HYDROGEN PEROXIDE (50% =H2O2.com

SAFETY DATA SHEET
North American Version
HYDROGEN PEROXIDE (50% =< Conc. < 60%)
1. PRODUCT AND COMPANY IDENTIFICATION
1.1. Identification of the substance or preparation
Product name
: HYDROGEN PEROXIDE (50% =< Conc. < 60%)
Product grade(s)
: Interox® 50%Standard EG Hydrogen Peroxide
Interox® Hydrogen Peroxide SVP - HP®, 50%
Interox® 50% UltraPure Hydrogen Peroxide
Interox® Hydrogen Peroxide Chemical Grade 50%
Interox® Hydrogen Peroxide Cosmetic Grade 50%
Interox® Hydrogen Peroxide Food Grade 50%
Interox® Hydrogen Peroxide PFP 50%
Interox® Hydrogen Peroxide Technical Grade 50%
Interox® Hydrogen Peroxide Standard Grade 50%
Interox® Hydrogen Peroxide Storage Grade 50%
Interox® Hydrogen Peroxide Technical Grade 50/C
Interox® Hydrogen Peroxide Technical Grade 50/D
Interox® SG Grade 50% Hydrogen Peroxide
Chemical Name
: Hydrogen peroxide
Synonyms
: Hydroperoxide, Hydrogen dioxide
Molecular formula
: H2O2
Molecular Weight
: 34 g/mol
1.2. Use of the Substance/Preparation
Recommended use
: -
Bleaching agent
Chemical industry
Electronic industry
Metal treatment
Odour agents
Oxidising Agents
Textile industry
Water treatment
Pulp and paper
1.3. Company/Undertaking Identification
Address
: SOLVAY CHEMICALS, INC.
3333 RICHMOND AVENUE
HOUSTON TX
77098-3099
United States
1.4. Emergency and contact telephone numbers
: 1 (800) 424-9300 CHEMTREC ® (USA & Canada)
Emergency telephone
01-800-00-214-00 (MEX. REPUBLIC)
Contact telephone number
(product information):
P 16413 / USA
Issuing date 04/14/2009 / Report version 1.0
Copyright 2009, SOLVAY CHEMICALS, INC.
All Rights Reserved
www.solvaychemicals.us
:
US: +1-800-765-8292 (Product information)
US: +1-713-525-6500 (Product information)
HYDROGEN PEROXIDE (50% =< Conc. < 60%)
SAFETY DATA SHEET
2. HAZARDS IDENTIFICATION
2.1. Emergency Overview:
NFPA
HMIS
:
:
H= 3 F= 0
H= 3 F= 0
conditions
Appearance
:
liquid
Colour
:
colourless
Odour
:
pungent
I= 1 S= OX
R= 1 PPE = Supplied by User; dependent on local
General Information
Main effects
-
Oxidising
Contact with combustible material may cause fire.
Harmful by inhalation and if swallowed.
Causes burns.
2.2. Potential Health Effects:
Inhalation
-
Inhalation of vapours is irritating to the respiratory system, may cause throat pain and cough.
Breathing difficulties
Inhaled corrosive substances can lead to a toxic oedema of the lungs.
Nausea
Vomiting
Repeated or prolonged exposure: Risk of sore throat, nose bleeds, chronic bronchitis.
Eye contact
-
Severe eye irritation
Redness
Lachrymation
Swelling of tissue
Risk of serious damage to eyes.
May cause permanent eye injury.
May cause blindness.
Skin contact
-
Severe skin irritation
Redness
Swelling of tissue
Causes burns.
Ingestion
-
Paleness and cyanosis of the face.
If ingested, severe burns of the mouth and throat, as well as a danger of perforation of the oesophagus and
the stomach.
Risk of shock.
Excessive fluid in the mouth and nose, with risk of suffocation.
Risk of throat (o)edema and suffocation.
Bloating of stomach, belching.
Nausea
Bloody vomiting
Cough
Breathing difficulties
P 16413 / USA
Issuing date 04/14/2009 / Report version 1.0
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All Rights Reserved
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2/13
HYDROGEN PEROXIDE (50% =< Conc. < 60%)
SAFETY DATA SHEET
-
Risk of chemical pneumonitis and pulmonary (o)edema.
Other toxicity effects
-
See section 11: Toxicological Information
2.3. Environmental Effects:
See section 12: Ecological Information
3. COMPOSITION/INFORMATION ON INGREDIENTS
Hydrogen peroxide
CAS-No.
Concentration
:
:
7722-84-1
>= 50.0 - < 60.0 %
4. FIRST AID MEASURES
4.1. Inhalation
In case of accident by inhalation: remove casualty to fresh air and keep at rest.
Oxygen or artificial respiration if needed.
Keep warm and in a quiet place.
Victim to lie down in the recovery position, cover and keep him warm.
Call a physician immediately.
4.2. Eye contact
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
In the case of difficulty of opening the lids, administer an analgesic eye wash (oxybuprocaine).
Consult with an ophthalmologist immediately in all cases.
Take victim immediately to hospital.
4.3. Skin contact
Take off contaminated clothing and shoes immediately.
Wash off immediately with plenty of water.
Keep warm and in a quiet place.
Wash contaminated clothing before re-use.
Call a physician immediately.
4.4. Ingestion
Call a physician immediately.
Take victim immediately to hospital.
If victim is conscious:
-
If swallowed, rinse mouth with water (only if the person is conscious).
Do NOT induce vomiting.
If victim is unconscious but breathing:
-
Artificial respiration and/or oxygen may be necessary.
5. FIRE-FIGHTING MEASURES
5.1. Suitable extinguishing media
Water
Water spray
5.2. Extinguishing media which shall not be used for safety reasons
None.
5.3. Special exposure hazards in a fire
P 16413 / USA
Issuing date 04/14/2009 / Report version 1.0
Copyright 2009, SOLVAY CHEMICALS, INC.
All Rights Reserved
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3/13
HYDROGEN PEROXIDE (50% =< Conc. < 60%)
SAFETY DATA SHEET
-
Oxidising
Oxygen released in thermal decomposition may support combustion
Contact with combustible material may cause fire.
Contact with flammables may cause fire or explosions.
Risk of explosion if heated under confinement.
5.4. Hazardous decomposition products
Oxygen
The release of other hazardous decomposition products is possible.
5.5. Special protective equipment for fire-fighters
Evacuate personnel to safe areas.
In the event of fire, wear self-contained breathing apparatus.
When intervention in close proximity wear acid resistant over suit.
Clean contaminated surface thoroughly.
5.6. Other information
Keep product and empty container away from heat and sources of ignition.
Keep containers and surroundings cool with water spray.
Approach from upwind.
6. ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions
Refer to protective measures listed in sections 7 and 8.
Isolate the area.
Keep away from Incompatible products.
Prevent further leakage or spillage if safe to do so.
In case of contact with combustible material, keep material wet with plenty of water.
6.2. Environmental precautions
In case of accidental release or spill, immediately notify the appropriate authorities if required by Federal,
State/Provincial and local laws and regulations.
Do not dump into any sewers, on the ground, or into any body of water. All disposal methods must be in
compliance with all Federal, State/Provincial and local laws and regulations. Regulations may vary in different
locations.
6.3. Methods for cleaning up
Dam up.
Soak up with inert absorbent material.
Dilute with plenty of water.
Do not add chemical products.
Treat recovered material as described in the section "Disposal considerations".
Never return spills in original containers for re-use.
7. HANDLING AND STORAGE
7.1. Handling
Use only in well-ventilated areas.
Keep away from heat.
Keep away from Incompatible products.
May not get in touch with:
Organic materials
Use only equipment and materials which are compatible with the product.
P 16413 / USA
Issuing date 04/14/2009 / Report version 1.0
Copyright 2009, SOLVAY CHEMICALS, INC.
All Rights Reserved
www.solvaychemicals.us
4/13
HYDROGEN PEROXIDE (50% =< Conc. < 60%)
SAFETY DATA SHEET
-
Before all operations, passivate the piping circuits and vessels according to the procedure recommended by
the producer.
Never return unused material to storage receptacle.
Use only in an area with adequate water supply
Containers and equipment used to handle the product should be used exclusively for that product.
7.2. Storage
Keep in a cool, well-ventilated place.
Keep away from heat.
Keep away from Incompatible products.
Keep away from combustible material.
Store in a receptacle equipped with a vent.
Store in original container.
Keep container closed.
Keep in a bunded area.
Regularly check the condition and temperature of the containers.
Information about special precautions needed for bulk handling is available on request.
7.3. Packaging material
aluminium 99,5 %
stainless steel 304L / 316L
Approved grades of HDPE.
7.4. Other information
Refer to protective measures listed in sections 7 and 8.
Do not confine the product in a circuit, between closed valves, or in a container without a vent.
In industrial installations, apply the rules for the prevention of major accidents (consult an expert).
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Exposure Limit Values
Hydrogen peroxide
US. ACGIH Threshold Limit Values 01 2006
time weighted average = 1 ppm
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) 02 2006
Permissible exposure limit = 1 ppm
Permissible exposure limit = 1.4 mg/m3
US. OSHA Table Z-1-A (29 CFR 1910.1000) 1989
time weighted average = 1 ppm
time weighted average = 1.4 mg/m3
-
ACGIH® and TLV® are registered trademarks of the American Conference of Governmental Industrial Hygienists.
SAEL = Solvay Acceptable Exposure Limit, Time Weighted Average for 8 hour workdays. No Specific TLV STEL (Short Term Exposure Level)
has been set. Excursions in exposure level may exceed 3 times the TLV TWA for no more than a total of 30 minutes during a workday and under
no circumstances should they exceed 5 times the TLV TWA.
8.2. Engineering controls
Ensure adequate ventilation.
Apply technical measures to comply with the occupational exposure limits.
Refer to protective measures listed in sections 7 and 8.
8.3. Personal protective equipment
8.3.1. Respiratory protection
-
Self-contained breathing apparatus in medium confinement/insufficient oxygen/in case of large uncontrolled
emissions/in all circumstances when the mask and cartridge do not give adequate protection.
Use only respiratory protection that conforms to international/ national standards.
P 16413 / USA
Issuing date 04/14/2009 / Report version 1.0
Copyright 2009, SOLVAY CHEMICALS, INC.
All Rights Reserved
www.solvaychemicals.us
5/13
HYDROGEN PEROXIDE (50% =< Conc. < 60%)
SAFETY DATA SHEET
-
Use NIOSH approved respiratory protection.
Wear an approved full-face air supplied respirator for excessive or unknown concentrations. Selected
chemical cartridges for respirators, i.e. OV, OV/AG, GME have been tested successfully under lab conditions
to remove hydrogen peroxide and peracetic acid vapors in concentrations exceeding the applicable exposure
limits. Further information is available in a Solvay Chemicals, Inc. Technical Communication, located at
http://www.solvaychemicals.us/resource.htm in the Peractic Acid section.
8.3.2. Hand protection
-
Protective gloves - impervious chemical resistant:
PVC
Rubber gloves
Take note of the information given by the producer concerning permeability and break through times, and of
special workplace conditions (mechanical strain, duration of contact).
8.3.3. Eye protection
-
Chemical resistant goggles must be worn.
If splashes are likely to occur, wear:
Tightly fitting safety goggles
Face-shield
8.3.4. Skin and body protection
-
Protective suit
If splashes are likely to occur, wear:
Apron
Boots
Suitable material
PVC
Rubber products
8.3.5. Hygiene measures
-
Use only in an area equipped with a safety shower.
Eye wash bottle with pure water
When using do not eat, drink or smoke.
Handle in accordance with good industrial hygiene and safety practice.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1. General Information
Appearance
:
liquid
Colour
:
colourless
Odour
:
pungent
9.2. Important health safety and environmental information
pH
:
1-4
Remarks: Apparent pH
Boiling point/boiling range
:
115 °C ( 239 °F ) (H2O2 50 %)
Flash point
:
Remarks: The product is not flammable.
Flammability
:
Lower explosion limit:
Remarks: The product is not flammable.
Explosive properties
:
Explosion danger:
Remarks: With certain materials (see section 10).
P 16413 / USA
Issuing date 04/14/2009 / Report version 1.0
Copyright 2009, SOLVAY CHEMICALS, INC.
All Rights Reserved
www.solvaychemicals.us
6/13
HYDROGEN PEROXIDE (50% =< Conc. < 60%)
SAFETY DATA SHEET
Remarks: In case of heating:
Oxidizing properties
:
Remarks: yes
Vapour pressure
:
1 mbar (H2O2 50 %)
Temperature: 30 °C ( 86 °F )
12 mbar (H2O2 50 %)
Remarks: Total pressure (H2O2 + H2O)
Temperature: 20 °C ( 68 °F )
72 mbar (H2O2 50 %)
Remarks: Total pressure (H2O2 + H2O)
Temperature: 50 °C ( 122 °F )
:
:
Relative density / Density
:
1.2 (H2O2 50 %)
Solubility
:
:
:
Soluble in:
Water
Polar organic solvents
Partition coefficient:
n-octanol/water
:
log Pow:
-1.1
Viscosity
:
1.17 mPa.s (H2O2 50 %)
Temperature: 20 °C ( 68 °F )
Vapour density
:
1 (H2O2 50 %)
Freezing point:
:
-52 °C ( -62 °F ) (H2O2 50 % )
Auto-flammability
:
Remarks: The product is not flammable.
Surface tension
:
75.6 mN/m (H2O2 50 %)
Temperature: 20 °C ( 68 °F )
Decomposition
temperature
:
9.3. Other data
>= 60 °C ( 140 °F )
Remarks: Self-Accelerating decomposition temperature (SADT)
:
< 60 °C ( 140 °F )
Remarks: Slow decomposition
10. STABILITY AND REACTIVITY
10.1. Stability
Potential for exothermic hazard
Stable under recommended storage conditions.
10.2. Conditions to avoid
Contamination
To avoid thermal decomposition, do not overheat.
Keep at temperature not exceeding: 60 °C ( 140 °F )
Keep at temperature not exceeding: 60 °C ( 140 °F )
10.3. Materials to avoid
Acids, Bases, Metals, Salts of metals, Reducing agents, Organic materials, Flammable materials
10.4. Hazardous decomposition products
Oxygen
P 16413 / USA
Issuing date 04/14/2009 / Report version 1.0
Copyright 2009, SOLVAY CHEMICALS, INC.
All Rights Reserved
www.solvaychemicals.us
7/13
HYDROGEN PEROXIDE (50% =< Conc. < 60%)
SAFETY DATA SHEET
-
The release of other hazardous decomposition products is possible.
11. TOXICOLOGICAL INFORMATION
Toxicological data
Acute oral toxicity
-
LD50, rat, 841 mg/kg (H2O2 60 %)
Acute inhalation toxicity
-
LC50, 4 h, rat, 2.000 mg/m3 (Hydrogen peroxide)
Acute dermal irritation/corrosion
-
LD50, rabbit, > 2.000 mg/kg (H2O2 70 %)
Skin irritation
-
rabbit, corrosive effects, 1 h (H2O2 50 %)
Eye irritation
-
Risk of serious damage to eyes. (H2O2 70 %)
Irritation (other route)
-
Inhalation, mouse, Irritating to respiratory system., RD 50 = 665 mg/m3 (Hydrogen peroxide)
Sensitisation
-
guinea pig, Did not cause sensitization on laboratory animals.
Chronic toxicity
-
Oral, Prolonged exposure, Various species, Target Organs: Gastrointestinal tract, observed effect
Inhalation, Repeated exposure, rat, LOEL (Lowest observable effect level): 14.6 mg/m3, irritant effects
Carcinogenicity
-
Oral, Prolonged exposure, mouse, Target Organs: duodenum, carcinogenic effects
Dermal, Prolonged exposure, mouse, Animal testing did not show any carcinogenic effects.
Genetic toxicity in vitro
-
In vitro tests have shown mutagenic effects.
Genetic toxicity in vivo
-
Animal testing did not show any mutagenic effects.
Remarks
-
corrosive effects
Carcinogenic effect not applicable to human
12. ECOLOGICAL INFORMATION
12.1. Ecotoxicity effects
Acute toxicity
-
Fishes, Pimephales promelas, LC50, 96 h, 16.4 mg/l
Fishes, Pimephales promelas, NOEC, 96 h, 5 mg/l
Crustaceans, EC50, 48 h, 2.4 mg/l
Crustaceans, NOEC, 48 h, 1 mg/l
Chronic toxicity
-
Molluscs, NOEC, 56 Days, 2 mg/l
Algae, Chlorella vulgaris, EC50, growth rate, 72 h, 4.3 mg/l
Algae, Chlorella vulgaris, NOEC, 72 h, 0.1 mg/l
12.2. Mobility
P 16413 / USA
Issuing date 04/14/2009 / Report version 1.0
Copyright 2009, SOLVAY CHEMICALS, INC.
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8/13
HYDROGEN PEROXIDE (50% =< Conc. < 60%)
SAFETY DATA SHEET
-
Air, Volatility, Henry's law constant (H) = 1 Pa.m³/mol
Conditions: 20 °C
Remarks: not significant
Air, condensation on contact with water droplets
Remarks: rain washout
Water
Remarks: The product evaporates slowly.
Soil/sediments
Remarks: non-significant evaporation and adsorption
12.3. Persistence and degradability
Abiotic degradation
-
Air, indirect photo-oxidation, t 1/2 from 16 - 20 h
Conditions: sensitizer: OH radicals
Water, redox reaction, t 1/2 from 25 - 100 h
Conditions: mineral and enzymatic catalysis, fresh water
Water, redox reaction, t 1/2 from 50 - 70 h
Conditions: mineral and enzymatic catalysis, salt water
Soil, redox reaction, t 1/2 from 0.05 - 15 h
Conditions: mineral catalysis
Biodegradation
-
aerobic, t 1/2 < 2 min
Conditions: biological treatment sludge
Remarks: Readily biodegradable.
aerobic, t 1/2 from 0.3 - 5 d
Conditions: fresh water
Remarks: Readily biodegradable.
anaerobic
Remarks: not applicable
Effects on waste water treatment plants, Inhibitor > 30 mg/l
Remarks: inhibitory action
12.4. Bioaccumulative potential
Bioaccumulative potential
Result: Does not bioaccumulate.
12.5. Other adverse effects
no data available
12.6. Remarks
Toxic to aquatic organisms.
Nevertheless, hazard for the environment is limited due to product properties:
. no toxicity of degradation products (H2O and O2).
Inherently biodegradable.
Does not bioaccumulate.
13. DISPOSAL CONSIDERATIONS
13.1. Waste from residues / unused products
In accordance with local and national regulations.
Limited quantity
Dilute with plenty of water.
Large quantities:
Contact manufacturer.
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Copyright 2009, SOLVAY CHEMICALS, INC.
All Rights Reserved
www.solvaychemicals.us
9/13
HYDROGEN PEROXIDE (50% =< Conc. < 60%)
SAFETY DATA SHEET
13.2. Packaging treatment
Empty containers.
Clean container with water.
Dispose of rinse water in accordance with local and national regulations.
Do not rinse the dedicated containers.
The empty and clean containers are to be reused in conformity with regulations.
13.3. RCRA Hazardous Waste
D001 (ignitable waste)
D002 (corrosive waste)
14. TRANSPORT INFORMATION
UN-Number
2014
IATA-DGR
Class
5.1
Sub-risks
Corrosive
Packing group
II
ICAO-Labels
5.1 + 8
Proper shipping name: HYDROGEN PEROXIDE, AQUEOUS SOLUTION
IMDG
Class
5.1
Sub-risks
Corrosive
Packing group
II
ICAO-Labels
OXIDIZING AGENT + CORROSIVE
HI/UN No.
2014
Proper shipping name: HYDROGEN PEROXIDE, AQUEOUS SOLUTION
U.S. Dept of Transportation
Class (Subsidiary)
5.1 (8)
Packing group
II
Label (Subsidiary)
Oxidising agent (Corrosive)
Marine pollutant:
no
Emergency info:
ERG: 143
Proper shipping name: HYDROGEN PEROXIDE, AQUEOUS SOLUTION
Canada (TDG)
Class (Subsidiary)
5.1 (8)
Packing group
II
Label (Subsidiary)
Oxidizer (Corrosive)
Marine pollutant:
no
Emergency info:
ERG: 143
Proper shipping name: HYDROGEN PEROXIDE, AQUEOUS SOLUTION
-
IATA: forbidden over 40 %
P 16413 / USA
Issuing date 04/14/2009 / Report version 1.0
Copyright 2009, SOLVAY CHEMICALS, INC.
All Rights Reserved
www.solvaychemicals.us
10/13
HYDROGEN PEROXIDE (50% =< Conc. < 60%)
SAFETY DATA SHEET
15. REGULATORY INFORMATION
15.1.
Inventory Information
Toxic Substance Control Act list
(TSCA)
Australian Inventory of Chemical
Substances (AICS)
Canadian Domestic Substances
List (DSL)
Korean Existing Chemicals List
(ECL)
EU list of existing chemical
substances (EINECS)
Japanese Existing and New
Chemical Substances (MITI List)
(ENCS)
Inventory of Existing Chemical
Substances (China) (IECS)
Philippine Inventory of Chemicals
and Chemical Substances
(PICCS)
New Zealand Inventory (in
preparation) (NZ)
Schweizer Giftliste-1 (GL-1)
15.2.
: -
In compliance with inventory.
: -
In compliance with inventory.
: -
In compliance with inventory.
: -
In compliance with inventory.
: -
In compliance with inventory.
: -
One or more components not listed on inventory.
: -
One or more components not listed on inventory.
: -
One or more components not listed on inventory.
: -
One or more components not on composite list considered for
transfer.
: -
One or more components not listed on inventory.
Other regulations
US. EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title III Section 302
Extremely Hazardous Substance (40 CFR 355, Appendix A)
yes.
SARA Hazard Designation (SARA 311/312)
Acute Health Hazard: Yes.
Fire Hazard: Yes.
US. EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title III Section 313 Toxic
Chemicals (40 CFR 372.65) - Supplier Notification Required
not regulated.
US. New Jersey Worker and Community Right-to-Know Act (New Jersey Statute Annotated Section 34:5A-5)
yes.
US. Pennsylvania Worker and Community Right-to-Know Law (34 Pa. Code Chap. 301-323)
yes.
US. California Safe Drinking Water & Toxic Enforcement Act (Proposition 65)
WARNING! This product contains a chemical known in the State of California to cause cancer..
15.3.
Classification and labelling
Canada. Canadian Environmental Protection Act (CEPA). WHMIS Ingredient Disclosure List (Can. Gaz., Part
II, Vol. 122, No. 2)
C Oxidizing Material
E Corrosive Material
P 16413 / USA
Issuing date 04/14/2009 / Report version 1.0
Copyright 2009, SOLVAY CHEMICALS, INC.
All Rights Reserved
www.solvaychemicals.us
11/13
HYDROGEN PEROXIDE (50% =< Conc. < 60%)
SAFETY DATA SHEET
-
F
Dangerously Reactive Material
Contains a controlled product
Remarks: This product has been classified in accordance with the hazard criteria of the Controlled Products
Regulations and the MSDS contains all the information required by the Controlled Products Regulations.
EC Label
The product is classified and labelled in accordance with Directive 1999/45/EC.
Symbol(s)
O
C
Oxidising
Corrosive
R-phrase(s)
R8
R20/22
R34
Contact with combustible material may cause fire.
Also harmful by inhalation and if swallowed.
Causes burns.
S-phrase(s)
S 1/2
S17
S26
Keep locked up and out of the reach of children.
Keep away from combustible material.
In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
After contact with skin, wash immediately with plenty of water.
Wear suitable protective clothing, gloves and eye/face protection.
In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
S28
S36/37/39
S45
16. OTHER INFORMATION
Ratings :
NFPA (National Fire Protection Association)
Health = 3 Flammability = 0 Instability = 1
Special =OX
HMIS (Hazardous Material Information System)
Health = 3 Fire = 0 Reactivity = 1 PPE : Supplied by User; dependent on local conditions
Further information
General revision
Distribute new edition to clients
Wear an approved full-face air supplied respirator for excessive or unknown concentrations. Selected
chemical cartridges for respirators, i.e. OV, OV/AG, GME have been tested successfully under lab conditions
to remove hydrogen peroxide and peracetic acid vapors in concentrations exceeding the applicable exposure
limits. Further information is available in a Solvay Chemicals, Inc. Technical Communication, located at
http://www.solvaychemicals.us/resource.htm in the Peractic Acid section.
The National Transportation Safety Board (NTSB) and Federal Aviation Administration (FAA) have requested
the following information be provided: Combustible materials exposed to hydrogen peroxide should be
immediately submerged in or rinsed with large amounts of water to ensure that all hydrogen peroxide is
removed. Residual hydrogen peroxide that is allowed to dry (upon evaporation hydrogen peroxide can
concentrate) on organic materials such as paper, fabrics, cotton, leather, wood or other combustibles can
cause the material to ignite and result in a fire.
P 16413 / USA
Issuing date 04/14/2009 / Report version 1.0
Copyright 2009, SOLVAY CHEMICALS, INC.
All Rights Reserved
www.solvaychemicals.us
12/13
HYDROGEN PEROXIDE (50% =< Conc. < 60%)
SAFETY DATA SHEET
-
Occupational Safety and Health Administration (OSHA) requirements for process safety management must
be followed anytime at least 7500 lbs. of Hydrogen Peroxide at concentrations of at least 52 % are used or
stored. Refer to 29 CFR 1910.119 for specific details.
Material Safety Data Sheets contain country specific regulatory information; therefore, the MSDS's provided are for use
only by customers of the company mentioned in section 1 in North America. If you are located in a country other than
Canada, Mexico or the United States, please contact the Solvay Group company in your country for MSDS information
applicable to your location. The previous information is based upon our current knowledge and experience of our
product and is not exhaustive. It applies to the product as defined by the specifications. In case of combinations or
mixtures, one must confirm that no new hazards are likely to exist. In any case, the user is not exempt from observing
all legal, administrative and regulatory procedures relating to the product, personal hygiene, and integrity of the work
environment. (Unless noted to the contrary, the technical information applies only to pure product). To our actual
knowledge, the information contained herein is accurate as of the date of this document. However, neither the company
mentioned in section 1 nor any of its affiliates makes any warranty, express or implied, including merchantability or
fitness for use, or accepts any liability in connection with this information or its use. This information is for use by
technically skilled persons at their own discretion and risk and does not relate to the use of this product in combination
with any other substance or any other process. This is not a license under any patent or other proprietary right. The
user alone must finally determine suitability of any information or material for any contemplated use in compliance with
applicable law, the manner of use and whether any patents are infringed. This information gives typical properties only
and is not to be used for specification purposes. The company mentioned in section 1 reserves the right to make
additions, deletions or modifications to the information at any time without prior notification. Trademarks and/or other
products of the company mentioned in section 1 referenced herein are either trademarks or registered trademarks of
the company mentioned in section 1 or its affiliates, unless otherwise indicated.
Copyright 2009, Company mentioned in Section 1. All Rights Reserved.
P 16413 / USA
Issuing date 04/14/2009 / Report version 1.0
Copyright 2009, SOLVAY CHEMICALS, INC.
All Rights Reserved
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