Corporate Profile Pursuing Infinite Potential of Titanium, Polycrystalline Silicon and High-performance Materials Headquarters/Amagasaki Plant Our predecessor, Osaka Titanium Co., Ltd., successfully to solve water resource issues, in semiconductors that industrialized titanium sponge manufacturing for the first support the electronics industry, and in digital home time in Japan in 1952. This marked our first step as a appliances and advanced medical devices that have pioneer in the titanium sponge industry. In 1960, the become part of every aspect of daily life. In a range of Company began producing polycrystalline silicon. Since areas from large-scale infrastructure to familiar consumer then, we have provided high-purity, high-quality materials goods, titanium and polycrystalline silicon are about to as a manufacturer of titanium sponge and polycrystalline realize their maximum potential. We have also focused silicon, mainly to the aerospace and electronics on the production and development of high-performance industries. materials, new materials based on titanium sponge and polycrystalline silicon. In recent years, titanium and polycrystalline silicon have been used to an increasing extent, including in In order to bring about a safer, richer and faster society, aircraft designed to be better performing and more we will continue to pursue the limitless possibilities of lightweight, in the growing number of plants producing titanium and polycrystalline silicon as a top manufacturer LNG, which has been recognized as low-carbon form of that harnesses the respective strengths of these energy, in large-scale power plants, in seawater materials. desalination plants for which global demand is increasing - 1- Kishiwada Works Product Flow Other companies’ business OSAKA Titanium technologies’ business Raw Materials for Titanium Titanium Ingot Mill Product Manufacturers Calcined Cokes Materials and Fabricated Product Manufacturers ・Aircraft Manufacturers ・Plant Manufacturers ・Consumer Product Manufacturers Titanium Sponge High-performance Materials High-purity Titanium SiO ・Digital Home Appliance Manufacturers ・Solar Cell Manufacturers,etc. TILOP Titanium Powder Metallic Silicon Monocrystalline Wafer Manufacturers Polycrystalline Silicon - 2- Semiconductor Manufacturers ・Digital Home Appliance Manufacturers ・Personal Computer Manufacturers ・Mobile Telephone Manufacturers Titanium Titanium Business OTC’s high-quality titanium sponge finds applications as a material used for important parts in aircraft and in power, chemical and other plants Reaction Vessel for Post Vacuum Separation Process Titanium Production Processes Chlorination Distillation Reduction and Vacuum Separation Crude TiCl4 Pure TiCl4 Ti Crushing Packing Titanium Sponge Raw Materials for Titanium Calcined Coke Raw materials for titanium production include natural rutile, synthetic rutile and titanium slag, all of which are imported. Raw materials for titanium and calcined cokes are reacted with chlorine gas to produce crude titanium tetrachloride. Crude titanium tetrachloride is refined by distillation. Titanium tetrachloride is reduced by molten magnesium in a metal reaction vessel to produce titanium sponge. Then, magnesium and magnesium chloride are separated through evaporation in a vacuum under high heat. Titanium sponge is crushed, sized and then packed. Melting Electrolysis Titanium Ingot Magnesium Chlorine Magnesium Chloride Some portions of titanium sponge go through the melting process. The molten titanium sponge is formed into ingots. Magnesium chloride is decomposed into chlorine and magnesium by electrolysis. - 3- Products The current process for producing titanium was developed by Dr. Kroll in 1946. In 1952, our company became the first company in Japan to succeed in commercially manufacturing titanium and we are now among the world’s largest makers of this product. Titanium sponge is mainly manufactured in Japan, the United States, Russia, Kazakhstan, Ukraine and China. However, only a few manufacturers, including our company, Titanium Sponge have the technology for manufacturing high-quality titanium sponge (referred to as premium grade) for use in the manufacture of critical parts such as aircraft engine components. Due to our capability to develop unique technologies and our accumulated expertise, we are recognized by our customers as a leading manufacturer of titanium sponge, in terms of both quality and quantity. We also manufacture titanium ingots using titanium Titanium Ingot sponge as the primary raw material. Distinctive features of our titanium ingots include their excellent surface condition and high internal quality. Lightweight, strong and rustproof, Production Capacity our titanium ingots are processed into pipes and sheets; pipes for such large-scale facilities as large-scale power plants, petrochemical and seawater desalination plants, and sheets for heat exchangers used in ships and LNG manufacturing plants. We intend to further expand our Titanium Sponge… 40,000 tons/year Titanium Ingots… (Amagasaki Plant) 6,000 tons/year (Amagasaki Plant) business based on the platform of titanium sponge manufacturing. End Use Examples for Titanium 【Aerospace】 Airframes/Engine Parts/Rocket Parts Reduction and Vacuum Separation Furnace 【Power and Other Plants】 Heat Transfer Pipes (for Seawater Desalination Plants, Chemical Plants) Plate Heat Exchangers/Condensers/ Power Generation Turbine Plates 【Construction】 Roofing/External Wall Materials Reaction Vessel for Post Vacuum Separation Process 【Marine/Civil Engineering]】 Marine Rigs/Deep Submergence Vehicles ©Boeing 【Automotive】 Motorbike Mufflers/Engine Parts/Exhaust Pipes 【Sporting Goods】 Golf Clubs/Racing Bikes Crushing 【Medical】 Artificial Bones/Artificial Joints/Cardiac Pacemakers 【Food】 Heat Exchangers for Brewing/ Alkaline-Ionized Water Filters 【General Articles】 VAR Furnace (Melting) Spectacle Frames/Watches/Cameras - 4- ©AIRBUS Titanium Sponge (unit weight: 13 tons) Plate Heat Exchangers (photo courtesy Alfa Laval Japan) Seawater Desalination Plants (photo courtesy Sasakura Co., Ltd.) Implants (Artificial Bones) (Harmless and Biocompatible) (photo courtesy Nakashima Medical Co., Ltd.) Electrolytic Cells for Sodium Hydroxide Production Tokyo Big Sight Spectacle Frames - 5- Polycrystalline Silicon Polycrystalline Silicon Business OTC’s high-purity polycrystalline silicon is employed as a monocrystalline silicon raw material for silicon wafers Polycrystalline Silicon Production Processes Conversion SiHCl3 Distillation Reduction SiHCl3 Machining/ Finishing Washing and Packaging Si Metallic Silicon Polycrystalline silicon for semiconductors is made from metallic silicon which is 98% pure. Metallic silicon is reacted with silicon tetrachloride and hydrogen gas to produce trichlorosilane. Silicon Tetrachloride Hydrogen Trichlorosilane is precision-distilled to form high-purity trichlorosilane. High-purity trichlorosilane is reduced by hydrogen gas to produce semiconductor-grade polycrystalline silicon. Trichlorosilane Hydrogen Distillation Recovery - 6- Trichlorosilane Silicon Tetrachloride Hydrogen Semiconductor-grade polycrystalline silicon is then cut, crushed, and made into forms in accordance with our customers’ specifications. Surface-washed, inspected and then shipped. Polycrystalline Silicon Product Silicon wafers are used as substrate materials for all semiconductors in products including personal computers, smartphones and digital cameras, and are indispensable materials in the electronics industry. These silicon wafers are produced at monocrystalline wafer manufacturers, and we manufacture and sell the material used to make them: high-purity polycrystalline silicon. Polycrystalline Silicon Since OTC began making polycrystalline silicon in 1960, it has made successive improvements to its developmental technologies while maintaining the world’ s top quality Production Capacity standards (11N=99.999999999%) for semiconductor-grade products. Polycrystalline Silicon… 3,000 tons/year A s a n e x t re m e l y h i g h p u r i t y l e v e l i s re q u i re d f o r (Kishiwada Plant) semiconductor-grade polycrystalline silicon, the number of manufacturers of this material worldwide is limited. Polycrystalline Silicon Rods Process for Producing Silicon Wafers from High-purity Semiconductor-grade Polycrystalline Silicon Process Adopted by Our Customer Conversion Polycrystalline Silicon Melting Dipping a Seed Crystal Withdrawal, with Rotation, of Seed Crystal Monocrystalline Silicon Ingot Silicon Wafers End Use Examples for Polycrystalline Silicon Distillation Smartphones Reduction Furnace Polycrystalline Silicon Rods Personal Computers - 7- Digital Cameras Titanium and silicon, materials that are driving industrial development, have huge untapped potential. We believe that one of our key responsibilities is to exploit their full potential and develop new products which meet our customers’ needs. Accordingly, we are planning to High-performance Materials foster the high-performance materials business as our company’s third core operation. Our high-purity titanium, with its high purity levels from 4N5 (99.995%) to 5N (99.999%), is mainly used for producing high-purity titanium sputtering targets used in the semiconductor industry. The titanium powder “TILOP” manufactured by the gas atomization method offers excellent fluidity due to its spherical shape, and is used as a raw material of Semiconductor/ High-performance Materials Business titanium target for liquid crystal and as a material use in metal injection molding (MIM). “TILOP” is also suitable for use with 3D printers, and there are expectations for expanding its application as a material for manufacturing medical or aircraft parts. We will focus on fostering a third core business SiO has a proven track record as a coating material for films for medical use and food packaging films, which cut off oxygen. There are also expectations that it can be used as next-generation negative electrode materials for lithium-ion rechargeable batteries. High-purity Titanium Sputtering Targets Products Block High-purity Titanium Powder TILOP SiO Aircraft parts/medical parts Packaging Materials Negative Electrode Materials Applications Target Materials (for Semiconductors/for Liquid crystal) (Materials for MIM/3D printers) (for Medical use/Foodstuffs) (for Lithium-ion Rechargeable Batteries) End Use Examples for High-performance Materials Personal Computers Liquid Crystal Televisions Packaging Materials for Medical Use and Foodstuffs - 8- Smartphones Established: November 26, 1952 Paid-up Capital: 8,739,620,000 yen Representative: Yasuaki Sugizaki President & Representative Director Market Listings: Tokyo Stock Exchange, 1st Section Business Overview: ●Titanium Business Titanium Sponge/Titanium Ingot/Titanium Tetrachloride Titanium Tetrachloride Aqueous Solution ●Polycrystalline Silicon Business Polycrystalline Silicon ●High-performance Materials Business High-purity Titanium/SiO/TILOP/Titanium Powder 【Headquarters/Amagasaki Plant】 【Kishiwada Works】 【Tokyo Office】 1 Higashihama-cho, Amagasaki, Hyogo, 660-8533, Japan Tel. +81-6-6413-9911 Fax. +81-6-6413-4343 3-2 Kishinoura-cho, Kishiwada, Osaka, 596-0016, Japan Tel. +81-72-479-3010 Fax. +81-72-479-3050 Sumitomo Hamamatsucho Building 8F 1-18-16 Hamamatsucho, Minato-ku, Tokyo, 105-0013, Japan Tel. +81-3-5776-3101 Fax. +81-3-5776-3111 I.C.(To Rinku) Takojizo Station To Wakayama 10 minutes by car from Kishiwada Station on Nankai Line. http://www.osaka-ti.co.jp/ Shibadaimon Daimon Police box 15 Shibadaimon2 To Mita Sumitomo Hamamatsucho Bldg. FamilyMart (Convenience store) A2 World Trade Center Bldg. Daimon World Trade Center Bldg. KyuShibarikyu JR. Gardens Hamamatsucho Hamamatsucho Station Station Tokyo Monorail Hamamatsucho2 To Shinagawa ■Kishiwada Minami Shiba-Daijingu Daiichi Keihin I.C. (From Rinku) Zojojimae To Shibakoen Hanshin Expressway Wangan Route 15 minutes walk from Deyashiki Station on Hanshin Line. ■Kishiwada Minami Hama Kogyo Park Minato City Office Toei (Subway) Oedo Line Daimon Station To Akabanebashi Headquarters / Amagasaki Plant I.C. (From Osaka) Keio University Shiba Kyoritsu Campus Tokaido Shinkan sen JR Yam te Line JR Keihin-ano Tohoku Line Jizo-hama Kita 39 Minato City Office Minato Pension office Seven-Eleven (Convenience store) Toei Asakusa Line Yomo River Kishinoura-Ohashi Bridge Hannan harbor ■Amagasaki Suehiro I.C. ■Kishiwada Minami Kishiwada Town Hall Nankai Line I.C. (To Osaka) Kishiwada Station Hibiya Ave ■Kishiwada Minami Tokyo Office A2 Toei Mita Line Kishinoura -cho Hamamatsucho1 o Rinkou-Route Namikiri Hall Kishiwada kankan Bayside Mall Hanshin Expressway Wangan Route Nishi Takasu-cho Route No.43 204 Sakai Hannan-Route Doi-Route Doi-cho6 Deyashiki-Route Deyashiki Kishiwada Works To Shimbashi Atago Police Sta. Onarimon Station To Shiodome Osaka Rinkai-Route Police box Hanshin Expressway Route No.3 To Namba To Tokyo 29 To Umeda To U chisai waich Hanshin Line Deyashiki Station To Kobe 2 minutes walk from A2 Exit of Daimon station on Toei Oedo Line and Toei Asakusa Line. 6 minutes walk from North Exit of Hamamatsucho station on JR Line and Tokyo Monorail Line. 6 minutes walk from A2 Exit of Onarimon station on Toei Mita Line.
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