products 28320 St. Michaels Rd Easton, MD 21601 2. Phone Number: EMERGENCY US 1-800-637-7807 Intl (11) 1-410-822-0318 CHEMTREC 1-800-424-9300 Hazards Identification Emergency Overview Hazard Statements: Warning Danger Warning Danger GHS Classifications Explosive Acute Toxicity Skin Corrosion / Irritation Division 1.4 Category 5 Product- Category 1A Contents - Category 2 Serious Eye Damage / Irritation Product-Category 1 Contents - Category 2B Respiratory or Skin Sensitization Contents - Category 1 STOT - Repeated Exposure Contents - Category 2 3. Fire or projection hazard May be harmful if swallowed Causes severe skin burns and eye damage Causes skin irritation Causes serious eye damage Causes eye irritation May cause allergy or asthma symptoms or breathing difficulties if inhaled May cause damage to thyroid through ingestion after prolonged or repeated exposure Precautionary Statements: Keep out of reach of children. Keep away from heat/sparks/open flames/hot surfaces. – No smoking. Keep/Store away from combustible materials. Protect from moisture. Use only non-sparking tools Avoid breathing dust/smoke Use only outdoors or in a well-ventilated area. Avoid release to the environment.(contents) Use personal protective equipment as required. In case of fire: use water deluge. Do not use dry powder or foam extinguishers! NFPA Rating Flammability 2 Health 2 Reactivity 1 HMIS Rating Flammability 1 Health 3 Physical Hazard 1 Composition / Information on Ingredients Component Strontium Nitrate Potassium Perchlorate Potassium Chlorate Sulfur Shellac Paraffinic Oil Sawdust / Wood Flour CAS # EINCS # %age 10042-76-9 7778-74-7 3811-04-9 7704-34-9 mixture 64742-54-7 9004-34-6 233-131-9 231-912-9 231-100-4 231-722-6 none 232-384-2 232-674-9 <75% <50% <25% <25% <25% <25% <10% 4. First Aid Measures If fumes from ignition or contents are inhaled, remove to fresh air. Watch for signs of allergic reaction. If other symptoms Inhalation develop, get medical aid immediately. For burns, cool with water and bandage appropriately. If contents are contacted, wash with area with soap and water for 15 minutes. Remove contaminated clothing and wash before reuse. Get medical aid if burned or irritation occurs. If burned, cover eye and get medical help immediately. If contents get into eye, flush with plenty of water for at least 15 minutes, occasionally lifting the up and lower lids. Remove contact lenses if easily possible. Do not use boric acid to rinse with; sulfur is an acid irritant. Get medical aid immediately. Get medical aid immediately. Skin Eyes Ingestion 5. Firefighting Measures Extinguishing Media Protective Equipment and Precautions for Firefighters Specific Hazards Arising from the Chemical Flashpoint fusee backfire sar camp Foam and dry chemical extinguishers and suffocation are ineffective. Wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. Prevent further propagation of fire by spraying unburnt nearby product with water. Combat fire from a sheltered position. Water deluge Unsuitable Extinguishing Media Flame and sparks are ejected out the open end of the flare when it functions. Do not point flare at any part of the body or flammable material. Only use outdoors – smoke is harmful. Contents may ignite and burn explosively when suspended in air and exposed to open flame or spark. Not Applicable Flammability Limits Page 1 of 4 Not Applicable Ignition Temperature >167F May 2012 6. Accidental Release Measures Personal Precautions Environmental Precautions Do not breathe contents and avoid contact with skin and eyes. Wear flame retardant clothing with long sleeves, dust mask, rubber or nitrile gloves, safety goggles, safety shoes. Avoid friction on the released product. Keep away from ignition sources. Prevent dispersion of contents on soil and in water. Prevent contents from spreading or entering into drains, ditches, groundwater or rivers by using appropriate barriers. Methods for Containment and Clean-up Use caution when cleaning up spilled product contents. Remove heat, flames, sparks and other sources of ignition. Use non-sparking tools and equipment. Prevent buildup of electrostatic charges by grounding. Clean spills in a manner that does not disperse dust into the air. Do not absorb in sawdust or other combustible absorbents. Pick up spill for recovery or disposal and place in an approved container. Wash away remainder with plenty of water. Collect wash water for approved disposal. 7. Handling and Storage Hold and point flare away from body when igniting. Exercise caution when using this product since molten flecks may be emitted. Avoid Handling contact with clothing and other combustible materials. Wear eye protection during use. Follow instructions on package. Use outdoors only! Do not ignite or burn product inside a vehicle or building. Flares should be allowed to burn to completion. Unburned and partially burned flares contain potassium perchlorate which should not be allowed to come into contact with surface and ground water. Perchlorate Material – special handling may apply. See www.dtsc.ca.gov/hazardouswaste/perchlorate. Avoid ingestion and inhalation of smoke and contents. Do not dismantle. Do not allow contents to touch eyes, skin or clothing. Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with skin and eyes. Avoid contact with heat sparks, and flame. Do not ingest contents as they may be harmful if swallowed. Store in a dry place away from direct sunlight, heat and incompatible materials. Store away from food and beverages. Store away from flammable materials, sources of heat, flame and sparks. Store at ambient temperature. Do not store partially burned flares in a vehicle, closed container, warehouse, or any other building. Storage 8. Exposure Controls / Personal Protection Exposure Limits OSHA PEL Not Established nuisance dust 15 mg/m³. Not Established Not Established Not Established Strontium Nitrate Potassium Perchlorate Potassium Chlorate Sulfur Shellac Paraffinic Oil TWA: 5 mg/m3 8 hour(s). Form: All forms Sawdust / Wood Flour wood dust 5.0 mg/m3 (respirable fraction) Western red cedar: TWA – 2.5 mg/m3 Engineering Controls Eye / Face Protection Skin Protection Respiratory Protection General Hygiene 9. ACGIH TLV Not Established nuisance dust 15 mg/m³. Not Established Not Established Not Established STEL: 10 mg/m3 15 minute(s). Form: All forms; TWA: 5 mg/m3 8 hour(s). Form: All forms TWA-5.0 mg/m3; STEL (15 min.) – 10 mg/m3 (softwood) TWA – 1.0 mg/m3 (certain hardwoods such as beech or oak) Use product outdoors only! When cleaning up powder, use local and/or general exhaust. Safety glasses or goggles None under normal conditions when using product unless prolonged handling is anticipated. Impervious protective clothing, including gloves, boots, and a lab coat, apron or coveralls, as appropriate, when cleaning up spilled product. Wash hands and face before eating, drinking or using tobacco products. None under normal conditions when using product. A particulate respirator (NIOSH t N95 or better filters) may be worn during the cleanup of spilled materials. Use product outdoors away from combustible products. For cleanup of spilled materials, emergency showers and eye wash stations should be available. Educate and train employees in the safe use and handling of hazardous materials. Physical and Chemical Properties Appearance (color, physical form, shape): pH: Not available Boiling Point Not applicable Vapor Pressure: Not applicable Red or yellow paper tube with plastic or cardboard cap on one end Melting Point: Freezing Point: Specific Gravity Not available Not applicable Not applicable 10. Stability and Reactivity Chemical Stability Stable Possibility of Hazardous Reactions Solubility: Evaporation Rate: Vapor Density: >300 g/l powder Not applicable Not applicable Hazardous polymerization will not occur. Conditions to Avoid Incompatible Materials Hazardous Decomposition Products Combustible materials, heat, flames, sparks and other sources of ignition. Moisture. Strong acids, strong fuels, ammonia salts, and strong bases. Strong oxidizers; chlorate salts, Carbon monoxide, carbon dioxide, sulfur oxides, and nitrogen oxides. 11. Toxicology Information Toxicology Strontium Nitrate Potassium Perchlorate Potassium Chlorate Sulfur Shellac Paraffinic Oil Sawdust / Wood Flour fusee backfire sar camp Oral LD50 Rat: 2750 mg/kg Rat: 2100 mg/kg Rat: 1870 mg/kg (CAT 4) Rat:>5050 mg/kg body weight No information found Rat: >2000 mg/kg No information found Page 2 of 4 skin LD50 No information found No information found No information found Rat:>2020 mg/kg body weight No information found Rat: >2000 mg/kg No information found LC50 No information found No information found No information found Rat:>5.49 mg/L air concentration No information found No information found No information found May 2012 Acute Dose Effects Repeated Dose Effects Burning flare can cause severe burns if in contact with body. Contents may cause moderate eye irritation or burns. Contact with skin causes irritation and possible burns, especially if skin is wet or moist. Ingestion of contents may cause gastrointestinal irritation with nausea, vomiting and diarrhea. Inhalation of smoke or contents will cause irritation to the lungs and mucus membrane. Individuals with known allergies to sulfide drugs may also have allergic reactions to elemental sulfur. Prolonged or repeated skin contact with contents may cause dermatitis. Irritation Irritating to the skin and eyes on contact. Inhalation will cause irritation to the lungs and mucus membrane. Corrosivity Burning flare can cause severe burns if in contact with body Carcinogenicity None of the ingredients are listed by NTP, IARC or regulated as a Carcinogen by OSHA Reproductive Effects No information found Genetic Effects No information found Neurological Effects No information found Developmental Effects Perchlorate exposure at certain levels can disrupt the function of the thyroid gland by interfering with the iodide uptake and thyroid hormone production. This interference may lead to developmental defects. Scientists consider pregnant women, children, infants, and individuals with thyroid disorders to be the populations most at risk of harm from being exposed to perchlorate. Sensitization No information found Target Organ Effects 12. Eye, skin, liver, kidney, and thyroid. Ecological Information Aquatic Toxicity Potassium Chlorate: fish: LC50 oncorhynchus mykiss (rainbow trout) 1750 mg/l – 96 hr, EC50 daphnia magna (water flea) 1093 mg/l 24 hr Strontium Nitrate: Acute toxicity - Fishes, Carassius auratus, LC100, 9,615 mg/l; Chronic toxicity - Fishes, Gasterosteus aculeatus, LC100, 2.912 mg/l Sulfur: Toxicity to fish LC50 - Oncorhynchus mykiss (rainbow trout) - > 180 mg/l - 96 h Toxicity to daphnia and other aquatic invertebrates: EC50 - Daphnia magna (Water flea) - > 5,000 mg/l - 48 h Paraffinic Oil: Oil Mist, Mineral Lepomis macrochirus (LC50) 96 hour(s) >100 mg/l Oncorhynchus mykiss (LC50) 96 hour(s) >100 mg/l 13. Persistence / Degradability No information found Bioaccumulation / Accumulation No information found Mobility in Environmental Media No information found Disposal Considerations Finished product is considered reactive and could ignite. Burning is the preferred method of disposal of pyrotechnic materials; product is considered inert after ignition. If quantities are too large to destroy by test firing, consult factory. Flares should be allowed to burn to completion. Partially burned, unburned flares, spilled contents, and ash from burned flares should be disposed of in accordance with federal, state, and local requirements. Do not store partially burned flares in a vehicle, closed container, warehouse, or any other building. Refer to California Code of Regulations, Title 33, Sections 67384.1-67384.10 for additional information on handling and disposal of potassium perchlorate containing materials. 14. Transportation Information Part Number United States 3153-08 3153-63 6020 6030 8900 8905 8901 8902 Description shipping name hazard class ID Number packing group Bulk flares Fusee 4.1 NA1325 II 3-15 min flares ORM-D / Limited Quantity ORM-D / Limited Quantity ORM-D / Limited Quantity ORM-D / Limited Quantity ORM-D / Limited Quantity ORM-D / Limited Quantity ORM-D / Limited Quantity ORM-D / Limited Quantity Not applicable Not applicable Not applicable Not applicable Not applicable Not applicable Not applicable Not applicable 3-15 min flare display 20 min flare 6 pack 30 min flare 6 pack Roadside Emergency Kit Flare Kit Plus Emergency Kit Deluxe Roadside Emergency Kit Extreme Weather Roadside Kit fusee backfire sar camp Page 3 of 4 UN3178 UN3178 UN3178 UN3178 UN3178 UN3178 UN3178 UN3178 Not applicable Not applicable Not applicable Not applicable Not applicable Not applicable Not applicable Not applicable EX Number Not applicable Not applicable Not applicable Not applicable Not applicable Not applicable Not applicable Not applicable Not applicable Reportable Quantities Shipping method none Ground only none Ground only none Ground only none Ground only none Ground only none Ground only none Ground only none Ground only none Ground only May 2012 Deluxe “5” Flare Roadside Kit Signal Flare / Fire 750 Starter International / Air 8902-5 Bulk flares 15. ORM-D / Limited Quantity ORM-D / Limited Quantity Not applicable Not applicable Signal Devices, Hand 1.4S Not applicable Not applicable Not applicable Not applicable UN0373 II EX-9209001 UN3178 UN3178 none Ground only none Ground only none Air / ground Regulatory Information TSCA CERCLA CWA CAA SARA 313 SARA 302 Acute Chronic Fire Reactivity Pressure yes yes yes yes no no no no no no no no no no no no no no no no no no no no no no yes no no no no yes no no no no no no yes no no no no no mixture mixture mixture mixture mixture mixture not stated not stated not stated not stated not stated Paraffinic Oil yes no no no no no no no no no no Sawdust / Wood Flour yes no no no no no not stated not stated not stated not stated not stated US Regulations Strontium Nitrate Potassium Perchlorate Potassium Chlorate Sulfur Shellac US States Strontium Nitrate Potassium Perchlorate Potassium Chlorate Sulfur Shellac Paraffinic Oil Sawdust / Wood Flour 16. Prop 65 no no no no mixture no yes NJ 1743 1577 1560 1757 mixture 1437 3227 Canada PA no no no yes mixture no yes WHMIS No results C No results No results mixture No results No results DSL yes yes yes yes mixture yes yes Europe wgk 2 1 2 1 / nwg not listed not listed not listed Other Information Revision Information: May, 2012 Risk and Safety Phrases: R10 Flammable R38, Irritating to skin R20 Harmful by inhalation. R21 Harmful in contact with skin. R22 Harmful if swallowed. R34 Causes burns R36 Irritating to eyes. R37 Irritating to respiratory system. S17 Keep away from combustible material S16 Keep away from sources of ignition S2 Keep out of the reach of children. S8 Keep container dry. S13 Keep away from food, drink and animal foodstuffs. S24 Avoid contact with skin. S25 Avoid contact with eyes. S29 Do not empty into drains. S41, In case of fire and / or explosion do not breathe fumes S43 In case of fire use water S51 Use only in well ventilated areas Key / Legend: HMIS: hazardous material identification system NFPA: national fire protection association CAS: Chemical Abstracts Service number EINECS: European inventory of existing chemical substances OSHA PEL: occupational safety and health administration permissible exposure limit NIOSH TLV: national institute of occupational safety and health Threshold Limit Value NTP: National Toxicology Program IARC: International Agency for Research on Cancer TSCA: toxic substance control act - US CERCLA: comprehensive environmental response, compensation and liability act – US CWA: clean water act - US CAA: clean air act - US SARA: superfund amendments and reauthorization act – US PROP 65:California’s Proposition 65 list WHMIS: workplace hazardous materials information system - Canada DSL: Domestic Substances List - Canada WGK: water hazard classes - Germany Legal Statement: This information is accurate to the best knowledge Orion Safety Products. Orion Safety Products makes no representations or warranties, either express or implied, including without limitation any warranties of merchantability or fitness for a particular purpose, with respect to the information set forth herein or the product to which the information refers. Accordingly, Orion Safety Products will not be responsible for damages resulting from use of or reliance upon this information. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation. fusee backfire sar camp Page 4 of 4 May 2012 DR Page 1/6 Safety Data Sheet Printing date 12.03.2010 Revision: 12.03.2010 1 Identification of the substance/preparation and of the company/undertaking · Product details · Trade name: liquid in glow stick and glow cup · Registration number: Not available · Application of the substance / the preparation: Chemiluminescer · Manufacturer/Supplier: XIAMEN LONG AFTERGLOW CO., LTD NO.1043, TONG JI ZHONG ROAD, TONG AN AREA, XIAMEN, FUJIAN PROVINCE, CHINA TEL :+86-592-3675699 FAX: +86-592-3675400 · Further information obtainable from: XIAMEN LONG AFTERGLOW CO., LTD · Information in case of emergency: Tina MP: +86-13600951446 · Email: [email protected] · Reference Number: GZHGR2010004483; GZ1003017899/CHEM 2 Hazards identification · Hazard description: Not Applicable · Information concerning particular hazards for human and environment: The product does not have to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version. · Classification system: The classification is according to the latest editions of the EU-lists, and extended by company and literature data. 3 Composition/information on ingredients · Chemical characterization · Description: Mixture of the substances listed below with nonhazardous additions. For the wording of listed risk phrases refer to section 16. · Dangerous components: CAS: 10075-85-1 9,10-bis(phenylvinyl)anthracene EINECS: 233-210-8 · Non-dangerous components: CAS: 136-60-7 butyl benzoate EINECS: 205-252-7 CAS: 75203-51-9 Bis(2,3,5-trichloro-6-((pentyloxy)carbonyl)phenyl) oxalate EINECS: 278-124-1 · Remark: Bis(2,3,5-trichloro-6-((pentyloxy)carbonyl)phenyl) oxalate (CAS No.: 75203-51-9) Synonym: CPPO Xi; R 36/37/38 0,3% 85,6% 14,1% 9,10-bis(phenylvinyl)anthracene (CAS No.: 10075-85-1) Note: Fluorescer 4 First aid measures · After inhalation: Supply fresh air; consult doctor in case of complaints. · After skin contact: Rinse with water. · After eye contact: Rinse opened eye for several minutes under running water. · After swallowing: If symptoms persist consult doctor. EU (Contd. on page 2) DR Page 2/6 Safety Data Sheet Printing date 12.03.2010 Revision: 12.03.2010 Trade name: liquid in glow stick and glow cup (Contd. of page 1) 5 Fire-fighting measures · Suitable extinguishing agents: CO₂, powder or water spray. Fight larger fires with water spray or alcohol resistant foam. · Protective equipment: Wear fully protective suit. 6 Accidental release measures · Person-related safety precautions: Wear protective equipment. Keep unprotected persons away. · Measures for environmental protection: Do not allow to enter sewers/ surface or ground water. · Measures for cleaning/collecting: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). · Additional information: See Section 7 for information on safe handling. 7 Handling and storage · Handling · Information for safe handling: Ensure good ventilation/exhaustion at the workplace. · Information about fire - and explosion protection: Keep ignition sources away - Do not smoke. · Storage · Requirements to be met by storerooms and receptacles: Store in a cool location. · Information about storage in one common storage facility: Store away from foodstuffs. 8 Exposure controls/personal protection · Additional information about design of technical facilities: No further data; see item 7. · Ingredients with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. · DNELs: Not available · PNECs: Not available · Additional information: The lists valid during the making were used as basis. · Personal protective equipment · General protective and hygienic measures: The usual precautionary measures are to be adhered to when handling chemicals. · Respiratory protection: Suitable respiratory protective device recommended. · Protection of hands: The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation · Material of gloves: The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. · Penetration time of glove material: The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. · Eye protection: Goggles recommended during refilling EU (Contd. on page 3) DR Page 3/6 Safety Data Sheet Printing date 12.03.2010 Revision: 12.03.2010 Trade name: liquid in glow stick and glow cup (Contd. of page 2) 9 Physical and chemical properties · General Information Form: Colour: Odour: Liquid Transparent Odourless · Change in condition Melting point/Melting range: Boiling point/Boiling range: Not available Not available · Flash point: Not available · Flammability (solid, gaseous): Not available · Ignition temperature: Not available · Self-igniting: Product is not selfigniting. · Danger of explosion: Product is not explosive. However, formation of explosive air/ vapour mixtures are possible. · Explosion limits: Lower: Upper: · Oxidizing properties Not available Not available Not available · Vapour pressure: Not available · Density: · Relative density · Vapour density · Evaporation rate Not available Not available Not available Not available · Solubility in / Miscibility with water: Not available · pH-value: Not available · Segregation coefficient (n-octanol/water): Not available. · Viscosity: Dynamic: Not available. 10 Stability and reactivity · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · Materials to be avoided: Not available · Dangerous reactions: No dangerous reactions known. · Dangerous decomposition products: No dangerous decomposition products known. 11 Toxicological information · Acute toxicity · LD/LC50 values relevant for classification: 136-60-7 butyl benzoate Oral LD50 5140 mg/kg (rat) Dermal LD50 4000 mg/kg (rabbit) · Primary irritant effect · on the skin: Irritating effect possible. · on the eye: Irritating effect possible. · Sensitization: Sensitization possible. (Contd. on page 4) EU DR Page 4/6 Safety Data Sheet Printing date 12.03.2010 Revision: 12.03.2010 Trade name: liquid in glow stick and glow cup (Contd. of page 3) · Additional toxicological information: The product is not subject to classification according to the calculation method of the General EU Classification Guidelines for Preparations as issued in the latest version. When used and handled according to specifications, the product does not have any harmful effects to our experience and the information provided to us. · Toxicokinetics, metabolism and distribution: Not available · Acute effects (acute toxicity, irritation and corrosivity): Not available · Repeated dose toxicity: Not available · CMR effects (carcinogenity, mutagenicity and toxicity for reproduction): Not available 12 Ecological information · Information about elimination (persistence and degradability): Not available · Behaviour in environmental systems · Mobility and bioaccumulation potential: Not available · Ecotoxical effects · Aquatic toxicity: Not available · Additional ecological information: · General notes: Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water Do not allow product to reach ground water, water course or sewage system. Danger to drinking water if even small quantities leak into the ground. · PBT assessments: Not available 13 Disposal considerations · Product · Recommendation: Smaller quantities can be disposed of with household waste. · Uncleaned packaging · Recommendation: Disposal must be made according to official regulations. 14 Transport information · Land transport ADR/RID (cross-border) · ADR/RID class: · Danger code (Kemler): · UN-Number: · Packaging group: · Hazard label: · Description of goods: · Limited quantities (LQ): · Transport category: · Maritime transport IMDG · IMDG Class: · UN Number: · Label: · Packaging group: · EMS Number: Yes · Marine pollutant: · Proper shipping name: · Air transport ICAO-TI and IATA-DGR · ICAO/IATA Class: · UN/ID Number: · Label: (Contd. on page 5) EU DR Page 5/6 Safety Data Sheet Printing date 12.03.2010 Revision: 12.03.2010 Trade name: liquid in glow stick and glow cup (Contd. of page 4) · Packaging group: · Proper shipping name: - 15 Regulatory information · Sara · Section 335(extremely hazadous substances): None of the ingredients is listed. · Section 313(specific toxic chemical listings): None of the ingredients is listed. · TSCA(Toxic Substances Control Act): 136-60-7 butyl benzoate 10075-85-1 9,10-bis(phenylvinyl)anthracene · Proposition 65 · Chemical known to cause cancer: None of the ingredients is listed. · Chemicals known to cause reproductive toxicity for females: None of the ingredients is listed. · Chemicals known to cause reproductive toxicity foe males: None of the ingredients is listed. · Chemicals known to cause developmental toxicity: None of the ingredients is listed. · Cancerogenity categories · EPA(Environmental Protection Agency) None of the ingredients is listed. · IARC(International Agency for Research on Cancer) None of the ingredients is listed. · NTP(National toxicology Program) None of the ingredients is listed. · TLV(Threshold Limit Value established by ACGIH) None of the ingredients is listed. · NIOSH-Ca(National Institution for Occupational Safety & Health ) None of the ingredients is listed. · OSHA-Ca(Occupational Safety & Health Administration) None of the ingredients is listed. · Labelling according to EU guidelines: Observe the general safety regulations when handling chemicals. The product is not classified as dangerous according to Directive 67/548/EEC, 1999/45/EC and 1272/2008/ EC. 16 Other information · Relevant R-phrases 36/37/38 Irritating to eyes, respiratory system and skin. · *************************************************************************************** The contents and format of this MSDS/SDS are in according with REGULATION(EC) No. 1907/2006, EU Commission Directive 1999/45/EC, 67/548/EEC. DISCLAIMER OF LIABILITY The information in this MSDS/SDS was obtained from sources which we believe are reliable. However, the (Contd. on page 6) EU DR Page 6/6 Safety Data Sheet Printing date 12.03.2010 Revision: 12.03.2010 Trade name: liquid in glow stick and glow cup (Contd. of page 5) information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in anyway connected with the handling, storage, use or disposal of the product. This MSDS/SDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS/SDS information may not be applicable. · *************************************************************************************** End of document EU DR Page 1/6 Safety Data Sheet Printing date 12.03.2010 Revision: 12.03.2010 1 Identification of the substance/preparation and of the company/undertaking · Product details · Trade name: liquid in glow stick and glow cup · Registration number: Not available · Application of the substance / the preparation: Activator · Manufacturer/Supplier: XIAMEN LONG AFTERGLOW CO., LTD NO.1043, TONG JI ZHONG ROAD, TONG AN AREA, XIAMEN, FUJIAN PROVINCE, CHINA TEL :+86-592-3675699 FAX: +86-592-3675400 · Further information obtainable from: XIAMEN LONG AFTERGLOW CO., LTD · Information in case of emergency: Tina MP: +86-13600951446 · Email: [email protected] · Reference Number: GZHGR2010004482; GZ1003017898/CHEM 2 Hazards identification · Hazard description: Not Applicable · Information concerning particular hazards for human and environment: The product does not have to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version. · Classification system: The classification is according to the latest editions of the EU-lists, and extended by company and literature data. 3 Composition/information on ingredients · Chemical characterization · Description: Mixture of the substances listed below with nonhazardous additions. For the wording of listed risk phrases refer to section 16. · Dangerous components: CAS: 7722-84-1 hydrogen peroxide solution C, EINECS: 231-765-0 EU number: 008-003-00-9 Xn, O; R 5-8-20/22-35 · Non-dangerous components: CAS: 7732-18-5 pure water EINECS: 231-791-2 CAS: 131-11-3 dimethyl phthalate EINECS: 205-011-6 3,3% 9,2% 87,5% 4 First aid measures · After inhalation: Supply fresh air; consult doctor in case of complaints. · After skin contact: Rinse with water. · After eye contact: Rinse opened eye for several minutes under running water. · After swallowing: If symptoms persist consult doctor. 5 Fire-fighting measures · Suitable extinguishing agents: Use fire extinguishing methods suitable to surrounding conditions. (Contd. on page 2) EU DR Page 2/6 Safety Data Sheet Printing date 12.03.2010 Revision: 12.03.2010 Trade name: liquid in glow stick and glow cup (Contd. of page 1) · Protective equipment: Wear fully protective suit. 6 Accidental release measures · Person-related safety precautions: Wear protective equipment. Keep unprotected persons away. · Measures for environmental protection: Do not allow to enter sewers/ surface or ground water. · Measures for cleaning/collecting: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). · Additional information: See Section 7 for information on safe handling. 7 Handling and storage · Handling · Information for safe handling: Ensure good ventilation/exhaustion at the workplace. · Information about fire - and explosion protection: Keep ignition sources away - Do not smoke. · Storage · Requirements to be met by storerooms and receptacles: Store in a cool location. · Information about storage in one common storage facility: Store away from foodstuffs. 8 Exposure controls/personal protection · Additional information about design of technical facilities: No further data; see item 7. · Ingredients with limit values that require monitoring at the workplace: 131-11-3 dimethyl phthalate PEL (USA) 5 mg/m³ REL (USA) 5 mg/m³ TLV (USA) 5 mg/m³ 7722-84-1 hydrogen peroxide solution PEL (USA) 1,4 mg/m³, 1 ppm REL (USA) 1,4 mg/m³, 1 ppm TLV (USA) 1,4 mg/m³, 1 ppm MAK (Germany) 0,71 mg/m³, 0,5 ppm · DNELs: Not available · PNECs: Not available · Additional information: The lists valid during the making were used as basis. · Personal protective equipment · General protective and hygienic measures: The usual precautionary measures are to be adhered to when handling chemicals. · Respiratory protection: Suitable respiratory protective device recommended. · Protection of hands: The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation · Material of gloves: The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. · Penetration time of glove material: The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. (Contd. on page 3) EU DR Page 3/6 Safety Data Sheet Printing date 12.03.2010 Revision: 12.03.2010 Trade name: liquid in glow stick and glow cup (Contd. of page 2) · Eye protection: Goggles recommended during refilling 9 Physical and chemical properties · General Information Form: Colour: Odour: Liquid Transparent Odourless · Change in condition Melting point/Melting range: Boiling point/Boiling range: Not available Not available · Flash point: Not available · Flammability (solid, gaseous): Not available · Ignition temperature: Not available · Self-igniting: Product is not selfigniting. · Danger of explosion: Product is not explosive. However, formation of explosive air/ vapour mixtures are possible. · Explosion limits: Lower: Upper: · Oxidizing properties Not available Not available Not available · Vapour pressure: Not available · Density: · Relative density · Vapour density · Evaporation rate Not available Not available Not available Not available · Solubility in / Miscibility with water: Not available · pH-value: Not available · Segregation coefficient (n-octanol/water): Not available. · Viscosity: Dynamic: Not available. 10 Stability and reactivity · Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. · Materials to be avoided: Not available · Dangerous reactions: No dangerous reactions known. · Dangerous decomposition products: No dangerous decomposition products known. 11 Toxicological information · Acute toxicity · LD/LC50 values relevant for classification: 131-11-3 dimethyl phthalate Oral LD50 6800 mg/kg (rat) Dermal LD50 >10 mg/kg (rabbit) (Contd. on page 4) EU DR Page 4/6 Safety Data Sheet Printing date 12.03.2010 Revision: 12.03.2010 Trade name: liquid in glow stick and glow cup (Contd. of page 3) · Primary irritant effect · on the skin: Irritating effect possible. · on the eye: Irritating effect possible. · Sensitization: Sensitization possible. · Additional toxicological information: The product is not subject to classification according to the calculation method of the General EU Classification Guidelines for Preparations as issued in the latest version. When used and handled according to specifications, the product does not have any harmful effects to our experience and the information provided to us. · Toxicokinetics, metabolism and distribution: Not available · Acute effects (acute toxicity, irritation and corrosivity): Not available · Repeated dose toxicity: Not available · CMR effects (carcinogenity, mutagenicity and toxicity for reproduction): Not available 12 Ecological information · Information about elimination (persistence and degradability): Not available · Behaviour in environmental systems · Mobility and bioaccumulation potential: Not available · Ecotoxical effects · Aquatic toxicity: Not available · Additional ecological information: · General notes: Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. · PBT assessments: Not available 13 Disposal considerations · Product · Recommendation: Smaller quantities can be disposed of with household waste. · Uncleaned packaging · Recommendation: Disposal must be made according to official regulations. 14 Transport information · Land transport ADR/RID (cross-border) · ADR/RID class: · Danger code (Kemler): · UN-Number: · Packaging group: · Hazard label: · Description of goods: · Limited quantities (LQ): · Transport category: · Maritime transport IMDG · IMDG Class: · UN Number: · Label: · Packaging group: · EMS Number: Yes · Marine pollutant: · Proper shipping name: (Contd. on page 5) EU DR Page 5/6 Safety Data Sheet Printing date 12.03.2010 Revision: 12.03.2010 Trade name: liquid in glow stick and glow cup (Contd. of page 4) · Air transport ICAO-TI and IATA-DGR · ICAO/IATA Class: · UN/ID Number: · Label: · Packaging group: · Proper shipping name: - 15 Regulatory information · Sara · Section 335(extremely hazadous substances): 7722-84-1 hydrogen peroxide solution · Section 313(specific toxic chemical listings): 131-11-3 dimethyl phthalate · TSCA(Toxic Substances Control Act): All ingredients are listed. · Proposition 65 · Chemical known to cause cancer: None of the ingredients is listed. · Chemicals known to cause reproductive toxicity for females: None of the ingredients is listed. · Chemicals known to cause reproductive toxicity foe males: None of the ingredients is listed. · Chemicals known to cause developmental toxicity: None of the ingredients is listed. · Cancerogenity categories · EPA(Environmental Protection Agency) 131-11-3 dimethyl phthalate D · IARC(International Agency for Research on Cancer) 7722-84-1 hydrogen peroxide solution 3 · NTP(National toxicology Program) None of the ingredients is listed. · TLV(Threshold Limit Value established by ACGIH) 7722-84-1 hydrogen peroxide solution A3 · NIOSH-Ca(National Institution for Occupational Safety & Health ) None of the ingredients is listed. · OSHA-Ca(Occupational Safety & Health Administration) None of the ingredients is listed. · Labelling according to EU guidelines: Observe the general safety regulations when handling chemicals. The product is not classified as dangerous according to Directive 67/548/EEC, 1999/45/EC and 1272/2008/ EC. · Special labelling of certain preparations: Safety data sheet available for professional user on request. EU (Contd. on page 6) DR Page 6/6 Safety Data Sheet Printing date 12.03.2010 Revision: 12.03.2010 Trade name: liquid in glow stick and glow cup (Contd. of page 5) 16 Other information · Relevant R-phrases 20/22 Harmful by inhalation and if swallowed. 35 Causes severe burns. 5 Heating may cause an explosion. 8 Contact with combustible material may cause fire. · *************************************************************************************** The contents and format of this MSDS/SDS are in according with REGULATION(EC) No. 1907/2006, EU Commission Directive 1999/45/EC, 67/548/EEC. DISCLAIMER OF LIABILITY The information in this MSDS/SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in anyway connected with the handling, storage, use or disposal of the product. This MSDS/SDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS/SDS information may not be applicable. · *************************************************************************************** End of document EU Corporation Telephone: (845) 365-8200 * Toll Free: (888) DYNAREX * Fax: (845) 365-8201 Website: www.dynarex.com Website: www.thcnet.com Reviewed on 4/11/13 Page 1 of 2 MATERIAL SAFETY DATA SHEET Reorder # 1303 / 1331 (BZK Antiseptic Towelettes) Emergency or Information Phone No.: 845-365-8200 (M-F Daytime) At other times, contact the local Poison Control Center. Executive Headquarters: Ten Glenshaw Street, Orangeburg, NY 10962 Corporation Telephone: (845) 365-8200 * Toll Free: (888) DYNAREX * Fax: (845) 365-8201 Website: www.dynarex.com Website: www.thcnet.com Page 2 of 2 The information furnished herein is believed to be accurate and represents the best data currently available to us. No warranty, expressed or implied, is made and Dynarex Corp. assumes no legal responsibility or liability resulting from its use. This MSDS has been compiled in accordance with - EC Directive 91/155/EC - OSHA's Hazcom Standard (29 CFR 1910.1200) Executive Headquarters: Ten Glenshaw Street, Orangeburg, NY 10962 Corporation Telephone: (845) 365-8200 * Toll Free: (888) DYNAREX * Fax: (845) 365-8201 Website: www.dynarex.com Website: www.thcnet.com MATERIAL SAFETY DATA SHEET Page 1 of 2 Dtd. 4/4/13 I. PRODUCT IDENTIFICATION PRODUCT/TRADE NAME: ALCOHOL PREP/SWAB – Reorder #’s AM-20200, 1103, 1104, 1106, 1113, 1114, 1116 1203, 1204. HAZARD RATING (NFPA) HEALTH: 1 FLAMMABILITY: 3 REACTIVITY: 0 SPECIFIC: NONE EMERGENCY OR INFORMATION TELEPHONE NO: 845-365-8200 (M-F DAYTIME) AT OTHER TIMES, CONTACT THE LOCAL POISON CONTROL CENTER CHEMICAL NAME: ISOPROPYL ALCOHOL II. HAZARDOUS INGREDIENTS PER 29 CFR 1910.1200 Hazardous Ingredients ISOPROPYL ALCOHOL % 70 ACGIH TLV 400 ppm CAS NUMBER 67-63-0 III. PHYSICAL/CHEMICAL CHARACTERISTICS COLOR/ODOR/APPEARANCE: TOWELETTE/PAD/SWAB SATURATED WITH CLEAR LIQUID WITH ALCOHOL ODOR.. BOILING POINT: N/A FLASH POINT: 78°F VAPOR DENSITY N/A EVAPORATION RATE: N/A SOLUBILITY IN WATER: COMPLETE SPECIFIC GRAVITY (H2O = 1):N/A IV. FIRE & EXPLOSION HAZARD DATA FLASH POINT (Method Used): 78°F TAG CLOSED CUP : LEL: 2.0 UEL: 12.0 EXTINGUISHING MEDIA: DRY CHEMICAL OR ALCOHOL TYPE FOAM, CARBON DIOXIDE SPECIAL FIRE FIGHTING PROCEDURES: HANDLE AS FLAMMABLE LIQUID. USE RESPIRATORY PROTECTION FOR FIRE FIGHTING PERSONNEL UNUSUAL FIRE AND EXPLOSION HAZARDS: CLASS 3 FLAMMABILITY V. REACTIVITY DATA STABILITY: STABLE CONDITIONS TO AVOID NONE INCOMPATIBILITY: NONE HAZARDOUS DECOMPOSITION OR BYPRODUCT: NONE POLYMERIZATION: WILL NOT OCCUR CONDITIONS TO AVOID: NONE Executive Headquarters: Ten Glenshaw Street, Orangeburg, NY 10962 Corporation Telephone: (845) 365-8200 * Toll Free: (888) DYNAREX * Fax: (845) 365-8201 Website: www.dynarex.com Website: www.thcnet.com ALCOHOL PREP/SWAB Page 2 of 2 VI. HEALTH HAZARD DATA EFFECTS OF OVER EXPOSURE: SKIN: IF RASH APPEARS, DISCONTINUE USE EYES: WILL CAUSE EYE STING IF SPLASHED INHALATION: NONE INGESTION NOT A NORMAL ROUTE OF ENTRY EMERGENCY AND FIRST AID PROCEDURES: SKIN CONTACT: DISCONTINUE USE IF RASH OR IRRITATION OCCURS EYE CONTACT: FLUSH WITH COLD WATER FOR 15 MINUTES INHALATION: REMOVE TO FRESH AIR INGESTION: INDUCE VOMITING. CALL PHYSICIAN TARGET ORGANS: N/A VII. SPILL AND DISPOSAL PROCEDURE SPILL CONTROL: ELIMINATE ALL SOURCES OF IGNITION WASTE DISPOSAL METHOD: FLUSH SPILLS WITH WATER. HANDLE AS FLAMMABLE LIQUID. FOLLOW LOCAL, STATE AND FEDERAL REGULATIONS. HANDLING AND STORAGE: STORE AWAY FROM HEAT AND SOURCES OF IGNITION VIII. CONTROL MEASURES/PROTECTION RESPIRATION: USE IF PERMISSABLE EXPOSURE LEVEL IS EXCEEDED WHEN HANDLING BULK LIQUID VENTILATION: RECOMMENDED PROTECTIVE GLOVES: NONE REQUIRED EYE PROTECTION: ONLY IF SPLASHING IS EXPECTED HYGIENIC PRACTICES: GOOD HOUSEKEEPING PRACTICES SHOULD BE FOLLOWED. OTHER: DON'T ALLOW LARGE QUANTITIES OF WASTE TO ACCUMULATE IX. TRANSPORT/SHIPPING DOT SHIPPING NAME: N/A TECHNICAL SHIPPING NAME: N/A DOT SHIPPING CLASSIFICATION: DOT-NOT REGULATED DOT ID NO.: N/A DOT LABEL REQUIREMENTS: N/A UN/NA NUMBER REGULATIONS: N/A REPORTABLE QUANTITY: N/A X. DISCLAIMER THE INFORMATION FURNISHED HEREIN IS BELIEVED TO BE ACCURATE AND REPRESENTS THE BEST DATA CURRENTLY AVAILABLE TO US. NO WARRANTY, EXPRESSED OR IMPLIED IS MADE AND DYNAREX CORPORATION ASSUMES NO LEGAL RESPONSIBILITY OR LIABILITY RESULTING FROM ITS USE. Executive Headquarters: Ten Glenshaw Street, Orangeburg, NY 10962 Corporation Telephone: (845) 365-8200 * Toll Free: (888) DYNAREX * Fax: (845) 365-8201 Reorder # 1408 Website: www.dynarex.com Website: www.thcnet.com Reviewed on 4/11/13 Material Safety Data Sheet SECTION 1. Product and Company Identification Product/Trade Name: Sting & Bite Pad Manufacturer's Name: Dynarex Corporation Manufacturer's Address: 10 Glenshaw Street Orangeburg, NY 10941 Emergency or Information 888-DYNAREX or 845-365-8201 Phone No.: At other times, contact the local Poison Control Center Page 1 of 4 Corporation Telephone: (845) 365-8200 * Toll Free: (888) DYNAREX * Fax: (845) 365-8201 Website: www.dynarex.com Website: www.thcnet.com Page 2 of 4 Corporation Telephone: (845) 365-8200 * Toll Free: (888) DYNAREX * Fax: (845) 365-8201 Website: www.dynarex.com Website: www.thcnet.com Page 3 of 4 Corporation Telephone: (845) 365-8200 * Toll Free: (888) DYNAREX * Fax: (845) 365-8201 Website: www.dynarex.com Website: www.thcnet.com SECTION 16. Other Information Disclaimer: The information furnished herein is believed to be accurate and represents the best data currently available to us. No warranty, expressed or implied, is made and Dynarex Corp. assumes no legal responsibility or liability resulting from its use. This MSDS has been compiled in accordance with - EC Directive 91/155/EC - OSHA's Hazcom Standard (29 CFR 1910.1200) Date Prepared: March 2011 Page 4 of 4
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