1. Which graph represents the relationship between solubility and temperature of most gases, such as NH 3 , in water? A) B) C) D) 3. In a beaker is a clear solution containing 20.g of KClO 3 in 100 g of water at 20°C. E) This solution is 2. How many grams of solute are undissolved after 100. grams of KNO 3 are added and mixed well with 100. g of H2O at 40 ° C? A) 36 B) 40 C) 64 D) 100 E) none A) unsaturated C) supersaturated E) weak B) saturated D) strong 4. In a beaker is a clear solution containing 50.g of NH 4 Cl in 100 g of water at 50°C. 6. Which compound is the most soluble at 20°C? A) B) C) D) E) 7. What is the net ionic equation for the reaction between potassium iodide solution, KI (aq), and silver nitrate solution, AgNO 3 (aq)? This solution is A) unsaturated C) supersaturated E) weak B) saturated D) strong 5. Which polyatomic ion combines with metallic ions to form salts, all of which are soluble in water? A) NO 3– C) SO 42– E) Cl – Substance A Substance B Substance C Substance D It cannot be determined from the information given. B) NH 4+ D) CH 3COO– A) B) C) D) E) K+ (aq) + I –(aq) ® KI(s) K+ (aq) + NO3–(aq) ® KNO3(s) Ag+ (aq) + NO3–(aq) ® AgNO3(s) Ag+ (aq) + I –(aq) ® AgI(s) KI(aq) + AgNO 3(aq) ® AgI(s) + KNO 3(aq) 8. Note the chart of interactions of equal volumes of various 0.100 M aqueous solutions. (Symbols of elements or ions have been replaced by capital letters, and soluble products are indicated.) What is the formula of the precipitate? A) AX B) BY C) CX D) DY E) XY 9. A white precipitate results when lead nitrate solution reacts with sodium chloride solution. A similar precipitate results when lead nitrate solution reacts with hydrochloric acid. What is the formula of the precipitate? A) PbH 2 C) NaNO3 E) PbCl 2 B) HNO3 D) Pb(NO 3) 2 A) maximum number of grams of solute that can be dissolved in 100 g of solvent at a specific temperature B) minimum number of grams of solute that can dissolve in 100 g of solvent to produce an unsaturated solution C) minimum number of grams of solvent that can dissolve 100 g of solute to produce an saturated solution D) ability of a solute to dissolve in various solvents at a specified temperature E) ability of a solvent to dissolve various solutes at a specified temperature g of water and A) B) C) D) E) raise the pressure raise the temperature evaporate some of the water add a crystal of potassium nitrate add a crystal of another salt 14. Which statements are correct? 10. Solubility is defined as the 11. A mixture of well shaken. 13. How would a saturated solution of KNO 3 be made unsaturated? g of table salt is I II Any solid dissolves readily in any liquid. When a solute dissolves in a solvent, the inter–ionic or–molecular forces of both have to be overcome. III All solid solutes break down into molecules when in solution. IV Some solids separate into molecules while others separate into ions as they dissolve. A) I and II only C) II and III only E) III and IV only B) I and III only D) II and IV only 15. At 20°C, 144 grams of KI dissolves in 100 cm 3 of water, and 0.068 g of PbI 2 dissolves in this amount of water. A solution containing 144 g KI/100 cm3 H2O at 20°C is When stirring produces no more change, the total mass of the solution phase in the container is A) C) E) B) D) 12. A salt forms a saturated solution containing 15.0% solute by mass. The solubility of the salt is A) B) C) D) E) 11.3 g solute/100 g of solvent 12.8 g solute/100 g of solvent 15.0 g solute/100 g of solvent 17.6 g solute/100 g of solvent 19.2 g solute/100 g of solvent A) B) C) D) E) dilute and saturated dilute and unsaturated concentrated and saturated concentrated and unsaturated concentrated and supersaturated 16. The solubility of PbI2 in water at 20°C is 0.07 g/100 g H2O. When the temperature of the solution is raised to 30°C, the solution becomes A) dilute. C) unsaturated. E) supersaturated. B) saturated. D) concentrated. 17. Which solution is the most concentrated? A) 1.0 mole of solute dissolved in 1.0 liter of solution B) 2.0 moles of solute dissolved in 3.0 liters of solution C) 4.0 moles of solute dissolved in 8.0 liters of solution D) 6.0 moles of solute dissolved in 4.0 liters of solution E) 8.0 moles of solute dissolved in 5.0 liters of solution 18. All solutions are A) liquids C) heterogeneous E) saturated B) homogeneous D) pure substances 19. The density of water, H 2O, is greater than that of octane, C8H18, because A) water has a higher boiling point than octane. B) the molecular mass of water is smaller than that of octane. C) there are no Van der Waals forces acting among octane molecules. D) intermolecular hydrogen bonding, present in water, is absent in octane. E) water is a polar molecule while octane is nonpolar. 20. How many phases are in a reaction vessel which holds a saturated solution of common salt in water and excess salt? A) B) C) D) E) 1 2 3 4 It cannot be determined. 22. What mass of HNO3 (MM = 63) is present in 50. mL of a 1.5 M solution? A) 2.1 g C) 7.5 g E) 18.9 g B) 4.7 g D) 15.0 g 23. A sample of 40. mL of 0.20 M NaI contains how many moles of iodide ion? A) 0.0080 moles C) 0.20 moles E) 8.00 moles B) 0.040 moles D) 0.40 moles 24. An aqueous solution of concentrated HBr contains 48% HBr (MM = 80.9) by mass. The density of the solution is 1.50 g•mL –1. What is the molarity of the HBr solution? A) 5.9 M C) 11.4 M E) 40.0 M B) 8.9 M D) 18.5 M 25. What is the in an aqueous solution prepared by adding of to sufficient water to make of solution? A) C) E) B) D) 26. Which aqueous solution has the same ion molarity as 1.0 M MgCl2? A) 1.0 M FeSO4 C) 1.5 M KI E) 1.0 M NaOH B) 2.0 M KCl D) 0.50 M NH 4Cl 27. How many grams of calcium are contained in 1000 grams of a 3 molal solution of calcium bromide 21. The graph is a plot of data obtained during the distillation of a solution. How many components are in the initial solution? A) 40 g C) 120 g E) 600 g B) 80 g D) 300 g 28. A solution contains 58 grams of NaCl in 5.6 moles of water, what is the solution's molality? A) 1 B) 2 C) 3 D) 4 E) 5 A) 3.32 m C) 9.92 m E) 15.18 m B) 5.80 m D) 12.62 m 29. What would be the molality of a solution containing 119 g of KBr dissolved in 500 g of water? A) .5 m C) 1.5 m E) 2.5 m B) 1 m D) 2 m 30. If a 750g solution of sodium bromide is 2 molal, how many grams of NaBr does it contain? A) 53 g C) 103 g E) 173 g B) 69 g D) 155 g 31. A solution contains 174 grams of lithium bromide in 360 grams of water, what is the mole fraction of lithium bromide? A) .05 B) .09 C) .10 D) .48 E) 11 32. If 116 g of sodium chloride are dissolved in 1800 g of water, what is the mole fraction of NaCl? A) 0.0098 B) 0.0143 C) 0.0196 D) 0.0230 E) none of the above 33. A solution contains 3 moles of CuBr 2 in 360 grams of water. What is the mass percent concentration of CuBr2? A) 9.0% C) 28.6% E) 47.4% B) 25.0% D) 40.0% 34. If a solution contains 4 moles of MgCl 2 in 40 moles of water, what is the mass percent concentration of MgCl 2? A) 17.6% C) 27.0% E) 34.6% B) 21.2% D) 31.5% 35. Which sugar solution has the highest boiling temperature? A) B) C) D) E) 0.50 mol sugar / 500. g H 2O 0.50 mol sugar / 2.0 kg H 2O 1.00 mol sugar / 500. g H 2O 4.00 mol sugar / 10.0 kg H 2O 50.0 mol sugar/ 100. kg H 2O 36. Water is boiling in a beaker. What might be done to raise the boiling temperature? A) B) C) D) Dissolve sugar in the water. Use a wire gauze to distribute the heat. Dissolve ethyl alcohol (ethanol) in the water. Increase the heating rate with a more efficient burner. E) Increase the temperature of the flame with a different fuel. 37. What is the boiling point of a solution of 93 grams of the nonelectrolyte ethylene glycol, C2H4(OH)2, (molar mass 62), mixed with 500 grams of water? (The Molal boiling point elevation constant for water is 0.52°C•m -1 ) A) 99.48°C C) 100.78°C E) 101.56°C B) 100.26°C D) 101.04°C 38. Mixtures are made, each of which has 1.0 mol of solute added to 1.0 kg of water. Which same solution has all of these attributes: I) the highest boiling temperature, II) the lowest freezing temperature, III) the best conductor of electricity? A) BaCO 3 C) Ag2CO 3 E) Na2CO 3 B) CaCO 3 D) NaNO3 39. What is the freezing temperature of a 2.0 molal solution of KBr in water? (The Molar freezing point deppresion constant for water is 1.86°C•m –1) A) –0.47°C C) –1.86°C E) –7.44°C B) –0.93°C D) –3.72°C 40. A solution consists of 200. g of a nonelectrolytic solute dissolved in 500. g of water. It freezes at –9.30°C. What is the molecular weight of the solute? (The Molal freezing point depression constant for water is 1.86°C•m –1) A) 40.0 B) 80.0 C) 200. D) 400. E) 500. 41. I. Addition of antifreeze to water lowers the freezing point of the solution 44. I. An aqueous salt solution is a good conductor of electricity BECAUSE II. the addition of antifreeze lowers the vapor pressure of the water. A) B) C) D) I is TRUE, II is FALSE I is FALSE, II is TRUE I and II are BOTH FALSE I and II are BOTH TRUE but II IS NOT a correct explanation of I E) I and II are BOTH TRUE and II IS a correct explanation of I 42. I. Water boils at a higher temperature at low altitudes than at high altitudes BECAUSE II. the solution contains positive and negative ions. A) B) C) D) I is TRUE, II is FALSE I is FALSE, II is TRUE I and II are BOTH FALSE I and II are BOTH TRUE but II IS NOT a correct explanation of I E) I and II are BOTH TRUE and II IS a correct explanation of I 45. I. Addition of a non-volatile solute to a solvent causes the freezing point of the solution to be lowered BECAUSE II. the atmospheric pressure decreases as the altitude increases. A) B) C) D) I is TRUE, II is FALSE I is FALSE, II is TRUE I and II are BOTH FALSE I and II are BOTH TRUE but II IS NOT a correct explanation of I E) I and II are BOTH TRUE and II IS a correct explanation of I 43. I. At standard pressure, water has a higher boiling point than alcohol BECAUSE II. the solute is always molecular. A) B) C) D) I is TRUE, II is FALSE I is FALSE, II is TRUE I and II are BOTH FALSE I and II are BOTH TRUE but II IS NOT a correct explanation of I E) I and II are BOTH TRUE and II IS a correct explanation of I 46. I. Antifreeze dissolved in water elevates the boiling point BECAUSE BECAUSE II. water has stronger intermolecular bonds. II. the antifreeze molecules prevent the water molecules from escaping to the atmosphere. A) B) C) D) A) B) C) D) I is TRUE, II is FALSE I is FALSE, II is TRUE I and II are BOTH FALSE I and II are BOTH TRUE but II IS NOT a correct explanation of I E) I and II are BOTH TRUE and II IS a correct explanation of I I is TRUE, II is FALSE I is FALSE, II is TRUE I and II are BOTH FALSE I and II are BOTH TRUE but II IS NOT a correct explanation of I E) I and II are BOTH TRUE and II IS a correct explanation of I 47. I. Antifreeze dissolved in water elevates the freezing point 49. I. Sugar dissolved in a polar solvent, such as water, will be a good electrical conductor BECAUSE II. the antifreeze molecules prevent the water molecules from crystallizing. A) B) C) D) I is TRUE, II is FALSE I is FALSE, II is TRUE I and II are BOTH FALSE I and II are BOTH TRUE but II IS NOT a correct explanation of I E) I and II are BOTH TRUE and II IS a correct explanation of I 48. I. Ammonia gas will escape from a saturated water solution when heated BECAUSE II. sugar dissolves in water to form ions. A) B) C) D) I is TRUE, II is FALSE I is FALSE, II is TRUE I and II are BOTH FALSE I and II are BOTH TRUE but II IS NOT a correct explanation of I E) I and II are BOTH TRUE and II IS a correct explanation of I 50. I. Sodium chloride in water is considered a non-electrolyte BECAUSE BECAUSE II. the solubility of gases decreases when the temperature increases. A) B) C) D) I is TRUE, II is FALSE I is FALSE, II is TRUE I and II are BOTH FALSE I and II are BOTH TRUE but II IS NOT a correct explanation of I E) I and II are BOTH TRUE and II IS a correct explanation of I II. the solution of an electrolyte conducts an electric current. A) B) C) D) I is TRUE, II is FALSE I is FALSE, II is TRUE I and II are BOTH FALSE I and II are BOTH TRUE but II IS NOT a correct explanation of I E) I and II are BOTH TRUE and II IS a correct explanation of I
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