TRIED AND TRUE Using Diet Coke and Mentos to teach scientific inquiry by Tracey Arnold Murray T he combination of Diet Coke and Mentos is a fun and messy example of the change in states of matter. Adding mint Mentos candy to a twoliter bottle of Diet Coke produces a fountain of soda foam that can reach 3 m high. A demonstration of this can get a “Wow” out of most audiences, usually followed by a “Do it again!”—but can it be used to teach anything? The answer is a definite “Yes,” and what follows is a guided inquiry activity that allows middle school students to do this experiment inside (with a minimum of mess). Students measure the heights of the soda fountains produced by different combinations of soda and candy to determine what factors are important in producing the fountains. This activity, in its simplest form, will provide middle school students with a safe and fun example of what happens when matter changes states, and a better understanding of scientific inquiry, including the development of a hypothesis, the development of experimental methods, and the interpretation of data. This activity can be split into two phases, demonstration and experimental design (about one hour) and experiment and analysis (about one hour). Figure 1 shows a minimum list of materials needed to do this activity. To allow students to explore Diet Coke and Mentos inside, one piece of candy is added to a 20-ounce bottle of soda. Adding only one piece of candy to the soda results in a measurable fountain, but not one that will spray soda all over the room. This should be done inside a tub that can catch the soda as it comes out of the bottle. For the reaction to work, an unopened, unshaken bottle of soda is required for each trial. The soda cannot be moved into different containers or split in any way; anything that will release carbonation from the soda will ruin the reaction. If there is a sink available in the classroom, students can empty their tubs frequently, which will aid in cleanup. If students follow 58 SCIENCE SCOPE Photography courtesy of Michael Murphy Preparation and hints TRIED AND TRUE the directions and add only one piece of candy to each soda bottle, there should be little spray on the table surface to wipe up at the end of the lesson. Spills are possible, so keep an eye on students and remind them to keep bottles capped unless they are about to be used. Used candy should go in the regular trash and any leftover soda should be poured down a sink and the bottles recycled. As in all experiments, students should not eat or drink any of the materials. Expected results (using minimum materials) FIGURE 1 Minimum materials needed to do this activity Materials Details Two-liter bottles of Diet Coke For the demonstration, two bottles minimum (more is recommended) Rolls or bags of mint Mentos candy The two-liter demos take 7 to 10 candies, the student experiments will take 1 candy each Device to get 7 to 10 mint Mentos into two liters of Diet Coke A paper tube the size of the Mentos works; alternatively, purchase a commercial product 20-ounce bottles of Diet Coke, Coke, and Sprite See the experimental design to estimate how many you will need One roll or bag of fruit-flavored Mentos candy One candy per experiment One bag of any mint-flavored Life Savers One candy per experiment One bag of fruit-flavored Life Savers One candy per experiment Tubs to catch the soda fountains One per student group; must be able to hold at least 20 ounces of liquid At a minimum, you will Meter sticks need Coke, Diet Coke, and Sprite to demonstrate Napkins or paper towels the importance of caffeine (Coke versus Sprite) and Chemical splash goggles artificial sugar (Diet Coke versus Coke). Diet Coke should make the tallest fountain, followed by Coke, then Sprite. Mint Mentos and mint Life Savers appear to make equally tall fountains. Fruit-flavored Life Savers do not produce a measurable fountain. I have gotten different results with fruit-flavored Mentos. When I first did this activity, fruit-flavored Mentos were coated and did not produce a fountain. More recently, the fruit-flavored Mentos have worked almost as well as the mint-flavored ones. The reason for this is the roughness of the candy; the now uncoated fruit-flavored Mentos are as rough as the mint. What happens when the candy is added to the soda is a physical reaction—the carbon dioxide dissolved in the soda all becomes a gas at once due to the presence of nucleation sites on certain types of candy. A nucleation site is a place where a bubble of carbon dioxide gas can form. When you have a lot of nucleation sites enter the soda, in the form of candy, this causes the rapid expansion of the gas, which is Must be able to get wet without permanent damage Lots of extras on hand One pair for every student and the teacher forced out of the top of the soda bottle (and carries some liquid with it). Rough surfaces provide the most nucleation sites for the formation of carbon dioxide bubbles and are necessary to make a fountain. You should check the Mentos you purchase to find out what type of reaction to expect. Demonstration Students need to obser ve this reaction and get excited about exploring it before they begin forming potential hypotheses. They may have done this experiment themselves or watched it on TV or online. Ask students if they have obser ved this phenomenon before and if they have any idea what causes the fountain. Students who are familiar with the fountains may also have experimented with different sodas or candies prior to class. Record any results the class already has to compare to the J a n u a r y 2011 59 TRIED AND TRUE results the class will collect during their experiments. Because not ever y student FIGURE 2 Sample materials lists will have seen this before, it is still best (and fun) to do a large-scale demonstraCandy labs Soda labs tion for students. To do the large-scale • 20-oz bottles of Diet Coke • Mint Mentos demonstration, take students outside and • Mint Mentos • 20-oz bottles of Diet Coke place 7 to 10 mint Mentos into a two-liter • Fruit-flavored Mentos • 20-oz bottles of Coke bottle of Diet Coke. If you are unable to • Wint-O-Green Lifesavers • 20-oz bottles of Sprite do the large-scale demonstration outside, • Fruit-flavored Lifesavers there are multiple videos of this available online. If you type “Diet Coke and Mentos” into any search engine, you will find many [from what students know and from what they saw in examples. The videos should still provide students the demonstration, describe why this will happen]. with some obser vations and motivation to perform The labs should write all their potential hypotheses the rest of the lesson. down as finished statements, even though they After they have seen the demonstration, pose the will only test one of the hypotheses during the exfollowing questions to students as a class: perimental part. Once all the labs are finished with their hypotheses, pose the following questions to • What factors are important in this reaction? students as a class: • Which important factors are from the candy? • Which important factors are from soda? • What hypotheses did the Candy Labs develop? • Are there any other hypotheses that need to You may need to prompt students on what types of be added? “factors” may affect the reaction. Examples include the • Are the hypotheses testable? sugar found in soda, the mint flavoring in the candy, • Are they using all the available materials? the sugar in the candy, the caffeine in the soda, the carbonation of the soda, the number of candies used, This should encourage the labs to test different the size of the soda bottle, the coloring in the soda, hypotheses and will ensure that all of the materials are the temperature outside, etc. During this discussion, used to get the most data about the factors. Although record potential factors; these are the beginnings of you do want students to test different aspects of the the hypotheses students will develop in the next part reaction, it is best if at least two labs test the same hyof the activity. pothesis. Repeat this process with the Soda Labs. Break the class into “labs” of three to five students. Provide students with a list of available materials Experimental design (Figure 2). One set of labs (roughly half the class) will be the Candy Labs and will develop and test hyIn order for this activity to teach students how scipotheses related to the important factors in the candy. ence is done, they need to think and put their ideas The other set of labs will be the Soda Labs and will on paper before they start experimenting. Students develop and test hypotheses related to the important also need to work as a class to use their resources factors in the soda. wisely. Students will have some constraints to keep Allow the lab groups 10–15 minutes to develop in mind as they develop their experimental meththeir hypotheses. At this point, each lab should ods. Besides the constraint that is due to the type of tr y to come up with a few hypotheses they would lab they are in (Candy or Soda), students will also like to test. Remind students that a hypothesis is have a common method to minimize the mess in a testable statement that says what will be tested, the classroom (one candy in a smaller soda bottle). predicts what the results will be, and explains why. After explaining these constraints and goals to stuThe hypothesis should be written in the “If…then… dents, ask each lab to choose a hypothesis to test because…” format. For example, “If [the factor to and develop an experimental method that they will test] is used then [predict what will happen] because use to test it. 60 SCIENCE SCOPE TRIED AND TRUE FIGURE 3 Student activity sheets Goals for this activity: • Experience the process that scientists use to develop and test hypotheses • Observe an example of a physical change in state of matter, CO2 dissolved in a liquid converting to a gas • Remember that science is fun and happens everywhere. Our methods: In order to test our hypothesis we will… Day 1 (introduction and planning) Your teacher will get the materials you need to do these experiments at a later time. Please generate a list of what you will need to do your experiments. Include how many of each item you will need. Experimental design: Are you a candy lab or a soda lab? _______________ Work with the other members of your lab to develop a few hypotheses you would like to test (you will have to pick one in the end, but you want a couple to choose from). You will have 10 minutes to develop at least two hypotheses. Record your hypotheses here: 1. 2. 3. Remember: A hypothesis is an educated guess about why a phenomenon happens—it is not a prediction of what will happen. For example, I have observed that being around cats makes me sneeze. A hypothesis I can develop from this observation is that “cat hair causes my allergic reaction.” After your class discussion; put a star next to the hypothesis you will test. Step 1: Step 2: Step 3: Step 4: Day 2 (experiment and analysis) • Finalize your procedures and gather the materials you asked for to do your experiments. • Follow your procedures and do your experiments. Remember to wear your safety goggles, and do not eat or drink anything. • Record your results (and any changes to your methods). • Organize the data you collected into a table or chart on the paper provided by your teacher. • Was your hypothesis confirmed? • What data do you have to support this? On the back of this page, record questions you still have about what causes the fountains. How would you go about answering those questions? Class methods: These will be discussed as a class. Record the class answers here. • • • • • How we will determine the height of the soda fountain: How many times we will repeat each experiment: What we will do as a control experiment: Anything else: Develop a set of experiments to test your hypothesis with your group. Write a step-by-step experimental method below. J a n u a r y 2011 61 TRIED AND TRUE FIGURE 4 Extensions Topic Details Different liquids The experiment can be easily expanded to include other types of carbonated liquids that are not usually considered soda (tonic water, soda water, etc.) or even other types of noncarbonated liquids. You can also compare different brands of sodas or other similar types of soda (i.e., Coke vs. Pepsi, Sprite vs. Sierra Mist). Different solids Different types of candy and noncandy substances can be explored. Items with rough surfaces will work and items with smooth surfaces will not. MythBusters used rock salt instead of candy in their record-breaking soda fountain. Students can experiment with many other substances with rough surfaces to see which would result in the tallest fountain. Surface area This might work best after exploring different solids. Compare surface areas of mints by cutting them in half or in fourths. Temperature The temperature of the soda bottles can be changed before adding the candy. A note of caution: Do not heat the soda bottles. They will either explode or melt. Change the temperature by making the soda colder. Colder soda will not work as well as warm soda because warm soda releases the carbonation more easily. Shaking Shaking the bottles before opening and adding the candy will also change the reaction. We all know what happens when you shake soda and then open the container—be careful! Because the carbonation is released before the candy is added, the fountain will be smaller. Open bottles Leaving the bottles open for different lengths of time can affect the size of the fountain. Again, the more carbonation that is released before adding the candy, the smaller the fountain. Chain reactions Have more advanced or inventive students try to replicate some of the scenes found on EepyBird (www.eepybird. com) or make their own series of chain-reaction fountains where one causes the release of another. More science You can ask students to use the internet to find out more about the science behind this reaction. There are many sites to explore. MythBusters also tried to figure out what the important factors are. Students can view this segment and compare their methods and results to those of the MythBusters. 62 SCIENCE SCOPE Discuss the methods with students. Pose the following questions to the class: • How are you going to measure the height of the soda fountain or the extent of reaction? • How many times should we repeat each experiment? • What will function as a control experiment? The question of how to measure the height of the fountain is possibly the most important of these questions. This is the trickiest part of the experimental design and demonstrates the creativity needed to be a good scientist. If students choose to directly measure the height of the fountain, there will need to be some sort of scale behind the fountain. A meter stick held behind the soda bottle works well. If multiple video cameras are available, your class could videotape their fountains for later measurement. If video cameras are not available, students will have to watch the fountain and estimate the height. If this is the case in your class, you need to emphasize the importance of multiple students watching the same fountain and deciding on a height for each trial. Although this is less accurate, it works fine. There should be enough difference in the heights of the soda fountains to overcome the errors students will make in estimating. A second method for measuring the extent of the reaction is to measure the change in amount of soda in the bottle before and after the reaction. This can be done by volume or mass difference. Volume is easier, as students can line up the bottles and compare directly, but it is less TRIED AND TRUE precise. Measuring mass is more precise, because it can be accurately measured before and after the reaction, but it requires balances. After all of the experimental methods are worked out, students should write a step-by-step experimental method in their science journals or on the Student Activity Sheet (Figure 3). When the labs have their methods written, ask students to gather the materials they will need. This allows you to know if there will be enough for every group. If students will be doing the experiments on a later day, ask them to prepare a materials list for you and then provide them with the materials on the day of the experiment. Experiment By this time, students will be very anxious to begin experimenting. Before they begin, remind students of the importance of wearing their chemical splash goggles at all times during the experiment. Also remind them never to eat or drink anything they are using in experiments, even when those things are normally consumable. Provide each group with materials, a tub, paper towels, and chemical splash goggles, and let them begin. In addition to doing their planned experiments, ask all groups to examine the ingredient lists on their materials to determine differences among the candies or sodas they are using. Students will need to look at these to make sense of their results. Wrapping up (data analysis) Once students are finished with their experiments, they should dispose of any soda or candy used in the experiments; soda may go down the sink and candy can go in the trash. They should also use the paper towels to clean up any soda that has sprayed onto their tables. After cleanup is complete, give the groups 10–15 minutes to make a chart of their data and decide whether their hypotheses were confirmed. Students should do this as a group but record the chart of their data and their outcome individually in a science journal or on the Activity Worksheet. Have each lab share their data with the class and then lead a discussion on which factors are important in the reaction. Students should notice a difference in the heights of the fountains using the different types of soda and should be able to recognize that some sodas have caffeine and some do not. Caffeine will make the soda fountain taller. The other factor that can be easily recognized is the different types of sugar (diet versus regular). Ask students to look on the ingedient list for “high fructose corn syrup” and “aspartame” if they do not recognize the difference. Aspartame causes a larger soda fountain. The important factor in the candy is the roughness of the surface, which may not be apparent from these experiments. However, if students examine the ingredients, they should find that the candies that produce a reaction are identical in composition to the candies that do not. This should lead to further discussion and questions—which is exactly what should happen in science! Once you have finished the discussion of the experimental results, you can have a discussion of the change in the state of matter that students observed in this experiment. The fountain would not be possible if the carbon dioxide dissolved in the soda (liquid) did not come out of the soda (become a gas) when the candy was dropped in. Because gases take up much more space than liquids, a fountain is seen shooting out from the bottle. You can see the fountain because some of the liquid molecules are carried along with the gas molecules as they expand out of the bottle. Extensions One of the strengths of this activity is the many different ways that this experimental setup can be extended. Some options are listed in Figure 4. Although many of these extensions will work best for older or more advanced students, even younger students could develop new hypotheses or methods based on their results and continue to test these new hypotheses. Conclusion This inquiry-based activity is a fun and engaging way to get students thinking like scientists. Although it does take some class time and will cause a little mess, students will enjoy making these soda fountains and learning about experimental design and states of matter. The combination of Diet Coke and Mentos will get students interested and excited about the activity, which can accurately replicate the process of scientific inquiry for them. n Tracey Arnold Murray ([email protected]) is an assistant professor in the Department of Chemistry at Capital University in Columbus, Ohio. J a n u a r y 2011 63
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